H2Pc and pentacene on Cu(110)-(2×1)O: A combined STM and nc-AFM study

Garlant, Angel; Maughan, Bret; Zahl, Percy; Monti, Oliver L. A.

doi:10.1016/j.susc.2020.121590

Title: H₂Pc and pentacene on Cu(110)-(2×1)O: A combined STM and nc-AFM study

Abstract

Scanning tunneling microscopy (STM) and non-contact atomic force microscopy (nc-AFM) with a CuO tip is used to investigate adsorption of metal-free phthalocyanine (H₂Pc) and pentacene on the Cu(110)-(2×1)O striped-phase reconstructed surface. We show that the combination of STM and nc-AFM is necessary to reveal the detailed adsorption geometry, necessary for interpreting the observed STM contrast. Comparison of the nc-AFM images with simulations shows that some of the H₂Pc molecules are deformed out-of-plane on this surface, while pentacene retains its molecular geometry regardless of adsorption site. Our research highlights how the stiffness of CuO tips makes it possible to probe the structure of organic semiconductor / metal interfaces.

Authors:

Garlant, Angel ^[1]; Maughan, Bret ^[2]; Zahl, Percy ^[3]; Monti, Oliver L. A. ^[2]

Northern Arizona Univ., Flagstaff, AZ (United States)
Univ. of Arizona, Tucson, AZ (United States). Dept. of Chemistry and Biochemistry
Brookhaven National Lab. (BNL), Upton, NY (United States)

Publication Date:: Fri Feb 07 00:00:00 EST 2020

Research Org.:: Brookhaven National Lab. (BNL), Upton, NY (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI Identifier:: 1599583

Alternate Identifier(s):: OSTI ID: 1776230

Report Number(s):: BNL-213633-2020-JAAM
Journal ID: ISSN 0039-6028

Grant/Contract Number:: SC0012704; CHE-1565497

Resource Type:: Accepted Manuscript

Journal Name:: Surface Science

Additional Journal Information:: Journal Volume: 696; Journal Issue: C; Journal ID: ISSN 0039-6028

Publisher:: Elsevier

Country of Publication:: United States

Language:: English

Subject:: 77 NANOSCIENCE AND NANOTECHNOLOGY

Citation Formats


                    Garlant, Angel, Maughan, Bret, Zahl, Percy, and Monti, Oliver L. A. H2Pc and pentacene on Cu(110)-(2×1)O: A combined STM and nc-AFM study.  United States: N. p., 2020. 
Web.  doi:10.1016/j.susc.2020.121590.

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                    Garlant, Angel, Maughan, Bret, Zahl, Percy, & Monti, Oliver L. A. H2Pc and pentacene on Cu(110)-(2×1)O: A combined STM and nc-AFM study.  United States.  https://doi.org/10.1016/j.susc.2020.121590

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                    Garlant, Angel, Maughan, Bret, Zahl, Percy, and Monti, Oliver L. A. Fri .  
"H2Pc and pentacene on Cu(110)-(2×1)O: A combined STM and nc-AFM study".  United States.  https://doi.org/10.1016/j.susc.2020.121590.  https://www.osti.gov/servlets/purl/1599583.

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@article{osti_1599583,

  title        = {H2Pc and pentacene on Cu(110)-(2×1)O: A combined STM and nc-AFM study},

  author       = {Garlant, Angel and Maughan, Bret and Zahl, Percy and Monti, Oliver L. A.},

  abstractNote = {Scanning tunneling microscopy (STM) and non-contact atomic force microscopy (nc-AFM) with a CuO tip is used to investigate adsorption of metal-free phthalocyanine (H2Pc) and pentacene on the Cu(110)-(2×1)O striped-phase reconstructed surface. We show that the combination of STM and nc-AFM is necessary to reveal the detailed adsorption geometry, necessary for interpreting the observed STM contrast. Comparison of the nc-AFM images with simulations shows that some of the H2Pc molecules are deformed out-of-plane on this surface, while pentacene retains its molecular geometry regardless of adsorption site. Our research highlights how the stiffness of CuO tips makes it possible to probe the structure of organic semiconductor / metal interfaces.},

  doi          = {10.1016/j.susc.2020.121590},

  journal      = {Surface Science},

  number       = C,

  volume       = 696,

  place        = {United States},

  year         = {Fri Feb 07 00:00:00 EST 2020},

  month        = {Fri Feb 07 00:00:00 EST 2020}

}

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https://doi.org/10.1016/j.susc.2020.121590

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Title: H2Pc and pentacene on Cu(110)-(2×1)O: A combined STM and nc-AFM study

Abstract

Citation Formats

The Chemical Structure of a Molecule Resolved by Atomic Force Microscopy journal, August 2009

Bond-Order Discrimination by Atomic Force Microscopy journal, September 2012

Submolecular Imaging by Noncontact Atomic Force Microscopy with an Oxygen Atom Rigidly Connected to a Metallic Probe journal, December 2015

Quantitative assessment of intermolecular interactions by atomic force microscopy imaging using copper oxide tips journal, April 2018

Real-Space Identification of Intermolecular Bonding with Atomic Force Microscopy journal, September 2013

Direct Imaging of Covalent Bond Structure in Single-Molecule Chemical Reactions journal, May 2013

Organic structure determination using atomic-resolution scanning probe microscopy journal, August 2010

Mapping the force field of a hydrogen-bonded assembly journal, May 2014

Origin of the Contrast Interpreted as Intermolecular and Intramolecular Bonds in Atomic Force Microscopy Images journal, June 2015

High-Resolution Model for Noncontact Atomic Force Microscopy with a Flexible Molecule on the Tip Apex journal, January 2015

Symmetry lowering of pentacene molecular states interacting with a Cu surface journal, December 2007

Self-organization of cobalt-phthalocyanine on a vicinal gold surface revealed by scanning tunnelling microscopy journal, September 2007

Absence of template induced ordering in organic multilayers: The growth of pentacene on a Cu(221) vicinal surface journal, March 2011

Evidence of Silicene in Honeycomb Structures of Silicon on Ag(111) journal, June 2012

Investigation of the electronic structures and associated properties including hyperfine interactions for halogen-adsorbed silicon surfaces: Fluorine through iodine journal, December 1988

Electronic properties and bonding sites for chlorine chemisorption on Si(111)-(7×7) journal, December 1985

Massive Surface Reshaping Mediated by Metal–Organic Complexes journal, December 2014

Water Formation for the Metalation of Porphyrin Molecules on Oxidized Cu(111) journal, August 2016

Mechanism of high-resolution STM/AFM imaging with functionalized tips journal, August 2014

Size relation for surface systems with long-range interactions journal, April 1994

Ensemble Control of Kondo Screening in Molecular Adsorbates journal, April 2017

Current-Induced Hydrogen Tautomerization and Conductance Switching of Naphthalocyanine Molecules journal, August 2007

Understanding Scanning Tunneling Microscopy Contrast Mechanisms on Metal Oxides: A Case Study journal, October 2013

Quantitative Atomic Resolution Force Imaging on Epitaxial Graphene with Reactive and Nonreactive AFM Probes journal, October 2012

Adsorption Geometry Determination of Single Molecules by Atomic Force Microscopy journal, September 2013

Suppression of electron–vibron coupling in graphene nanoribbons contacted via a single atom journal, June 2013

Formation and Characterization of a Molecule–Metal–Molecule Bridge in Real Space journal, June 2013

The Influence of Chemical Bonding Configuration on Atomic Identification by Force Spectroscopy journal, July 2013

Revealing the Angular Symmetry of Chemical Bonds by Atomic Force Microscopy journal, April 2012

Multimorphism in molecular monolayers: Pentacene on Cu(110) journal, June 2009

Electronic Structure of an Organic/Metal Interface: Pentacene/Cu(110) journal, October 2012

Ordered Structures of Tetracene and Pentacene on Cu(110) Surfaces journal, November 2003

Ordered structures of pentacene on Cu(110) journal, January 2009

Epitaxial growth of pentacene films on Cu(110) journal, January 2004

Novel Mechanism for Molecular Self-Assembly on Metal Substrates: Unidirectional Rows of Pentacene on Cu(110) Produced by a Substrate-Mediated Repulsion journal, December 2001

Modification of the Cu(110) Shockley surface state by an adsorbed pentacene monolayer journal, March 2009

Title: H₂Pc and pentacene on Cu(110)-(2×1)O: A combined STM and nc-AFM study

The Chemical Structure of a Molecule Resolved by Atomic Force Microscopy
journal, August 2009

Bond-Order Discrimination by Atomic Force Microscopy
journal, September 2012

Submolecular Imaging by Noncontact Atomic Force Microscopy with an Oxygen Atom Rigidly Connected to a Metallic Probe
journal, December 2015

Quantitative assessment of intermolecular interactions by atomic force microscopy imaging using copper oxide tips
journal, April 2018

Real-Space Identification of Intermolecular Bonding with Atomic Force Microscopy
journal, September 2013

Direct Imaging of Covalent Bond Structure in Single-Molecule Chemical Reactions
journal, May 2013

Organic structure determination using atomic-resolution scanning probe microscopy
journal, August 2010

Mapping the force field of a hydrogen-bonded assembly
journal, May 2014

Origin of the Contrast Interpreted as Intermolecular and Intramolecular Bonds in Atomic Force Microscopy Images
journal, June 2015

High-Resolution Model for Noncontact Atomic Force Microscopy with a Flexible Molecule on the Tip Apex
journal, January 2015

Symmetry lowering of pentacene molecular states interacting with a Cu surface
journal, December 2007

Self-organization of cobalt-phthalocyanine on a vicinal gold surface revealed by scanning tunnelling microscopy
journal, September 2007

Absence of template induced ordering in organic multilayers: The growth of pentacene on a Cu(221) vicinal surface
journal, March 2011

Evidence of Silicene in Honeycomb Structures of Silicon on Ag(111)
journal, June 2012

Investigation of the electronic structures and associated properties including hyperfine interactions for halogen-adsorbed silicon surfaces: Fluorine through iodine
journal, December 1988

Electronic properties and bonding sites for chlorine chemisorption on Si(111)-(7×7)
journal, December 1985

Massive Surface Reshaping Mediated by Metal–Organic Complexes
journal, December 2014

Water Formation for the Metalation of Porphyrin Molecules on Oxidized Cu(111)
journal, August 2016

Mechanism of high-resolution STM/AFM imaging with functionalized tips
journal, August 2014

Size relation for surface systems with long-range interactions
journal, April 1994

Ensemble Control of Kondo Screening in Molecular Adsorbates
journal, April 2017

Current-Induced Hydrogen Tautomerization and Conductance Switching of Naphthalocyanine Molecules
journal, August 2007

Understanding Scanning Tunneling Microscopy Contrast Mechanisms on Metal Oxides: A Case Study
journal, October 2013

Quantitative Atomic Resolution Force Imaging on Epitaxial Graphene with Reactive and Nonreactive AFM Probes
journal, October 2012

Adsorption Geometry Determination of Single Molecules by Atomic Force Microscopy
journal, September 2013

Suppression of electron–vibron coupling in graphene nanoribbons contacted via a single atom
journal, June 2013

Formation and Characterization of a Molecule–Metal–Molecule Bridge in Real Space
journal, June 2013

The Influence of Chemical Bonding Configuration on Atomic Identification by Force Spectroscopy
journal, July 2013

Revealing the Angular Symmetry of Chemical Bonds by Atomic Force Microscopy
journal, April 2012

Multimorphism in molecular monolayers: Pentacene on Cu(110)
journal, June 2009

Electronic Structure of an Organic/Metal Interface: Pentacene/Cu(110)
journal, October 2012

Ordered Structures of Tetracene and Pentacene on Cu(110) Surfaces
journal, November 2003

Ordered structures of pentacene on Cu(110)
journal, January 2009

Epitaxial growth of pentacene films on Cu(110)
journal, January 2004

Novel Mechanism for Molecular Self-Assembly on Metal Substrates: Unidirectional Rows of Pentacene on Cu(110) Produced by a Substrate-Mediated Repulsion
journal, December 2001

Modification of the Cu(110) Shockley surface state by an adsorbed pentacene monolayer
journal, March 2009