Microwave assisted synthesis of heterometallic 3d–4f M4 Ln complexes
Abstract
Here, we describe the synthesis and magnetic properties of a series of 3d–4f complexes of general formula [M4Ln(OH)2(chp)4(SALOH)5(H2O)(MeCN)(Solv)] (Solv = MeOH, MeCN, H2O; chp stands for deprotonated 6-chloro-2-hydroxypyridine (C5H3ClNO), SALOH stands for monodeprotonated 3,5-ditert-butylsalicylic acid (C15H21O3)) obtained by a solvent-free microwave assisted synthesis method. The Ni(II) complexes (Ni4Gd, Solv = MeOH; Ni4Dy, Solv = MeCN) are not SMMs in the absence of an applied dc field. The replacement of Ni(II) by Co(II) (Co4La, Solv = MeOH; Co4Gd, Solv = H2O; Co4Gd-MeCN, Solv = MeCN; Co4Tb, Solv = MeOH; Co4Dy, Solv = H2O) results in improved SMM properties.
- Authors:
-
- Univ. de Barcelona (Spain)
- Indian Inst. of Technology Bombay, Mumbai (India)
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Advanced Light Source (ALS)
- Publication Date:
- Research Org.:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES); Spanish Government
- OSTI Identifier:
- 1581606
- Grant/Contract Number:
- AC02-05CH11231; CTQ2015-68370-P
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Dalton Transactions
- Additional Journal Information:
- Journal Volume: 48; Journal Issue: 33; Journal ID: ISSN 1477-9226
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Rosado Piquer, L., Dey, S., Castilla-Amorós, L., Teat, S. J., Cirera, J., Rajaraman, G., and Sañudo, E. C. Microwave assisted synthesis of heterometallic 3d–4f M4 Ln complexes. United States: N. p., 2019.
Web. doi:10.1039/c9dt02567g.
Rosado Piquer, L., Dey, S., Castilla-Amorós, L., Teat, S. J., Cirera, J., Rajaraman, G., & Sañudo, E. C. Microwave assisted synthesis of heterometallic 3d–4f M4 Ln complexes. United States. https://doi.org/10.1039/c9dt02567g
Rosado Piquer, L., Dey, S., Castilla-Amorós, L., Teat, S. J., Cirera, J., Rajaraman, G., and Sañudo, E. C. Fri .
"Microwave assisted synthesis of heterometallic 3d–4f M4 Ln complexes". United States. https://doi.org/10.1039/c9dt02567g. https://www.osti.gov/servlets/purl/1581606.
@article{osti_1581606,
title = {Microwave assisted synthesis of heterometallic 3d–4f M4 Ln complexes},
author = {Rosado Piquer, L. and Dey, S. and Castilla-Amorós, L. and Teat, S. J. and Cirera, J. and Rajaraman, G. and Sañudo, E. C.},
abstractNote = {Here, we describe the synthesis and magnetic properties of a series of 3d–4f complexes of general formula [M4Ln(OH)2(chp)4(SALOH)5(H2O)(MeCN)(Solv)] (Solv = MeOH, MeCN, H2O; chp stands for deprotonated 6-chloro-2-hydroxypyridine (C5H3ClNO), SALOH stands for monodeprotonated 3,5-ditert-butylsalicylic acid (C15H21O3)) obtained by a solvent-free microwave assisted synthesis method. The Ni(II) complexes (Ni4Gd, Solv = MeOH; Ni4Dy, Solv = MeCN) are not SMMs in the absence of an applied dc field. The replacement of Ni(II) by Co(II) (Co4La, Solv = MeOH; Co4Gd, Solv = H2O; Co4Gd-MeCN, Solv = MeCN; Co4Tb, Solv = MeOH; Co4Dy, Solv = H2O) results in improved SMM properties.},
doi = {10.1039/c9dt02567g},
journal = {Dalton Transactions},
number = 33,
volume = 48,
place = {United States},
year = {Fri Jul 19 00:00:00 EDT 2019},
month = {Fri Jul 19 00:00:00 EDT 2019}
}
Web of Science
Figures / Tables:
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Works referencing / citing this record:
Coordination control of a semicarbazide Schiff base ligand for spontaneous aggregation of a Ni 2 Ln 2 cubane family: influence of ligand arms and carboxylate bridges on the organization of the magnetic core
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