Pristine or Highly Defective? Understanding the Role of Graphene Structure for Stable Lithium Metal Plating
Abstract
Abstract The role of graphene host structure/chemistry in plating–stripping in lithium metal anodes employed for lithium metal batteries is first examined in this study. Structural and chemical defects are bad, since highly defective graphene promotes unstable solid electrolyte interphase (SEI) growth. This consumes the fluoroethylene carbonate (FEC) additive in the carbonate electrolyte and is correlated with rapid decay in Coulombic efficiency (CE) and formation of filament‐like Li dendrites. A unique flow‐aided sonication exfoliation method is employed to synthesize “defect‐free” graphene (df‐G), allowing for a direct performance comparison with conventional reduced graphene oxide (r‐GO). At cycle 1, the r‐GO is better electrochemically wetted by Li than df‐G, indicating that initially it is more lithiophilic. With cycling, the nucleation overpotential with r‐GO becomes higher than with df‐G, indicating less facile plating reactions. The df‐G yields state‐of‐the‐art electrochemical performance, with the post cycled metal surface being relatively smooth and dendrite‐free. Conversely, r‐GO templates have CE rapidly degrade from the onset, with extensive dendrites after cycling. Severe SEI growth and associated FEC depletion with r‐GO are further confirmed by electrochemical impedance analysis and surface science methods. A new design rule is provided for Li metal templates: An ideal host must be noncatalytic toward SEImore »
- Authors:
-
[1];
[4]
- Sichuan Univ., Chengdu (China). Inst. of New-Energy and Low-Carbon Technology
- Sichuan Univ., Chengdu (China). Inst. of New-Energy and Low-Carbon Technology; Sichuan Univ., Chengdu (China)
- Clarkson Univ., Potsdam, NY (United States)
- Sichuan Univ., Chengdu (China). Inst. of New-Energy and Low-Carbon Technology; Clarkson Univ., Potsdam, NY (United States)
- Publication Date:
- Research Org.:
- Clarkson Univ., Potsdam, NY (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES). Materials Sciences & Engineering Division; National Natural Science Foundation of China (NSFC); China Postdoctoral Science Foundation; USDOE
- OSTI Identifier:
- 1612832
- Alternate Identifier(s):
- OSTI ID: 1483440
- Grant/Contract Number:
- SC0018074; 51702223; 2017M623028; DE‐SC0018074
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Advanced Energy Materials
- Additional Journal Information:
- Journal Volume: 9; Journal Issue: 3; Journal ID: ISSN 1614-6832
- Publisher:
- Wiley
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; liquid phase exfoliation (LPE); mossy dendrites; sodium metal batteries (SMB); solid electrolyte interfaces (SEI)
Citation Formats
Liu, Wei, Xia, Yuting, Wang, Wenwu, Wang, Yizhe, Jin, Jialun, Chen, Yungui, Paek, Eunsu, and Mitlin, David. Pristine or Highly Defective? Understanding the Role of Graphene Structure for Stable Lithium Metal Plating. United States: N. p., 2018.
Web. doi:10.1002/aenm.201802918.
Liu, Wei, Xia, Yuting, Wang, Wenwu, Wang, Yizhe, Jin, Jialun, Chen, Yungui, Paek, Eunsu, & Mitlin, David. Pristine or Highly Defective? Understanding the Role of Graphene Structure for Stable Lithium Metal Plating. United States. https://doi.org/10.1002/aenm.201802918
Liu, Wei, Xia, Yuting, Wang, Wenwu, Wang, Yizhe, Jin, Jialun, Chen, Yungui, Paek, Eunsu, and Mitlin, David. Tue .
"Pristine or Highly Defective? Understanding the Role of Graphene Structure for Stable Lithium Metal Plating". United States. https://doi.org/10.1002/aenm.201802918. https://www.osti.gov/servlets/purl/1612832.
@article{osti_1612832,
title = {Pristine or Highly Defective? Understanding the Role of Graphene Structure for Stable Lithium Metal Plating},
author = {Liu, Wei and Xia, Yuting and Wang, Wenwu and Wang, Yizhe and Jin, Jialun and Chen, Yungui and Paek, Eunsu and Mitlin, David},
abstractNote = {Abstract The role of graphene host structure/chemistry in plating–stripping in lithium metal anodes employed for lithium metal batteries is first examined in this study. Structural and chemical defects are bad, since highly defective graphene promotes unstable solid electrolyte interphase (SEI) growth. This consumes the fluoroethylene carbonate (FEC) additive in the carbonate electrolyte and is correlated with rapid decay in Coulombic efficiency (CE) and formation of filament‐like Li dendrites. A unique flow‐aided sonication exfoliation method is employed to synthesize “defect‐free” graphene (df‐G), allowing for a direct performance comparison with conventional reduced graphene oxide (r‐GO). At cycle 1, the r‐GO is better electrochemically wetted by Li than df‐G, indicating that initially it is more lithiophilic. With cycling, the nucleation overpotential with r‐GO becomes higher than with df‐G, indicating less facile plating reactions. The df‐G yields state‐of‐the‐art electrochemical performance, with the post cycled metal surface being relatively smooth and dendrite‐free. Conversely, r‐GO templates have CE rapidly degrade from the onset, with extensive dendrites after cycling. Severe SEI growth and associated FEC depletion with r‐GO are further confirmed by electrochemical impedance analysis and surface science methods. A new design rule is provided for Li metal templates: An ideal host must be noncatalytic toward SEI formation.},
doi = {10.1002/aenm.201802918},
journal = {Advanced Energy Materials},
number = 3,
volume = 9,
place = {United States},
year = {Tue Nov 27 00:00:00 EST 2018},
month = {Tue Nov 27 00:00:00 EST 2018}
}
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journal, November 2019
- Tang, Xiao; Zhou, Dong; Li, Peng
- Advanced Materials, Vol. 32, Issue 4
A Review of Composite Lithium Metal Anode for Practical Applications
journal, November 2019
- Shi, Peng; Zhang, Xue‐Qiang; Shen, Xin
- Advanced Materials Technologies, Vol. 5, Issue 1
Nanoscaled Lithium Powders with Protection of Ionic Liquid for Highly Stable Rechargeable Lithium Metal Batteries
journal, October 2019
- Pu, Kaichao; Qu, Xiaolei; Zhang, Xin
- Advanced Science, Vol. 6, Issue 24
Facile Patterning of Laser‐Induced Graphene with Tailored Li Nucleation Kinetics for Stable Lithium‐Metal Batteries
journal, August 2019
- Yi, Jingsi; Chen, Jiahua; Yang, Zheng
- Advanced Energy Materials, Vol. 9, Issue 38
In Situ Generation of Artificial Solid‐Electrolyte Interphases on 3D Conducting Scaffolds for High‐Performance Lithium‐Metal Anodes
journal, January 2020
- Zhai, Pengbo; Wei, Yi; Xiao, Jing
- Advanced Energy Materials, Vol. 10, Issue 8
Synergy of Epoxy Chemical Tethers and Defect‐Free Graphene in Enabling Stable Lithium Cycling of Silicon Nanoparticles
journal, September 2019
- Liu, Wei; Li, Hongju; Jin, Jialun
- Angewandte Chemie International Edition, Vol. 58, Issue 46
A functional SrF 2 coated separator enabling a robust and dendrite-free solid electrolyte interphase on a lithium metal anode
journal, January 2019
- Li, Xing; Liu, Yang; Pan, Yong
- Journal of Materials Chemistry A, Vol. 7, Issue 37