Tearing and reliability of photovoltaic module backsheets
Abstract
We report that the backsheet in photovoltaic modules belongs to an important class of layered materials where the tearing behavior of the individual layers does not necessarily represent the tearing behavior of the entire backsheet. Such characteristic arises from the interaction between the individual layers during the tearing process, where one layer of the backsheet is mechanically constrained by its neighboring layers and the layers may debond from each other. The mechanical constraint and debonding change the amount of energy dissipated during tearing and affect the overall tearing energy. In this article, we exposed a wide selection of backsheets with polymers including ethylene-vinyl acetate (EVA), polyethylene terephthalate (PET), polyvinylidene fluoride (PVDF), and ethylene tetrafluoroethylene (ETFE) to damp heat (85°C/85%RH) for up to 2000 hours. We report on the effect of damp heat on the tearing energy as a function of damp heat exposure. We developed a model that describes the tearing energy of a layered structure by accounting for the tearing of the individual layers in the backsheet, the effect of mechanical constraint, and the adhesive debonding between the layers. Additionally, we explore the relationship between the microstructural change in the polymers which resulted from the damp heat exposure andmore »
- Authors:
-
- Stanford Univ., CA (United States)
- SLAC National Accelerator Lab., Menlo Park, CA (United States)
- SolarCity, Fremont, CA (United States)
- Publication Date:
- Research Org.:
- SLAC National Accelerator Laboratory (SLAC), Menlo Park, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE Office of Energy Efficiency and Renewable Energy (EERE), Renewable Power Office. Solar Energy Technologies Office
- OSTI Identifier:
- 1560684
- Alternate Identifier(s):
- OSTI ID: 1523542
- Grant/Contract Number:
- AC02‐76SF00515; ECCS‐1542152
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Progress in Photovoltaics
- Additional Journal Information:
- Journal Volume: 27; Journal Issue: 8; Journal ID: ISSN 1062-7995
- Publisher:
- Wiley
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; backsheet; damp heat; MDSC; polymer; reliability; small and wide angle X‐ray scattering; tearing; tensile testing
Citation Formats
Yuen, Pak Yan, Moffitt, Stephanie L., Novoa, Fernando D., Schelhas, Laura T., and Dauskardt, Reinhold H. Tearing and reliability of photovoltaic module backsheets. United States: N. p., 2019.
Web. doi:10.1002/pip.3144.
Yuen, Pak Yan, Moffitt, Stephanie L., Novoa, Fernando D., Schelhas, Laura T., & Dauskardt, Reinhold H. Tearing and reliability of photovoltaic module backsheets. United States. https://doi.org/10.1002/pip.3144
Yuen, Pak Yan, Moffitt, Stephanie L., Novoa, Fernando D., Schelhas, Laura T., and Dauskardt, Reinhold H. Wed .
"Tearing and reliability of photovoltaic module backsheets". United States. https://doi.org/10.1002/pip.3144. https://www.osti.gov/servlets/purl/1560684.
@article{osti_1560684,
title = {Tearing and reliability of photovoltaic module backsheets},
author = {Yuen, Pak Yan and Moffitt, Stephanie L. and Novoa, Fernando D. and Schelhas, Laura T. and Dauskardt, Reinhold H.},
abstractNote = {We report that the backsheet in photovoltaic modules belongs to an important class of layered materials where the tearing behavior of the individual layers does not necessarily represent the tearing behavior of the entire backsheet. Such characteristic arises from the interaction between the individual layers during the tearing process, where one layer of the backsheet is mechanically constrained by its neighboring layers and the layers may debond from each other. The mechanical constraint and debonding change the amount of energy dissipated during tearing and affect the overall tearing energy. In this article, we exposed a wide selection of backsheets with polymers including ethylene-vinyl acetate (EVA), polyethylene terephthalate (PET), polyvinylidene fluoride (PVDF), and ethylene tetrafluoroethylene (ETFE) to damp heat (85°C/85%RH) for up to 2000 hours. We report on the effect of damp heat on the tearing energy as a function of damp heat exposure. We developed a model that describes the tearing energy of a layered structure by accounting for the tearing of the individual layers in the backsheet, the effect of mechanical constraint, and the adhesive debonding between the layers. Additionally, we explore the relationship between the microstructural change in the polymers which resulted from the damp heat exposure and the mechanical properties using modulated differential scanning calorimetry (MDSC), small and wide angle X-ray scattering (SAXS and WAXS), and tensile testing.},
doi = {10.1002/pip.3144},
journal = {Progress in Photovoltaics},
number = 8,
volume = 27,
place = {United States},
year = {Wed May 29 00:00:00 EDT 2019},
month = {Wed May 29 00:00:00 EDT 2019}
}
Web of Science
Works referenced in this record:
Correlation of the loss in photovoltaic module performance with the ageing behaviour of the backsheets used: Influence of backsheet on photovoltaic module performance
journal, January 2015
- Voronko, Yuliya; Eder, Gabriele C.; Knausz, Marlene
- Progress in Photovoltaics: Research and Applications, Vol. 23, Issue 11
Effect of Mechanical Constraint on Tearing Energy of Polymer Membranes
journal, June 2016
- Yuen, Pak Yan; Dauskardt, Reinhold H.
- Macromolecular Materials and Engineering, Vol. 301, Issue 9
Physical ageing studies in semicrystalline poly(ethylene terephthalate)
journal, April 1995
- Montserrat, S.; Cortés, P.
- Journal of Materials Science, Vol. 30, Issue 7
Nika : software for two-dimensional data reduction
journal, March 2012
- Ilavsky, Jan
- Journal of Applied Crystallography, Vol. 45, Issue 2
Glass transition and structural relaxation in semi-crystalline poly(ethylene terephthalate): a DSC study
journal, July 2002
- Alves, N. M.; Mano, J. F.; Balaguer, E.
- Polymer, Vol. 43, Issue 15
Failure Modes Evaluation of PV Module via Materials Degradation Approach
journal, January 2013
- Wang, Ethan; Yang, Hsinjin Edwin; Yen, Jerry
- Energy Procedia, Vol. 33
Long-term performance and reliability assessment of 8 PV arrays at Sandia National Laboratories
conference, June 2009
- Granata, J. E.; Boyson, W. E.; Kratochvil, J. A.
- 2009 34th IEEE Photovoltaic Specialists Conference (PVSC)
Environmental mechanisms of debonding in photovoltaic backsheets
journal, January 2014
- Novoa, Fernando D.; Miller, David C.; Dauskardt, Reinhold H.
- Solar Energy Materials and Solar Cells, Vol. 120
Crystalline character in polymers
journal, January 1965
- Peterlin, A.
- Journal of Polymer Science Part C: Polymer Symposia, Vol. 9, Issue 1
Influence of alternating sequential fraction on the melting and glass transition temperatures of ethylene–tetrafluoroethylene copolymer
journal, October 2010
- Arai, Kiyotaka; Funaki, Atsushi; Phongtamrug, Suttinun
- Polymer, Vol. 51, Issue 21
Structure and basic properties of photovoltaic module backsheet films
journal, January 2016
- Geretschläger, Klaus J.; Wallner, Gernot M.; Fischer, Jörg
- Solar Energy Materials and Solar Cells, Vol. 144
Degradation of photovoltaic backsheets: Comparison of the aging induced changes on module and component level
journal, March 2015
- Knausz, Marlene; Oreski, Gernot; Eder, Gabriele C.
- Journal of Applied Polymer Science, Vol. 132, Issue 24
Study of single crystals and their associations in polymers
journal, January 1958
- Keller, A.; O'Connor, A.
- Discussions of the Faraday Society, Vol. 25
Aging mechanisms of polymeric films for PV encapsulation
journal, December 2005
- Oreski, G.; Wallner, G. M.
- Solar Energy, Vol. 79, Issue 6
GSAS-II : the genesis of a modern open-source all purpose crystallography software package
journal, March 2013
- Toby, Brian H.; Von Dreele, Robert B.
- Journal of Applied Crystallography, Vol. 46, Issue 2
Structural evolution of PVDF during storage or annealing
journal, March 2004
- Neidhöfer, M.; Beaume, F.; Ibos, L.
- Polymer, Vol. 45, Issue 5
Performance and degradation analysis for long term reliability of solar photovoltaic systems: A review
journal, November 2013
- Sharma, Vikrant; Chandel, S. S.
- Renewable and Sustainable Energy Reviews, Vol. 27
Study on the degradation of different types of backsheets used in PV module under accelerated conditions
journal, January 2014
- Kim, Namsu; Kang, Hyunwoo; Hwang, Kyung-Jun
- Solar Energy Materials and Solar Cells, Vol. 120
A Comparison of Key PV Backsheet and Module Performance from Fielded Module Exposures and Accelerated Tests
journal, May 2014
- Gambogi, W.; Heta, Y.; Hashimoto, K.
- IEEE Journal of Photovoltaics, Vol. 4, Issue 3
Recrystallization of polyethylene during annealing
journal, May 1960
- Statton, W. O.; Geil, P. H.
- Journal of Applied Polymer Science, Vol. 3, Issue 9
Study of the morphology of semicrystalline poly(ethylene terephthalate) by hydrolysis etching
journal, January 1993
- Cagiao, M. E.; Calleja, F. J. Baltá; Vanderdonckt, C.
- Polymer, Vol. 34, Issue 10
Morphology of n-alkanes, linear polyethylene, and isotactic polypropylene crystallized from solution
journal, June 1960
- Rånby, B. G.; Morehead, F. F.; Walter, N. M.
- Journal of Polymer Science, Vol. 44, Issue 144
A study of enthalpic relaxation of poly(ethylene terephthalate) by conventional and modulated temperature DSC
journal, March 2001
- Bailey, Nicola A.; Hay, James N.; Price, Duncan M.
- Thermochimica Acta, Vol. 367-368
Thermal properties of proton-conducting radiation-grafted membranes
journal, January 2008
- Gürsel, Selmiye Alkan; Schneider, Julian; Ben Youcef, Hicham
- Journal of Applied Polymer Science, Vol. 108, Issue 6
The role of crystalline, mobile amorphous and rigid amorphous fractions in the performance of recycled poly (ethylene terephthalate) (PET)
journal, January 2012
- Badia, J. D.; Strömberg, E.; Karlsson, S.
- Polymer Degradation and Stability, Vol. 97, Issue 1
Introduction to physical polymer science
journal, May 1988
- Brooks, B. W.
- The Chemical Engineering Journal, Vol. 38, Issue 1