Resonant inelastic X-ray scattering using a miniature dispersive Rowland refocusing spectrometer

Ditter, Alexander S.; Holden, William M.; Cary, Samantha K.; Mocko, Veronika; Latimer, Matthew J.; Nelson, Erik J.; Kozimor, Stosh A.; Seidler, Gerald T.

doi:10.1107/s1600577520001022

Title: Resonant inelastic X-ray scattering using a miniature dispersive Rowland refocusing spectrometer

Abstract

X-ray absorption spectroscopy (XAS) beamlines worldwide are steadily increasing their emphasis on full photon-in/photon-out spectroscopies, such as resonant inelastic X-ray scattering (RIXS), resonant X-ray emission spectroscopy (RXES) and high energy resolution fluorescence detection XAS (HERFD-XAS). In such cases, each beamline must match the choice of emission spectrometer to the scientific mission of its users. Previous work has recently reported a miniature tender X-ray spectrometer using a dispersive Rowland refocusing (DRR) geometry that functions with high energy resolution even with a large X-ray spot size on the sample. This instrument has been used in the laboratory in multiple studies of non-resonant X-ray emission spectroscopy using a conventional X-ray tube, though only for preliminary measurements at a low-intensity microfocus synchrotron beamline. This paper reports an extensive study of the performance of a miniature DRR spectrometer at an unfocused wiggler beamline, where the incident monochromatic flux allows for resonant studies which are impossible in the laboratory. Here, the results support the broader use of the present design and also suggest that the DRR method with an unfocused beam could have important applications for materials with low radiation damage thresholds and that would not survive analysis on focused beamlines.

Authors:

^[1]; Holden, William M. ^[2];

^[3];

^[3]; Latimer, Matthew J. ^[4]; Nelson, Erik J. ^[4];

^[3];

^[2]

Univ. of Washington, Seattle, WA (United States); Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
Univ. of Washington, Seattle, WA (United States)
Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
SLAC National Accelerator Lab., Menlo Park, CA (United States)

Publication Date:: Thu Feb 20 00:00:00 EST 2020

Research Org.:: SLAC National Accelerator Laboratory (SLAC), Menlo Park, CA (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE Office of Science (SC), Biological and Environmental Research (BER); National Inst. of Health

OSTI Identifier:: 1608487

Grant/Contract Number:: 89233218CNA000001; AC02-76SF00515; SC0016251

Resource Type:: Accepted Manuscript

Journal Name:: Journal of Synchrotron Radiation (Online)

Additional Journal Information:: Journal Name: Journal of Synchrotron Radiation (Online); Journal Volume: 27; Journal Issue: 2; Journal ID: ISSN 1600-5775

Publisher:: International Union of Crystallography

Country of Publication:: United States

Language:: English

Subject:: 46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND TECHNOLOGY; RIXS; XES; X-ray spectroscopy; instrumentation

Citation Formats


                    Ditter, Alexander S., Holden, William M., Cary, Samantha K., Mocko, Veronika, Latimer, Matthew J., Nelson, Erik J., Kozimor, Stosh A., and Seidler, Gerald T. Resonant inelastic X-ray scattering using a miniature dispersive Rowland refocusing spectrometer.  United States: N. p., 2020. 
Web.  doi:10.1107/s1600577520001022.

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                    Ditter, Alexander S., Holden, William M., Cary, Samantha K., Mocko, Veronika, Latimer, Matthew J., Nelson, Erik J., Kozimor, Stosh A., & Seidler, Gerald T. Resonant inelastic X-ray scattering using a miniature dispersive Rowland refocusing spectrometer.  United States.  https://doi.org/10.1107/s1600577520001022

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                    Ditter, Alexander S., Holden, William M., Cary, Samantha K., Mocko, Veronika, Latimer, Matthew J., Nelson, Erik J., Kozimor, Stosh A., and Seidler, Gerald T. Thu .  
"Resonant inelastic X-ray scattering using a miniature dispersive Rowland refocusing spectrometer".  United States.  https://doi.org/10.1107/s1600577520001022.  https://www.osti.gov/servlets/purl/1608487.

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@article{osti_1608487,

  title        = {Resonant inelastic X-ray scattering using a miniature dispersive Rowland refocusing spectrometer},

  author       = {Ditter, Alexander S. and Holden, William M. and Cary, Samantha K. and Mocko, Veronika and Latimer, Matthew J. and Nelson, Erik J. and Kozimor, Stosh A. and Seidler, Gerald T.},

  abstractNote = {X-ray absorption spectroscopy (XAS) beamlines worldwide are steadily increasing their emphasis on full photon-in/photon-out spectroscopies, such as resonant inelastic X-ray scattering (RIXS), resonant X-ray emission spectroscopy (RXES) and high energy resolution fluorescence detection XAS (HERFD-XAS). In such cases, each beamline must match the choice of emission spectrometer to the scientific mission of its users. Previous work has recently reported a miniature tender X-ray spectrometer using a dispersive Rowland refocusing (DRR) geometry that functions with high energy resolution even with a large X-ray spot size on the sample. This instrument has been used in the laboratory in multiple studies of non-resonant X-ray emission spectroscopy using a conventional X-ray tube, though only for preliminary measurements at a low-intensity microfocus synchrotron beamline. This paper reports an extensive study of the performance of a miniature DRR spectrometer at an unfocused wiggler beamline, where the incident monochromatic flux allows for resonant studies which are impossible in the laboratory. Here, the results support the broader use of the present design and also suggest that the DRR method with an unfocused beam could have important applications for materials with low radiation damage thresholds and that would not survive analysis on focused beamlines.},

  doi          = {10.1107/s1600577520001022},

  journal      = {Journal of Synchrotron Radiation (Online)},

  number       = 2,

  volume       = 27,

  place        = {United States},

  year         = {Thu Feb 20 00:00:00 EST 2020},

  month        = {Thu Feb 20 00:00:00 EST 2020}

}

Copy to clipboard

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Title: Resonant inelastic X-ray scattering using a miniature dispersive Rowland refocusing spectrometer

Abstract

Citation Formats

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Sulfur-edge X-ray absorption near edge spectra (XANES) of some thiometallates and thiometallato complexes journal, July 1989

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Electronic structure of thiometalates [MS4]n− (M=Mo, W, Re). XANES spectra and SCF-Xα-SW calculations journal, August 1994

Application of a transmission crystal x-ray spectrometer to moderate-intensity laser driven sources journal, April 2012

Resonant inelastic X-ray scattering as a probe of optical scale excitations in strongly electron-correlated systems: quasi-localized view journal, October 2000

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Spectral sharpening of the Pt L edges by high-resolution x-ray emission journal, November 2002

CAT-ACT—A new highly versatile x-ray spectroscopy beamline for catalysis and radionuclide science at the KIT synchrotron light facility ANKA journal, November 2017

Snapshots of laser wakefields journal, October 2006

4-1: Invited Paper: Role of Phosphorus Oxidation in Controlling the Luminescent Properties of Indium Phosphide Quantum Dots journal, May 2018

Photometric study of single-shot energy-dispersive x-ray diffraction at a laser plasma facility journal, January 2014

The role of the 5f valence orbitals of early actinides in chemical bonding journal, July 2017

Reactions of tetrathiotungstate and tetrathiomolybdate with substituted haloalkanes journal, January 2002

Development of X-ray Thomson scattering for implosion target characterization journal, December 2011

Electronic Structure of Sulfur Studied by X-ray Absorption and Emission Spectroscopy journal, August 2009

Elimination of the inner-shell lifetime broadening in x-ray-absorption spectroscopy journal, November 1991

Design and performance of a curved-crystal x-ray emission spectrometer journal, May 2007

Nanosecond x-ray Laue diffraction apparatus suitable for laser shock compression experiments journal, August 2010

A large reservoir of sulfate and sulfonate resides within plasma cells from ascidia ceratodes, revealed by x-ray absorption near-edge structure spectroscopy journal, August 1987

Ligand K-edge X-ray absorption spectroscopy: covalency of ligand–metal bonds journal, January 2005

Core Level Spectroscopy of Solids book, January 2008

X-ray Thomson scattering in high energy density plasmas journal, December 2009

Experimental K and L relative x-ray emission ratess journal, August 1974

Probing Covalency in the UO 3 Polymorphs by U M 4 edge HR- XANES journal, May 2016

Direct tomography with chemical-bond contrast journal, May 2011

A novel technique for single-shot energy-resolved 2D x-ray imaging of plasmas relevant for the inertial confinement fusion journal, October 2012

High-resolution large-acceptance analyzer for x-ray fluorescence and Raman spectroscopy conference, December 1998

Low-Emittance Electron Bunches from a Laser-Plasma Accelerator Measured using Single-Shot X-Ray Spectroscopy
journal, August 2012

ATHENA , ARTEMIS , HEPHAESTUS : data analysis for X-ray absorption spectroscopy using IFEFFIT
journal, June 2005

A high-energy x-ray spectrometer diagnostic for the OMEGA laser
journal, June 2002

A color x-ray camera for 2–6 keV using a mass produced back illuminated complementary metal oxide semiconductor sensor
journal, September 2018

K /K X-ray intensity ratios for elements in the range 16⩽Z⩽92 excited by 5.9, 59.5 and 123.6 keV photons
journal, January 2007

Mechanistic Study of Magnesium–Sulfur Batteries
journal, October 2017

A compact dispersive refocusing Rowland circle X-ray emission spectrometer for laboratory, synchrotron, and XFEL applications
journal, July 2017

Structure of dicaesium tetrachlorodioxouranium(VI)
journal, December 1991

Operando Resonant Inelastic X-ray Scattering: An Appropriate Tool to Characterize Sulfur in Li–S Batteries
journal, October 2016

Using solution- and solid-state S K-edge X-ray absorption spectroscopy with density functional theory to evaluate M–S bonding for MS ₄ ²⁻ (M = Cr, Mo, W) dianions
journal, January 2014

Synthesis, Characterization, and Multielectron Reduction Chemistry of Uranium Supported by Redox-Active α-Diimine Ligands
journal, October 2011

High resolution 1s core hole X-ray spectroscopy in 3d transition metal complexes—electronic and structural information
journal, January 2005

Five-element Johann-type x-ray emission spectrometer with a single-photon-counting pixel detector
journal, June 2011

Talbot–Lau x-ray deflectometry phase-retrieval methods for electron density diagnostics in high-energy density experiments
journal, January 2018

Actinide and lanthanide speciation with high-energy resolution X-ray techniques
journal, April 2013

Polarization Dependent High Energy Resolution X-ray Absorption Study of Dicesium Uranyl Tetrachloride
journal, December 2014

Precision X-ray spectroscopy of intense laser-plasma interactions
journal, June 2011

Design and performance of a versatile curved-crystal spectrometer for high-resolution spectroscopy in the tender x-ray range
journal, March 2012

Sulfur-edge X-ray absorption near edge spectra (XANES) of some thiometallates and thiometallato complexes
journal, July 1989

Probing Surface Defects of InP Quantum Dots Using Phosphorus Kα and Kβ X-ray Emission Spectroscopy
journal, August 2018

Single-shot Z_eff dense plasma diagnostic through simultaneous refraction and attenuation measurements with a Talbot–Lau x-ray moiré deflectometer
journal, January 2015

Imaging x-ray Thomson scattering spectrometer design and demonstration (invited)
journal, October 2012

X-ray fluorescent spectrometer with linear position sensitive detector
journal, July 1984

Electronic structure of thiometalates [MS4]n− (M=Mo, W, Re). XANES spectra and SCF-Xα-SW calculations
journal, August 1994

Application of a transmission crystal x-ray spectrometer to moderate-intensity laser driven sources
journal, April 2012

Resonant inelastic X-ray scattering as a probe of optical scale excitations in strongly electron-correlated systems: quasi-localized view
journal, October 2000

Sulfur-Metal Orbital Hybridization in Sulfur-Bearing Compounds Studied by X-ray Emission Spectroscopy
journal, July 2010

Dehydration of the Uranyl Peroxide Studtite, [UO ₂ (η ² -O ₂ )(H ₂ O) ₂ ]·2H ₂ O, Affords a Drastic Change in the Electronic Structure: A Combined X-ray Spectroscopic and Theoretical Analysis
journal, February 2018

Investigation of Aquo and Chloro Complexes of UO ₂ ²⁺ , NpO ₂ ⁺ , Np ⁴⁺ , and Pu ³⁺ by X-ray Absorption Fine Structure Spectroscopy
journal, October 1997

Sulfur Speciation in Biochars by Very High Resolution Benchtop Kα X-ray Emission Spectroscopy
journal, May 2018

Role of resonant inelastic X-ray scattering in high-resolution core-level spectroscopy of actinide materials
journal, June 2014

Spectral sharpening of the Pt L edges by high-resolution x-ray emission
journal, November 2002

CAT-ACT—A new highly versatile x-ray spectroscopy beamline for catalysis and radionuclide science at the KIT synchrotron light facility ANKA
journal, November 2017

Snapshots of laser wakefields
journal, October 2006

4-1: Invited Paper: Role of Phosphorus Oxidation in Controlling the Luminescent Properties of Indium Phosphide Quantum Dots
journal, May 2018

Photometric study of single-shot energy-dispersive x-ray diffraction at a laser plasma facility
journal, January 2014

The role of the 5f valence orbitals of early actinides in chemical bonding
journal, July 2017

Reactions of tetrathiotungstate and tetrathiomolybdate with substituted haloalkanes
journal, January 2002

Development of X-ray Thomson scattering for implosion target characterization
journal, December 2011

Electronic Structure of Sulfur Studied by X-ray Absorption and Emission Spectroscopy
journal, August 2009

Elimination of the inner-shell lifetime broadening in x-ray-absorption spectroscopy
journal, November 1991

Design and performance of a curved-crystal x-ray emission spectrometer
journal, May 2007

Nanosecond x-ray Laue diffraction apparatus suitable for laser shock compression experiments
journal, August 2010

A large reservoir of sulfate and sulfonate resides within plasma cells from ascidia ceratodes, revealed by x-ray absorption near-edge structure spectroscopy
journal, August 1987

Ligand K-edge X-ray absorption spectroscopy: covalency of ligand–metal bonds
journal, January 2005

Core Level Spectroscopy of Solids
book, January 2008

X-ray Thomson scattering in high energy density plasmas
journal, December 2009

Experimental K and L relative x-ray emission ratess
journal, August 1974

Probing Covalency in the UO ₃ Polymorphs by U M ₄ edge HR- XANES
journal, May 2016

Direct tomography with chemical-bond contrast
journal, May 2011

A novel technique for single-shot energy-resolved 2D x-ray imaging of plasmas relevant for the inertial confinement fusion
journal, October 2012

High-resolution large-acceptance analyzer for x-ray fluorescence and Raman spectroscopy
conference, December 1998