Record-Setting Sorbents for Reversible Water Uptake by Systematic Anion Exchanges in Metal–Organic Frameworks
Abstract
The reversible capture of water vapor at low humidity can enable transformative applications such as atmospheric water harvesting and heat transfer that uses water as a refrigerant, replacing environmentally detrimental hydro- and chloro-fluorocarbons. The driving force for these applications is governed by the relative humidity at which the pores of a porous material fill with water. Here, we demonstrate modulation of the onset of pore-filling in a family of metal-organic frameworks with record water sorption capacities by employing anion exchange. Unexpectedly, the replacement of the structural bridging Cl- with the more hydrophilic anions F- and OH- does not induce porefilling at lower relative humidity, whereas the introduction of the larger Br- results in a substantial shift toward lower relative humidity. We rationalize these results in terms of pore size modifications as well as the water hydrogen bonding structure based on detailed infrared spectroscopic measurements. Fundamentally, our data suggest that, in the presence of strong nucleation sites, the thermodynamic favorability of water pore-filling depends more strongly on the pore diameter and the interface between water in the center of the pore and water bound to the pore walls than the hydrophilicity of the pore wall itself. On the basis of thesemore »
- Authors:
-
[1];
[1];
[2];
[1]
- Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States). Dept. of Chemistry
- Univ. of Oregon, Eugene, OR (United States). Dept. of Chemistry and Biochemistry
- Publication Date:
- Research Org.:
- Argonne National Laboratory (ANL), Argonne, IL (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- Contributing Org.:
- Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States)
- OSTI Identifier:
- 1560063
- Grant/Contract Number:
- AC02-06CH11357
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of the American Chemical Society
- Additional Journal Information:
- Journal Volume: 141; Journal Issue: 35; Journal ID: ISSN 0002-7863
- Publisher:
- American Chemical Society (ACS)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Rieth, Adam J., Wright, Ashley M., Skorupskii, Grigorii, Mancuso, Jenna L., Hendon, Christopher H., and Dincă, Mircea. Record-Setting Sorbents for Reversible Water Uptake by Systematic Anion Exchanges in Metal–Organic Frameworks. United States: N. p., 2019.
Web. doi:10.1021/jacs.9b06246.
Rieth, Adam J., Wright, Ashley M., Skorupskii, Grigorii, Mancuso, Jenna L., Hendon, Christopher H., & Dincă, Mircea. Record-Setting Sorbents for Reversible Water Uptake by Systematic Anion Exchanges in Metal–Organic Frameworks. United States. https://doi.org/10.1021/jacs.9b06246
Rieth, Adam J., Wright, Ashley M., Skorupskii, Grigorii, Mancuso, Jenna L., Hendon, Christopher H., and Dincă, Mircea. Fri .
"Record-Setting Sorbents for Reversible Water Uptake by Systematic Anion Exchanges in Metal–Organic Frameworks". United States. https://doi.org/10.1021/jacs.9b06246. https://www.osti.gov/servlets/purl/1560063.
@article{osti_1560063,
title = {Record-Setting Sorbents for Reversible Water Uptake by Systematic Anion Exchanges in Metal–Organic Frameworks},
author = {Rieth, Adam J. and Wright, Ashley M. and Skorupskii, Grigorii and Mancuso, Jenna L. and Hendon, Christopher H. and Dincă, Mircea},
abstractNote = {The reversible capture of water vapor at low humidity can enable transformative applications such as atmospheric water harvesting and heat transfer that uses water as a refrigerant, replacing environmentally detrimental hydro- and chloro-fluorocarbons. The driving force for these applications is governed by the relative humidity at which the pores of a porous material fill with water. Here, we demonstrate modulation of the onset of pore-filling in a family of metal-organic frameworks with record water sorption capacities by employing anion exchange. Unexpectedly, the replacement of the structural bridging Cl- with the more hydrophilic anions F- and OH- does not induce porefilling at lower relative humidity, whereas the introduction of the larger Br- results in a substantial shift toward lower relative humidity. We rationalize these results in terms of pore size modifications as well as the water hydrogen bonding structure based on detailed infrared spectroscopic measurements. Fundamentally, our data suggest that, in the presence of strong nucleation sites, the thermodynamic favorability of water pore-filling depends more strongly on the pore diameter and the interface between water in the center of the pore and water bound to the pore walls than the hydrophilicity of the pore wall itself. On the basis of these results, we report two materials that exhibit record water uptake capacities in their respective humidity regions and extended stability over 400 water adsorption-desorption cycles.},
doi = {10.1021/jacs.9b06246},
journal = {Journal of the American Chemical Society},
number = 35,
volume = 141,
place = {United States},
year = {Fri Aug 09 00:00:00 EDT 2019},
month = {Fri Aug 09 00:00:00 EDT 2019}
}
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Figures / Tables:
Figure 1: Structure of Ni2X2BTDD (X = Cl, F, Br, OH). Left: View parallel to the c axis. Right: View of anion-exchanged SBUs perpendicular to the c axis and synthetic pathways.
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Highly Hydrophobic Isoreticular Porous Metal-Organic Frameworks for the Capture of Harmful Volatile Organic Compounds
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Effect of functional groups in MIL-101 on water sorption behavior
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Adsorption-Based Atmospheric Water Harvesting: Impact of Material and Component Properties on System-Level Performance
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Synthesis of Highly Crystalline NH 2 -MIL-125 (Ti) with S-Shaped Water Isotherms for Adsorption Heat Transformation
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Computational Exploration of the Water Concentration Dependence of the Proton Transport in the Porous UiO–66(Zr)–(CO 2 H) 2 Metal–Organic Framework
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A Functional Full-Scale Heat Exchanger Coated with Aluminum Fumarate Metal–Organic Framework for Adsorption Heat Transformation
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Infrared Spectroscopy of Protonated Phenol–Water Clusters
journal, June 2018
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Metal–Organic Frameworks in Adsorption-Driven Heat Pumps: The Potential of Alcohols as Working Fluids
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Tuning Water Sorption in Highly Stable Zr(IV)-Metal–Organic Frameworks through Local Functionalization of Metal Clusters
journal, July 2018
- Zhang, Yong-Zheng; He, Tao; Kong, Xiang-Jing
- ACS Applied Materials & Interfaces, Vol. 10, Issue 33
Record Atmospheric Fresh Water Capture and Heat Transfer with a Material Operating at the Water Uptake Reversibility Limit
journal, May 2017
- Rieth, Adam J.; Yang, Sungwoo; Wang, Evelyn N.
- ACS Central Science, Vol. 3, Issue 6
Water Sorption Cycle Measurements on Functionalized MIL-101Cr for Heat Transformation Application
journal, February 2013
- Khutia, Anupam; Rammelberg, Holger Urs; Schmidt, Thomas
- Chemistry of Materials, Vol. 25, Issue 5
The Determination of Pore Volume and Area Distributions in Porous Substances. I. Computations from Nitrogen Isotherms
journal, January 1951
- Barrett, Elliott P.; Joyner, Leslie G.; Halenda, Paul P.
- Journal of the American Chemical Society, Vol. 73, Issue 1
Unusual Hydrogen Bonding in Water-Filled Carbon Nanotubes
journal, September 2006
- Byl, Oleg; Liu, Jin-Chen; Wang, Yang
- Journal of the American Chemical Society, Vol. 128, Issue 37
Water Adsorption in Porous Metal–Organic Frameworks and Related Materials
journal, March 2014
- Furukawa, Hiroyasu; Gándara, Felipe; Zhang, Yue-Biao
- Journal of the American Chemical Society, Vol. 136, Issue 11, p. 4369-4381
Water in Carbon Nanotubes: The Peculiar Hydrogen Bond Network Revealed by Infrared Spectroscopy
journal, August 2016
- Dalla Bernardina, Simona; Paineau, Erwan; Brubach, Jean-Blaise
- Journal of the American Chemical Society, Vol. 138, Issue 33
High and Reversible Ammonia Uptake in Mesoporous Azolate Metal–Organic Frameworks with Open Mn, Co, and Ni Sites
journal, July 2016
- Rieth, Adam J.; Tulchinsky, Yuri; Dincă, Mircea
- Journal of the American Chemical Society, Vol. 138, Issue 30
Controlled Gas Uptake in Metal–Organic Frameworks with Record Ammonia Sorption
journal, February 2018
- Rieth, Adam J.; Dincă, Mircea
- Journal of the American Chemical Society, Vol. 140, Issue 9
Tunable Metal–Organic Frameworks Enable High-Efficiency Cascaded Adsorption Heat Pumps
journal, November 2018
- Rieth, Adam J.; Wright, Ashley M.; Rao, Sameer
- Journal of the American Chemical Society, Vol. 140, Issue 50
Reticular Access to Highly Porous acs -MOFs with Rigid Trigonal Prismatic Linkers for Water Sorption
journal, February 2019
- Chen, Zhijie; Li, Penghao; Zhang, Xuan
- Journal of the American Chemical Society, Vol. 141, Issue 7
Application of Large Pore MCM-41 Molecular Sieves To Improve Pore Size Analysis Using Nitrogen Adsorption Measurements
journal, November 1997
- Kruk, M.; Jaroniec, M.; Sayari, A.
- Langmuir, Vol. 13, Issue 23
Formation of ordered ice nanotubes inside carbon nanotubes
journal, August 2001
- Koga, Kenichiro; Gao, G. T.; Tanaka, Hideki
- Nature, Vol. 412, Issue 6849
Water structural transformation at molecular hydrophobic interfaces
journal, November 2012
- Davis, Joel G.; Gierszal, Kamil P.; Wang, Ping
- Nature, Vol. 491, Issue 7425
Adsorption-based atmospheric water harvesting device for arid climates
journal, March 2018
- Kim, Hyunho; Rao, Sameer R.; Kapustin, Eugene A.
- Nature Communications, Vol. 9, Issue 1
A robust large-pore zirconium carboxylate metal–organic framework for energy-efficient water-sorption-driven refrigeration
journal, October 2018
- Wang, Sujing; Lee, Ji Sun; Wahiduzzaman, Mohammad
- Nature Energy, Vol. 3, Issue 11
Postsynthetic tuning of hydrophilicity in pyrazolate MOFs to modulate water adsorption properties
journal, January 2013
- Wade, Casey R.; Corrales-Sanchez, Tachmajal; Narayan, Tarun C.
- Energy & Environmental Science, Vol. 6, Issue 7
The Chemistry and Applications of Metal-Organic Frameworks
journal, August 2013
- Furukawa, H.; Cordova, K. E.; O'Keeffe, M.
- Science, Vol. 341, Issue 6149, p. 1230444-1230444
Fast elementary steps in chemical reaction mechanisms
journal, January 1963
- Eigen, M.
- Pure and Applied Chemistry, Vol. 6, Issue 1
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