Blue-Light-Excitable, Quantum Yield Enhanced, Yellow-Emitting, Zirconium-Based Metal–Organic Framework Phosphors Formed by Immobilizing Organic Chromophores

Yu, Liang; Wang, Hao; Liu, Wei; Teat, Simon J.; Li, Jing

doi:10.1021/acs.cgd.9b01284

Title: Blue-Light-Excitable, Quantum Yield Enhanced, Yellow-Emitting, Zirconium-Based Metal–Organic Framework Phosphors Formed by Immobilizing Organic Chromophores

Abstract

Here, we demonstrate that two new zirconium-based metal-organic frameworks can be constructed from organic chromophore ligands. Both compounds show intense yellow emission when excited by blue light, with a notable fluorescence red shift and quantum yield enhancement compared to the organic chromophore.

Authors:

Yu, Liang ^[1];

^[1]; Liu, Wei ^[1]; Teat, Simon J. ^[2];

^[1]

Shenzhen Polytechnic (China)
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Advanced Light Source (ALS)

Publication Date:: Mon Oct 28 00:00:00 EDT 2019

Research Org.:: Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI Identifier:: 1581611

Grant/Contract Number:: AC02-05CH11231

Resource Type:: Accepted Manuscript

Journal Name:: Crystal Growth and Design

Additional Journal Information:: Journal Volume: 19; Journal Issue: 12; Journal ID: ISSN 1528-7483

Publisher:: American Chemical Society

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE; phosphors; ligands; metal organic frameworks; chromophores energy

Citation Formats


                    Yu, Liang, Wang, Hao, Liu, Wei, Teat, Simon J., and Li, Jing. Blue-Light-Excitable, Quantum Yield Enhanced, Yellow-Emitting, Zirconium-Based Metal–Organic Framework Phosphors Formed by Immobilizing Organic Chromophores.  United States: N. p., 2019. 
Web.  doi:10.1021/acs.cgd.9b01284.

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                    Yu, Liang, Wang, Hao, Liu, Wei, Teat, Simon J., & Li, Jing. Blue-Light-Excitable, Quantum Yield Enhanced, Yellow-Emitting, Zirconium-Based Metal–Organic Framework Phosphors Formed by Immobilizing Organic Chromophores.  United States.  https://doi.org/10.1021/acs.cgd.9b01284

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                    Yu, Liang, Wang, Hao, Liu, Wei, Teat, Simon J., and Li, Jing. Mon .  
"Blue-Light-Excitable, Quantum Yield Enhanced, Yellow-Emitting, Zirconium-Based Metal–Organic Framework Phosphors Formed by Immobilizing Organic Chromophores".  United States.  https://doi.org/10.1021/acs.cgd.9b01284.  https://www.osti.gov/servlets/purl/1581611.

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@article{osti_1581611,

  title        = {Blue-Light-Excitable, Quantum Yield Enhanced, Yellow-Emitting, Zirconium-Based Metal–Organic Framework Phosphors Formed by Immobilizing Organic Chromophores},

  author       = {Yu, Liang and Wang, Hao and Liu, Wei and Teat, Simon J. and Li, Jing},

  abstractNote = {Here, we demonstrate that two new zirconium-based metal-organic frameworks can be constructed from organic chromophore ligands. Both compounds show intense yellow emission when excited by blue light, with a notable fluorescence red shift and quantum yield enhancement compared to the organic chromophore.},

  doi          = {10.1021/acs.cgd.9b01284},

  journal      = {Crystal Growth and Design},

  number       = 12,

  volume       = 19,

  place        = {United States},

  year         = {Mon Oct 28 00:00:00 EDT 2019},

  month        = {Mon Oct 28 00:00:00 EDT 2019}

}

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https://doi.org/10.1021/acs.cgd.9b01284

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Title: Blue-Light-Excitable, Quantum Yield Enhanced, Yellow-Emitting, Zirconium-Based Metal–Organic Framework Phosphors Formed by Immobilizing Organic Chromophores

Abstract

Citation Formats

Thermal design and analysis of multi-chip LED module with ceramic substrate journal, December 2010

Chromophore-Based Luminescent Metal–Organic Frameworks as Lighting Phosphors journal, May 2016

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Turn-On Fluorescence in Tetraphenylethylene-Based Metal–Organic Frameworks: An Alternative to Aggregation-Induced Emission journal, December 2011

Solution Processable MOF Yellow Phosphor with Exceptionally High Quantum Efficiency journal, November 2014

Achieving exceptionally high luminescence quantum efficiency by immobilizing an AIE molecular chromophore into a metal–organic framework journal, January 2015

Metal–organic frameworks: functional luminescent and photonic materials for sensing applications journal, January 2017

Luminescent metal–organic frameworks and coordination polymers as alternative phosphors for energy efficient lighting devices journal, October 2018

AIE-active Metal-organic Coordination Complexes Based on Tetraphenylethylene Unit and Their Applications journal, January 2019

Immobilization of AIEgens into metal-organic frameworks: Ligand design, emission behavior, and applications journal, March 2017

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