Structure and Magnetism Evolution from FeCo Nanoparticles to Hollow Nanostructure Conversion for Magnetic Applications
Abstract
Hollow nanostructures have witnessed an increasing interest in emerging fields, including energy storage electrodes, nanocatalysis, photonics, and biomedical carriers, etc. The fundamental mechanisms for hollowing conversion chemistry of complex nanoalloys is indispensable to grow such nanostructures with controlled compositions and functionalities. In this contribution, the Kirkendall effect on magnetic Fe-Co bimetallic alloys with the formation of hollow nanostructures for exchange interactions was studied. The rich diffusion kinetics of binary Fe-Co alloys accompanied with its conversion from solid, core-shell to hollow nanostructures were been captured through X-ray spectroscopy and electron microscopy. We further report the cation exchange improved magnetic performance of hollow nanostructures with increasing the crystallinity.
- Authors:
-
[2];
[2];
[2];
[1]
- State Univ. of New York (SUNY), Buffalo, NY (United States)
- Temple Univ., Philadelphia, PA (United States)
- Publication Date:
- Research Org.:
- Energy Frontier Research Centers (EFRC) (United States). Center for Complex Materials from First Principles (CCM); Temple Univ., Philadelphia, PA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1608424
- Grant/Contract Number:
- SC0012575
- Resource Type:
- Accepted Manuscript
- Journal Name:
- ACS Applied Nano Materials
- Additional Journal Information:
- Journal Volume: 1; Journal Issue: 10; Journal ID: ISSN 2574-0970
- Publisher:
- American Chemical Society (ACS)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; Magnetic Nanoparticles; Kirkendal Effect; Hollow Structure; Exchange Coupling; Ion Exchange
Citation Formats
Zhang, Zhuolei, Zhang, Jingmin, Thenuwara, Akila C., Strongin, Daniel R., Sun, Yugang, and Ren, Shenqiang. Structure and Magnetism Evolution from FeCo Nanoparticles to Hollow Nanostructure Conversion for Magnetic Applications. United States: N. p., 2018.
Web. doi:10.1021/acsanm.8b01488.
Zhang, Zhuolei, Zhang, Jingmin, Thenuwara, Akila C., Strongin, Daniel R., Sun, Yugang, & Ren, Shenqiang. Structure and Magnetism Evolution from FeCo Nanoparticles to Hollow Nanostructure Conversion for Magnetic Applications. United States. https://doi.org/10.1021/acsanm.8b01488
Zhang, Zhuolei, Zhang, Jingmin, Thenuwara, Akila C., Strongin, Daniel R., Sun, Yugang, and Ren, Shenqiang. Wed .
"Structure and Magnetism Evolution from FeCo Nanoparticles to Hollow Nanostructure Conversion for Magnetic Applications". United States. https://doi.org/10.1021/acsanm.8b01488. https://www.osti.gov/servlets/purl/1608424.
@article{osti_1608424,
title = {Structure and Magnetism Evolution from FeCo Nanoparticles to Hollow Nanostructure Conversion for Magnetic Applications},
author = {Zhang, Zhuolei and Zhang, Jingmin and Thenuwara, Akila C. and Strongin, Daniel R. and Sun, Yugang and Ren, Shenqiang},
abstractNote = {Hollow nanostructures have witnessed an increasing interest in emerging fields, including energy storage electrodes, nanocatalysis, photonics, and biomedical carriers, etc. The fundamental mechanisms for hollowing conversion chemistry of complex nanoalloys is indispensable to grow such nanostructures with controlled compositions and functionalities. In this contribution, the Kirkendall effect on magnetic Fe-Co bimetallic alloys with the formation of hollow nanostructures for exchange interactions was studied. The rich diffusion kinetics of binary Fe-Co alloys accompanied with its conversion from solid, core-shell to hollow nanostructures were been captured through X-ray spectroscopy and electron microscopy. We further report the cation exchange improved magnetic performance of hollow nanostructures with increasing the crystallinity.},
doi = {10.1021/acsanm.8b01488},
journal = {ACS Applied Nano Materials},
number = 10,
volume = 1,
place = {United States},
year = {Wed Aug 01 00:00:00 EDT 2018},
month = {Wed Aug 01 00:00:00 EDT 2018}
}
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Works referencing / citing this record:
Structure evolution from Prussian-blue nanocubes to hollow nanocage composites via sodium tungstate etching
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