In situ redox reactions facilitate the assembly of a mixed-valence metal-organic nanocapsule
Abstract
C-alkylpyrogallol[4]arenes (PgCs) have been studied for their ability to form metal-organic nanocapsules (MONCs) through coordination to appropriate metal ions. Here we present the synthesis and characterization of an MnII/MnIII-seamed MONC in addition to its electrochemical and magnetic behavior. This MONC assembles from 24 manganese ions and 6 PgCs, while an additional metal ion is located on the capsule interior, anchored through the introduction of bridging nitrite ions. The latter originate from an in situ redox reaction that occurs during the self-assembly process, thus representing a new route to otherwise unobtainable nanocapsules.
- Authors:
-
[1];
[4];
[1]
- Univ. of Missouri, Columbia, MO (United States)
- Univ. of Edinburgh, Scotland (United Kingdom)
- Heriot-Watt Univ., Edinburgh, Scotland (United Kingdom)
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
- Publication Date:
- Research Org.:
- Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1571128
- Grant/Contract Number:
- AC02-05CH11231
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Nature Communications
- Additional Journal Information:
- Journal Volume: 9; Journal Issue: 1; Journal ID: ISSN 2041-1723
- Publisher:
- Nature Publishing Group
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Rathnayake, Asanka S., Fraser, Hector W. L., Brechin, Euan K., Dalgarno, Scott J., Baumeister, Jakob E., White, Joshua, Rungthanaphatsophon, Pokpong, Walensky, Justin R., Barnes, Charles L., Teat, Simon J., and Atwood, Jerry L. In situ redox reactions facilitate the assembly of a mixed-valence metal-organic nanocapsule. United States: N. p., 2018.
Web. doi:10.1038/s41467-018-04541-w.
Rathnayake, Asanka S., Fraser, Hector W. L., Brechin, Euan K., Dalgarno, Scott J., Baumeister, Jakob E., White, Joshua, Rungthanaphatsophon, Pokpong, Walensky, Justin R., Barnes, Charles L., Teat, Simon J., & Atwood, Jerry L. In situ redox reactions facilitate the assembly of a mixed-valence metal-organic nanocapsule. United States. https://doi.org/10.1038/s41467-018-04541-w
Rathnayake, Asanka S., Fraser, Hector W. L., Brechin, Euan K., Dalgarno, Scott J., Baumeister, Jakob E., White, Joshua, Rungthanaphatsophon, Pokpong, Walensky, Justin R., Barnes, Charles L., Teat, Simon J., and Atwood, Jerry L. Tue .
"In situ redox reactions facilitate the assembly of a mixed-valence metal-organic nanocapsule". United States. https://doi.org/10.1038/s41467-018-04541-w. https://www.osti.gov/servlets/purl/1571128.
@article{osti_1571128,
title = {In situ redox reactions facilitate the assembly of a mixed-valence metal-organic nanocapsule},
author = {Rathnayake, Asanka S. and Fraser, Hector W. L. and Brechin, Euan K. and Dalgarno, Scott J. and Baumeister, Jakob E. and White, Joshua and Rungthanaphatsophon, Pokpong and Walensky, Justin R. and Barnes, Charles L. and Teat, Simon J. and Atwood, Jerry L.},
abstractNote = {C-alkylpyrogallol[4]arenes (PgCs) have been studied for their ability to form metal-organic nanocapsules (MONCs) through coordination to appropriate metal ions. Here we present the synthesis and characterization of an MnII/MnIII-seamed MONC in addition to its electrochemical and magnetic behavior. This MONC assembles from 24 manganese ions and 6 PgCs, while an additional metal ion is located on the capsule interior, anchored through the introduction of bridging nitrite ions. The latter originate from an in situ redox reaction that occurs during the self-assembly process, thus representing a new route to otherwise unobtainable nanocapsules.},
doi = {10.1038/s41467-018-04541-w},
journal = {Nature Communications},
number = 1,
volume = 9,
place = {United States},
year = {Tue May 29 00:00:00 EDT 2018},
month = {Tue May 29 00:00:00 EDT 2018}
}
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