The Transport of Asian Dust and Combustion Aerosols and Associated Ozone to North America as Observed From a Mountaintop Monitoring Site in the California Coast Range
Abstract
Aerosol and tropospheric ozone transport to North America has important implications for regional air quality and climate. We present data from Chews Ridge, a remote mountaintop site in California, in February–September 2012, which identifies separate Asian dust and Asian combustion aerosol signals and quantifies exogenous ozone. We use positive matrix factorization of size-fractionated aerosol X-ray fluorescence data and 206Pb/207Pb and 208Pb/207Pb isotope measurements to isolate aerosol signals of Asian origins and find good agreement between both types source attribution techniques. Power spectra of Asian dust and Asian combustion signals reveal two distinct peaks, one seasonal (~90 days) and one monthly (~25–30 days). Overall, 89% of the Asian dust signal occurs in March–May, compared with June–September, whereas only 51% of the Asian combustion signal occurs in March–May. Nearly half the Pb observed at Chews Ridge was derived from Asia (46%; 8.3% from Asian dust, 23% from Asian combustion, and 15% of the Asian Pb signal was not explained by the positive matrix factorization). A positive correlation between deseasonalized ozone concentrations and the Asian factors suggests that ozone is elevated by 6.3 ± 0.8 ppb due to transpacific transport. Scanning mobility particle size spectra were also measured from May to September and indicate that new particles aremore »
- Authors:
-
- Univ. of California, Davis, CA (United States). Dept. of Land Air and Water Resources; National Center for Atmospheric Research, Boulder, CO (United States)
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
- Univ. of California, Davis, CA (United States). Dept. of Land Air and Water Resources
- Univ. of Utah, Salt Lake City, UT (United States). Atmospheric Sciences
- Univ. of California, Davis, CA (United States). Air Quality Research Center
- Publication Date:
- Research Org.:
- Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1561890
- Grant/Contract Number:
- AC02-05CH11231
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of Geophysical Research: Atmospheres
- Additional Journal Information:
- Journal Volume: 123; Journal Issue: 10; Journal ID: ISSN 2169-897X
- Publisher:
- American Geophysical Union
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 54 ENVIRONMENTAL SCIENCES
Citation Formats
Asher, Elizabeth C., Christensen, John N., Post, Andrew, Perry, Kevin, Cliff, Steven S., Zhao, Yongjing, Trousdell, Justin, and Faloona, Ian. The Transport of Asian Dust and Combustion Aerosols and Associated Ozone to North America as Observed From a Mountaintop Monitoring Site in the California Coast Range. United States: N. p., 2018.
Web. doi:10.1029/2017JD028075.
Asher, Elizabeth C., Christensen, John N., Post, Andrew, Perry, Kevin, Cliff, Steven S., Zhao, Yongjing, Trousdell, Justin, & Faloona, Ian. The Transport of Asian Dust and Combustion Aerosols and Associated Ozone to North America as Observed From a Mountaintop Monitoring Site in the California Coast Range. United States. https://doi.org/10.1029/2017JD028075
Asher, Elizabeth C., Christensen, John N., Post, Andrew, Perry, Kevin, Cliff, Steven S., Zhao, Yongjing, Trousdell, Justin, and Faloona, Ian. Mon .
"The Transport of Asian Dust and Combustion Aerosols and Associated Ozone to North America as Observed From a Mountaintop Monitoring Site in the California Coast Range". United States. https://doi.org/10.1029/2017JD028075. https://www.osti.gov/servlets/purl/1561890.
@article{osti_1561890,
title = {The Transport of Asian Dust and Combustion Aerosols and Associated Ozone to North America as Observed From a Mountaintop Monitoring Site in the California Coast Range},
author = {Asher, Elizabeth C. and Christensen, John N. and Post, Andrew and Perry, Kevin and Cliff, Steven S. and Zhao, Yongjing and Trousdell, Justin and Faloona, Ian},
abstractNote = {Aerosol and tropospheric ozone transport to North America has important implications for regional air quality and climate. We present data from Chews Ridge, a remote mountaintop site in California, in February–September 2012, which identifies separate Asian dust and Asian combustion aerosol signals and quantifies exogenous ozone. We use positive matrix factorization of size-fractionated aerosol X-ray fluorescence data and 206Pb/207Pb and 208Pb/207Pb isotope measurements to isolate aerosol signals of Asian origins and find good agreement between both types source attribution techniques. Power spectra of Asian dust and Asian combustion signals reveal two distinct peaks, one seasonal (~90 days) and one monthly (~25–30 days). Overall, 89% of the Asian dust signal occurs in March–May, compared with June–September, whereas only 51% of the Asian combustion signal occurs in March–May. Nearly half the Pb observed at Chews Ridge was derived from Asia (46%; 8.3% from Asian dust, 23% from Asian combustion, and 15% of the Asian Pb signal was not explained by the positive matrix factorization). A positive correlation between deseasonalized ozone concentrations and the Asian factors suggests that ozone is elevated by 6.3 ± 0.8 ppb due to transpacific transport. Scanning mobility particle size spectra were also measured from May to September and indicate that new particles are often produced and grow throughout the afternoon during onshore flow. We hypothesize that particle nucleation on the windward edge of the continent is an important source of new particles.},
doi = {10.1029/2017JD028075},
journal = {Journal of Geophysical Research: Atmospheres},
number = 10,
volume = 123,
place = {United States},
year = {Mon May 14 00:00:00 EDT 2018},
month = {Mon May 14 00:00:00 EDT 2018}
}
Web of Science
Figures / Tables:
Works referenced in this record:
Isoprene and monoterpene fluxes measured above Amazonian rainforest and their dependence on light and temperature
journal, May 2002
- Rinne, H. J. I.; Guenther, A. B.; Greenberg, J. P.
- Atmospheric Environment, Vol. 36, Issue 14
Flood or Drought: How Do Aerosols Affect Precipitation?
journal, September 2008
- Rosenfeld, D.; Lohmann, U.; Raga, G. B.
- Science, Vol. 321, Issue 5894
Asian aerosols in North America: Frequency and concentration of fine dust
journal, January 2002
- VanCuren, Richard A.
- Journal of Geophysical Research, Vol. 107, Issue D24
Measured black carbon deposition on the Sierra Nevada snow pack and implication for snow pack retreat
journal, January 2010
- Hadley, O. L.; Corrigan, C. E.; Kirchstetter, T. W.
- Atmospheric Chemistry and Physics, Vol. 10, Issue 15
Understanding and controlling rotations in factor analytic models
journal, January 2002
- Paatero, Pentti; Hopke, Philip K.; Song, Xin-Hua
- Chemometrics and Intelligent Laboratory Systems, Vol. 60, Issue 1-2
Seasonality and weather-driven variability of transpacific transport
journal, January 2005
- Holzer, Mark; Hall, Timothy M.; Stull, Roland B.
- Journal of Geophysical Research, Vol. 110, Issue D23
Evaluating inter-continental transport of fine aerosols:(2) Global health impact
journal, September 2009
- Liu, Junfeng; Mauzerall, Denise L.; Horowitz, Larry W.
- Atmospheric Environment, Vol. 43, Issue 28
Global data set of biogenic VOC emissions calculated by the MEGAN model over the last 30 years
journal, January 2014
- Sindelarova, K.; Granier, C.; Bouarar, I.
- Atmospheric Chemistry and Physics, Vol. 14, Issue 17
Unraveling the sources of ground level ozone in the Intermountain Western United States using Pb isotopes
journal, October 2015
- Christensen, John N.; Weiss-Penzias, Peter; Fine, Rebekka
- Science of The Total Environment, Vol. 530-531
Long-Range Atmospheric Transport of Soil Dust from Asia to the Tropical North Pacific: Temporal Variability
journal, September 1980
- Duce, R. A.; Unni, C. K.; Ray, B. J.
- Science, Vol. 209, Issue 4464
Characterization of the 8-stage Rotating Drum Impactor under low concentration conditions
journal, October 2016
- Venecek, Melissa A.; Zhao, Yongjing; Mojica, Jose
- Journal of Aerosol Science, Vol. 100
Asian dust transported one full circuit around the globe
journal, July 2009
- Uno, Itsushi; Eguchi, Kenta; Yumimoto, Keiya
- Nature Geoscience, Vol. 2, Issue 8
US surface ozone trends and extremes from 1980 to 2014: quantifying the roles of rising Asian emissions, domestic controls, wildfires, and climate
journal, January 2017
- Lin, Meiyun; Horowitz, Larry W.; Payton, Richard
- Atmospheric Chemistry and Physics, Vol. 17, Issue 4
Magnitudes and sources of precipitation and dry deposition fluxes of indestrial and natural leads to the North Pacific at Enewetak
journal, January 1982
- Settle, Dorothy M.; Patterson, Clair C.
- Journal of Geophysical Research, Vol. 87, Issue C11
Increasing springtime ozone mixing ratios in the free troposphere over western North America
journal, January 2010
- Cooper, O. R.; Parrish, D. D.; Stohl, A.
- Nature, Vol. 463, Issue 7279
Low-level transpacific transport
journal, January 2007
- Holzer, Mark; Hall, Timothy M.
- Journal of Geophysical Research, Vol. 112, Issue D9
Atmospheric Aerosols: Composition, Transformation, Climate and Health Effects
journal, November 2005
- Pöschl, Ulrich
- Angewandte Chemie International Edition, Vol. 44, Issue 46
Gas-Phase Tropospheric Chemistry of Volatile Organic Compounds: 1. Alkanes and Alkenes
journal, March 1997
- Atkinson, R.
- Journal of Physical and Chemical Reference Data, Vol. 26, Issue 2
High secondary aerosol contribution to particulate pollution during haze events in China
journal, September 2014
- Huang, Ru-Jin; Zhang, Yanlin; Bozzetti, Carlo
- Nature, Vol. 514, Issue 7521
Highly reactive light‐dependent monoterpenes in the Amazon
journal, March 2015
- Jardine, A. B.; Jardine, K. J.; Fuentes, J. D.
- Geophysical Research Letters, Vol. 42, Issue 5
Evidence for Asian dust effects from aerosol plume measurements during INTEX-B 2006 near Whistler, BC
journal, January 2009
- Leaitch, W. R.; Macdonald, A. M.; Anlauf, K. G.
- Atmospheric Chemistry and Physics, Vol. 9, Issue 11
Large-Scale Structure of the June–July 1996 Marine Boundary Layer along California and Oregon
journal, June 2000
- Dorman, C. E.; Holt, T.; Rogers, D. P.
- Monthly Weather Review, Vol. 128, Issue 6
Evolution of Asian aerosols during transpacific transport in INTEX-B
journal, January 2009
- Dunlea, E. J.; DeCarlo, P. F.; Aiken, A. C.
- Atmospheric Chemistry and Physics, Vol. 9, Issue 19
Natural aerosols explain seasonal and spatial patterns of Southern Ocean cloud albedo
journal, July 2015
- McCoy, Daniel T.; Burrows, Susannah M.; Wood, Robert
- Science Advances, Vol. 1, Issue 6
The elemental signature of transported Asian dust at Mauna Loa observatory
journal, January 1996
- Holmes, Jennifer; Zoller, William
- Tellus B: Chemical and Physical Meteorology, Vol. 48, Issue 1
Trans-Pacific transport and evolution of aerosols: evaluation of quasi-global WRF-Chem simulation with multiple observations
journal, January 2016
- Hu, Zhiyuan; Zhao, Chun; Huang, Jianping
- Geoscientific Model Development, Vol. 9, Issue 5
Meteorological indices for Asian outflow and transpacific transport on daily to interannual timescales
journal, January 2005
- Liang, Qing
- Journal of Geophysical Research, Vol. 110, Issue D18
Interpreting aerosol lifetimes using the GEOS-Chem model and constraints from radionuclide measurements
journal, January 2014
- Croft, B.; Pierce, J. R.; Martin, R. V.
- Atmospheric Chemistry and Physics, Vol. 14, Issue 8
Long-term changes in lower tropospheric baseline ozone concentrations at northern mid-latitudes
journal, January 2012
- Parrish, D. D.; Law, K. S.; Staehelin, J.
- Atmospheric Chemistry and Physics, Vol. 12, Issue 23
Variations in tropospheric submicron particle size distributions across the European continent 2008–2009
journal, January 2014
- Beddows, D. C. S.; Dall'Osto, M.; Harrison, R. M.
- Atmospheric Chemistry and Physics, Vol. 14, Issue 8
Summertime influence of Asian pollution in the free troposphere over North America
journal, January 2007
- Liang, Q.; Jaeglé, L.; Hudman, R. C.
- Journal of Geophysical Research, Vol. 112, Issue D12
Iron deficiency limits phytoplankton growth in the north-east Pacific subarctic
journal, January 1988
- Martin, John H.; Fitzwater, Steve E.
- Nature, Vol. 331, Issue 6154
Size-resolved aerosol chemistry on Whistler Mountain, Canada with a high-resolution aerosol mass spectrometer during INTEX-B
journal, January 2009
- Sun, Y.; Zhang, Q.; Macdonald, A. M.
- Atmospheric Chemistry and Physics, Vol. 9, Issue 9
Asian aerosols in North America: Extracting the chemical composition and mass concentration of the Asian continental aerosol plume from long-term aerosol records in the western United States
journal, January 2003
- VanCuren, Richard A.
- Journal of Geophysical Research, Vol. 108, Issue D20
Particle Loss Calculator – a new software tool for the assessment of the performance of aerosol inlet systems
journal, January 2009
- von der Weiden, S. -L.; Drewnick, F.; Borrmann, S.
- Atmospheric Measurement Techniques, Vol. 2, Issue 2
Formation of Secondary Organic Aerosols Through Photooxidation of Isoprene
journal, February 2004
- Claeys, M.
- Science, Vol. 303, Issue 5661
The Effects of Tropospheric Ozone on Net Primary Productivity and Implications for Climate Change
journal, June 2012
- Ainsworth, Elizabeth A.; Yendrek, Craig R.; Sitch, Stephen
- Annual Review of Plant Biology, Vol. 63, Issue 1
The rise and fall of leaded gasoline
journal, March 1990
- Nriagu, Jerome O.
- Science of The Total Environment, Vol. 92
Stable Lead Isotope Compositions In Selected Coals From Around The World And Implications For Present Day Aerosol Source Tracing
journal, February 2009
- Díaz-Somoano, M.; Kylander, M. E.; López-Antón, M. A.
- Environmental Science & Technology, Vol. 43, Issue 4
The temporal stability in lead isotopic signatures at selected sites in the Southern and Northern Hemispheres
journal, April 2002
- Bollhöfer, A.; Rosman, K. J. R.
- Geochimica et Cosmochimica Acta, Vol. 66, Issue 8
Pb Isotopes as an Indicator of the Asian Contribution to Particulate Air Pollution in Urban California
journal, December 2010
- Ewing, Stephanie A.; Christensen, John N.; Brown, Shaun T.
- Environmental Science & Technology, Vol. 44, Issue 23
Six ‘new’ episodes of trans-Pacific transport of air pollutants
journal, January 2003
- Jaffe, Dan; McKendry, Ian; Anderson, Tad
- Atmospheric Environment, Vol. 37, Issue 3
Particle characteristics following cloud-modified transport from Asia to North America: CLOUD-MODIFIED TRANSPORT FROM ASIA
journal, July 2004
- Brock, Charles A.; Hudson, Paula K.; Lovejoy, Edward R.
- Journal of Geophysical Research: Atmospheres, Vol. 109, Issue D23
Trans-Pacific dust events observed at Whistler, British Columbia during INTEX-B
journal, January 2008
- McKendry, I. G.; Macdonald, A. M.; Leaitch, W. R.
- Atmospheric Chemistry and Physics, Vol. 8, Issue 20
Formation of atmospheric particles from organic acids produced by forests
journal, October 1998
- Kavouras, Ilias G.; Mihalopoulos, Nikolaos; Stephanou, Euripides G.
- Nature, Vol. 395, Issue 6703
Improving Source Apportionment of Fine Particles in the Eastern United States Utilizing Temperature-Resolved Carbon Fractions
journal, October 2005
- Kim, Eugene; Hopke, Philip K.
- Journal of the Air & Waste Management Association, Vol. 55, Issue 10
Asian continental aerosol persistence above the marine boundary layer over the eastern North Pacific: Continuous aerosol measurements from Intercontinental Transport and Chemical Transformation 2002 (ITCT 2K2)
journal, January 2005
- VanCuren, Richard A.
- Journal of Geophysical Research, Vol. 110, Issue D9
Comprehensive Study of Lead Pollution in Shanghai by Multiple Techniques
journal, December 2006
- Tan, M. G.; Zhang, G. L.; Li, X. L.
- Analytical Chemistry, Vol. 78, Issue 23
Modeled size-segregated wet and dry deposition budgets of soil dust aerosol during ACE-Asia 2001: Implications for trans-Pacific transport
journal, January 2003
- Zhao, T. L.
- Journal of Geophysical Research, Vol. 108, Issue D23
Calibration studies of the drum impactor
journal, April 1988
- Raabe, Otto G.; Braaten, David A.; Axelbaum, Richard L.
- Journal of Aerosol Science, Vol. 19, Issue 2
?How to find bananas in the atmospheric aerosol?: new approach for analyzing atmospheric nucleation and growth events
journal, April 2007
- Heintzenberg, Jost; Wehner, Birgit; Birmili, Wolfram
- Tellus B, Vol. 59, Issue 2
Aerosols from Overseas Rival Domestic Emissions over North America
journal, August 2012
- Yu, H.; Remer, L. A.; Chin, M.
- Science, Vol. 337, Issue 6094
Isotopic source signatures for atmospheric lead: the Northern Hemisphere
journal, June 2001
- Bollhöfer, A.; Rosman, K. J. R.
- Geochimica et Cosmochimica Acta, Vol. 65, Issue 11
Climate Change 2013 – The Physical Science Basis
book, March 2014
- Intergovernmental Panel on Climate Change,
Identification of sources contributing to PM 2.5 and ozone at elevated sites in the western U.S. by receptor analysis: Lassen Volcanic National Park, California, and Great Basin National Park, Nevada
journal, October 2015
- VanCuren, Richard (Tony); Gustin, Mae Sexauer
- Science of The Total Environment, Vol. 530-531
A Climatology of Atmospheric Wavenumber Spectra of Wind and Temperature Observed by Commercial Aircraft
journal, May 1985
- Nastrom, G. D.; Gage, K. S.
- Journal of the Atmospheric Sciences, Vol. 42, Issue 9
Optical and chemical properties of aerosols transported to Mount Bachelor during spring 2010
journal, January 2011
- Fischer, E. V.; Perry, K. D.; Jaffe, D. A.
- Journal of Geophysical Research, Vol. 116, Issue D18
Atmospheric Aerosols: Composition, Transformation, Climate and Health Effects
journal, February 2006
- Poeschl, Ulrich
- ChemInform, Vol. 37, Issue 7
Evolution of Asian aerosols during transpacific transport in INTEX-B
journal, January 2008
- Dunlea, E. J.; DeCarlo, P. F.; Aiken, A. C.
- Atmospheric Chemistry and Physics Discussions, Vol. 8, Issue 4
Evidence for Asian dust effects from aerosol plume measurements during INTEX-B 2006 near Whistler, BC
journal, January 2008
- Leaitch, W. R.; Macdonald, A. M.; Anlauf, K. G.
- Atmospheric Chemistry and Physics Discussions, Vol. 8, Issue 5
Seasonality and weather-driven variability of transpacific transport
text, January 2005
- Holzer, Mark; Hall, Timothy M.; Stull, Roland B.
- American Geophysical Union
Long-term changes in lower tropospheric baseline ozone concentrations at northern mid-latitudes
text, January 2012
- Parrish, David D.; Law, K. S.; Staehelin, Johannes
- ETH Zurich
The elemental signature of transported Asian dust at Mauna Loa observatory
journal, February 1996
- Holmes, Jennifer; Zoller, William
- Tellus B, Vol. 48, Issue 1
‘How to find bananas in the atmospheric aerosol’: new approach for analyzing atmospheric nucleation and growth events
journal, April 2007
- Heintzenberg, Jost; Wehner, Birgit; Birmili, Wolfram
- Tellus B, Vol. 59, Issue 2
High secondary aerosol contribution to particulate pollution during haze events in China
text, January 2014
- Zhang, Yanlin; Baltensperger, Urs; Schnelle-Kreis, Jürgen
- Macmillan Journals Ltd.
Variations in tropospheric submicron particle size distributions across the European continent 2008-2009
text, January 2014
- Beddows, D. C. S.; Dall'Osto, M.; Harrison, R. M.
- ETH Zurich
Works referencing / citing this record:
Intercomparison of lidar, aircraft, and surface ozone measurements in the San Joaquin Valley during the California Baseline Ozone Transport Study (CABOTS)
journal, January 2019
- Langford, Andrew O.; Alvarez II, Raul J.; Kirgis, Guillaume
- Atmospheric Measurement Techniques, Vol. 12, Issue 3