New Type of 2D Perovskites with Alternating Cations in the Interlayer Space, (C(NH2)3)(CH3NH3)nPbnI3n+1: Structure, Properties, and Photovoltaic Performance
Abstract
In this study, we present the new homologous series (C(NH2)3)(CH3NH3)nPbnI3n+1 (n = 1, 2, 3) of layered 2D perovskites. Structural characterization by single-crystal X-ray diffraction reveals that these compounds adopt an unprecedented structure type, which is stabilized by the alternating ordering of the guanidinium and methylammonium cations in the interlayer space (ACI). Compared to the more common Ruddlesden–Popper (RP) 2D perovskites, the ACI perovskites have a different stacking motif and adopt a higher crystal symmetry. The higher symmetry of the ACI perovskites is expressed in their physical properties, which show a characteristic decrease of the bandgap with respect to their RP perovskite counterparts with the same perovskite layer thickness (n). The compounds show a monotonic decrease in the optical gap as n increases: Eg = 2.27 eV for n = 1 to Eg = 1.99 eV for n = 2 and Eg = 1.73 eV for n = 3, which show slightly narrower gaps compared to the corresponding RP perovskites. First-principles theoretical electronic structure calculations confirm the experimental optical gap trends suggesting that the ACI perovskites are direct bandgap semiconductors with wide valence and conduction bandwidths. To assess the potential of the ACI perovskites toward solar cell applications, we studiedmore »
- Authors:
-
[1];
[2];
[2];
[2];
[4];
[3];
[2];
[1];
[1]
- Northwestern Univ., Evanston, IL (United States)
- Université de Rennes (France)
- Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
- Univ. of California, Santa Barbara, CA (United States)
- Publication Date:
- Research Org.:
- Energy Frontier Research Centers (EFRC) (United States). Center for Light Energy Activated Redox Processes (LEAP); Univ. of California, Santa Barbara, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Materials Sciences & Engineering Division; National Science Foundation (NSF)
- OSTI Identifier:
- 1599738
- Grant/Contract Number:
- SC0012541; SC0001059; AC52-06NA25396; AC02-06CH11357; ECCS-1542205; DMR-1121262
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of the American Chemical Society
- Additional Journal Information:
- Journal Volume: 139; Journal Issue: 45; Journal ID: ISSN 0002-7863
- Publisher:
- American Chemical Society (ACS)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 14 SOLAR ENERGY; 36 MATERIALS SCIENCE; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Soe, Chan Myae Myae, Stoumpos, Constantinos C., Kepenekian, Mikaël, Traoré, Boubacar, Tsai, Hsinhan, Nie, Wanyi, Wang, Binghao, Katan, Claudine, Seshadri, Ram, Mohite, Aditya D., Even, Jacky, Marks, Tobin J., and Kanatzidis, Mercouri G. New Type of 2D Perovskites with Alternating Cations in the Interlayer Space, (C(NH2)3)(CH3NH3)nPbnI3n+1: Structure, Properties, and Photovoltaic Performance. United States: N. p., 2017.
Web. doi:10.1021/jacs.7b09096.
Soe, Chan Myae Myae, Stoumpos, Constantinos C., Kepenekian, Mikaël, Traoré, Boubacar, Tsai, Hsinhan, Nie, Wanyi, Wang, Binghao, Katan, Claudine, Seshadri, Ram, Mohite, Aditya D., Even, Jacky, Marks, Tobin J., & Kanatzidis, Mercouri G. New Type of 2D Perovskites with Alternating Cations in the Interlayer Space, (C(NH2)3)(CH3NH3)nPbnI3n+1: Structure, Properties, and Photovoltaic Performance. United States. https://doi.org/10.1021/jacs.7b09096
Soe, Chan Myae Myae, Stoumpos, Constantinos C., Kepenekian, Mikaël, Traoré, Boubacar, Tsai, Hsinhan, Nie, Wanyi, Wang, Binghao, Katan, Claudine, Seshadri, Ram, Mohite, Aditya D., Even, Jacky, Marks, Tobin J., and Kanatzidis, Mercouri G. Thu .
"New Type of 2D Perovskites with Alternating Cations in the Interlayer Space, (C(NH2)3)(CH3NH3)nPbnI3n+1: Structure, Properties, and Photovoltaic Performance". United States. https://doi.org/10.1021/jacs.7b09096. https://www.osti.gov/servlets/purl/1599738.
@article{osti_1599738,
title = {New Type of 2D Perovskites with Alternating Cations in the Interlayer Space, (C(NH2)3)(CH3NH3)nPbnI3n+1: Structure, Properties, and Photovoltaic Performance},
author = {Soe, Chan Myae Myae and Stoumpos, Constantinos C. and Kepenekian, Mikaël and Traoré, Boubacar and Tsai, Hsinhan and Nie, Wanyi and Wang, Binghao and Katan, Claudine and Seshadri, Ram and Mohite, Aditya D. and Even, Jacky and Marks, Tobin J. and Kanatzidis, Mercouri G.},
abstractNote = {In this study, we present the new homologous series (C(NH2)3)(CH3NH3)nPbnI3n+1 (n = 1, 2, 3) of layered 2D perovskites. Structural characterization by single-crystal X-ray diffraction reveals that these compounds adopt an unprecedented structure type, which is stabilized by the alternating ordering of the guanidinium and methylammonium cations in the interlayer space (ACI). Compared to the more common Ruddlesden–Popper (RP) 2D perovskites, the ACI perovskites have a different stacking motif and adopt a higher crystal symmetry. The higher symmetry of the ACI perovskites is expressed in their physical properties, which show a characteristic decrease of the bandgap with respect to their RP perovskite counterparts with the same perovskite layer thickness (n). The compounds show a monotonic decrease in the optical gap as n increases: Eg = 2.27 eV for n = 1 to Eg = 1.99 eV for n = 2 and Eg = 1.73 eV for n = 3, which show slightly narrower gaps compared to the corresponding RP perovskites. First-principles theoretical electronic structure calculations confirm the experimental optical gap trends suggesting that the ACI perovskites are direct bandgap semiconductors with wide valence and conduction bandwidths. To assess the potential of the ACI perovskites toward solar cell applications, we studied the (C(NH2)3)(CH3NH3)3Pb3I10 (n = 3) compound. Compact thin films from the (C(NH2)3)(CH3NH3)3Pb3I10 compound with excellent surface coverage can be obtained from the antisolvent dripping method. Planar photovoltaic devices from optimized ACI perovskite films yield a power-conversion-efficiency of 7.26% with a high open-circuit voltage of ~1 V and a striking fill factor of ~80%.},
doi = {10.1021/jacs.7b09096},
journal = {Journal of the American Chemical Society},
number = 45,
volume = 139,
place = {United States},
year = {Thu Nov 02 00:00:00 EDT 2017},
month = {Thu Nov 02 00:00:00 EDT 2017}
}
Free Publicly Available Full Text
Publisher's Version of Record
Other availability
Search WorldCat to find libraries that may hold this journal
Cited by: 306 works
Citation information provided by
Web of Science
Web of Science
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
High Members of the 2D Ruddlesden-Popper Halide Perovskites: Synthesis, Optical Properties, and Solar Cells of (CH 3 (CH 2 ) 3 NH 3 ) 2 (CH 3 NH 3 ) 4 Pb 5 I 16
journal, March 2017
- Stoumpos, Constantinos C.; Soe, Chan Myae Myae; Tsai, Hsinhan
- Chem, Vol. 2, Issue 3
High-efficiency two-dimensional Ruddlesden–Popper perovskite solar cells
journal, July 2016
- Tsai, Hsinhan; Nie, Wanyi; Blancon, Jean-Christophe
- Nature, Vol. 536, Issue 7616
Extremely efficient internal exciton dissociation through edge states in layered 2D perovskites
journal, March 2017
- Blancon, J. -C.; Tsai, H.; Nie, W.
- Science, Vol. 355, Issue 6331
2D Homologous Perovskites as Light-Absorbing Materials for Solar Cell Applications
journal, June 2015
- Cao, Duyen H.; Stoumpos, Constantinos C.; Farha, Omar K.
- Journal of the American Chemical Society, Vol. 137, Issue 24
Role of Organic Counterion in Lead- and Tin-Based Two-Dimensional Semiconducting Iodide Perovskites and Application in Planar Solar Cells
journal, October 2016
- Mao, Lingling; Tsai, Hsinhan; Nie, Wanyi
- Chemistry of Materials, Vol. 28, Issue 21
Ruddlesden–Popper Hybrid Lead Iodide Perovskite 2D Homologous Semiconductors
journal, April 2016
- Stoumpos, Constantinos C.; Cao, Duyen H.; Clark, Daniel J.
- Chemistry of Materials, Vol. 28, Issue 8, p. 2852-2867
White-Light Emission and Structural Distortion in New Corrugated Two-Dimensional Lead Bromide Perovskites
journal, March 2017
- Mao, Lingling; Wu, Yilei; Stoumpos, Constantinos C.
- Journal of the American Chemical Society, Vol. 139, Issue 14
A Layered Hybrid Perovskite Solar-Cell Absorber with Enhanced Moisture Stability
journal, September 2014
- Smith, Ian C.; Hoke, Eric T.; Solis-Ibarra, Diego
- Angewandte Chemie International Edition, Vol. 53, Issue 42
Solid-state principles applied to organic–inorganic perovskites: new tricks for an old dog
journal, January 2014
- Kieslich, Gregor; Sun, Shijing; Cheetham, Anthony K.
- Chem. Sci., Vol. 5, Issue 12
The Renaissance of Halide Perovskites and Their Evolution as Emerging Semiconductors
journal, September 2015
- Stoumpos, Constantinos C.; Kanatzidis, Mercouri G.
- Accounts of Chemical Research, Vol. 48, Issue 10
Structure–Band Gap Relationships in Hexagonal Polytypes and Low-Dimensional Structures of Hybrid Tin Iodide Perovskites
journal, December 2016
- Stoumpos, Constantinos C.; Mao, Lingling; Malliakas, Christos D.
- Inorganic Chemistry, Vol. 56, Issue 1
Structural, optical and related properties of some natural three- and lower-dimensional semiconductor systems
journal, April 1995
- Papavassiliou, G. C.; Koutselas, I. B.
- Synthetic Metals, Vol. 71, Issue 1-3, p. 1713-1714
Reduced Band Gap Hybrid Perovskites Resulting from Combined Hydrogen and Halogen Bonding at the Organic−Inorganic Interface
journal, February 2007
- Sourisseau, Sebastien; Louvain, Nicolas; Bi, Wenhua
- Chemistry of Materials, Vol. 19, Issue 3
Inorganic–organic hybrid materials incorporating primary cyclic ammonium cations: The lead iodide series
journal, January 2007
- Billing, David G.; Lemmerer, Andreas
- CrystEngComm, Vol. 9, Issue 3
Organic−Inorganic Perovskites Containing Trivalent Metal Halide Layers: The Templating Influence of the Organic Cation Layer
journal, December 2000
- Mitzi, David B.
- Inorganic Chemistry, Vol. 39, Issue 26
Synthesis and Characterization of [NH2C(I):NH2]3MI5 (M = Sn, Pb): Stereochemical Activity in Divalent Tin and Lead Halides Containing Single .ltbbrac.110.rtbbrac. Perovskite Sheets
journal, May 1995
- Wang, Shumin; Mitzi, David B.; Feild, Chris A.
- Journal of the American Chemical Society, Vol. 117, Issue 19
Preparation, structure and optical properties of [CH3SC(NH2)NH2]3PbI5, [CH3SC(NH2)NH2]4Pb2Br8and [CH3SC(NH2)NH2]3PbCl5·CH3SC(NH2)NH2Cl
journal, January 1998
- Mousdis, G. A.; Gionis, V.; Papavassiliou, G. C.
- Journal of Materials Chemistry, Vol. 8, Issue 10
Crystal structures of isotypic poly[bis(benzimidazolium) [tetra-μ-iodido-stannate(II)]] and poly[bis(5,6-difluorobenzimidazolium) [tetra-μ-iodido-stannate(II)]]
journal, September 2014
- Zimmermann, Iwan; Keene, Tony D.; Hauser, Jürg
- Acta Crystallographica Section E Structure Reports Online, Vol. 70, Issue 10
The reaction of tin(iv) iodide with phosphines: formation of new halotin anions
journal, January 2009
- Apostolico, Leonardo; Kociok-Köhn, Gabriele; Molloy, Kieran C.
- Dalton Transactions, Issue 47
New compounds of the K 2 NIF 4 type
journal, August 1957
- Ruddlesden, S. N.; Popper, P.
- Acta Crystallographica, Vol. 10, Issue 8
Nouvelles familles de phases MIMII2Nb3O10 a feuillets “perovskites”
journal, November 1981
- Dion, Michel; Ganne, Marcel; Tournoux, Michel
- Materials Research Bulletin, Vol. 16, Issue 11
Interlayer chemistry between thick transition-metal oxide layers: synthesis and intercalation reactions of K[Ca2Nan-3NbnO3n+1] (3 .ltoreq. n .ltoreq. 7)
journal, November 1985
- Jacobson, A. J.; Johnson, Jack W.; Lewandowski, J. T.
- Inorganic Chemistry, Vol. 24, Issue 23
A Variable-Temperature Powder Neutron Diffraction Study of Ferroelectric Bi 4 Ti 3 O 12
journal, November 1999
- Hervoches, Charles H.; Lightfoot, Philip
- Chemistry of Materials, Vol. 11, Issue 11
Recent Developments in Oxide Ion Conductors: Aurivillius Phases
journal, January 1996
- Kendall, Kurt R.; Navas, Carlos; Thomas, Julie K.
- Chemistry of Materials, Vol. 8, Issue 3
Structure determination of KLaNb2O7 exhibiting ion exchange ability by X-ray powder diffraction
journal, March 1992
- Sato, M.; Abo, J.; Jin, T.
- Solid State Ionics, Vol. 51, Issue 1-2
CsLaNb2O7
journal, May 1996
- Kumada, N.; Kinomura, N.; Sleight, A. W.
- Acta Crystallographica Section C Crystal Structure Communications, Vol. 52, Issue 5
Emergent Noncentrosymmetry and Piezoelectricity Driven by Oxygen Octahedral Rotations in n = 2 Dion-Jacobson Phase Layer Perovskites
journal, February 2016
- Strayer, Megan E.; Gupta, Arnab Sen; Akamatsu, Hirofumi
- Advanced Functional Materials, Vol. 26, Issue 12
Understanding ferroelectricity in layered perovskites: new ideas and insights from theory and experiments
journal, January 2015
- Benedek, Nicole A.; Rondinelli, James M.; Djani, Hania
- Dalton Transactions, Vol. 44, Issue 23
Origin of Ferroelectricity in a Family of Polar Oxides: The Dion—Jacobson Phases
journal, March 2014
- Benedek, Nicole A.
- Inorganic Chemistry, Vol. 53, Issue 7
Perovskites by Design: A Toolbox of Solid-State Reactions
journal, April 2002
- Schaak, Raymond E.; Mallouk, Thomas E.
- Chemistry of Materials, Vol. 14, Issue 4, p. 1455-1471
Semiconducting Tin and Lead Iodide Perovskites with Organic Cations: Phase Transitions, High Mobilities, and Near-Infrared Photoluminescent Properties
journal, July 2013
- Stoumpos, Constantinos C.; Malliakas, Christos D.; Kanatzidis, Mercouri G.
- Inorganic Chemistry, Vol. 52, Issue 15, p. 9019-9038
Conducting Layered Organic-inorganic Halides Containing <110>-Oriented Perovskite Sheets
journal, March 1995
- Mitzi, D. B.; Wang, S.; Feild, C. A.
- Science, Vol. 267, Issue 5203, p. 1473-1476
NMR Study of Cation Motion in Guanidinium Iodoplumbates
journal, November 1997
- Grottel, M.; Szafrański, M.; Pająk, Z.
- Zeitschrift für Naturforschung A, Vol. 52, Issue 11
Phase transitions in the layered structure of diguanidinium tetraiodoplumbate
journal, January 2000
- Szafrański, Marek; Katrusiak, Andrzej
- Physical Review B, Vol. 61, Issue 2
Pressure-induced decoupling of the order-disorder and displacive contributions to the phase transition in diguanidinium tetrachlorostannate
journal, October 2000
- Szafrański, Marek; Ståhl, Kenny
- Physical Review B, Vol. 62, Issue 13
Synthesis, Crystal Structures, Optical Properties, and Phase Transitions of the Layered Guanidinium-Based Hybrid Perovskites [C(NH 2 ) 3 ] 2 M I 4 ; M = Sn, Pb : Synthesis, Crystal Structures, Optical Properties, and Phase Transitions of the Layered Guanidinium-Based Hybrid Perovskites [C(NH
journal, February 2017
- Daub, Michael; Haber, Christoph; Hillebrecht, Harald
- European Journal of Inorganic Chemistry, Vol. 2017, Issue 7
Luminescent and Photoconductive Layered Lead Halide Perovskite Compounds Comprising Mixtures of Cesium and Guanidinium Cations
journal, September 2017
- Nazarenko, Olga; Kotyrba, Martin Robert; Wörle, Michael
- Inorganic Chemistry, Vol. 56, Issue 19
Chemistry in Molten Alkali Metal Polyselenophosphate Fluxes. Influence of Flux Composition on Dimensionality. Layers and Chains in APbPSe4, A4Pb(PSe4)2 (A = Rb, Cs), and K4Eu(PSe4)2
journal, January 1996
- Chondroudis, Konstantinos; McCarthy, Timothy J.; Kanatzidis, Mercouri G.
- Inorganic Chemistry, Vol. 35, Issue 4
Synthesis in Molten Alkali Metal Polyselenophosphate Fluxes: A New Family of Transition Metal Selenophosphate Compounds, A2MP2Se6 (A = K, Rb, Cs; M = Mn, Fe) and A2M'2P2Se6 (A = K, Cs; M' = Cu, Ag)
journal, March 1995
- McCarthy, Timothy J.; Kanatzidis, Mercouri G.
- Inorganic Chemistry, Vol. 34, Issue 5
Crystallographic Computing System JANA2006: General features
journal, January 2014
- Petříček, Václav; Dušek, Michal; Palatinus, Lukáš
- Zeitschrift für Kristallographie - Crystalline Materials, Vol. 229, Issue 5
Structure validation in chemical crystallography
journal, January 2009
- Spek, Anthony L.
- Acta Crystallographica Section D Biological Crystallography, Vol. 65, Issue 2, p. 148-155
The SIESTA method for ab initio order- N materials simulation
journal, March 2002
- Soler, José M.; Artacho, Emilio; Gale, Julian D.
- Journal of Physics: Condensed Matter, Vol. 14, Issue 11
Generalized Gradient Approximation Made Simple
journal, October 1996
- Perdew, John P.; Burke, Kieron; Ernzerhof, Matthias
- Physical Review Letters, Vol. 77, Issue 18, p. 3865-3868
On-site approximation for spin–orbit coupling in linear combination of atomic orbitals density functional methods
journal, August 2006
- Fernández-Seivane, L.; Oliveira, M. A.; Sanvito, S.
- Journal of Physics: Condensed Matter, Vol. 18, Issue 34
Efficient pseudopotentials for plane-wave calculations
journal, January 1991
- Troullier, N.; Martins, José Luriaas
- Physical Review B, Vol. 43, Issue 3
Linear-Scaling ab-initio Calculations for Large and Complex Systems
journal, September 1999
- Artacho, E.; S�nchez-Portal, D.; Ordej�n, P.
- physica status solidi (b), Vol. 215, Issue 1
Synthesis and Characterization of [NH 2 C(I)NH 2 ] 2 ASnI 5 with A = Iodoformamidinium or Formamidinium: The Chemistry of Cyanamide and Tin(II) Iodide in Concentrated Aqueous Hydriodic Acid Solutions
journal, January 1998
- Mitzi, David B.; Liang, Kangning; Wang, Shumin
- Inorganic Chemistry, Vol. 37, Issue 2
(HO2C(CH2)3NH3)2(CH3NH3)Pb2I7: a predicted non-centrosymmetrical structure built up from carboxylic acid supramolecular synthons and bilayer perovskite sheets
journal, January 2005
- Mercier, Nicolas
- CrystEngComm, Vol. 7, Issue 70
Mechanism of Pressure-Induced Phase Transitions, Amorphization, and Absorption-Edge Shift in Photovoltaic Methylammonium Lead Iodide
journal, August 2016
- Szafrański, Marek; Katrusiak, Andrzej
- The Journal of Physical Chemistry Letters, Vol. 7, Issue 17
Significance tests on the crystallographic R factor
journal, May 1965
- Hamilton, W. C.
- Acta Crystallographica, Vol. 18, Issue 3
On the application of Hamilton's ratio test to the assignment of absolute configuration and an alternative test
journal, September 1981
- Rogers, D.
- Acta Crystallographica Section A, Vol. 37, Issue 5
Crystal Structure of a Layered Perovskite Niobate KCa2Nb3O10
journal, April 2000
- Fukuoka, Hiroshi; Isami, Toshiyuki; Yamanaka, Shoji
- Journal of Solid State Chemistry, Vol. 151, Issue 1
The Hydrogen Bond in the Solid State
journal, January 2002
- Steiner, Thomas
- Angewandte Chemie International Edition, Vol. 41, Issue 1
The classification of tilted octahedra in perovskites
journal, November 1972
- Glazer, A. M.
- Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry, Vol. 28, Issue 11
Preparation and characterization of layered lead halide compounds
journal, March 1991
- Calabrese, J.; Jones, N. L.; Harlow, R. L.
- Journal of the American Chemical Society, Vol. 113, Issue 6, p. 2328-2330
Advances and Promises of Layered Halide Hybrid Perovskite Semiconductors
journal, October 2016
- Pedesseau, Laurent; Sapori, Daniel; Traore, Boubacar
- ACS Nano, Vol. 10, Issue 11
Dielectric confinement effect on excitons in -based layered semiconductors
journal, March 1992
- Hong, X.; Ishihara, T.; Nurmikko, A. V.
- Physical Review B, Vol. 45, Issue 12
Optical properties due to electronic transitions in two-dimensional semiconductors (
journal, December 1990
- Ishihara, Teruya; Takahashi, Jun; Goto, Takenari
- Physical Review B, Vol. 42, Issue 17
Excitons in ultrathin organic-inorganic perovskite crystals
journal, July 2015
- Yaffe, Omer; Chernikov, Alexey; Norman, Zachariah M.
- Physical Review B, Vol. 92, Issue 4
Quantum confinement and dielectric profiles of colloidal nanoplatelets of halide inorganic and hybrid organic–inorganic perovskites
journal, January 2016
- Sapori, Daniel; Kepenekian, Mikaël; Pedesseau, Laurent
- Nanoscale, Vol. 8, Issue 12
Understanding Quantum Confinement of Charge Carriers in Layered 2D Hybrid Perovskites
journal, September 2014
- Even, Jacky; Pedesseau, Laurent; Katan, Claudine
- ChemPhysChem, Vol. 15, Issue 17
Room Temperature Phase Transition in Methylammonium Lead Iodide Perovskite Thin Films Induced by Hydrohalic Acid Additives
journal, September 2016
- Soe, Chan Myae Myae; Stoumpos, Constantinos C.; Harutyunyan, Boris
- ChemSusChem, Vol. 9, Issue 18, p. 2656-2665
Solvent engineering for high-performance inorganic–organic hybrid perovskite solar cells
journal, July 2014
- Jeon, Nam Joong; Noh, Jun Hong; Kim, Young Chan
- Nature Materials, Vol. 13, Issue 9, p. 897-903
A Fast Deposition-Crystallization Procedure for Highly Efficient Lead Iodide Perovskite Thin-Film Solar Cells
journal, July 2014
- Xiao, Manda; Huang, Fuzhi; Huang, Wenchao
- Angewandte Chemie International Edition, Vol. 53, Issue 37
Guanidinium: A Route to Enhanced Carrier Lifetime and Open-Circuit Voltage in Hybrid Perovskite Solar Cells
journal, January 2016
- De Marco, Nicholas; Zhou, Huanping; Chen, Qi
- Nano Letters, Vol. 16, Issue 2
Crystal structure and ferroelectric properties of Sr, and Ba)
journal, March 2000
- Shimakawa, Y.; Kubo, Y.; Nakagawa, Y.
- Physical Review B, Vol. 61, Issue 10
Works referencing / citing this record:
Unravelling Light-Induced Degradation of Layered Perovskite Crystals and Design of Efficient Encapsulation for Improved Photostability
journal, April 2018
- Fang, Hong-Hua; Yang, Jie; Tao, Shuxia
- Advanced Functional Materials, Vol. 28, Issue 21
Prediction of Novel p -Type Transparent Conductors in Layered Double Perovskites: A First-Principles Study
journal, April 2018
- Xu, Jian; Liu, Jian-Bo; Wang, Jianfeng
- Advanced Functional Materials, Vol. 28, Issue 26
Mixed Dimensional 2D/3D Hybrid Perovskite Absorbers: The Future of Perovskite Solar Cells?
journal, December 2018
- Krishna, Anurag; Gottis, Sébastien; Nazeeruddin, Mohammad Khaja
- Advanced Functional Materials, Vol. 29, Issue 8
Introduction of Hydrophobic Ammonium Salts with Halogen Functional Groups for High‐Efficiency and Stable 2D/3D Perovskite Solar Cells
journal, January 2019
- Liu, Guozhen; Zheng, Haiying; Xu, Xiaoxiao
- Advanced Functional Materials, Vol. 29, Issue 47
Band‐Edge Exciton Fine Structure and Exciton Recombination Dynamics in Single Crystals of Layered Hybrid Perovskites
journal, December 2019
- Fang, Hong‐Hua; Yang, Jie; Adjokatse, Sampson
- Advanced Functional Materials, Vol. 30, Issue 6
Merits and Challenges of Ruddlesden-Popper Soft Halide Perovskites in Electro-Optics and Optoelectronics
journal, October 2018
- Chen, Zhizhong; Guo, Yuwei; Wertz, Esther
- Advanced Materials, Vol. 31, Issue 1
Low‐Dimensional Perovskites with Diammonium and Monoammonium Alternant Cations for High‐Performance Photovoltaics
journal, July 2019
- Li, Pengwei; Liang, Chao; Liu, Xiao‐Long
- Advanced Materials, Vol. 31, Issue 35
Compositional Control in 2D Perovskites with Alternating Cations in the Interlayer Space for Photovoltaics with Efficiency over 18%
journal, September 2019
- Luo, Tao; Zhang, Yalan; Xu, Zhuo
- Advanced Materials, Vol. 31, Issue 44
Highly Sensitive and Ultrafast Responding Array Photodetector Based on a Newly Tailored 2D Lead Iodide Perovskite Crystal
journal, March 2019
- Xu, Zhiyun; Li, Yaobin; Liu, Xitao
- Advanced Optical Materials, Vol. 7, Issue 11
Highly Emissive Self-Trapped Excitons in Fully Inorganic Zero-Dimensional Tin Halides
journal, July 2018
- Benin, Bogdan M.; Dirin, Dmitry N.; Morad, Viktoriia
- Angewandte Chemie, Vol. 130, Issue 35
Hybrid Halide Perovskites: Discussions on Terminology and Materials
journal, October 2019
- Mercier, Nicolas
- Angewandte Chemie International Edition, Vol. 58, Issue 50
Low‐Dimensional Dion–Jacobson‐Phase Lead‐Free Perovskites for High‐Performance Photovoltaics with Improved Stability
journal, March 2020
- Li, Pengwei; Liu, Xiaolong; Zhang, Yiqiang
- Angewandte Chemie International Edition, Vol. 59, Issue 17
Tailoring the Band Gap in 3D Hybrid Perovskites by Substitution of the Organic Cations: (CH 3 NH 3 ) 1−2 y (NH 3 (CH 2 ) 2 NH 3 ) 2 y Pb 1− y I 3 (0≤ y ≤0.25)
journal, June 2018
- Daub, Michael; Hillebrecht, Harald
- Chemistry - A European Journal, Vol. 24, Issue 36
Insight into the Mechanochemical Synthesis and Structural Evolution of Hybrid Organic-Inorganic Guanidinium Lead(II) Iodides
journal, November 2018
- Wilke, Manuel; Casati, Nicola
- Chemistry - A European Journal, Vol. 24, Issue 67
Two‐Step Structure Phase Transition, Dielectric Anomalies, and Thermochromic Luminescence Behavior in a Direct Band Gap 2D Corrugated Layer Lead Chloride Hybrid of [(CH 3 ) 4 N ] 4 Pb 3 Cl 10
journal, March 2019
- Xue, Chen; Wang, Shu; Liu, Wen‐Long
- Chemistry – A European Journal, Vol. 25, Issue 20
Two‐Dimensional Halide Perovskites in Solar Cells: 2D or not 2D?
journal, March 2019
- Ortiz‐Cervantes, Carmen; Carmona‐Monroy, Paulina; Solis‐Ibarra, Diego
- ChemSusChem, Vol. 12, Issue 8
Stability Issue of Perovskite Solar Cells under Real‐World Operating Conditions
journal, April 2020
- Wu, Mian; Haji Ladi, Najib; Yi, Zijun
- Energy Technology, Vol. 8, Issue 4
An Effective Strategy for Photoelectric Performance Enhancement of 2D Perovskite via Halogenating Organic Cation: A Theoretical Prediction
journal, January 2020
- Tang, Yong; Zhou, Yingtang; Zhong, Xiangli
- physica status solidi (b), Vol. 257, Issue 5
Highly Efficient Guanidinium‐Based Quasi 2D Perovskite Solar Cells via a Two‐Step Post‐Treatment Process
journal, May 2019
- Zhang, Yingzhu; Chen, Jiehuan; Lian, Xiaomei
- Small Methods, Vol. 3, Issue 11
Aromatic Alkylammonium Spacer Cations for Efficient Two-Dimensional Perovskite Solar Cells with Enhanced Moisture and Thermal Stability
journal, February 2018
- Thrithamarassery Gangadharan, Deepak; Han, Yujie; Dubey, Ashish
- Solar RRL, Vol. 2, Issue 4
Present Status and Research Prospects of Tin‐based Perovskite Solar Cells
journal, August 2019
- Hasan, Syed Azkar Ul; Lee, David S.; Im, Sang Hyuk
- Solar RRL, Vol. 4, Issue 2
Impact of Temperature‐Dependent Hydration Water on Perovskite Solar Cells
journal, October 2019
- Zhang, Weihai; Xiong, Juan; Li, Jinhua
- Solar RRL, Vol. 4, Issue 1
Unveiling the Importance of Precursor Preparation for Highly Efficient and Stable Phenethylammonium‐Based Perovskite Solar Cells
journal, April 2020
- Lee, Da Seul; Kim, Jincheol; Bing, Jueming
- Solar RRL, Vol. 4, Issue 4
Design principles for electronic charge transport in solution-processed vertically stacked 2D perovskite quantum wells
journal, May 2018
- Tsai, Hsinhan; Asadpour, Reza; Blancon, Jean-Christophe
- Nature Communications, Vol. 9, Issue 1
Dimensional tailoring of hybrid perovskites for photovoltaics
journal, November 2018
- Grancini, Giulia; Nazeeruddin, Mohammad Khaja
- Nature Reviews Materials, Vol. 4, Issue 1
A simple method for phase control in two-dimensional perovskite solar cells
journal, January 2018
- Ma, Chunqing; Lo, Ming-Fai; Lee, Chun-Sing
- Journal of Materials Chemistry A, Vol. 6, Issue 39
Emission enhancement and bandgap retention of a two-dimensional mixed cation lead halide perovskite under high pressure
journal, January 2019
- Chen, Yaping; Fu, Ruijing; Wang, Lingrui
- Journal of Materials Chemistry A, Vol. 7, Issue 11
Low-dimensional emissive states in non-stoichiometric methylammonium lead halide perovskites
journal, January 2019
- Freestone, Benjamin G.; Smith, Joel A.; Piana, Giacomo
- Journal of Materials Chemistry A, Vol. 7, Issue 18
Factors determining the vertical orientation of two-dimensional perovskites
journal, January 2019
- Arai, R.; Yoshizawa-Fujita, M.; Takeoka, Y.
- CrystEngComm, Vol. 21, Issue 31
Hydrophobic perovskites based on an alkylamine compound for high efficiency solar cells with improved environmental stability
journal, January 2019
- Jung, Mi-Hee
- Journal of Materials Chemistry A, Vol. 7, Issue 24
Guanidinium induced phase separated perovskite layer for efficient and highly stable solar cells
journal, January 2019
- Zhang, Weihai; Xiong, Juan; Li, Jinhua
- Journal of Materials Chemistry A, Vol. 7, Issue 16
Octahedral connectivity and its role in determining the phase stabilities and electronic structures of low-dimensional, perovskite-related iodoplumbates
journal, November 2018
- Deng, Zeyu; Kieslich, Gregor; Bristowe, Paul D.
- APL Materials, Vol. 6, Issue 11
Structural and thermodynamic limits of layer thickness in 2D halide perovskites
journal, December 2018
- Soe, Chan Myae Myae; Nagabhushana, G. P.; Shivaramaiah, Radha
- Proceedings of the National Academy of Sciences, Vol. 116, Issue 1
DFT study of electronic structure and optical properties of layered two-dimensional CH 3 NH 3 PbX 3 (X=Cl, Br, I)
journal, January 2019
- Faghihnasiri, Mahdi; Izadifard, Morteza; Ghazi, Mohammad Ebrahim
- Energy Sources, Part A: Recovery, Utilization, and Environmental Effects, Vol. 41, Issue 22
Efficient and accurate calculation of band gaps of halide perovskites with the Tran-Blaha modified Becke-Johnson potential
journal, January 2019
- Traoré, Boubacar; Bouder, Gaëlle; Lafargue-Dit-Hauret, William
- Physical Review B, Vol. 99, Issue 3
First representatives of (210)-oriented perovskite variants−Synthesis, crystal structures and properties of the new 2D hybrid perovskites A[HC(NH2)2]PbI4; A=[C(NH2)3], [HSC(NH2)2]
journal, July 2018
- Daub, Michael; Hillebrecht, Harald
- Zeitschrift für Kristallographie - Crystalline Materials, Vol. 233, Issue 8
Low‐Dimensional Dion–Jacobson‐Phase Lead‐Free Perovskites for High‐Performance Photovoltaics with Improved Stability
journal, April 2020
- Li, Pengwei; Liu, Xiaolong; Zhang, Yiqiang
- Angewandte Chemie, Vol. 132, Issue 17
Unveiling the Importance of Precursor Preparation for Highly Efficient and Stable Phenethylammonium‐Based Perovskite Solar Cells
journal, April 2020
- Lee, Da Seul; Kim, Jincheol; Bing, Jueming
- Solar RRL, Vol. 4, Issue 4
Octahedral connectivity and its role in determining the phase stabilities and electronic structures of low-dimensional, perovskite-related iodoplumbates
text, January 2018
- Deng, Zeyu; Kieslich, G.; Bristowe, Paul
- Apollo - University of Cambridge Repository
Hybrid Halide Perovskites: Discussions on Terminology and Materials
journal, October 2019
- Mercier, Nicolas
- Angewandte Chemie, Vol. 131, Issue 50
Highly Emissive Self-Trapped Excitons in Fully Inorganic Zero-Dimensional Tin Halides
journal, July 2018
- Benin, Bogdan M.; Dirin, Dmitry N.; Morad, Viktoriia
- Angewandte Chemie International Edition, Vol. 57, Issue 35
Band-edge Exciton Fine Structure and Exciton Recombination Dynamics in Single crystals of Layered Hybrid Perovskites
preprint, January 2019
- Fang, Hong-Hua; Yang, Jie; Adjokatse, Sampson
- arXiv
Highly Emissive Self-Trapped Excitons in Fully Inorganic Zero-Dimensional Tin Halides
journal, July 2018
- Benin, Bogdan M.; Dirin, Dmitry N.; Morad, Viktoriia
- Angewandte Chemie International Edition, Vol. 57, Issue 35
Incorporating Large A Cations into Lead Iodide Perovskite Cages: Relaxed Goldschmidt Tolerance Factor and Impact on Exciton–Phonon Interaction
journal, July 2019
- Fu, Yongping; Hautzinger, Matthew P.; Luo, Ziyu
- ACS Central Science, Vol. 5, Issue 8
Guanidinium-Formamidinium Lead Iodide: A Layered Perovskite-Related Compound with Red Luminescence at Room Temperature
journal, February 2018
- Nazarenko, Olga; Kotyrba, Martin R.; Yakunin, Sergii
- Journal of the American Chemical Society, Vol. 140, Issue 11
Two-Dimensional Dion–Jacobson Hybrid Lead Iodide Perovskites with Aromatic Diammonium Cations
journal, July 2019
- Li, Xiaotong; Ke, Weijun; Traoré, Boubacar
- Journal of the American Chemical Society, Vol. 141, Issue 32
Design principles for electronic charge transport in solution-processed vertically stacked 2D perovskite quantum wells
journal, May 2018
- Tsai, Hsinhan; Asadpour, Reza; Blancon, Jean-Christophe
- Nature Communications, Vol. 9, Issue 1
Structural and thermodynamic limits of layer thickness in 2D halide perovskites
journal, December 2018
- Soe, Chan Myae Myae; Nagabhushana, G. P.; Shivaramaiah, Radha
- Proceedings of the National Academy of Sciences, Vol. 116, Issue 1
Phase-Transition-Induced Carrier Mass Enhancement in 2D Ruddlesden-Popper Perovskites
text, January 2019
- Baranowski, M.; Zelewski, Sj; Kepenekian, M.
- Apollo - University of Cambridge Repository