Perovskite magnet with quantum mechanical glassiness
Abstract
Magnetic materials of strongly correlated origin are at the forefront of research in the exploration of new quantum mechanical properties involving spin and charges. Quantum magnetic material with certain intrinsic functionalities, such as continuously fluctuating spins to the lowest accessible temperature - reminiscing a liquid pattern, is argued to form a new phase of matter. Envisaging a phenomenon where the continuously fluctuating spins are also randomly frozen in space, can diminish the distinction between the two opposite extremes of quantum and classical magnetism. Here, we report new evidence in this regard where the coexistence of quantum spin continuum with a spin glass order in Co-doped CaRuO3 perovskite is demonstrated. In experimental investigations of Co-doped CaRuO3 perovskite, we find that (a) a continuum spectrum in the energy-momentum space, due to the uncorrelated spin fluctuations, persists across the weak spin glass transition at 23 K and (b) the quantum fluctuation of magnetic moment is spatially confined to individual sites only, thereby making it an extremely local event. Thus, the fluctuating spins, at a given time, are also randomly frozen macroscopically. The experimental observations suggest the discovery of a new magnetic phase at the cross-road of classical and quantum physics in strongly correlated perovskite materials.
- Authors:
-
[1];
[4];
- Univ. of Missouri, Columbia, MO (United States)
- National Inst. of Standards and Technology (NIST), Gaithersburg, MD (United States). Center for Neutron Research; Univ. of Maryland, College Park, MD (United States)
- National Inst. of Standards and Technology (NIST), Gaithersburg, MD (United States). Center for Neutron Research
- Rzeszów Univ. of Technology, Rzeszów (Poland)
- Max-Planck-Inst. für Mikrostrukturphysik, Halle (Germany)
- Publication Date:
- Research Org.:
- Univ. of Missouri, Columbia, MO (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES); National Science Center in Poland
- OSTI Identifier:
- 1594066
- Alternate Identifier(s):
- OSTI ID: 1605613
- Grant/Contract Number:
- SC0014461; DEC-2017/27/B/ST3/02881
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Materials Today Physics
- Additional Journal Information:
- Journal Volume: 12; Journal ID: ISSN 2542-5293
- Publisher:
- Elsevier
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; Perovskite; Magnetic quantum fluctuation; Spin glass; Quantum spin liquid
Citation Formats
Chen, Y., Dahal, A., Rodriguez-Rivera, J. A., Xu, G., Heitmann, T. W., Dugaev, V., Ernst, A., and Singh, D. K. Perovskite magnet with quantum mechanical glassiness. United States: N. p., 2019.
Web. doi:10.1016/j.mtphys.2019.100163.
Chen, Y., Dahal, A., Rodriguez-Rivera, J. A., Xu, G., Heitmann, T. W., Dugaev, V., Ernst, A., & Singh, D. K. Perovskite magnet with quantum mechanical glassiness. United States. https://doi.org/10.1016/j.mtphys.2019.100163
Chen, Y., Dahal, A., Rodriguez-Rivera, J. A., Xu, G., Heitmann, T. W., Dugaev, V., Ernst, A., and Singh, D. K. Mon .
"Perovskite magnet with quantum mechanical glassiness". United States. https://doi.org/10.1016/j.mtphys.2019.100163. https://www.osti.gov/servlets/purl/1594066.
@article{osti_1594066,
title = {Perovskite magnet with quantum mechanical glassiness},
author = {Chen, Y. and Dahal, A. and Rodriguez-Rivera, J. A. and Xu, G. and Heitmann, T. W. and Dugaev, V. and Ernst, A. and Singh, D. K.},
abstractNote = {Magnetic materials of strongly correlated origin are at the forefront of research in the exploration of new quantum mechanical properties involving spin and charges. Quantum magnetic material with certain intrinsic functionalities, such as continuously fluctuating spins to the lowest accessible temperature - reminiscing a liquid pattern, is argued to form a new phase of matter. Envisaging a phenomenon where the continuously fluctuating spins are also randomly frozen in space, can diminish the distinction between the two opposite extremes of quantum and classical magnetism. Here, we report new evidence in this regard where the coexistence of quantum spin continuum with a spin glass order in Co-doped CaRuO3 perovskite is demonstrated. In experimental investigations of Co-doped CaRuO3 perovskite, we find that (a) a continuum spectrum in the energy-momentum space, due to the uncorrelated spin fluctuations, persists across the weak spin glass transition at TG≃ 23 K and (b) the quantum fluctuation of magnetic moment is spatially confined to individual sites only, thereby making it an extremely local event. Thus, the fluctuating spins, at a given time, are also randomly frozen macroscopically. The experimental observations suggest the discovery of a new magnetic phase at the cross-road of classical and quantum physics in strongly correlated perovskite materials.},
doi = {10.1016/j.mtphys.2019.100163},
journal = {Materials Today Physics},
number = ,
volume = 12,
place = {United States},
year = {Mon Dec 02 00:00:00 EST 2019},
month = {Mon Dec 02 00:00:00 EST 2019}
}
Free Publicly Available Full Text
Publisher's Version of Record
Other availability
Search WorldCat to find libraries that may hold this journal
Cited by: 1 work
Citation information provided by
Web of Science
Web of Science
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
The perovskite structure—a review of its role in ceramic science and technology
journal, November 2000
- Bhalla, A. S.; Guo, Ruyan; Roy, Rustum
- Materials Research Innovations, Vol. 4, Issue 1
Review of the magnetocaloric effect in manganite materials
journal, January 2007
- Phan, Manh-Huong; Yu, Seong-Cho
- Journal of Magnetism and Magnetic Materials, Vol. 308, Issue 2
Possible highT c superconductivity in the Ba?La?Cu?O system
journal, June 1986
- Bednorz, J. G.; M�ller, K. A.
- Zeitschrift f�r Physik B Condensed Matter, Vol. 64, Issue 2
Multiferroics: a magnetic twist for ferroelectricity
journal, January 2007
- Cheong, Sang-Wook; Mostovoy, Maxim
- Nature Materials, Vol. 6, Issue 1
Quantum Magnetism of CuGe
journal, August 1995
- Castilla, G.; Chakravarty, S.; Emery, V. J.
- Physical Review Letters, Vol. 75, Issue 9
Magnetic fluctuations driven insulator-to-metal transition in Ca(Ir1−xRux)O3
journal, December 2015
- Gunasekera, J.; Harriger, L.; Dahal, A.
- Scientific Reports, Vol. 5, Issue 1
Tomonaga–Luttinger liquid behavior and spinon confinement in YbAlO3
journal, February 2019
- Wu, L. S.; Nikitin, S. E.; Wang, Z.
- Nature Communications, Vol. 10, Issue 1
Quantum magnetism and criticality
journal, March 2008
- Sachdev, Subir
- Nature Physics, Vol. 4, Issue 3
From high temperature superconductivity to quantum spin liquid: progress in strong correlation physics
journal, December 2007
- Lee, Patrick A.
- Reports on Progress in Physics, Vol. 71, Issue 1
Experimental Realization of a 2D Fractional Quantum Spin Liquid
journal, February 2001
- Coldea, R.; Tennant, D. A.; Tsvelik, A. M.
- Physical Review Letters, Vol. 86, Issue 7
Exact Spin Liquid Ground States of the Quantum Dimer Model on the Square and Honeycomb Lattices
journal, June 2012
- Yao, Hong; Kivelson, Steven A.
- Physical Review Letters, Vol. 108, Issue 24
Spin glasses: Experimental facts, theoretical concepts, and open questions
journal, October 1986
- Binder, K.; Young, A. P.
- Reviews of Modern Physics, Vol. 58, Issue 4
Quenching of the nonlinear susceptibility at a T =0 spin glass transition
journal, September 1993
- Wu, Wenhao; Bitko, D.; Rosenbaum, T. F.
- Physical Review Letters, Vol. 71, Issue 12
Solvable spin glass of quantum rotors
journal, June 1993
- Ye, J.; Sachdev, S.; Read, N.
- Physical Review Letters, Vol. 70, Issue 25
Spin glasses enter the quantum regime
journal, October 1994
- Sachdev, Subir
- Physics World, Vol. 7, Issue 10
Quasilocal critical nature of cooperative paramagnetic fluctuations in metal
journal, June 2015
- Gunasekera, J.; Harriger, L.; Heitmann, T.
- Physical Review B, Vol. 91, Issue 24
Physical Properties of Single-Crystalline CaRuO 3 Grown by a Floating-Zone Method
journal, January 2009
- Kikugawa, Naoki; Balicas, Luis; Peter Mackenzie, Andrew
- Journal of the Physical Society of Japan, Vol. 78, Issue 1
Spin fluctuations in the ruthenium oxides and probed by Ru NMR
journal, November 1999
- Mukuda, H.; Ishida, K.; Kitaoka, Y.
- Physical Review B, Vol. 60, Issue 17
Electronic structure and magnetism in Ru-based perovskites
journal, August 1997
- Mazin, I. I.; Singh, D. J.
- Physical Review B, Vol. 56, Issue 5
The effect of Ru-site dopants on the magnetic properties of CaRuO 3
journal, August 2001
- He, T.; Cava, R. J.
- Journal of Physics: Condensed Matter, Vol. 13, Issue 36
Evolution of transport and magnetic properties near the ferromagnetic quantum critical point in the series
journal, October 2004
- Khalifah, P.; Ohkubo, I.; Christen, H. M.
- Physical Review B, Vol. 70, Issue 13
Quantum Magnetic Properties in Perovskite with Anderson Localized Artificial Spin-1/2
journal, March 2018
- Gunasekera, Jagath; Dahal, Ashutosh; Chen, Yiyao
- Advanced Science, Vol. 5, Issue 5
Thermodynamic properties of perovskite ARuO3 (A=Ca, Sr, and Ba) single crystals
journal, April 1997
- Shepard, M.; McCall, S.; Cao, G.
- Journal of Applied Physics, Vol. 81, Issue 8
Gapless quantum spin liquid, stripe, and antiferromagnetic phases in frustrated Hubbard models in two dimensions
journal, July 2006
- Mizusaki, Takahiro; Imada, Masatoshi
- Physical Review B, Vol. 74, Issue 1
Quantum spin liquid emerging in two-dimensional correlated Dirac fermions
journal, April 2010
- Meng, Z. Y.; Lang, T. C.; Wessel, S.
- Nature, Vol. 464, Issue 7290
Mott Transition between a Spin-Liquid Insulator and a Metal in Three Dimensions
journal, May 2009
- Podolsky, Daniel; Paramekanti, Arun; Kim, Yong Baek
- Physical Review Letters, Vol. 102, Issue 18
Nonconventional Spin Glass Transition in a Chemically Ordered Pyrochlore
journal, December 2012
- Singh, D. K.; Lee, Y. S.
- Physical Review Letters, Vol. 109, Issue 24
Low temperature specific heat of Ni 3 Al and Ni 3 Ga
journal, May 1973
- Dood, W. de; Chatel, P. F. de
- Journal of Physics F: Metal Physics, Vol. 3, Issue 5
Spin-glass state induced by cobalt substitution in CaRuO 3
journal, April 2007
- Bréard, Y.; Hardy, V.; Raveau, B.
- Journal of Physics: Condensed Matter, Vol. 19, Issue 21
Angular dependence of the magnetic susceptibility in the itinerant metamagnet
journal, June 2003
- Grigera, S. A.; Borzi, R. A.; Mackenzie, A. P.
- Physical Review B, Vol. 67, Issue 21
The low temperature magnetic excitation spectrum of A Mn spin glass alloy
journal, December 1979
- Scheuer, H.; Suck, J. -B.; Murani, A. P.
- Journal of Magnetism and Magnetic Materials, Vol. 14, Issue 2-3
Magnetic excitation in CuMn spin glass alloy
journal, April 1985
- Tsunoda, Y.; Kunitomi, N.; Cable, J. W.
- Journal of Applied Physics, Vol. 57, Issue 8
Non-Fermi-liquid behavior in single-crystal CaRuO3: Comparison to ferromagnetic SrRuO3
journal, November 2008
- Cao, G.; Korneta, O.; Chikara, S.
- Solid State Communications, Vol. 148, Issue 7-8
Inelastic neutron scattering studies of II‐VI diluted magnetic semiconductors (invited)
journal, May 1990
- Giebultowicz, T. M.; Rhyne, J. J.; Furdyna, J. K.
- Journal of Applied Physics, Vol. 67, Issue 9
Magnetic diffuse scattering in disordered systems studied by neutron polarization analysis (invited)
journal, May 2000
- Stewart, J. R.; Andersen, K. H.; Cywinski, R.
- Journal of Applied Physics, Vol. 87, Issue 9
Neutron inelastic scattering from isolated clusters of magnetic ions
journal, December 1979
- Furrer, Albert; Güdel, Hans U.
- Journal of Magnetism and Magnetic Materials, Vol. 14, Issue 2-3
Muon spin relaxation investigation of the spin dynamics of geometrically frustrated antiferromagnets and
journal, October 1996
- Dunsiger, S. R.; Kiefl, R. F.; Chow, K. H.
- Physical Review B, Vol. 54, Issue 13
Field-induced quantum fluctuations in the heavy fermion superconductor CeCu2Ge2
journal, October 2011
- Singh, D. K.; Thamizhavel, A.; Lynn, J. W.
- Scientific Reports, Vol. 1, Issue 1
Magnetic cluster excitations
journal, March 2013
- Furrer, Albert; Waldmann, Oliver
- Reviews of Modern Physics, Vol. 85, Issue 1