Chemically controlled crystal growth of (CH3NH3) 2 AgInBr6
Abstract
We report the successful crystal growth of a previously unknown mixed-metal organic compound (CH3NH3)2AgInBr6. This phase, which is not obtained by direct combination of reactants, is crystallized through the use of Pb2+ (from CH3NH3PbBr3) to modulate the soluble intermediates and force formation of (CH3NH3)2AgInBr6. Lastly, our results provide insights into mechanism and design-driven crystal growth and discovery of new halide materials that are chemically related to perovskites with photovoltaic and related applications.
- Authors:
-
[1];
[1];
[1];
[1];
[1];
[2];
[3]
- Johns Hopkins Univ., Baltimore, MD (United States). Inst. for Quantum Matter
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Spallation Neutron Source (SNS)
- Department of Chemistry; Department of Physics and Astronomy; Institute for Quantum Matter; Johns Hopkins University; Baltimore
- Publication Date:
- Research Org.:
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1559738
- Alternate Identifier(s):
- OSTI ID: 1455078
- Grant/Contract Number:
- AC05-00OR22725
- Resource Type:
- Accepted Manuscript
- Journal Name:
- CrystEngComm
- Additional Journal Information:
- Journal Volume: 20; Journal Issue: 39; Journal ID: ISSN 1466-8033
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE
Citation Formats
Tran, Thao T., Quintero, Michael A., Arpino, Kathryn E., Kelly, Zachary A., Panella, Jessica R., Wang, Xiaoping, and McQueen, Tyrel M. Chemically controlled crystal growth of (CH3NH3) 2 AgInBr6. United States: N. p., 2018.
Web. doi:10.1039/C8CE00702K.
Tran, Thao T., Quintero, Michael A., Arpino, Kathryn E., Kelly, Zachary A., Panella, Jessica R., Wang, Xiaoping, & McQueen, Tyrel M. Chemically controlled crystal growth of (CH3NH3) 2 AgInBr6. United States. https://doi.org/10.1039/C8CE00702K
Tran, Thao T., Quintero, Michael A., Arpino, Kathryn E., Kelly, Zachary A., Panella, Jessica R., Wang, Xiaoping, and McQueen, Tyrel M. Wed .
"Chemically controlled crystal growth of (CH3NH3) 2 AgInBr6". United States. https://doi.org/10.1039/C8CE00702K. https://www.osti.gov/servlets/purl/1559738.
@article{osti_1559738,
title = {Chemically controlled crystal growth of (CH3NH3) 2 AgInBr6},
author = {Tran, Thao T. and Quintero, Michael A. and Arpino, Kathryn E. and Kelly, Zachary A. and Panella, Jessica R. and Wang, Xiaoping and McQueen, Tyrel M.},
abstractNote = {We report the successful crystal growth of a previously unknown mixed-metal organic compound (CH3NH3)2AgInBr6. This phase, which is not obtained by direct combination of reactants, is crystallized through the use of Pb2+ (from CH3NH3PbBr3) to modulate the soluble intermediates and force formation of (CH3NH3)2AgInBr6. Lastly, our results provide insights into mechanism and design-driven crystal growth and discovery of new halide materials that are chemically related to perovskites with photovoltaic and related applications.},
doi = {10.1039/C8CE00702K},
journal = {CrystEngComm},
number = 39,
volume = 20,
place = {United States},
year = {Wed Jun 13 00:00:00 EDT 2018},
month = {Wed Jun 13 00:00:00 EDT 2018}
}
Free Publicly Available Full Text
Publisher's Version of Record
Other availability
Search WorldCat to find libraries that may hold this journal
Cited by: 16 works
Citation information provided by
Web of Science
Web of Science
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Synthesis and Properties of a Lead-Free Hybrid Double Perovskite: (CH 3 NH 3 ) 2 AgBiBr 6
journal, January 2017
- Wei, Fengxia; Deng, Zeyu; Sun, Shijing
- Chemistry of Materials, Vol. 29, Issue 3
Interplay between defects, disorder and flexibility in metal-organic frameworks
journal, December 2016
- Bennett, Thomas D.; Cheetham, Anthony K.; Fuchs, Alain H.
- Nature Chemistry, Vol. 9, Issue 1
Synthesis and Characterization of the Rare-Earth Hybrid Double Perovskites: (CH 3 NH 3 ) 2 KGdCl 6 and (CH 3 NH 3 ) 2 KYCl 6
journal, September 2017
- Deng, Zeyu; Wei, Fengxia; Brivio, Federico
- The Journal of Physical Chemistry Letters, Vol. 8, Issue 20
The crystal structure of BaNiO3
journal, August 1976
- Takeda, Y.; Kanamura, F.; Shimada, M.
- Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry, Vol. 32, Issue 8
Formation of Stable Mixed Guanidinium–Methylammonium Phases with Exceptionally Long Carrier Lifetimes for High-Efficiency Lead Iodide-Based Perovskite Photovoltaics
journal, February 2018
- Kubicki, Dominik J.; Prochowicz, Daniel; Hofstetter, Albert
- Journal of the American Chemical Society, Vol. 140, Issue 9
The Role of Oxygen in the Degradation of Methylammonium Lead Trihalide Perovskite Photoactive Layers
journal, May 2015
- Aristidou, Nicholas; Sanchez-Molina, Irene; Chotchuangchutchaval, Thana
- Angewandte Chemie International Edition, Vol. 54, Issue 28
Cs 2 InAgCl 6 : A New Lead-Free Halide Double Perovskite with Direct Band Gap
journal, January 2017
- Volonakis, George; Haghighirad, Amir Abbas; Milot, Rebecca L.
- The Journal of Physical Chemistry Letters, Vol. 8, Issue 4
Kinetics of Ion Transport in Perovskite Active Layers and Its Implications for Active Layer Stability
journal, September 2015
- Bag, Monojit; Renna, Lawrence A.; Adhikari, Ramesh Y.
- Journal of the American Chemical Society, Vol. 137, Issue 40
Syntheses and structure of hydrothermally prepared CsNiX3 (X=Cl, Br, I)
journal, August 2012
- Raw, Adam D.; Ibers, James A.; Poeppelmeier, Kenneth R.
- Journal of Solid State Chemistry, Vol. 192
The synthesis, structure and electronic properties of a lead-free hybrid inorganic–organic double perovskite (MA) 2 KBiCl 6 (MA = methylammonium)
journal, January 2016
- Wei, Fengxia; Deng, Zeyu; Sun, Shijing
- Materials Horizons, Vol. 3, Issue 4
White-Light Emission and Structural Distortion in New Corrugated Two-Dimensional Lead Bromide Perovskites
journal, March 2017
- Mao, Lingling; Wu, Yilei; Stoumpos, Constantinos C.
- Journal of the American Chemical Society, Vol. 139, Issue 14
Thin Films and Solar Cells Based on Semiconducting Two-Dimensional Ruddlesden–Popper (CH 3 (CH 2 ) 3 NH 3 ) 2 (CH 3 NH 3 ) n −1 Sn n I 3 n +1 Perovskites
journal, April 2017
- Cao, Duyen H.; Stoumpos, Constantinos C.; Yokoyama, Takamichi
- ACS Energy Letters, Vol. 2, Issue 5
Interplay of Orientational Order and Electronic Structure in Methylammonium Lead Iodide: Implications for Solar Cell Operation
journal, November 2014
- Quarti, Claudio; Mosconi, Edoardo; De Angelis, Filippo
- Chemistry of Materials, Vol. 26, Issue 22
Thermal Behavior of Methylammonium Lead-Trihalide Perovskite Photovoltaic Light Harvesters
journal, October 2014
- Dualeh, Amalie; Gao, Peng; Seok, Sang Il
- Chemistry of Materials, Vol. 26, Issue 21
Relativistic quasiparticle self-consistent electronic structure of hybrid halide perovskite photovoltaic absorbers
journal, April 2014
- Brivio, Federico; Butler, Keith T.; Walsh, Aron
- Physical Review B, Vol. 89, Issue 15
Atomistic Origins of High-Performance in Hybrid Halide Perovskite Solar Cells
journal, April 2014
- Frost, Jarvist M.; Butler, Keith T.; Brivio, Federico
- Nano Letters, Vol. 14, Issue 5
High-efficiency two-dimensional Ruddlesden–Popper perovskite solar cells
journal, July 2016
- Tsai, Hsinhan; Nie, Wanyi; Blancon, Jean-Christophe
- Nature, Vol. 536, Issue 7616
Dielectric and Thermodynamic Signatures of Low-Temperature Glassy Dynamics in the Hybrid Perovskites CH 3 NH 3 PbI 3 and HC(NH 2 ) 2 PbI 3
journal, January 2016
- Fabini, Douglas H.; Hogan, Tom; Evans, Hayden A.
- The Journal of Physical Chemistry Letters, Vol. 7, Issue 3
Exploring the properties of lead-free hybrid double perovskites using a combined computational-experimental approach
journal, January 2016
- Deng, Zeyu; Wei, Fengxia; Sun, Shijing
- Journal of Materials Chemistry A, Vol. 4, Issue 31
Complete structure and cation orientation in the perovskite photovoltaic methylammonium lead iodide between 100 and 352 K
journal, January 2015
- Weller, Mark T.; Weber, Oliver J.; Henry, Paul F.
- Chemical Communications, Vol. 51, Issue 20
Band Gaps of the Lead-Free Halide Double Perovskites Cs 2 BiAgCl 6 and Cs 2 BiAgBr 6 from Theory and Experiment
journal, June 2016
- Filip, Marina R.; Hillman, Samuel; Haghighirad, Amir Abbas
- The Journal of Physical Chemistry Letters, Vol. 7, Issue 13
Charge Accumulation and Hysteresis in Perovskite-Based Solar Cells: An Electro-Optical Analysis
journal, July 2015
- Wu, Bo; Fu, Kunwu; Yantara, Natalia
- Advanced Energy Materials, Vol. 5, Issue 19
Direct–indirect character of the bandgap in methylammonium lead iodide perovskite
journal, October 2016
- Hutter, Eline M.; Gélvez-Rueda, María C.; Osherov, Anna
- Nature Materials, Vol. 16, Issue 1
Evolution of Chemical Composition, Morphology, and Photovoltaic Efficiency of CH 3 NH 3 PbI 3 Perovskite under Ambient Conditions
journal, December 2015
- Huang, Weixin; Manser, Joseph S.; Kamat, Prashant V.
- Chemistry of Materials, Vol. 28, Issue 1
The Origin of Lower Hole Carrier Concentration in Methylammonium Tin Halide Films Grown by a Vapor-Assisted Solution Process
journal, December 2016
- Yokoyama, Takamichi; Song, Tze-Bin; Cao, Duyen H.
- ACS Energy Letters, Vol. 2, Issue 1
Monitoring a Silent Phase Transition in CH 3 NH 3 PbI 3 Solar Cells via Operando X-ray Diffraction
journal, October 2016
- Schelhas, Laura T.; Christians, Jeffrey A.; Berry, Joseph J.
- ACS Energy Letters, Vol. 1, Issue 5
The infrared spectra of solid methylammonium halides
journal, June 1962
- Cabana, A.; Sandorfy, C.
- Spectrochimica Acta, Vol. 18, Issue 6
Universal Dynamics of Molecular Reorientation in Hybrid Lead Iodide Perovskites
journal, November 2017
- Fabini, Douglas H.; Siaw, Ting Ann; Stoumpos, Constantinos C.
- Journal of the American Chemical Society, Vol. 139, Issue 46
Efficient Lead-Free Solar Cells Based on Hollow {en}MASnI 3 Perovskites
journal, October 2017
- Ke, Weijun; Stoumpos, Constantinos C.; Spanopoulos, Ioannis
- Journal of the American Chemical Society, Vol. 139, Issue 41
Cs 2 AgBiX 6 (X = Br, Cl): New Visible Light Absorbing, Lead-Free Halide Perovskite Semiconductors
journal, February 2016
- McClure, Eric T.; Ball, Molly R.; Windl, Wolfgang
- Chemistry of Materials, Vol. 28, Issue 5
Orientation of Organic Cations in Hybrid Inorganic–Organic Perovskite CH 3 NH 3 PbI 3 from Subatomic Resolution Single Crystal Neutron Diffraction Structural Studies
journal, April 2016
- Ren, Yixin; Oswald, Iain W. H.; Wang, Xiaoping
- Crystal Growth & Design, Vol. 16, Issue 5
Revealing the detailed path of sequential deposition for metal halide perovskite formation
journal, February 2018
- Ummadisingu, Amita; Grätzel, Michael
- Science Advances, Vol. 4, Issue 2
Lead-free solid-state organic–inorganic halide perovskite solar cells
journal, May 2014
- Hao, Feng; Stoumpos, Constantinos C.; Cao, Duyen Hanh
- Nature Photonics, Vol. 8, Issue 6
Tailored Engineering of an Unusual (C 4 H 9 NH 3 ) 2 (CH 3 NH 3 ) 2 Pb 3 Br 10 Two-Dimensional Multilayered Perovskite Ferroelectric for a High-Performance Photodetector
journal, September 2017
- Li, Lina; Sun, Zhihua; Wang, Peng
- Angewandte Chemie International Edition, Vol. 56, Issue 40
Chemically diverse and multifunctional hybrid organic–inorganic perovskites
journal, February 2017
- Li, Wei; Wang, Zheming; Deschler, Felix
- Nature Reviews Materials, Vol. 2, Issue 3
A Bismuth-Halide Double Perovskite with Long Carrier Recombination Lifetime for Photovoltaic Applications
journal, February 2016
- Slavney, Adam H.; Hu, Te; Lindenberg, Aaron M.
- Journal of the American Chemical Society, Vol. 138, Issue 7
Designing indirect–direct bandgap transitions in double perovskites
journal, January 2017
- Tran, T. Thao; Panella, Jessica R.; Chamorro, Juan R.
- Materials Horizons, Vol. 4, Issue 4
The Role of Oxygen in the Degradation of Methylammonium Lead Trihalide Perovskite Photoactive Layers
journal, May 2015
- Aristidou, Nicholas; Sanchez-Molina, Irene; Chotchuangchutchaval, Thana
- Angewandte Chemie, Vol. 127, Issue 28
Tailored Engineering of an Unusual (C 4 H 9 NH 3 ) 2 (CH 3 NH 3 ) 2 Pb 3 Br 10 Two-Dimensional Multilayered Perovskite Ferroelectric for a High-Performance Photodetector
journal, September 2017
- Li, Lina; Sun, Zhihua; Wang, Peng
- Angewandte Chemie, Vol. 129, Issue 40
The synthesis, structure and electronic properties of a lead-free hybrid inorganic–organic double perovskite (MA)2KBiCl6 (MA = methylammonium)
text, January 2018
- Wei, Fengxia; Deng, Zeyu; Sun, Shijing
- Apollo - University of Cambridge Repository
Direct-indirect character of the bandgap in methylammonium lead iodide perovskite.
text, January 2017
- Hutter, Em; Gélvez-Rueda, Mc; Osherov, A.
- Apollo - University of Cambridge Repository
Relativistic quasiparticle self-consistent electronic structure of hybrid halide perovskite photovoltaic absorbers
text, January 2014
- Brivio, Federico; Butler, Keith T.; Walsh, Aron
- arXiv
Exploring the properties of lead-free hybrid double perovskites using a combined computational-experimental approach
text, January 2016
- Deng, Zeyu; Wei, Fengxia; Sun, Shijing
- arXiv
Works referencing / citing this record:
Structural Diversity and Magnetic Properties of Hybrid Ruthenium Halide Perovskites and Related Compounds
journal, April 2020
- Vishnoi, Pratap; Zuo, Julia L.; Strom, T. Amanda
- Angewandte Chemie International Edition, Vol. 59, Issue 23
Advances in lead-free double perovskite nanocrystals, engineering band-gaps and enhancing stability through composition tunability
journal, January 2019
- Khalfin, Sasha; Bekenstein, Yehonadav
- Nanoscale, Vol. 11, Issue 18
Additive-assisted synthesis and optoelectronic properties of (CH 3 NH 3 ) 4 Bi 6 I 22
journal, January 2020
- Sharma, Manila; Yangui, Aymen; Lusson, Alain
- Inorganic Chemistry Frontiers, Vol. 7, Issue 7
Structural Diversity and Magnetic Properties of Hybrid Ruthenium Halide Perovskites and Related Compounds
journal, April 2020
- Vishnoi, Pratap; Zuo, Julia L.; Strom, T. Amanda
- Angewandte Chemie, Vol. 132, Issue 23