Inkjet Printing of Magnetic Particles Toward Anisotropic Magnetic Properties
Abstract
Unique properties of one-dimensional assemblies of particles have attracted great attention during the past decades, particularly with respect to the potential for anisotropic magnetism. Patterned films can be created using inkjet printing; however, drying of particle-laden colloidal droplets on solid surfaces is usually accompanied by the well-known coffee-ring effect, deteriorating both the uniformity and resolution of the printed configurations. Here, we examine the effect of externally applied magnetic field on particle deposition patterns. Ferromagnetic Gd5Si4 particles were formulated in terpineol oil and directly deposited via magnetic field-assisted inkjet printing on a photopaper to generate patterned films with suppressed coffee-ring effect. The particle deposition morphology is determined by both solvent imbibition and particle-magnetic field interactions. Three characteristic times are considered, namely, the critical time for solvent imbibition into the substrate (tim), the time it takes for particles to form chains in the presence of the magnetic field (tch), and the time in which the particles reach the substrate in the direction normal to the substrate (tpz). The characteristic time ratios (tpz/tim) and (tpz/tch) determine the final deposition morphology in the presence of magnetic field. Finally, the ability to control particle deposition and assembly, thus tuning the magnetic anisotropic properties of nanostructuredmore »
- Authors:
-
- Virginia Commonwealth Univ., Richmond, VA (United States). Dept. of Mechanical and Nuclear Engineering
- Iowa State Univ., Ames, IA (United States); Ames Lab., Ames, IA (United States). Division of Materials Science and Engineering
- Iowa State Univ., Ames, IA (United States). Dept. of Materials Science and Engineering; Ames Lab., Ames, IA (United States). Division of Materials Science and Engineering;
- Publication Date:
- Research Org.:
- Ames Laboratory (AMES), Ames, IA (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1574819
- Report Number(s):
- IS-J-10081
Journal ID: ISSN 2045-2322
- Grant/Contract Number:
- AC02-07CH11358
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Scientific Reports
- Additional Journal Information:
- Journal Volume: 9; Journal Issue: 1; Journal ID: ISSN 2045-2322
- Publisher:
- Nature Publishing Group
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 42 ENGINEERING
Citation Formats
Al-Milaji, Karam Nashwan, Hadimani, Ravi L., Gupta, Shalabh, Pecharsky, Vitalij K., and Zhao, Hong. Inkjet Printing of Magnetic Particles Toward Anisotropic Magnetic Properties. United States: N. p., 2019.
Web. doi:10.1038/s41598-019-52699-0.
Al-Milaji, Karam Nashwan, Hadimani, Ravi L., Gupta, Shalabh, Pecharsky, Vitalij K., & Zhao, Hong. Inkjet Printing of Magnetic Particles Toward Anisotropic Magnetic Properties. United States. https://doi.org/10.1038/s41598-019-52699-0
Al-Milaji, Karam Nashwan, Hadimani, Ravi L., Gupta, Shalabh, Pecharsky, Vitalij K., and Zhao, Hong. Thu .
"Inkjet Printing of Magnetic Particles Toward Anisotropic Magnetic Properties". United States. https://doi.org/10.1038/s41598-019-52699-0. https://www.osti.gov/servlets/purl/1574819.
@article{osti_1574819,
title = {Inkjet Printing of Magnetic Particles Toward Anisotropic Magnetic Properties},
author = {Al-Milaji, Karam Nashwan and Hadimani, Ravi L. and Gupta, Shalabh and Pecharsky, Vitalij K. and Zhao, Hong},
abstractNote = {Unique properties of one-dimensional assemblies of particles have attracted great attention during the past decades, particularly with respect to the potential for anisotropic magnetism. Patterned films can be created using inkjet printing; however, drying of particle-laden colloidal droplets on solid surfaces is usually accompanied by the well-known coffee-ring effect, deteriorating both the uniformity and resolution of the printed configurations. Here, we examine the effect of externally applied magnetic field on particle deposition patterns. Ferromagnetic Gd5Si4 particles were formulated in terpineol oil and directly deposited via magnetic field-assisted inkjet printing on a photopaper to generate patterned films with suppressed coffee-ring effect. The particle deposition morphology is determined by both solvent imbibition and particle-magnetic field interactions. Three characteristic times are considered, namely, the critical time for solvent imbibition into the substrate (tim), the time it takes for particles to form chains in the presence of the magnetic field (tch), and the time in which the particles reach the substrate in the direction normal to the substrate (tpz). The characteristic time ratios (tpz/tim) and (tpz/tch) determine the final deposition morphology in the presence of magnetic field. Finally, the ability to control particle deposition and assembly, thus tuning the magnetic anisotropic properties of nanostructured materials is a promising approach for many engineering applications.},
doi = {10.1038/s41598-019-52699-0},
journal = {Scientific Reports},
number = 1,
volume = 9,
place = {United States},
year = {Thu Nov 07 00:00:00 EST 2019},
month = {Thu Nov 07 00:00:00 EST 2019}
}
Free Publicly Available Full Text
Publisher's Version of Record
Other availability
Search WorldCat to find libraries that may hold this journal
Cited by: 11 works
Citation information provided by
Web of Science
Web of Science
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
XMCD and XMCD-PEEM Studies on Magnetic-Field-Assisted Self-Assembled 1D Nanochains of Spherical Ferrite Particles
journal, May 2017
- Zhang, Wen; Wong, Ping Kwan Johnny; Zhang, Dong
- Advanced Functional Materials, Vol. 27, Issue 29
Nanostructured Soft Matter with Magnetic Nanoparticles
journal, March 2016
- Tokarev, Alexander; Yatvin, Jeremy; Trotsenko, Oleksandr
- Advanced Functional Materials, Vol. 26, Issue 22
Magnetic recording beyond the first 100 Years
journal, March 1999
- Speliotis, DennisE.
- Journal of Magnetism and Magnetic Materials, Vol. 193, Issue 1-3
Printed Thin Magnetic Films Based on Diblock Copolymer and Magnetic Nanoparticles
journal, January 2018
- Xia, Senlin; Metwalli, Ezzeldin; Opel, Matthias
- ACS Applied Materials & Interfaces, Vol. 10, Issue 3
The Magnetocaloric Effect and Magnetic Refrigeration Near Room Temperature: Materials and Models
journal, August 2012
- Franco, V.; Blázquez, J. S.; Ingale, B.
- Annual Review of Materials Research, Vol. 42, Issue 1
Bioinspired 1D Superparamagnetic Magnetite Arrays with Magnetic Field Perception
journal, May 2016
- Jiang, Xiangyu; Feng, Jiangang; Huang, Lei
- Advanced Materials, Vol. 28, Issue 32
One-dimensional magnetic inorganic–organic hybrid nanomaterials
journal, January 2011
- Yuan, Jiayin; Xu, Youyong; Müller, Axel H. E.
- Chemical Society Reviews, Vol. 40, Issue 2
A magnetic protein biocompass
journal, November 2015
- Qin, Siying; Yin, Hang; Yang, Celi
- Nature Materials, Vol. 15, Issue 2
Printing 1D Assembly Array of Single Particle Resolution for Magnetosensing
journal, March 2018
- Gao, Meng; Kuang, Minxuan; Li, Lihong
- Small, Vol. 14, Issue 19
Inkjet printing of magnetic materials with aligned anisotropy
journal, May 2014
- Song, Han; Spencer, Jeremy; Jander, Albrecht
- Journal of Applied Physics, Vol. 115, Issue 17
Inkjet Printing of Functional and Structural Materials: Fluid Property Requirements, Feature Stability, and Resolution
journal, June 2010
- Derby, Brian
- Annual Review of Materials Research, Vol. 40, Issue 1
Inkjet printing as a deposition and patterning tool for polymers and inorganic particles
journal, January 2008
- Tekin, Emine; Smith, Patrick J.; Schubert, Ulrich S.
- Soft Matter, Vol. 4, Issue 4
Controlling Coffee Ring Formation during Drying of Inkjet Printed 2D Inks
journal, September 2017
- He, Pei; Derby, Brian
- Advanced Materials Interfaces, Vol. 4, Issue 22
Manipulating the Coffee-Ring Effect: Interactions at Work
journal, July 2015
- Anyfantakis, Manos; Baigl, Damien
- ChemPhysChem, Vol. 16, Issue 13
A review on suppression and utilization of the coffee-ring effect
journal, February 2018
- Mampallil, Dileep; Eral, Huseyin Burak
- Advances in Colloid and Interface Science, Vol. 252
Recent Advances in Controlling the Depositing Morphologies of Inkjet Droplets
journal, December 2015
- Sun, Jiazhen; Bao, Bin; He, Min
- ACS Applied Materials & Interfaces, Vol. 7, Issue 51
Protein Adsorption and Reorganization on Nanoparticles Probed by the Coffee-Ring Effect: Application to Single Point Mutation Detection
journal, September 2016
- Devineau, Stéphanie; Anyfantakis, Manos; Marichal, Laurent
- Journal of the American Chemical Society, Vol. 138, Issue 36
Pattern formation in drying drops
journal, January 2000
- Deegan, Robert D.
- Physical Review E, Vol. 61, Issue 1
Capillary flow as the cause of ring stains from dried liquid drops
journal, October 1997
- Deegan, Robert D.; Bakajin, Olgica; Dupont, Todd F.
- Nature, Vol. 389, Issue 6653, p. 827-829
Contact line deposits in an evaporating drop
journal, July 2000
- Deegan, Robert D.; Bakajin, Olgica; Dupont, Todd F.
- Physical Review E, Vol. 62, Issue 1
Effect of Substrate Temperature on Pattern Formation of Nanoparticles from Volatile Drops
journal, March 2015
- Parsa, Maryam; Harmand, Souad; Sefiane, Khellil
- Langmuir, Vol. 31, Issue 11
Effect of relative humidity on contact angle and particle deposition morphology of an evaporating colloidal drop
journal, December 2010
- Chhasatia, Viral H.; Joshi, Abhijit S.; Sun, Ying
- Applied Physics Letters, Vol. 97, Issue 23
Overcoming the “Coffee-Stain” Effect by Compositional Marangoni-Flow-Assisted Drop-Drying
journal, May 2012
- Majumder, Mainak; Rendall, Clint S.; Eukel, J. Alexander
- The Journal of Physical Chemistry B, Vol. 116, Issue 22
Control over Coffee-Ring Formation in Evaporating Liquid Drops Containing Ellipsoids
journal, July 2014
- Dugyala, Venkateshwar Rao; Basavaraj, Madivala G.
- Langmuir, Vol. 30, Issue 29
Suppression of the coffee-ring effect by shape-dependent capillary interactions
journal, August 2011
- Yunker, Peter J.; Still, Tim; Lohr, Matthew A.
- Nature, Vol. 476, Issue 7360
Deposition and drying dynamics of liquid crystal droplets
journal, May 2017
- Davidson, Zoey S.; Huang, Yongyang; Gross, Adam
- Nature Communications, Vol. 8, Issue 1
Suppression of the Coffee-Ring Effect and Evaporation-Driven Disorder to Order Transition in Colloidal Droplets
journal, September 2017
- Das, Shyamashis; Dey, Atreya; Reddy, Govardhan
- The Journal of Physical Chemistry Letters, Vol. 8, Issue 19
Evaporation Stains: Suppressing the Coffee-Ring Effect by Contact Angle Hysteresis
journal, June 2013
- Li, Yueh-Feng; Sheng, Yu-Jane; Tsao, Heng-Kwong
- Langmuir, Vol. 29, Issue 25
Surfactant-driven flow transitions in evaporating droplets
journal, January 2016
- Marin, Alvaro; Liepelt, Robert; Rossi, Massimiliano
- Soft Matter, Vol. 12, Issue 5
Printing Small Dots from Large Drops
journal, February 2015
- Talbot, Emma L.; Yow, Huai N.; Yang, Lisong
- ACS Applied Materials & Interfaces, Vol. 7, Issue 6
Auto-production of biosurfactants reverses the coffee ring effect in a bacterial system
journal, April 2013
- Sempels, Wouter; De Dier, Raf; Mizuno, Hideaki
- Nature Communications, Vol. 4, Issue 1
Influence of Evaporation on Contact Angle
journal, July 1995
- Bourges-Monnier, C.; Shanahan, M. E. R.
- Langmuir, Vol. 11, Issue 7
Nanochromatography Driven by the Coffee Ring Effect
journal, March 2011
- Wong, Tak-Sing; Chen, Ting-Hsuan; Shen, Xiaoying
- Analytical Chemistry, Vol. 83, Issue 6
Ordered patterns and structures via interfacial self-assembly: superlattices, honeycomb structures and coffee rings
journal, January 2011
- Ma, Hongmin; Hao, Jingcheng
- Chemical Society Reviews, Vol. 40, Issue 11
Probing the Colloidal Particle Dynamics in Drying Sessile Droplets
journal, January 2019
- Al-Milaji, Karam Nashwan; Zhao, Hong
- Langmuir, Vol. 35, Issue 6
Ink-Jet Printing of Zirconia: Coffee Staining and Line Stability
journal, July 2011
- Dou, Rui; Wang, Tianming; Guo, Yunshan
- Journal of the American Ceramic Society, Vol. 94, Issue 11
Formation of Coffee Stains on Porous Surfaces
journal, March 2012
- Dou, Rui; Derby, Brian
- Langmuir, Vol. 28, Issue 12
Colloidal Drop Deposition on Porous Substrates: Competition among Particle Motion, Evaporation, and Infiltration
journal, July 2015
- Pack, Min; Hu, Han; Kim, Dong-Ook
- Langmuir, Vol. 31, Issue 29
Coffee stains on paper
journal, June 2015
- Nilghaz, Azadeh; Zhang, Liyuan; Shen, Wei
- Chemical Engineering Science, Vol. 129
Influence of magnetic field on evaporation of a ferrofluid droplet
journal, October 2017
- Jadav, Mudra; Patel, R. J.; Mehta, R. V.
- Journal of Applied Physics, Vol. 122, Issue 14
Ferromagnetic Gd5Si4 Nanoparticles as T2 Contrast Agents for Magnetic Resonance Imaging
journal, January 2017
- El-Gendy, Ahmed A.; Harstad, Shane M.; Vijayaragavan, Vimalan
- IEEE Magnetics Letters, Vol. 8
Investigation of Room Temperature Ferromagnetic Nanoparticles of Gd 5 Si 4
journal, November 2015
- Hadimani, R. L.; Gupta, S.; Harstad, S. M.
- IEEE Transactions on Magnetics, Vol. 51, Issue 11
Minimal Size of Coffee Ring Structure
journal, April 2010
- Shen, Xiaoying; Ho, Chih-Ming; Wong, Tak-Sing
- The Journal of Physical Chemistry B, Vol. 114, Issue 16
An Analytic Solution for the Force Between Two Magnetic Dipoles
journal, January 1998
- Yung, Kar W.; Landecker, Peter B.; Villani, Daniel D.
- Magnetic and Electrical Separation, Vol. 9, Issue 1
Nanostructured Soft Matter with Magnetic Nanoparticles
journal, March 2016
- Tokarev, Alexander; Yatvin, Jeremy; Trotsenko, Oleksandr
- Advanced Functional Materials, Vol. 26, Issue 22
XMCD and XMCD-PEEM Studies on Magnetic-Field-Assisted Self-Assembled 1D Nanochains of Spherical Ferrite Particles
journal, May 2017
- Zhang, Wen; Wong, Ping Kwan Johnny; Zhang, Dong
- Advanced Functional Materials, Vol. 27, Issue 29
Bioinspired 1D Superparamagnetic Magnetite Arrays with Magnetic Field Perception
journal, May 2016
- Jiang, Xiangyu; Feng, Jiangang; Huang, Lei
- Advanced Materials, Vol. 28, Issue 32
Manipulating the Coffee-Ring Effect: Interactions at Work
journal, July 2015
- Anyfantakis, Manos; Baigl, Damien
- ChemPhysChem, Vol. 16, Issue 13
Printing 1D Assembly Array of Single Particle Resolution for Magnetosensing
journal, March 2018
- Gao, Meng; Kuang, Minxuan; Li, Lihong
- Small, Vol. 14, Issue 19
Coffee stains on paper
journal, June 2015
- Nilghaz, Azadeh; Zhang, Liyuan; Shen, Wei
- Chemical Engineering Science, Vol. 129
Suppression of the Coffee-Ring Effect and Evaporation-Driven Disorder to Order Transition in Colloidal Droplets
journal, September 2017
- Das, Shyamashis; Dey, Atreya; Reddy, Govardhan
- The Journal of Physical Chemistry Letters, Vol. 8, Issue 19
Effect of Substrate Temperature on Pattern Formation of Nanoparticles from Volatile Drops
journal, March 2015
- Parsa, Maryam; Harmand, Souad; Sefiane, Khellil
- Langmuir, Vol. 31, Issue 11
Colloidal Drop Deposition on Porous Substrates: Competition among Particle Motion, Evaporation, and Infiltration
journal, July 2015
- Pack, Min; Hu, Han; Kim, Dong-Ook
- Langmuir, Vol. 31, Issue 29
Probing the Colloidal Particle Dynamics in Drying Sessile Droplets
journal, January 2019
- Al-Milaji, Karam Nashwan; Zhao, Hong
- Langmuir, Vol. 35, Issue 6
Recent Advances in Controlling the Depositing Morphologies of Inkjet Droplets
journal, December 2015
- Sun, Jiazhen; Bao, Bin; He, Min
- ACS Applied Materials & Interfaces, Vol. 7, Issue 51
Printed Thin Magnetic Films Based on Diblock Copolymer and Magnetic Nanoparticles
journal, January 2018
- Xia, Senlin; Metwalli, Ezzeldin; Opel, Matthias
- ACS Applied Materials & Interfaces, Vol. 10, Issue 3
Overcoming the “Coffee-Stain” Effect by Compositional Marangoni-Flow-Assisted Drop-Drying
journal, May 2012
- Majumder, Mainak; Rendall, Clint S.; Eukel, J. Alexander
- The Journal of Physical Chemistry B, Vol. 116, Issue 22
Minimal Size of Coffee Ring Structure
journal, April 2010
- Shen, Xiaoying; Ho, Chih-Ming; Wong, Tak-Sing
- The Journal of Physical Chemistry B, Vol. 114, Issue 16
Influence of Evaporation on Contact Angle
journal, July 1995
- Bourges-Monnier, C.; Shanahan, M. E. R.
- Langmuir, Vol. 11, Issue 7
Formation of Coffee Stains on Porous Surfaces
journal, March 2012
- Dou, Rui; Derby, Brian
- Langmuir, Vol. 28, Issue 12
Ordered patterns and structures via interfacial self-assembly: superlattices, honeycomb structures and coffee rings
journal, January 2011
- Ma, Hongmin; Hao, Jingcheng
- Chemical Society Reviews, Vol. 40, Issue 11
Effect of relative humidity on contact angle and particle deposition morphology of an evaporating colloidal drop
journal, December 2010
- Chhasatia, Viral H.; Joshi, Abhijit S.; Sun, Ying
- Applied Physics Letters, Vol. 97, Issue 23
Inkjet printing of magnetic materials with aligned anisotropy
journal, May 2014
- Song, Han; Spencer, Jeremy; Jander, Albrecht
- Journal of Applied Physics, Vol. 115, Issue 17
Flow Transition within an Evaporating Binary Mixture Sessile Drop
journal, May 2011
- Christy, John R. E.; Hamamoto, Yoshinori; Sefiane, Khellil
- Physical Review Letters, Vol. 106, Issue 20
Self-Pinning by Colloids Confined at a Contact Line
journal, January 2013
- Weon, Byung Mook; Je, Jung Ho
- Physical Review Letters, Vol. 110, Issue 2
Controlled Uniform Coating from the Interplay of Marangoni Flows and Surface-Adsorbed Macromolecules
journal, March 2016
- Kim, Hyoungsoo; Boulogne, François; Um, Eujin
- Physical Review Letters, Vol. 116, Issue 12
Ink-Jet Printing of Zirconia: Coffee Staining and Line Stability
journal, July 2011
- Dou, Rui; Wang, Tianming; Guo, Yunshan
- Journal of the American Ceramic Society, Vol. 94, Issue 11
The Magnetocaloric Effect and Magnetic Refrigeration Near Room Temperature: Materials and Models
journal, August 2012
- Franco, V.; Blázquez, J. S.; Ingale, B.
- Annual Review of Materials Research, Vol. 42, Issue 1
Inkjet Printing of Functional and Structural Materials: Fluid Property Requirements, Feature Stability, and Resolution
journal, June 2010
- Derby, Brian
- Annual Review of Materials Research, Vol. 40, Issue 1
Simple and rapid method for selective enumeration of lactic acid bacteria in commercially prepared yogurt by image analysis and K-means clustering
journal, January 2022
- Nakao, Hidenobu; Magariyama, Yukio
- Analytical Sciences, Vol. 38, Issue 1
Surfactant-driven flow transitions in evaporating droplets
text, January 2015
- Marin, Alvaro; Liepelt, Robert; Rossi, Massimiliano
- arXiv