Salt Effects on Li-Ion Exchange Kinetics of Na2Mg2P3O9N: Systematic In Situ Synchrotron Diffraction Studies

Cosby, Monty R.; Mattei, Gerard S.; Wang, Yusu; Li, Zhuo; Bechtold, Nicholas; Chapman, Karena W.; Khalifah, Peter G.

doi:10.1021/acs.jpcc.0c00067

Title: Salt Effects on Li-Ion Exchange Kinetics of Na₂Mg₂P₃O₉N: Systematic In Situ Synchrotron Diffraction Studies

Abstract

The kinetics and thermodynamics of solid-state ion exchange of Li⁺ into Na₂Mg₂P₃O₉N were explored using in situ synchrotron X-ray diffraction methods for a series of Li-containing salts, allowing systematic trends with general applicability to ion exchange reactions to be elucidated. The collection of data for a wide range of reaction conditions was enabled through the use of a novel multi-well sample environment which leverages the ability of the synchrotron beamline to rapidly (~1 second) collect high-quality data suitable for monitoring reaction progress. From this data, it was possible to resolve the influence of salt choice and salt concentration on the ion exchange reaction kinetics. Moreover, by carrying out experiments at different temperatures, initial estimates of activation energies were obtained. It was generally found that the ion exchange reaction kinetics strongly depended on the salt chosen as the ion source rather than being primarily determined by the ion mobility of the ceramic.

Authors:

^[1]; Mattei, Gerard S. ^[1]; Wang, Yusu ^[1]; Li, Zhuo ^[2]; Bechtold, Nicholas ^[3];

^[1];

^[2]

Stony Brook Univ., NY (United States)
Stony Brook Univ., NY (United States); Brookhaven National Lab. (BNL), Upton, NY (United States)
Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS)

Publication Date:: Mon Feb 24 00:00:00 EST 2020

Research Org.:: Energy Frontier Research Centers (EFRC) (United States). A Next Generation Synthesis Center (GENESIS); Stony Brook Univ., NY (United States); Argonne National Lab. (ANL), Argonne, IL (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI Identifier:: 1602770

Grant/Contract Number:: SC0019212; AC02-06CH11357

Resource Type:: Accepted Manuscript

Journal Name:: Journal of Physical Chemistry. C

Additional Journal Information:: Journal Volume: 124; Journal Issue: 12; Journal ID: ISSN 1932-7447

Publisher:: American Chemical Society

Country of Publication:: United States

Language:: English

Subject:: 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats


                    Cosby, Monty R., Mattei, Gerard S., Wang, Yusu, Li, Zhuo, Bechtold, Nicholas, Chapman, Karena W., and Khalifah, Peter G. Salt Effects on Li-Ion Exchange Kinetics of Na2Mg2P3O9N: Systematic In Situ Synchrotron Diffraction Studies.  United States: N. p., 2020. 
Web.  doi:10.1021/acs.jpcc.0c00067.

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                    Cosby, Monty R., Mattei, Gerard S., Wang, Yusu, Li, Zhuo, Bechtold, Nicholas, Chapman, Karena W., & Khalifah, Peter G. Salt Effects on Li-Ion Exchange Kinetics of Na2Mg2P3O9N: Systematic In Situ Synchrotron Diffraction Studies.  United States.  https://doi.org/10.1021/acs.jpcc.0c00067

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                    Cosby, Monty R., Mattei, Gerard S., Wang, Yusu, Li, Zhuo, Bechtold, Nicholas, Chapman, Karena W., and Khalifah, Peter G. Mon .  
"Salt Effects on Li-Ion Exchange Kinetics of Na2Mg2P3O9N: Systematic In Situ Synchrotron Diffraction Studies".  United States.  https://doi.org/10.1021/acs.jpcc.0c00067.  https://www.osti.gov/servlets/purl/1602770.

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@article{osti_1602770,

  title        = {Salt Effects on Li-Ion Exchange Kinetics of Na2Mg2P3O9N: Systematic In Situ Synchrotron Diffraction Studies},

  author       = {Cosby, Monty R. and Mattei, Gerard S. and Wang, Yusu and Li, Zhuo and Bechtold, Nicholas and Chapman, Karena W. and Khalifah, Peter G.},

  abstractNote = {The kinetics and thermodynamics of solid-state ion exchange of Li+ into Na2Mg2P3O9N were explored using in situ synchrotron X-ray diffraction methods for a series of Li-containing salts, allowing systematic trends with general applicability to ion exchange reactions to be elucidated. The collection of data for a wide range of reaction conditions was enabled through the use of a novel multi-well sample environment which leverages the ability of the synchrotron beamline to rapidly (~1 second) collect high-quality data suitable for monitoring reaction progress. From this data, it was possible to resolve the influence of salt choice and salt concentration on the ion exchange reaction kinetics. Moreover, by carrying out experiments at different temperatures, initial estimates of activation energies were obtained. It was generally found that the ion exchange reaction kinetics strongly depended on the salt chosen as the ion source rather than being primarily determined by the ion mobility of the ceramic.},

  doi          = {10.1021/acs.jpcc.0c00067},

  journal      = {Journal of Physical Chemistry. C},

  number       = 12,

  volume       = 124,

  place        = {United States},

  year         = {Mon Feb 24 00:00:00 EST 2020},

  month        = {Mon Feb 24 00:00:00 EST 2020}

}

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Works referenced in this record:

Role of ion exchange in solid-state chemistry
journal, January 1988

Clearfield, Abraham
Chemical Reviews, Vol. 88, Issue 1
DOI: 10.1021/cr00083a007

Exceptional Ion-Exchange Selectivity in a Flexible Open Framework Lanthanum(III)tetrakisphosphonate
journal, December 2009

Plabst, Monika; McCusker, Lynne B.; Bein, Thomas
Journal of the American Chemical Society, Vol. 131, Issue 50
DOI: 10.1021/ja904636y

Ion Exchange in Hydroxyapatite with Lanthanides
journal, January 2015

Cawthray, Jacqueline F.; Creagh, A. Louise; Haynes, Charles A.
Inorganic Chemistry, Vol. 54, Issue 4
DOI: 10.1021/ic502425e

In Situ Tracking Kinetic Pathways of Li ⁺ /Na ⁺ Substitution during Ion-Exchange Synthesis of Li _x Na _{1.5– x} VOPO ₄ F _0.5
journal, August 2017

Park, Young-Uk; Bai, Jianming; Wang, Liping
Journal of the American Chemical Society, Vol. 139, Issue 36
DOI: 10.1021/jacs.7b05302

In Situ Synchrotron X-Ray Diffraction Studies of the Phase Transitions in Li[sub x]Mn[sub 2]O[sub 4] Cathode Materials
journal, January 1999

Yang, X. Q.
Electrochemical and Solid-State Letters, Vol. 2, Issue 4
DOI: 10.1149/1.1390768

Ionic conductivities and structure of lithium phosphorus oxynitride glasses
journal, April 1995

Wang, B.; Kwak, B. S.; Sales, B. C.
Journal of Non-Crystalline Solids, Vol. 183, Issue 3
DOI: 10.1016/0022-3093(94)00665-2

In Situ Neutron Diffraction Studies of the Ion Exchange Synthesis Mechanism of Li ₂ Mg ₂ P ₃ O ₉ N: Evidence for a Hidden Phase Transition
journal, June 2017

Liu, Jue; Whitfield, Pamela S.; Saccomanno, Michael R.
Journal of the American Chemical Society, Vol. 139, Issue 27
DOI: 10.1021/jacs.7b02323

Divalent Iron Nitridophosphates: A New Class of Cathode Materials for Li-Ion Batteries
journal, September 2013

Liu, Jue; Yu, Xiqian; Hu, Enyuan
Chemistry of Materials, Vol. 25, Issue 20
DOI: 10.1021/cm402567e

Synthesis of layered LiMnO2 as an electrode for rechargeable lithium batteries
journal, June 1996

Armstrong, A. Robert; Bruce, Peter G.
Nature, Vol. 381, Issue 6582
DOI: 10.1038/381499a0

Ion-exchange reactions of mixed oxides
journal, October 1983

England, W. A.; Goodenough, J. B.; Wiseman, P. J.
Journal of Solid State Chemistry, Vol. 49, Issue 3
DOI: 10.1016/S0022-4596(83)80006-1

The fast azimuthal integration Python library: pyFAI
journal, March 2015

Ashiotis, Giannis; Deschildre, Aurore; Nawaz, Zubair
Journal of Applied Crystallography, Vol. 48, Issue 2
DOI: 10.1107/S1600576715004306

Diffusion-Limited Aggregation, a Kinetic Critical Phenomenon
journal, November 1981

Witten, T. A.; Sander, L. M.
Physical Review Letters, Vol. 47, Issue 19
DOI: 10.1103/PhysRevLett.47.1400

The ionic conductivity of Li-halide crystals
journal, January 1950

Haven, Y.
Recueil des Travaux Chimiques des Pays-Bas, Vol. 69, Issue 12
DOI: 10.1002/recl.19500691203

The contribution of vacancy defects to mass transport in alkali halides-an assessment using theoretical calculations of defect energies
journal, February 1979

Catlow, C. R. A.; Corish, J.; Diller, K. M.
Journal of Physics C: Solid State Physics, Vol. 12, Issue 3
DOI: 10.1088/0022-3719/12/3/013

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Title: Salt Effects on Li-Ion Exchange Kinetics of Na2Mg2P3O9N: Systematic In Situ Synchrotron Diffraction Studies

Abstract

Citation Formats

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In Situ Neutron Diffraction Studies of the Ion Exchange Synthesis Mechanism of Li 2 Mg 2 P 3 O 9 N: Evidence for a Hidden Phase Transition journal, June 2017

Divalent Iron Nitridophosphates: A New Class of Cathode Materials for Li-Ion Batteries journal, September 2013

Synthesis of layered LiMnO2 as an electrode for rechargeable lithium batteries journal, June 1996

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Diffusion-Limited Aggregation, a Kinetic Critical Phenomenon journal, November 1981

The ionic conductivity of Li-halide crystals journal, January 1950

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Title: Salt Effects on Li-Ion Exchange Kinetics of Na₂Mg₂P₃O₉N: Systematic In Situ Synchrotron Diffraction Studies

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Exceptional Ion-Exchange Selectivity in a Flexible Open Framework Lanthanum(III)tetrakisphosphonate
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Ionic conductivities and structure of lithium phosphorus oxynitride glasses
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