Isotopic effect on electrochemical CO2 reduction activity and selectivity in H2O- and D2O-based electrolytes over palladium
Abstract
The isotopic effect on the electrochemical CO2 reduction reaction (CO2RR) is investigated in this study. Here, a higher CO2RR selectivity over its competing hydrogen evolution reaction was observed in D2O-based electrolytes compared with the H2O-based counterparts, which can be attributed to the lower [D+] concentration than [H+].
- Authors:
-
- Columbia Univ., New York, NY (United States)
- Brookhaven National Lab. (BNL), Upton, NY (United States)
- Columbia Univ., New York, NY (United States); Brookhaven National Lab. (BNL), Upton, NY (United States)
- Publication Date:
- Research Org.:
- Brookhaven National Laboratory (BNL), Upton, NY (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1580238
- Alternate Identifier(s):
- OSTI ID: 1576829
- Report Number(s):
- BNL-212467-2019-JAAM
Journal ID: ISSN 1359-7345; CHCOFS
- Grant/Contract Number:
- SC0012704; FG02-13ER16381; AC02-06CH11357; NRF-2017R1A6A3A03004202; SC0009476
- Resource Type:
- Accepted Manuscript
- Journal Name:
- ChemComm
- Additional Journal Information:
- Journal Volume: 56; Journal Issue: 1; Journal ID: ISSN 1359-7345
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE
Citation Formats
Lee, Ji Hoon, Tackett, Brian M., Xie, Zhenhua, Hwang, Sooyeon, and Chen, Jingguang G. Isotopic effect on electrochemical CO2 reduction activity and selectivity in H2O- and D2O-based electrolytes over palladium. United States: N. p., 2019.
Web. doi:10.1039/C9CC07611E.
Lee, Ji Hoon, Tackett, Brian M., Xie, Zhenhua, Hwang, Sooyeon, & Chen, Jingguang G. Isotopic effect on electrochemical CO2 reduction activity and selectivity in H2O- and D2O-based electrolytes over palladium. United States. https://doi.org/10.1039/C9CC07611E
Lee, Ji Hoon, Tackett, Brian M., Xie, Zhenhua, Hwang, Sooyeon, and Chen, Jingguang G. Thu .
"Isotopic effect on electrochemical CO2 reduction activity and selectivity in H2O- and D2O-based electrolytes over palladium". United States. https://doi.org/10.1039/C9CC07611E. https://www.osti.gov/servlets/purl/1580238.
@article{osti_1580238,
title = {Isotopic effect on electrochemical CO2 reduction activity and selectivity in H2O- and D2O-based electrolytes over palladium},
author = {Lee, Ji Hoon and Tackett, Brian M. and Xie, Zhenhua and Hwang, Sooyeon and Chen, Jingguang G.},
abstractNote = {The isotopic effect on the electrochemical CO2 reduction reaction (CO2RR) is investigated in this study. Here, a higher CO2RR selectivity over its competing hydrogen evolution reaction was observed in D2O-based electrolytes compared with the H2O-based counterparts, which can be attributed to the lower [D+] concentration than [H+].},
doi = {10.1039/C9CC07611E},
journal = {ChemComm},
number = 1,
volume = 56,
place = {United States},
year = {Thu Nov 21 00:00:00 EST 2019},
month = {Thu Nov 21 00:00:00 EST 2019}
}
Free Publicly Available Full Text
Publisher's Version of Record
Other availability
Cited by: 13 works
Citation information provided by
Web of Science
Web of Science
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Greenhouse-gas emission targets for limiting global warming to 2 °C
journal, April 2009
- Meinshausen, Malte; Meinshausen, Nicolai; Hare, William
- Nature, Vol. 458, Issue 7242
Net reduction of CO2 via its thermocatalytic and electrocatalytic transformation reactions in standard and hybrid processes
journal, April 2019
- Tackett, Brian M.; Gomez, Elaine; Chen, Jingguang G.
- Nature Catalysis, Vol. 2, Issue 5
Defining a Materials Database for the Design of Copper Binary Alloy Catalysts for Electrochemical CO 2 Conversion
journal, January 2018
- Lee, Chan Woo; Yang, Ki Dong; Nam, Dae-Hyun
- Advanced Materials, Vol. 30, Issue 42
Bimetallic Electrocatalysts for CO2 Reduction
journal, October 2018
- Zhu, Wenlei; Tackett, Brian M.; Chen, Jingguang G.
- Topics in Current Chemistry, Vol. 376, Issue 6
Tuning the activity and selectivity of electroreduction of CO2 to synthesis gas using bimetallic catalysts
journal, August 2019
- Lee, Ji Hoon; Kattel, Shyam; Jiang, Zhao
- Nature Communications, Vol. 10, Issue 1
Electrochemical reduction of CO 2 to synthesis gas with controlled CO/H 2 ratios
journal, January 2017
- Sheng, Wenchao; Kattel, Shyam; Yao, Siyu
- Energy & Environmental Science, Vol. 10, Issue 5
Switchable CO2 electroreduction via engineering active phases of Pd nanoparticles
journal, April 2017
- Gao, Dunfeng; Zhou, Hu; Cai, Fan
- Nano Research, Vol. 10, Issue 6
Tuning the Catalytic Activity and Selectivity of Cu for CO 2 Electroreduction in the Presence of Halides
journal, February 2016
- Varela, Ana Sofia; Ju, Wen; Reier, Tobias
- ACS Catalysis, Vol. 6, Issue 4
Understanding the Role of Functional Groups in Polymeric Binder for Electrochemical Carbon Dioxide Reduction on Gold Nanoparticles
journal, September 2018
- Lee, Ji Hoon; Kattel, Shyam; Xie, Zhenhua
- Advanced Functional Materials, Vol. 28, Issue 45
Achieving Selective and Efficient Electrocatalytic Activity for CO 2 Reduction Using Immobilized Silver Nanoparticles
journal, October 2015
- Kim, Cheonghee; Jeon, Hyo Sang; Eom, Taedaehyeong
- Journal of the American Chemical Society, Vol. 137, Issue 43
The Role of Adsorbed CN and Cl on an Au Electrode for Electrochemical CO 2 Reduction
journal, January 2018
- Cho, Minhyung; Song, Jun Tae; Back, Seoin
- ACS Catalysis, Vol. 8, Issue 2
Effect of Chloride Anions on the Synthesis and Enhanced Catalytic Activity of Silver Nanocoral Electrodes for CO 2 Electroreduction
journal, August 2015
- Hsieh, Yu-Chi; Senanayake, Sanjaya D.; Zhang, Yu
- ACS Catalysis, Vol. 5, Issue 9
Promoter Effects of Alkali Metal Cations on the Electrochemical Reduction of Carbon Dioxide
journal, August 2017
- Resasco, Joaquin; Chen, Leanne D.; Clark, Ezra
- Journal of the American Chemical Society, Vol. 139, Issue 32
Hydrolysis of Electrolyte Cations Enhances the Electrochemical Reduction of CO 2 over Ag and Cu
journal, September 2016
- Singh, Meenesh R.; Kwon, Youngkook; Lum, Yanwei
- Journal of the American Chemical Society, Vol. 138, Issue 39
A formula for correlating p K a values determined in D 2 O and H 2 O
journal, January 2004
- Krȩżel, Artur; Bal, Wojciech
- Journal of Inorganic Biochemistry, Vol. 98, Issue 1
ATHENA , ARTEMIS , HEPHAESTUS : data analysis for X-ray absorption spectroscopy using IFEFFIT
journal, June 2005
- Ravel, B.; Newville, M.
- Journal of Synchrotron Radiation, Vol. 12, Issue 4
Monodisperse Au Nanoparticles for Selective Electrocatalytic Reduction of CO 2 to CO
journal, October 2013
- Zhu, Wenlei; Michalsky, Ronald; Metin, Önder
- Journal of the American Chemical Society, Vol. 135, Issue 45
An In Situ Surface-Enhanced Infrared Absorption Spectroscopy Study of Electrochemical CO 2 Reduction: Selectivity Dependence on Surface C-Bound and O-Bound Reaction Intermediates
journal, December 2018
- Katayama, Yu; Nattino, Francesco; Giordano, Livia
- The Journal of Physical Chemistry C, Vol. 123, Issue 10
An In Situ Surface-Enhanced Infrared Absorption Spectroscopy Study of Electrochemical CO2 Reduction: Selectivity Dependence on Surface C-Bound and O-Bound Reaction Intermediates
text, January 2019
- Katayama, Yu; Nattino, Francesco; Giordano, Livia
- arXiv