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Title: Dissociate lattice oxygen redox reactions from capacity and voltage drops of battery electrodes

Abstract

The oxygen redox (OR) reaction is a promising concept for improving battery energy density, however oxygen activities are generally considered detrimental to the stability and kinetics of batteries. Studies of OR activities often mix the lattice OR with other oxygen-involved reactions, such as gas release, radical oxygen evolution and surface reactions, further shadowing the true property of the practically meaningful lattice OR activities. Here, based on high-efficiency mapping of resonant inelastic X-ray scattering (mRIXS) of both the transition-metals and oxygen, we distinguish and quantify the lattice OR activities Na0.6[Li0.2Mn0.8]O2.

Authors:
ORCiD logo [1];  [2];  [3];  [4]; ORCiD logo [5]; ORCiD logo [6];  [7]; ORCiD logo [8]; ORCiD logo [9]; ORCiD logo [6];  [6]; ORCiD logo [3];  [10]; ORCiD logo [11]; ORCiD logo [6]
  1. Stanford Univ., CA (United States). Geballe Lab. for Advanced Materials; Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Advanced Light Source (ALS); SLAC National Accelerator Lab., Menlo Park, CA (United States). Stanford Institute for Materials and Energy Science (SIMES)
  2. Peking Univ. Shenzhen Graduate School, Shenzhen (China); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Advanced Light Source (ALS)
  3. Chinese Academy of Sciences (CAS), Beijing (China). Inst. of Physics; Univ. of Chinese Academy of Sciences, Beijing (China)
  4. Northeastern Univ., Shenyang (China); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Advanced Light Source (ALS)
  5. Binghamton Univ., NY (United States); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Advanced Light Source (ALS)
  6. Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Advanced Light Source (ALS)
  7. Peking Univ. Shenzhen Graduate School, Shenzhen (China)
  8. Binghamton Univ., NY (United States)
  9. Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
  10. Tsinghua Univ., Beijing (China)
  11. Stanford Univ., CA (United States). Geballe Lab. for Advanced Materials; SLAC National Accelerator Lab., Menlo Park, CA (United States). Stanford Institute for Materials and Energy Science (SIMES); Stanford Univ., CA (United States)
Publication Date:
Research Org.:
Energy Frontier Research Centers (EFRC) (United States). Northeastern Center for Chemical Energy Storage (NECCES); Binghamton Univ., NY (United States); SLAC National Accelerator Laboratory (SLAC), Menlo Park, CA (United States); Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
Sponsoring Org.:
USDOE Office of Energy Efficiency and Renewable Energy (EERE); USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Materials Sciences & Engineering Division; China’s National Key R&D Programmes; USDOE Office of Science (SC), Basic Energy Sciences (BES). Scientific User Facilities Division
OSTI Identifier:
1598793
Alternate Identifier(s):
OSTI ID: 1573374; OSTI ID: 1601224
Grant/Contract Number:  
SC0012583; AC02-05CH11231; AC02-76SF00515
Resource Type:
Accepted Manuscript
Journal Name:
Science Advances
Additional Journal Information:
Journal Volume: 6; Journal Issue: 6; Journal ID: ISSN 2375-2548
Publisher:
AAAS
Country of Publication:
United States
Language:
English
Subject:
25 ENERGY STORAGE

Citation Formats

Wu, Jinpeng, Zhuo, Zengqing, Rong, Xiaohui, Dai, Kehua, Lebens-Higgins, Zachary, Sallis, Shawn, Pan, Feng, Piper, Louis F. J., Liu, Gao, Chuang, Yi-de, Hussain, Zahid, Li, Qinghao, Zeng, Rong, Shen, Zhi-xun, and Yang, Wanli. Dissociate lattice oxygen redox reactions from capacity and voltage drops of battery electrodes. United States: N. p., 2020. Web. doi:10.1126/sciadv.aaw3871.
Wu, Jinpeng, Zhuo, Zengqing, Rong, Xiaohui, Dai, Kehua, Lebens-Higgins, Zachary, Sallis, Shawn, Pan, Feng, Piper, Louis F. J., Liu, Gao, Chuang, Yi-de, Hussain, Zahid, Li, Qinghao, Zeng, Rong, Shen, Zhi-xun, & Yang, Wanli. Dissociate lattice oxygen redox reactions from capacity and voltage drops of battery electrodes. United States. https://doi.org/10.1126/sciadv.aaw3871
Wu, Jinpeng, Zhuo, Zengqing, Rong, Xiaohui, Dai, Kehua, Lebens-Higgins, Zachary, Sallis, Shawn, Pan, Feng, Piper, Louis F. J., Liu, Gao, Chuang, Yi-de, Hussain, Zahid, Li, Qinghao, Zeng, Rong, Shen, Zhi-xun, and Yang, Wanli. Sat . "Dissociate lattice oxygen redox reactions from capacity and voltage drops of battery electrodes". United States. https://doi.org/10.1126/sciadv.aaw3871. https://www.osti.gov/servlets/purl/1598793.
@article{osti_1598793,
title = {Dissociate lattice oxygen redox reactions from capacity and voltage drops of battery electrodes},
author = {Wu, Jinpeng and Zhuo, Zengqing and Rong, Xiaohui and Dai, Kehua and Lebens-Higgins, Zachary and Sallis, Shawn and Pan, Feng and Piper, Louis F. J. and Liu, Gao and Chuang, Yi-de and Hussain, Zahid and Li, Qinghao and Zeng, Rong and Shen, Zhi-xun and Yang, Wanli},
abstractNote = {The oxygen redox (OR) reaction is a promising concept for improving battery energy density, however oxygen activities are generally considered detrimental to the stability and kinetics of batteries. Studies of OR activities often mix the lattice OR with other oxygen-involved reactions, such as gas release, radical oxygen evolution and surface reactions, further shadowing the true property of the practically meaningful lattice OR activities. Here, based on high-efficiency mapping of resonant inelastic X-ray scattering (mRIXS) of both the transition-metals and oxygen, we distinguish and quantify the lattice OR activities Na0.6[Li0.2Mn0.8]O2.},
doi = {10.1126/sciadv.aaw3871},
journal = {Science Advances},
number = 6,
volume = 6,
place = {United States},
year = {Sat Feb 01 00:00:00 EST 2020},
month = {Sat Feb 01 00:00:00 EST 2020}
}

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