Chiral liquid crystal colloids
Abstract
Colloidal particles disturb the alignment of rod-like molecules of liquid crystals, giving rise to long-range interactions that minimize the free energy of distorted regions. Particle shape and topology are known to guide this self-assembly process. However, how chirality of colloidal inclusions affects these long-range interactions is unclear. Here we study the effects of distortions caused by chiral springs and helices on the colloidal self-organization in a nematic liquid crystal using laser tweezers, particle tracking and optical imaging. We show that chirality of colloidal particles interacts with the nematic elasticity to predefine chiral or racemic colloidal superstructures in nematic colloids. These findings are consistent with numerical modelling based on the minimization of Landau–de Gennes free energy. In conclusion, our study uncovers the role of chirality in defining the mesoscopic order of liquid crystal colloids, suggesting that this feature may be a potential tool to modulate the global orientated self-organization of these systems.
- Authors:
-
- Univ. of Colorado, Boulder, CO (United States)
- Max-Planck-Inst. für Intelligente Systeme, Stuttgart (Germany); Univ. Stuttgart, Stuttgart (Germany). Inst. für Theoretische Physik; Univ. de Lisboa, Lisboa (Portugal). Centro de Física Teórica e Computacional, Dept. de Física, Faculdade de Ciências
- Univ. of Colorado, Boulder, CO (United States); National Renewable Energy Lab. (NREL), Golden, CO (United States)
- Publication Date:
- Research Org.:
- Univ. of Colorado, Boulder, CO (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Materials Sciences & Engineering Division
- OSTI Identifier:
- 1594991
- Grant/Contract Number:
- SC0010305
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Nature Materials
- Additional Journal Information:
- Journal Volume: 17; Journal Issue: 1; Journal ID: ISSN 1476-1122
- Publisher:
- Springer Nature - Nature Publishing Group
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE
Citation Formats
Yuan, Ye, Martinez, Angel, Senyuk, Bohdan, Tasinkevych, Mykola, and Smalyukh, Ivan I. Chiral liquid crystal colloids. United States: N. p., 2017.
Web. doi:10.1038/nmat5032.
Yuan, Ye, Martinez, Angel, Senyuk, Bohdan, Tasinkevych, Mykola, & Smalyukh, Ivan I. Chiral liquid crystal colloids. United States. https://doi.org/10.1038/nmat5032
Yuan, Ye, Martinez, Angel, Senyuk, Bohdan, Tasinkevych, Mykola, and Smalyukh, Ivan I. Mon .
"Chiral liquid crystal colloids". United States. https://doi.org/10.1038/nmat5032. https://www.osti.gov/servlets/purl/1594991.
@article{osti_1594991,
title = {Chiral liquid crystal colloids},
author = {Yuan, Ye and Martinez, Angel and Senyuk, Bohdan and Tasinkevych, Mykola and Smalyukh, Ivan I.},
abstractNote = {Colloidal particles disturb the alignment of rod-like molecules of liquid crystals, giving rise to long-range interactions that minimize the free energy of distorted regions. Particle shape and topology are known to guide this self-assembly process. However, how chirality of colloidal inclusions affects these long-range interactions is unclear. Here we study the effects of distortions caused by chiral springs and helices on the colloidal self-organization in a nematic liquid crystal using laser tweezers, particle tracking and optical imaging. We show that chirality of colloidal particles interacts with the nematic elasticity to predefine chiral or racemic colloidal superstructures in nematic colloids. These findings are consistent with numerical modelling based on the minimization of Landau–de Gennes free energy. In conclusion, our study uncovers the role of chirality in defining the mesoscopic order of liquid crystal colloids, suggesting that this feature may be a potential tool to modulate the global orientated self-organization of these systems.},
doi = {10.1038/nmat5032},
journal = {Nature Materials},
number = 1,
volume = 17,
place = {United States},
year = {Mon Nov 27 00:00:00 EST 2017},
month = {Mon Nov 27 00:00:00 EST 2017}
}
Web of Science
Works referenced in this record:
Chemoresponsive assemblies of microparticles at liquid crystalline interfaces
journal, January 2010
- Koenig, G. M.; Lin, I. -H.; Abbott, N. L.
- Proceedings of the National Academy of Sciences, Vol. 107, Issue 9
Physics of colloidal dispersions in nematic liquid crystals
journal, October 2001
- Stark, Holger
- Physics Reports, Vol. 351, Issue 6
Triclinic nematic colloidal crystals from competing elastic and electrostatic interactions
journal, March 2016
- Mundoor, H.; Senyuk, B.; Smalyukh, I. I.
- Science, Vol. 352, Issue 6281
Optical manipulation of colloids and defect structures in anisotropic liquid crystal fluids
journal, March 2011
- Trivedi, R. P.; Engström, D.; Smalyukh, I. I.
- Journal of Optics, Vol. 13, Issue 4
Nematic liquid crystal boojums with handles on colloidal handlebodies
journal, May 2013
- Liu, Qingkun; Senyuk, Bohdan; Tasinkevych, Mykola
- Proceedings of the National Academy of Sciences, Vol. 110, Issue 23
Linked topological colloids in a nematic host
journal, March 2015
- Martinez, Angel; Hermosillo, Leonardo; Tasinkevych, Mykola
- Proceedings of the National Academy of Sciences, Vol. 112, Issue 15
Gmsh: A 3-D finite element mesh generator with built-in pre- and post-processing facilities
journal, September 2009
- Geuzaine, Christophe; Remacle, Jean-François
- International Journal for Numerical Methods in Engineering, Vol. 79, Issue 11
Novel Colloidal Interactions in Anisotropic Fluids
journal, March 1997
- Poulin, P.
- Science, Vol. 275, Issue 5307
Stokes drag of spherical particles in a nematic environment at low Ericksen numbers
journal, August 2001
- Stark, Holger; Ventzki, Dieter
- Physical Review E, Vol. 64, Issue 3
Shape-Controlled Colloidal Interactions in Nematic Liquid Crystals
journal, November 2009
- Lapointe, C. P.; Mason, T. G.; Smalyukh, I. I.
- Science, Vol. 326, Issue 5956
Three-dimensional parallel particle manipulation and tracking by integrating holographic optical tweezers and engineered point spread functions
journal, January 2011
- Conkey, Donald B.; Trivedi, Rahul P.; Pavani, Sri Rama Prasanna
- Optics Express, Vol. 19, Issue 5
Brownian Motion of an Ellipsoid
journal, October 2006
- Han, Y.; Alsayed, A. M.; Nobili, M.
- Science, Vol. 314, Issue 5799
Liquid crystal boojum-colloids
journal, July 2012
- Tasinkevych, M.; Silvestre, N. M.; Telo da Gama, M. M.
- New Journal of Physics, Vol. 14, Issue 7
Hexadecapolar colloids
journal, February 2016
- Senyuk, Bohdan; Puls, Owen; Tovkach, Oleh M.
- Nature Communications, Vol. 7, Issue 1
Spontaneous skyrmion ground states in magnetic metals
journal, August 2006
- Rößler, U. K.; Bogdanov, A. N.; Pfleiderer, C.
- Nature, Vol. 442, Issue 7104, p. 797-801
Chiral colloidal clusters
journal, September 2008
- Zerrouki, D.; Baudry, J.; Pine, D.
- Nature, Vol. 455, Issue 7211
Effect of Collective Molecular Reorientations on Brownian Motion of Colloids in Nematic Liquid Crystal
journal, December 2013
- Turiv, T.; Lazo, I.; Brodin, A.
- Science, Vol. 342, Issue 6164
Ordering nano- and microparticles assemblies with liquid crystals
journal, December 2013
- Blanc, Christophe; Coursault, Delphine; Lacaze, Emmanuelle
- Liquid Crystals Reviews, Vol. 1, Issue 2
Generating the Hopf Fibration Experimentally in Nematic Liquid Crystals
journal, June 2013
- Chen, Bryan Gin-ge; Ackerman, Paul J.; Alexander, Gareth P.
- Physical Review Letters, Vol. 110, Issue 23
Modeling planar degenerate wetting and anchoring in nematic liquid crystals
journal, November 2005
- Fournier, J. -B; Galatola, P.
- Europhysics Letters (EPL), Vol. 72, Issue 3
Mutually tangled colloidal knots and induced defect loops in nematic fields
journal, January 2014
- Martinez, Angel; Ravnik, Miha; Lucero, Brice
- Nature Materials, Vol. 13, Issue 3
Fractal nematic colloids
journal, January 2017
- Hashemi, S. M.; Jagodič, U.; Mozaffari, M. R.
- Nature Communications, Vol. 8, Issue 1
Topological colloids
journal, December 2012
- Senyuk, Bohdan; Liu, Qingkun; He, Sailing
- Nature, Vol. 493, Issue 7431
Ring around the colloid
journal, January 2013
- Cavallaro Jr, Marcello; Gharbi, Mohamed A.; Beller, Daniel A.
- Soft Matter, Vol. 9, Issue 38
Monte Carlo simulation of topological defects in the nematic liquid crystal matrix around a spherical colloid particle
journal, November 1997
- Ruhwandl, R. W.; Terentjev, E. M.
- Physical Review E, Vol. 56, Issue 5
Nematic-isotropic phase transition in a liquid-crystal droplet
journal, March 1991
- Kralj, S.; Žumer, S.; Allender, D. W.
- Physical Review A, Vol. 43, Issue 6
Stokes Drag on a Sphere in a Nematic Liquid Crystal
journal, November 2004
- Loudet, J. C.
- Science, Vol. 306, Issue 5701
Optical manipulation and self-assembly of nematic colloids: colloidal crystals and superstructures
journal, June 2010
- Muševič, Igor
- Liquid Crystals Today, Vol. 19, Issue 1
Electrically Driven Multiaxis Rotational Dynamics of Colloidal Platelets in Nematic Liquid Crystals
journal, October 2010
- Lapointe, Clayton P.; Hopkins, Sharla; Mason, Thomas G.
- Physical Review Letters, Vol. 105, Issue 17
Topological defects and interactions in nematic emulsions
journal, January 1998
- Lubensky, T. C.; Pettey, David; Currier, Nathan
- Physical Review E, Vol. 57, Issue 1
Mesostructured Composite Materials with Electrically Tunable Upconverting Properties
journal, August 2015
- Mundoor, Haridas; Smalyukh, Ivan I.
- Small, Vol. 11, Issue 41
Cell polarisation in a bulk-surface model can be driven by both classic and non-classic Turing instability
journal, February 2021
- Borgqvist, Johannes; Malik, Adam; Lundholm, Carl
- npj Systems Biology and Applications, Vol. 7, Issue 1
Liquid Crystals
journal, January 1977
- Gray, G. W.; Leadbetter, A. J.
- Physics Bulletin, Vol. 28, Issue 1
Brownian Motion of an Ellipsoid
conference, January 2006
- Han, Y.; Alsayed, A. M.; Nobili, M.
- Laser Science, Frontiers in Optics
Ring around the colloid
text, January 2013
- Cavallaro, Marcello; Gharbi, Mohamed A.; Beller, Daniel A.
- arXiv
Effect of collective molecular reorientations on Brownian motion of colloids in nematic liquid crystal
text, January 2013
- Turiv, Taras; Lazo, Israel; Brodin, Alexander
- arXiv
Triclinic nematic colloidal crystals from competing elastic and electrostatic interactions
text, January 2016
- Mundoor, Haridas; Senyuk, Bohdan; Smalyukh, Ivan I.
- arXiv
Nematic liquid crystal boojums with handles on colloidal handlebodies
text, January 2016
- Liu, Qingkun; Senyuk, Bohdan; Tasinkevych, Mykola
- arXiv
Chiral colloidal clusters
journal, September 2008
- Zerrouki, D.; Baudry, J.; Pine, D.
- Nature, Vol. 455, Issue 7211
Linked topological colloids in a nematic host
journal, March 2015
- Martinez, Angel; Hermosillo, Leonardo; Tasinkevych, Mykola
- Proceedings of the National Academy of Sciences, Vol. 112, Issue 15
Ordering nano- and microparticles assemblies with liquid crystals
journal, December 2013
- Blanc, Christophe; Coursault, Delphine; Lacaze, Emmanuelle
- Liquid Crystals Reviews, Vol. 1, Issue 2
Quasi-two-dimensional diffusion of single ellipsoids: Aspect ratio and confinement effects
journal, July 2009
- Han, Yilong; Alsayed, Ahmed; Nobili, Maurizio
- Physical Review E, Vol. 80, Issue 1
Stokes Drag on a Sphere in a Nematic Liquid Crystal
journal, November 2004
- Loudet, J. C.
- Science, Vol. 306, Issue 5701
Effect of collective molecular reorientations on Brownian motion of colloids in nematic liquid crystal
text, January 2014
- Turiv, Taras; Lazo, Israel; Brodin, Alexander
- Unpublished
Triclinic nematic colloidal crystals from competing elastic and electrostatic interactions
text, January 2016
- Mundoor, Haridas; Senyuk, Bohdan; Smalyukh, Ivan I.
- arXiv
Diversity of knot solitons in liquid crystals manifested by linking of preimages in torons and hopfions
text, January 2017
- Ackerman, P. J.; Smalyukh, I. I.
- arXiv
Works referencing / citing this record:
Chirality-Based Biosensors
journal, November 2018
- Ma, Wei; Xu, Liguang; Wang, Libing
- Advanced Functional Materials, Vol. 29, Issue 1
Nature‐Inspired Emerging Chiral Liquid Crystal Nanostructures: From Molecular Self‐Assembly to DNA Mesophase and Nanocolloids
journal, August 2018
- Wang, Ling; Urbas, Augustine M.; Li, Quan
- Advanced Materials, Vol. 32, Issue 41
Supramolecular Chiral Nanoarchitectonics
journal, March 2020
- Ariga, Katsuhiko; Mori, Taizo; Kitao, Takashi
- Advanced Materials, Vol. 32, Issue 41
Colloidal interactions and unusual crystallization versus de-mixing of elastic multipoles formed by gold mesoflowers
journal, January 2020
- Yuan, Ye; Tasinkevych, Mykola; Smalyukh, Ivan I.
- Nature Communications, Vol. 11, Issue 1
Geometric stabilisation of topological defects on micro-helices and grooved rods in nematic liquid crystals
journal, January 2018
- Nikkhou, Maryam; Muševič, Igor
- Soft Matter, Vol. 14, Issue 48
Multifunctional chiral nematic cellulose nanocrystals/glycerol structural colored nanocomposites for intelligent responsive films, photonic inks and iridescent coatings
journal, January 2018
- Xu, Mingcong; Li, Wei; Ma, Chunhui
- Journal of Materials Chemistry C, Vol. 6, Issue 20
Graphene-based chiral liquid crystal materials for optical applications
journal, January 2019
- Zhai, Fei; Feng, Yiyu; Zhou, Kang
- Journal of Materials Chemistry C, Vol. 7, Issue 8
Optically active and photoswitchable Tröger's base analogs
journal, January 2019
- Kazem-Rostami, Masoud
- New Journal of Chemistry, Vol. 43, Issue 20
Defect-mediated colloidal interactions in a nematic-phase discotic solvent
journal, January 2019
- González-Martínez, Aurora D.; Chávez-Rojo, Marco A.; Sambriski, Edward J.
- RSC Advances, Vol. 9, Issue 57
Morphological analysis of chiral rod clusters from a coarse-grained single-site chiral potential
journal, January 2019
- Sutherland, B. J.; Olesen, S. W.; Kusumaatmaja, H.
- Soft Matter, Vol. 15, Issue 40
Soft matter from liquid crystals
journal, January 2019
- Kim, Young-Ki; Noh, JungHyun; Nayani, Karthik
- Soft Matter, Vol. 15, Issue 35
Brownian Dynamics of Particles “Dressed” by Chiral Director Configurations in Lyotropic Chromonic Liquid Crystals
journal, October 2018
- Martinez, Angel; Collings, Peter J.; Yodh, A. G.
- Physical Review Letters, Vol. 121, Issue 17
Curvature-Induced Twist in Homeotropic Nematic Tori
journal, December 2018
- Ellis, Perry W.; Nayani, Karthik; McInerney, James P.
- Physical Review Letters, Vol. 121, Issue 24
Interactions, topology and photonic properties of liquid crystal colloids and dispersions
journal, March 2019
- Muševič, Igor
- The European Physical Journal Special Topics, Vol. 227, Issue 17
Colloidal plasmonic DNA-origami with photo-switchable chirality in liquid crystals
journal, January 2019
- Liu, Qingkun; Kuzyk, Anton; Endo, Masayuki
- Optics Letters, Vol. 44, Issue 11
Morphological analysis of chiral rod clusters from a coarse-grained single-site chiral potential.
text, January 2019
- Sutherland, Bj; Olesen, Sw; Kusumaatmaja, H.
- Apollo - University of Cambridge Repository
Colloidal interactions and unusual crystallization versus de-mixing of elastic multipoles formed by gold mesoflowers
text, January 2020
- Yuan, Ye; Tasinkevych, Mykola; Smalyukh, Ivan I.
- arXiv
Additive-Free MXene Liquid Crystals and Fibers
journal, February 2020
- Zhang, Jizhen; Uzun, Simge; Seyedin, Shayan
- ACS Central Science, Vol. 6, Issue 2
Colloidal interactions and unusual crystallization versus de-mixing of elastic multipoles formed by gold mesoflowers
journal, January 2020
- Yuan, Ye; Tasinkevych, Mykola; Smalyukh, Ivan I.
- Nature Communications, Vol. 11, Issue 1
Liquid Crystal Enabled Dynamic Nanodevices
journal, October 2018
- Ma, Zhenhe; Meng, Xianghe; Liu, Xiaodi
- Nanomaterials, Vol. 8, Issue 11