Pt/Ferric Hydroxyphosphate: An Effective Catalyst for the Selective Hydrogenation of α,β-Unsaturated Aldehydes (Ketones) into α,β-Unsaturated Alcohols
Abstract
Four micro (nano)-sized mesoporous ferric hydroxyphosphates (FHP) are synthesized by a reverse microemulsion-solvothermal method, and then are used as supports to prepare supported Pt catalysts. The mean particle diameter of Pt nanoparticles (NPs) was 4.5–4.6 nm. When the four different Pt/FHP catalysts were used into the hydrogenation of α,β-unsaturated aldehydes (ketones) to their corresponding unsaturated alcohols, Pt/FHP (c) catalyst showed better catalytic performance than the other three partners. Under the optimal experimental conditions, several tested α,β-unsaturated aldehydes could be effectively transformed into corresponding unsaturated alcohols over Pt/FHP (c) catalyst. The catalyst could be recycled and reused several times without activity loss. We propose the stronger interaction between the Pt NPs and ferric ions of the FHP (c) are responsible for its good catalytic performance, and this stronger interaction should be rooted in its enhanced Lewis acid strength.
- Authors:
-
- Nanjing Normal Univ. (China). College of Chemistry and Materials Science
- Nanjing Tech Univ. (China). College of Chemistry and Molecular Engineering
- Univ. of Connecticut, Storrs, CT (United States)
- Publication Date:
- Research Org.:
- Univ. of Connecticut, Storrs, CT (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences, and Biosciences Division
- OSTI Identifier:
- 1597845
- Grant/Contract Number:
- FG02-86ER-13622
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Catalysis Letters
- Additional Journal Information:
- Journal Volume: 148; Journal Issue: 2; Journal ID: ISSN 1011-372X
- Publisher:
- Springer
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; α,β-Unsaturated aldehydes (ketones); Ferric hydroxyphosphates; Lewis acid; Pt nanoparticles; Selective hydrogenation
Citation Formats
Liu, Cheng, Luo, Wei, Liu, Junhua, Sun, Lei, Yang, Yue, Liu, Gui, Wang, Fang, Zhong, Wei, Guild, Curtis, and Suib, Steven L. Pt/Ferric Hydroxyphosphate: An Effective Catalyst for the Selective Hydrogenation of α,β-Unsaturated Aldehydes (Ketones) into α,β-Unsaturated Alcohols. United States: N. p., 2018.
Web. doi:10.1007/s10562-017-2280-5.
Liu, Cheng, Luo, Wei, Liu, Junhua, Sun, Lei, Yang, Yue, Liu, Gui, Wang, Fang, Zhong, Wei, Guild, Curtis, & Suib, Steven L. Pt/Ferric Hydroxyphosphate: An Effective Catalyst for the Selective Hydrogenation of α,β-Unsaturated Aldehydes (Ketones) into α,β-Unsaturated Alcohols. United States. https://doi.org/10.1007/s10562-017-2280-5
Liu, Cheng, Luo, Wei, Liu, Junhua, Sun, Lei, Yang, Yue, Liu, Gui, Wang, Fang, Zhong, Wei, Guild, Curtis, and Suib, Steven L. Thu .
"Pt/Ferric Hydroxyphosphate: An Effective Catalyst for the Selective Hydrogenation of α,β-Unsaturated Aldehydes (Ketones) into α,β-Unsaturated Alcohols". United States. https://doi.org/10.1007/s10562-017-2280-5. https://www.osti.gov/servlets/purl/1597845.
@article{osti_1597845,
title = {Pt/Ferric Hydroxyphosphate: An Effective Catalyst for the Selective Hydrogenation of α,β-Unsaturated Aldehydes (Ketones) into α,β-Unsaturated Alcohols},
author = {Liu, Cheng and Luo, Wei and Liu, Junhua and Sun, Lei and Yang, Yue and Liu, Gui and Wang, Fang and Zhong, Wei and Guild, Curtis and Suib, Steven L.},
abstractNote = {Four micro (nano)-sized mesoporous ferric hydroxyphosphates (FHP) are synthesized by a reverse microemulsion-solvothermal method, and then are used as supports to prepare supported Pt catalysts. The mean particle diameter of Pt nanoparticles (NPs) was 4.5–4.6 nm. When the four different Pt/FHP catalysts were used into the hydrogenation of α,β-unsaturated aldehydes (ketones) to their corresponding unsaturated alcohols, Pt/FHP (c) catalyst showed better catalytic performance than the other three partners. Under the optimal experimental conditions, several tested α,β-unsaturated aldehydes could be effectively transformed into corresponding unsaturated alcohols over Pt/FHP (c) catalyst. The catalyst could be recycled and reused several times without activity loss. We propose the stronger interaction between the Pt NPs and ferric ions of the FHP (c) are responsible for its good catalytic performance, and this stronger interaction should be rooted in its enhanced Lewis acid strength.},
doi = {10.1007/s10562-017-2280-5},
journal = {Catalysis Letters},
number = 2,
volume = 148,
place = {United States},
year = {Thu Jan 04 00:00:00 EST 2018},
month = {Thu Jan 04 00:00:00 EST 2018}
}
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