Enhanced Electrochemical Performance of Sodium Manganese Ferrocyanide by Na3 (VOPO4)2 F Coating for Sodium-Ion Batteries

Peng, Fangwei; Yu, Lei; Yuan, Siqi; Liao, Xiao-Zhen; Wen, Jianguo; Tan, Guoqiang; Feng, Fan; Ma, Zi-Feng

doi:10.1021/acsami.9b12041

Title: Enhanced Electrochemical Performance of Sodium Manganese Ferrocyanide by Na₃ (VOPO₄)₂ F Coating for Sodium-Ion Batteries

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Abstract

Sodium manganese ferrocyanide Na_xMn[Fe(CN)₆]_y is an attractive cathode material for sodium-ion batteries. However, NaxMn[Fe(CN)₆]_y prepared by simple coprecipitation of Mn²⁺ and [Fe(CN)₆]^4– usually shows poor cycling performance, which hinders its practical application. In this work, electrochemical performance of a Na_1.6Mn[Fe(CN)₆]_0.9 (PBM) sample prepared by the simple precipitation method was greatly improved by coating with Na₃(VOPO₄)₂F (NVOPF) via a solution precipitation method. The as-prepared PBM@NVOPF with a coating quantity of 2.0% molar ratio showed enhanced rate capability and superior cyclic stability. The discharge capacities of PBM@NVOPF were 101.5 mA h g^–1 (1 C) and 91.4 mA h g^–1 (10 C), with a capacity retention of 84.3% after 500 cycles at 1 C, 20 °C. It also exhibited excellent cyclic stability at elevated temperature with an initial capacity of 109.5 mA h g^–1 and a capacity retention of 78.8% after 200 cycles at 1 C, 55 °C. In comparison, uncoated PBM showed a discharge capacity of 105.7 mA h g–1 (1 C) and 76.7 mA h g^–1 (10 C), with a capacity retention of only 42.0% after 500 cycles at 1 C, 20 °C. The high-temperature performance of bare PBM was very poor, and the capacity retention was only 35.7% after 40more »« less

Authors:

Peng, Fangwei ^[1]; Yu, Lei ^[2]; Yuan, Siqi ^[1];

^[1];

^[3];

^[4]; Feng, Fan ^[1]; Ma, Zi-Feng ^[1]

Shanghai Jiao Tong Univ. (China). Shanghai Electrochemical Energy Devices Research Center, Dept. of Chemistry and Chemical Engineering
Argonne National Lab. (ANL), Argonne, IL (United States). Center for Nanoscale Materials; Nanjing Univ. of Technology (China). Key Lab. for Soft Chemistry and Functional Materials
Argonne National Lab. (ANL), Argonne, IL (United States). Center for Nanoscale Materials
Beijing Inst. of Technology (China). School of Materials Science and Engineering

Publication Date:: Tue Sep 17 00:00:00 EDT 2019

Research Org.:: Argonne National Lab. (ANL), Argonne, IL (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES); National Natural Science Foundation of China (NSFC)

OSTI Identifier:: 1604984

Grant/Contract Number:: AC02-06CH11357

Resource Type:: Accepted Manuscript

Journal Name:: ACS Applied Materials and Interfaces

Additional Journal Information:: Journal Volume: 11; Journal Issue: 41; Journal ID: ISSN 1944-8244

Publisher:: American Chemical Society (ACS)

Country of Publication:: United States

Language:: English

Subject:: 25 ENERGY STORAGE; Na3(VOPO4)2F; cathode material; sodium manganese ferrocyanide; sodium-ion batteries; surface coating

Citation Formats


                    Peng, Fangwei, Yu, Lei, Yuan, Siqi, Liao, Xiao-Zhen, Wen, Jianguo, Tan, Guoqiang, Feng, Fan, and Ma, Zi-Feng. Enhanced Electrochemical Performance of Sodium Manganese Ferrocyanide by Na3 (VOPO4)2 F Coating for Sodium-Ion Batteries.  United States: N. p., 2019. 
Web.  doi:10.1021/acsami.9b12041.

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                    Peng, Fangwei, Yu, Lei, Yuan, Siqi, Liao, Xiao-Zhen, Wen, Jianguo, Tan, Guoqiang, Feng, Fan, & Ma, Zi-Feng. Enhanced Electrochemical Performance of Sodium Manganese Ferrocyanide by Na3 (VOPO4)2 F Coating for Sodium-Ion Batteries.  United States.  https://doi.org/10.1021/acsami.9b12041

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                    Peng, Fangwei, Yu, Lei, Yuan, Siqi, Liao, Xiao-Zhen, Wen, Jianguo, Tan, Guoqiang, Feng, Fan, and Ma, Zi-Feng. Tue .  
"Enhanced Electrochemical Performance of Sodium Manganese Ferrocyanide by Na3 (VOPO4)2 F Coating for Sodium-Ion Batteries".  United States.  https://doi.org/10.1021/acsami.9b12041.  https://www.osti.gov/servlets/purl/1604984.

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@article{osti_1604984,

  title        = {Enhanced Electrochemical Performance of Sodium Manganese Ferrocyanide by Na3 (VOPO4)2 F Coating for Sodium-Ion Batteries},

  author       = {Peng, Fangwei and Yu, Lei and Yuan, Siqi and Liao, Xiao-Zhen and Wen, Jianguo and Tan, Guoqiang and Feng, Fan and Ma, Zi-Feng},

  abstractNote = {Sodium manganese ferrocyanide NaxMn[Fe(CN)6]y is an attractive cathode material for sodium-ion batteries. However, NaxMn[Fe(CN)6]y prepared by simple coprecipitation of Mn2+ and [Fe(CN)6]4– usually shows poor cycling performance, which hinders its practical application. In this work, electrochemical performance of a Na1.6Mn[Fe(CN)6]0.9 (PBM) sample prepared by the simple precipitation method was greatly improved by coating with Na3(VOPO4)2F (NVOPF) via a solution precipitation method. The as-prepared PBM@NVOPF with a coating quantity of 2.0% molar ratio showed enhanced rate capability and superior cyclic stability. The discharge capacities of PBM@NVOPF were 101.5 mA h g–1 (1 C) and 91.4 mA h g–1 (10 C), with a capacity retention of 84.3% after 500 cycles at 1 C, 20 °C. It also exhibited excellent cyclic stability at elevated temperature with an initial capacity of 109.5 mA h g–1 and a capacity retention of 78.8% after 200 cycles at 1 C, 55 °C. In comparison, uncoated PBM showed a discharge capacity of 105.7 mA h g–1 (1 C) and 76.7 mA h g–1 (10 C), with a capacity retention of only 42.0% after 500 cycles at 1 C, 20 °C. The high-temperature performance of bare PBM was very poor, and the capacity retention was only 35.7% after 40 cycles because of serious Mn/Fe dissolution which caused structural deterioration of PBM. NVOPF coating protected the PBM from suffering corrosion in the electrolyte, thus ensured the framework stability of PBM during long-term cycling and contributed to the excellent electrochemical performance.},

  doi          = {10.1021/acsami.9b12041},

  journal      = {ACS Applied Materials and Interfaces},

  number       = 41,

  volume       = 11,

  place        = {United States},

  year         = {Tue Sep 17 00:00:00 EDT 2019},

  month        = {Tue Sep 17 00:00:00 EDT 2019}

}

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Title: Enhanced Electrochemical Performance of Sodium Manganese Ferrocyanide by Na3 (VOPO4)2 F Coating for Sodium-Ion Batteries

Abstract

Citation Formats

Title: Enhanced Electrochemical Performance of Sodium Manganese Ferrocyanide by Na₃ (VOPO₄)₂ F Coating for Sodium-Ion Batteries