High-refractive index acrylate polymers for applications in nanoimprint lithography
Abstract
The development of polymeric optical materials with a higher refractive index, transparency in the visible spectrum region and easier processability is increasingly desirable for advanced optical applications such as microlenses, image sensors, and organic light-emitting diodes. Most acrylates have a low refractive index (around 1.50) which does not meet the high performance requirements of advanced optical materials. In this research, three novel acrylates were synthesized via a facile one-step approach and used to fabricate optical transparent polymers. All of the polymers reveal good optical properties including high transparency (≥90%) in the visible spectrum region and high refractive index values (1.6363) at 550 nm. Moreover, nanostructures of these acrylate polymers with various feature sizes including nanogratings and photonic crystals were successfully fabricated using nanoimprint lithography. Finally, these results indicate that these acrylates can be used in a wide range of optical and optoelectronic devices where nanopatterned films with high refractive index and transparency are required.
- Authors:
-
- Beijing Univ. of Chemical Technology (China); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
- Beijing Univ. of Chemical Technology (China)
- aBeam Technologies, Castro Valley, CA (United States)
- Publication Date:
- Research Org.:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1597724
- Alternate Identifier(s):
- OSTI ID: 1778570
- Grant/Contract Number:
- AC02-05CH11231; 201706880022; 51573011
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Chinese Chemical Letters
- Additional Journal Information:
- Journal Volume: 31; Journal Issue: 1; Journal ID: ISSN 1001-8417
- Publisher:
- Elsevier
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; high refractive index; acrylate; facile synthesis; nanostructure; nanoimprint lithography
Citation Formats
Tang, Yunhui, Cabrini, Stefano, Nie, Jun, and Pina-Hernandez, Carlos. High-refractive index acrylate polymers for applications in nanoimprint lithography. United States: N. p., 2019.
Web. doi:10.1016/j.cclet.2019.04.012.
Tang, Yunhui, Cabrini, Stefano, Nie, Jun, & Pina-Hernandez, Carlos. High-refractive index acrylate polymers for applications in nanoimprint lithography. United States. https://doi.org/10.1016/j.cclet.2019.04.012
Tang, Yunhui, Cabrini, Stefano, Nie, Jun, and Pina-Hernandez, Carlos. Wed .
"High-refractive index acrylate polymers for applications in nanoimprint lithography". United States. https://doi.org/10.1016/j.cclet.2019.04.012. https://www.osti.gov/servlets/purl/1597724.
@article{osti_1597724,
title = {High-refractive index acrylate polymers for applications in nanoimprint lithography},
author = {Tang, Yunhui and Cabrini, Stefano and Nie, Jun and Pina-Hernandez, Carlos},
abstractNote = {The development of polymeric optical materials with a higher refractive index, transparency in the visible spectrum region and easier processability is increasingly desirable for advanced optical applications such as microlenses, image sensors, and organic light-emitting diodes. Most acrylates have a low refractive index (around 1.50) which does not meet the high performance requirements of advanced optical materials. In this research, three novel acrylates were synthesized via a facile one-step approach and used to fabricate optical transparent polymers. All of the polymers reveal good optical properties including high transparency (≥90%) in the visible spectrum region and high refractive index values (1.6363) at 550 nm. Moreover, nanostructures of these acrylate polymers with various feature sizes including nanogratings and photonic crystals were successfully fabricated using nanoimprint lithography. Finally, these results indicate that these acrylates can be used in a wide range of optical and optoelectronic devices where nanopatterned films with high refractive index and transparency are required.},
doi = {10.1016/j.cclet.2019.04.012},
journal = {Chinese Chemical Letters},
number = 1,
volume = 31,
place = {United States},
year = {Wed Apr 10 00:00:00 EDT 2019},
month = {Wed Apr 10 00:00:00 EDT 2019}
}
Web of Science