Search Menu
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information
Search Scholarly Publications

Title: Syntheses of Colloidal F:In2O3 Cubes: Fluorine-Induced Faceting and Infrared Plasmonic Response

Abstract

Cube-shaped nanocrystals (NCs) of conventional metals like gold and silver generally exhibit localized surface plasmon resonance (LSPR) in the visible region with spectral modes determined by their faceted shapes. Yet, faceted NCs exhibiting LSPR response in the infrared (IR) region are relatively rare. Here, we describe the colloidal synthesis of nanoscale fluorine-doped indium oxide (F:In2O3) cubes with LSPR response in the IR region, wherein fluorine was discovered to both direct the cubic morphology and act as an aliovalent dopant. Single-crystalline 160 nm F:In2O3 cubes terminated by (100) facets and concave cubes were synthesized using a colloidal heat-up method. The presence of fluorine was found to impart higher stabilization to the (100) facets through density functional theory calculations that evaluated the energetics of F-substitution at surface oxygen sites. These calculations suggest that the cubic morphology results from surface binding of F atoms. In addition, fluorine acts as an anionic aliovalent dopant in the cubic bixbyite lattice of In2O3, introducing a high concentration of free electrons leading to LSPR. We confirmed the presence of lattice fluorine dopants in these cubes using solid-state 19F and 115In nuclear magnetic resonance spectroscopy. The cubes exhibit narrow, shape-dependent multimodal LSPR extinction peaks due to corner- andmore » edge-centered modes. The spatial origin of these different contributions to the spectral response is directly visualized by electron energy loss spectroscopy in a scanning transmission electron microscope.« less

Authors:
ORCiD logo [1]; ORCiD logo [1]; ORCiD logo [2]; ORCiD logo [3];  [1];  [1];  [1]; ORCiD logo [4];  [1];  [1]; ORCiD logo [1];  [3]; ORCiD logo [2]; ORCiD logo [1]
+ Show Author Affiliations
  1. Univ. of Texas, Austin, TX (United States)
  2. Univ. of California, Santa Barbara, CA (United States)
  3. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
  4. Materials Department, University of California, Santa Barbara, Engineering II Building 1355, Santa Barbara, California 93106-5050, United States
Publication Date:
Research Org.:
Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
Sponsoring Org.:
USDOE Office of Energy Efficiency and Renewable Energy (EERE); USDOE Office of Science (SC), Basic Energy Sciences (BES). Scientific User Facilities Division; National Science Foundation (NSF)
OSTI Identifier:
1558540
Grant/Contract Number:  
AC05-00OR22725
Resource Type:
Accepted Manuscript
Journal Name:
Chemistry of Materials
Additional Journal Information:
Journal Volume: 31; Journal Issue: 7; Journal ID: ISSN 0897-4756
Publisher:
American Chemical Society (ACS)
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Cho, Shin Hum, Ghosh, Sandeep, Berkson, Zachariah J., Hachtel, Jordan A., Shi, Jianjian, Zhao, Xunhua, Reimnitz, Lauren C., Dahlman, Clayton J., Ho, Yujing, Yang, Anni, Liu, Yuanyue, Idrobo, Juan-Carlos, Chmelka, Bradley F., and Milliron, Delia J. Syntheses of Colloidal F:In2O3 Cubes: Fluorine-Induced Faceting and Infrared Plasmonic Response. United States: N. p., 2019. Web. doi:10.1021/acs.chemmater.9b00906.
Copy to clipboard
Cho, Shin Hum, Ghosh, Sandeep, Berkson, Zachariah J., Hachtel, Jordan A., Shi, Jianjian, Zhao, Xunhua, Reimnitz, Lauren C., Dahlman, Clayton J., Ho, Yujing, Yang, Anni, Liu, Yuanyue, Idrobo, Juan-Carlos, Chmelka, Bradley F., & Milliron, Delia J. Syntheses of Colloidal F:In2O3 Cubes: Fluorine-Induced Faceting and Infrared Plasmonic Response. United States. https://doi.org/10.1021/acs.chemmater.9b00906
Copy to clipboard
Cho, Shin Hum, Ghosh, Sandeep, Berkson, Zachariah J., Hachtel, Jordan A., Shi, Jianjian, Zhao, Xunhua, Reimnitz, Lauren C., Dahlman, Clayton J., Ho, Yujing, Yang, Anni, Liu, Yuanyue, Idrobo, Juan-Carlos, Chmelka, Bradley F., and Milliron, Delia J. Thu . "Syntheses of Colloidal F:In2O3 Cubes: Fluorine-Induced Faceting and Infrared Plasmonic Response". United States. https://doi.org/10.1021/acs.chemmater.9b00906. https://www.osti.gov/servlets/purl/1558540.
Copy to clipboard
@article{osti_1558540,
title = {Syntheses of Colloidal F:In2O3 Cubes: Fluorine-Induced Faceting and Infrared Plasmonic Response},
author = {Cho, Shin Hum and Ghosh, Sandeep and Berkson, Zachariah J. and Hachtel, Jordan A. and Shi, Jianjian and Zhao, Xunhua and Reimnitz, Lauren C. and Dahlman, Clayton J. and Ho, Yujing and Yang, Anni and Liu, Yuanyue and Idrobo, Juan-Carlos and Chmelka, Bradley F. and Milliron, Delia J.},
abstractNote = {Cube-shaped nanocrystals (NCs) of conventional metals like gold and silver generally exhibit localized surface plasmon resonance (LSPR) in the visible region with spectral modes determined by their faceted shapes. Yet, faceted NCs exhibiting LSPR response in the infrared (IR) region are relatively rare. Here, we describe the colloidal synthesis of nanoscale fluorine-doped indium oxide (F:In2O3) cubes with LSPR response in the IR region, wherein fluorine was discovered to both direct the cubic morphology and act as an aliovalent dopant. Single-crystalline 160 nm F:In2O3 cubes terminated by (100) facets and concave cubes were synthesized using a colloidal heat-up method. The presence of fluorine was found to impart higher stabilization to the (100) facets through density functional theory calculations that evaluated the energetics of F-substitution at surface oxygen sites. These calculations suggest that the cubic morphology results from surface binding of F atoms. In addition, fluorine acts as an anionic aliovalent dopant in the cubic bixbyite lattice of In2O3, introducing a high concentration of free electrons leading to LSPR. We confirmed the presence of lattice fluorine dopants in these cubes using solid-state 19F and 115In nuclear magnetic resonance spectroscopy. The cubes exhibit narrow, shape-dependent multimodal LSPR extinction peaks due to corner- and edge-centered modes. The spatial origin of these different contributions to the spectral response is directly visualized by electron energy loss spectroscopy in a scanning transmission electron microscope.},
doi = {10.1021/acs.chemmater.9b00906},
journal = {Chemistry of Materials},
number = 7,
volume = 31,
place = {United States},
year = {Thu Mar 21 00:00:00 EDT 2019},
month = {Thu Mar 21 00:00:00 EDT 2019}
}
Copy to clipboard
Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
https://doi.org/10.1021/acs.chemmater.9b00906
Copyright Statement
Other availability
Search WorldCat Search WorldCat to find libraries that may hold this journal
Citation Metrics:
Cited by: 31 works
Citation information provided by
Web of Science
Save / Share:
Export Metadata
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.

Works referenced in this record:

Localized Surface Plasmon Resonance in Semiconductor Nanocrystals
journal, February 2018

One-step solvothermal synthesis of cubic-shaped ITO nanoparticles precisely controlled in size and shape and their electrical resistivity
journal, January 2010

  • Sasaki, Takafumi; Endo, Yosuke; Nakaya, Masafumi
  • Journal of Materials Chemistry, Vol. 20, Issue 37
  • DOI: 10.1039/c0jm01338b

Shape-Controlled Synthesis of Colloidal Metal Nanocrystals: Thermodynamic versus Kinetic Products
journal, June 2015

  • Xia, Younan; Xia, Xiaohu; Peng, Hsin-Chieh
  • Journal of the American Chemical Society, Vol. 137, Issue 25
  • DOI: 10.1021/jacs.5b04641

Polyhedral Gold Nanocrystals with O h Symmetry:  From Octahedra to Cubes
journal, November 2006

  • Seo, Daeha; Park, Ji Chan; Song, Hyunjoon
  • Journal of the American Chemical Society, Vol. 128, Issue 46
  • DOI: 10.1021/ja062892u

Facile Synthesis of Silver Nanocubes with Sharp Corners and Edges in an Aqueous Solution
journal, September 2016

Size-Controlled Synthesis of Au/Pd Octopods with High Refractive Index Sensitivity
journal, February 2012

  • DeSantis, Christopher J.; Skrabalak, Sara E.
  • Langmuir, Vol. 28, Issue 24
  • DOI: 10.1021/la3002509

Optical Absorption Spectra of Nanocrystal Gold Molecules
journal, May 1997

  • Alvarez, Marcos M.; Khoury, Joseph T.; Schaaff, T. Gregory
  • The Journal of Physical Chemistry B, Vol. 101, Issue 19
  • DOI: 10.1021/jp962922n

Alternative Plasmonic Materials: Beyond Gold and Silver
journal, May 2013

  • Naik, Gururaj V.; Shalaev, Vladimir M.; Boltasseva, Alexandra
  • Advanced Materials, Vol. 25, Issue 24
  • DOI: 10.1002/adma.201205076

Localized surface plasmon resonances arising from free carriers in doped quantum dots
journal, April 2011

  • Luther, Joseph M.; Jain, Prashant K.; Ewers, Trevor
  • Nature Materials, Vol. 10, Issue 5, p. 361-366
  • DOI: 10.1038/nmat3004

Shape-Dependent Field Enhancement and Plasmon Resonance of Oxide Nanocrystals
journal, March 2015

  • Agrawal, Ankit; Kriegel, Ilka; Milliron, Delia J.
  • The Journal of Physical Chemistry C, Vol. 119, Issue 11
  • DOI: 10.1021/acs.jpcc.5b01648

Indium Tin Oxide Nanoparticles with Compositionally Tunable Surface Plasmon Resonance Frequencies in the Near-IR Region
journal, December 2009

  • Kanehara, Masayuki; Koike, Hayato; Yoshinaga, Taizo
  • Journal of the American Chemical Society, Vol. 131, Issue 49
  • DOI: 10.1021/ja9064415

Tunable Infrared Absorption and Visible Transparency of Colloidal Aluminum-Doped Zinc Oxide Nanocrystals
journal, November 2011

  • Buonsanti, Raffaella; Llordes, Anna; Aloni, Shaul
  • Nano Letters, Vol. 11, Issue 11, p. 4706-4710
  • DOI: 10.1021/nl203030f

Shape-Dependent Plasmonic Response and Directed Self-Assembly in a New Semiconductor Building Block, Indium-Doped Cadmium Oxide (ICO)
journal, May 2013

  • Gordon, Thomas R.; Paik, Taejong; Klein, Dahlia R.
  • Nano Letters, Vol. 13, Issue 6, p. 2857-2863
  • DOI: 10.1021/nl4012003

The Many “Facets” of Halide Ions in the Chemistry of Colloidal Inorganic Nanocrystals
journal, July 2018

On the role of surface diffusion in determining the shape or morphology of noble-metal nanocrystals
journal, April 2013

  • Xia, X.; Xie, S.; Liu, M.
  • Proceedings of the National Academy of Sciences, Vol. 110, Issue 17
  • DOI: 10.1073/pnas.1222109110

Titanium Dioxide Crystals with Tailored Facets
journal, May 2014

  • Liu, Gang; Yang, Hua Gui; Pan, Jian
  • Chemical Reviews, Vol. 114, Issue 19
  • DOI: 10.1021/cr400621z

Shape Evolution of CdSe Nanoparticles Controlled by Halogen Compounds
journal, January 2014

  • Meyns, Michaela; Iacono, Fabiola; Palencia, Cristina
  • Chemistry of Materials, Vol. 26, Issue 5
  • DOI: 10.1021/cm4037082

Pyramid-Shaped Wurtzite CdSe Nanocrystals with Inverted Polarity
journal, July 2015

Expanding the Spectral Tunability of Plasmonic Resonances in Doped Metal-Oxide Nanocrystals through Cooperative Cation–Anion Codoping
journal, August 2014

  • Ye, Xingchen; Fei, Jiayang; Diroll, Benjamin T.
  • Journal of the American Chemical Society, Vol. 136, Issue 33
  • DOI: 10.1021/ja5039903

Resonant Coupling between Molecular Vibrations and Localized Surface Plasmon Resonance of Faceted Metal Oxide Nanocrystals
journal, March 2017

Nonaqueous Synthesis of TiO 2 Nanocrystals Using TiF 4 to Engineer Morphology, Oxygen Vacancy Concentration, and Photocatalytic Activity
journal, April 2012

  • Gordon, Thomas R.; Cargnello, Matteo; Paik, Taejong
  • Journal of the American Chemical Society, Vol. 134, Issue 15
  • DOI: 10.1021/ja300823a

Study on the Defect Structure of SnO 2 :F Nanoparticles by High-Resolution Solid-State NMR
journal, March 2011

  • Avadhut, Yamini S.; Weber, Johannes; Hammarberg, Elin
  • Chemistry of Materials, Vol. 23, Issue 6
  • DOI: 10.1021/cm103286t

Localized Surface Plasmon Resonance Spectroscopy of Single Silver Nanocubes
journal, October 2005

  • Sherry, Leif J.; Chang, Shih-Hui; Schatz, George C.
  • Nano Letters, Vol. 5, Issue 10
  • DOI: 10.1021/nl0515753

Ultrafast spontaneous emission source using plasmonic nanoantennas
journal, July 2015

  • Hoang, Thang B.; Akselrod, Gleb M.; Argyropoulos, Christos
  • Nature Communications, Vol. 6, Issue 1
  • DOI: 10.1038/ncomms8788

Halide-Directed Synthesis of Square Prismatic Ag Nanocrystals by the Polyol Method
journal, June 2018

Single gold nanostars enhance Raman scattering
journal, April 2009

  • Hrelescu, Calin; Sau, Tapan K.; Rogach, Andrey L.
  • Applied Physics Letters, Vol. 94, Issue 15
  • DOI: 10.1063/1.3119642

Surface-Enhanced Raman Spectroscopy
journal, July 2008

Compound Copper Chalcogenide Nanocrystals
journal, April 2017

Localized Surface Plasmon Resonances of Anisotropic Semiconductor Nanocrystals
journal, November 2011

  • Hsu, Su-Wen; On, Kathy; Tao, Andrea R.
  • Journal of the American Chemical Society, Vol. 133, Issue 47
  • DOI: 10.1021/ja2089876

InN Nanocrystals, Nanowires, and Nanotubes
journal, September 2004

Control of Plasmonic and Interband Transitions in Colloidal Indium Nitride Nanocrystals
journal, September 2013

  • Palomaki, Peter K. B.; Miller, Elisa M.; Neale, Nathan R.
  • Journal of the American Chemical Society, Vol. 135, Issue 38
  • DOI: 10.1021/ja404599g

The Interplay of Shape and Crystalline Anisotropies in Plasmonic Semiconductor Nanocrystals
journal, May 2016

GSAS-II : the genesis of a modern open-source all purpose crystallography software package
journal, March 2013

Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set
journal, October 1996

From ultrasoft pseudopotentials to the projector augmented-wave method
journal, January 1999

Generalized Gradient Approximation Made Simple
journal, October 1996

  • Perdew, John P.; Burke, Kieron; Ernzerhof, Matthias
  • Physical Review Letters, Vol. 77, Issue 18, p. 3865-3868
  • DOI: 10.1103/PhysRevLett.77.3865

Special points for Brillouin-zone integrations
journal, June 1976

  • Monkhorst, Hendrik J.; Pack, James D.
  • Physical Review B, Vol. 13, Issue 12, p. 5188-5192
  • DOI: 10.1103/PhysRevB.13.5188

Electrical and ionic conductivity effects on magic-angle spinning nuclear magnetic resonance parameters of CuI
journal, December 2010

  • Yesinowski, James P.; Ladouceur, Harold D.; Purdy, Andrew P.
  • The Journal of Chemical Physics, Vol. 133, Issue 23
  • DOI: 10.1063/1.3526484

Measurement of sample temperatures under magic-angle spinning from the chemical shift and spin-lattice relaxation rate of 79Br in KBr powder
journal, January 2009

Symmetry-Based 29 Si Dipolar Recoupling Magic Angle Spinning NMR Spectroscopy:  A New Method for Investigating Three-Dimensional Structures of Zeolite Frameworks
journal, January 2005

  • Brouwer, Darren H.; Kristiansen, Per Eugen; Fyfe, Colin A.
  • Journal of the American Chemical Society, Vol. 127, Issue 2
  • DOI: 10.1021/ja043228l

Application of the Carr−Purcell Meiboom−Gill Pulse Sequence for the Acquisition of Solid-State NMR Spectra of Spin- 1 / 2 Nuclei
journal, August 2004

  • Hung, Ivan; Rossini, Aaron J.; Schurko, Robert W.
  • The Journal of Physical Chemistry A, Vol. 108, Issue 34
  • DOI: 10.1021/jp0401123

Monochromated STEM with a 30 meV-wide, atom-sized electron probe
journal, January 2013

  • Krivanek, Ondrej L.; Lovejoy, Tracy C.; Dellby, Niklas
  • Microscopy, Vol. 62, Issue 1
  • DOI: 10.1093/jmicro/dfs089

Local low rank denoising for enhanced atomic resolution imaging
journal, April 2018

Formation of Nearly Monodisperse In 2 O 3 Nanodots and Oriented-Attached Nanoflowers:  Hydrolysis and Alcoholysis vs Pyrolysis
journal, August 2006

  • Narayanaswamy, Arun; Xu, Huifang; Pradhan, Narayan
  • Journal of the American Chemical Society, Vol. 128, Issue 31
  • DOI: 10.1021/ja0627601

Non-monotonic Size Dependence of Electron Mobility in Indium Oxide Nanocrystals Thin Film Transistor
journal, August 2014

Influence of Iron Oleate Complex Structure on Iron Oxide Nanoparticle Formation
journal, July 2007

  • Bronstein, Lyudmila M.; Huang, Xinlei; Retrum, John
  • Chemistry of Materials, Vol. 19, Issue 15
  • DOI: 10.1021/cm062948j

Molecular mechanism of monodisperse colloidal tin-doped indium oxide nanocrystals by a hot-injection approach
journal, April 2013

Aminolysis Route to Monodisperse Titania Nanorods with Tunable Aspect Ratio
journal, May 2005

  • Zhang, Zhihua; Zhong, Xinhua; Liu, Shuhua
  • Angewandte Chemie International Edition, Vol. 44, Issue 22
  • DOI: 10.1002/anie.200500410

Shape-Controlled Synthesis of Zinc Oxide: A Simple Method for the Preparation of Metal Oxide Nanocrystals in Non-aqueous Medium
journal, January 2007

  • Zhang, Zhihua; Lu, Meihua; Xu, Hairuo
  • Chemistry - A European Journal, Vol. 13, Issue 2
  • DOI: 10.1002/chem.200600293

Kinetics and Mechanisms of Aggregative Nanocrystal Growth
journal, September 2013

  • Wang, Fudong; Richards, Vernal N.; Shields, Shawn P.
  • Chemistry of Materials, Vol. 26, Issue 1
  • DOI: 10.1021/cm402139r

Influence of Dopant Distribution on the Plasmonic Properties of Indium Tin Oxide Nanocrystals
journal, April 2014

  • Lounis, Sebastien D.; Runnerstrom, Evan L.; Bergerud, Amy
  • Journal of the American Chemical Society, Vol. 136, Issue 19
  • DOI: 10.1021/ja502541z

Thermodynamics versus Kinetics in Nanosynthesis
journal, December 2014

  • Wang, Yawen; He, Jiating; Liu, Cuicui
  • Angewandte Chemie International Edition, Vol. 54, Issue 7
  • DOI: 10.1002/anie.201402986

Anatase TiO2 single crystals with a large percentage of reactive facets
journal, May 2008

  • Yang, Hua Gui; Sun, Cheng Hua; Qiao, Shi Zhang
  • Nature, Vol. 453, Issue 7195
  • DOI: 10.1038/nature06964

Modification of Indium Tin Oxide Films by Alkanethiol and Fatty Acid Self-Assembled Monolayers:  A Comparative Study
journal, March 2006

  • Karsi, Nadia; Lang, Philippe; Chehimi, Mohamed
  • Langmuir, Vol. 22, Issue 7
  • DOI: 10.1021/la052677b

Structure, stability and work functions of the low index surfaces of pure indium oxide and Sn-doped indium oxide (ITO) from density functional theory
journal, January 2010

  • Walsh, Aron; Catlow, C. Richard A.
  • Journal of Materials Chemistry, Vol. 20, Issue 46
  • DOI: 10.1039/c0jm01816c

Living Nanocrystals
journal, June 2017

Mechanism and controlled growth of shape and size variant core/shell FeO/Fe3O4 nanoparticles
journal, January 2013

  • Khurshid, Hafsa; Li, Wanfeng; Chandra, Sayan
  • Nanoscale, Vol. 5, Issue 17
  • DOI: 10.1039/c3nr02596a

NMR parameters in column 13 metal fluoride compounds (AlF3, GaF3, InF3 and TlF) from first principle calculations
journal, May 2014

Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides
journal, September 1976

Structural and electrical properties of fluorine doped tin oxide films prepared by spray-pyrolysis technique
journal, November 2006

Fluorine‐doped indium oxide thin films prepared by chemical vapor deposition
journal, March 1992

  • Maruyama, Toshiro; Nakai, Tsuyoshi
  • Journal of Applied Physics, Vol. 71, Issue 6
  • DOI: 10.1063/1.351023

Electrical properties and defect model of tin-doped indium oxide layers
journal, April 1982

  • Frank, G.; K�stlin, H.
  • Applied Physics A Solids and Surfaces, Vol. 27, Issue 4
  • DOI: 10.1007/BF00619080

Size-induced lattice relaxation in CeO2 nanoparticles
journal, November 2001

  • Zhou, X. -D.; Huebner, W.
  • Applied Physics Letters, Vol. 79, Issue 21
  • DOI: 10.1063/1.1419235

Structural Studies of Tin-Doped Indium Oxide (ITO) and In4Sn3O12
journal, January 1998

  • Nadaud, N.; Lequeux, N.; Nanot, M.
  • Journal of Solid State Chemistry, Vol. 135, Issue 1
  • DOI: 10.1006/jssc.1997.7613

Physicochemical characterization of point defects in fluorine doped tin oxide films
journal, July 2012

  • Akkad, Fikry El; Joseph, Sudeep
  • Journal of Applied Physics, Vol. 112, Issue 2
  • DOI: 10.1063/1.4736798

New compositions of fluoroindate glasses with higher chemical resistance
journal, January 1998

Tracking the Local Effect of Fluorine Self-Doping in Anodic TiO 2 Nanotubes
journal, February 2016

  • Li, Jun; Liu, Changhai; Ye, Yifan
  • The Journal of Physical Chemistry C, Vol. 120, Issue 8
  • DOI: 10.1021/acs.jpcc.5b11445

Surface oxygen vacancy origin of electron accumulation in indium oxide
journal, June 2011

Epsilon-near-Zero Modes and Surface Plasmon Resonance in Fluorine-Doped Cadmium Oxide Thin Films
journal, July 2017

Solution-Processed Flexible Fluorine-doped Indium Zinc Oxide Thin-Film Transistors Fabricated on Plastic Film at Low Temperature
journal, June 2013

  • Seo, Jin-Suk; Jeon, Jun-Hyuck; Hwang, Young Hwan
  • Scientific Reports, Vol. 3, Issue 1
  • DOI: 10.1038/srep02085

Comparison of extra electrons in colloidal n-type Al3+-doped and photochemically reduced ZnO nanocrystals
journal, January 2012

  • Schimpf, Alina M.; Ochsenbein, Stefan T.; Buonsanti, Raffaella
  • Chemical Communications, Vol. 48, Issue 75
  • DOI: 10.1039/c2cc34635d

Controlling Carrier Densities in Photochemically Reduced Colloidal ZnO Nanocrystals: Size Dependence and Role of the Hole Quencher
journal, October 2013

  • Schimpf, Alina M.; Gunthardt, Carolyn E.; Rinehart, Jeffrey D.
  • Journal of the American Chemical Society, Vol. 135, Issue 44
  • DOI: 10.1021/ja408030u

Origin of Visible Photoluminescence of ZnO Quantum Dots: Defect-Dependent and Size-Dependent
journal, May 2010

  • Zhang, Luyuan; Yin, Longwei; Wang, Chengxiang
  • The Journal of Physical Chemistry C, Vol. 114, Issue 21
  • DOI: 10.1021/jp101324a

Electron Confinement Effects in the EPR Spectra of Colloidal n-Type ZnO Quantum Dots
journal, August 2008

  • Whitaker, Kelly M.; Ochsenbein, Stefan T.; Polinger, Victor Z.
  • The Journal of Physical Chemistry C, Vol. 112, Issue 37
  • DOI: 10.1021/jp804763y

Nb-Doped Colloidal TiO 2 Nanocrystals with Tunable Infrared Absorption
journal, August 2013

  • De Trizio, Luca; Buonsanti, Raffaella; Schimpf, Alina M.
  • Chemistry of Materials, Vol. 25, Issue 16
  • DOI: 10.1021/cm402396c

Fluorine sites in calcium and barium oxyfluorides: F-19 NMR on crystalline model compounds and glasses
journal, August 2002

The Effect of Fictive Temperature on the Structural Environment of Fluorine in Silicate and Aluminosilicate Glasses
journal, January 2006

Spatially correlated distributions of local metallic properties in bulk and nanocrystalline GaN
journal, June 2017

  • Yesinowski, James P.; Berkson, Zachariah J.; Cadars, Sylvian
  • Physical Review B, Vol. 95, Issue 23
  • DOI: 10.1103/PhysRevB.95.235201

Nuclear Magnetic Resonance Shift in Metals
journal, October 1949

Principles of Magnetic Resonance
book, January 1990

Nuclear magnetic relaxation and resonnance line shift in metals
journal, July 1950

Phase transition in In3Sb5O12 by NQR of 115In nuclei
journal, April 1987

Solid‐state ‘‘magic‐angle’’ sample‐spinning nuclear magnetic resonance spectroscopic study of group III–V (13–15) semiconductors
journal, November 1988

  • Han, Oc Hee; Timken, Hye Kyung C.; Oldfield, Eric
  • The Journal of Chemical Physics, Vol. 89, Issue 10
  • DOI: 10.1063/1.455418

Characterization of wurtzite indium nitride synthesized from indium oxide by In-115 MAS NMR spectroscopy
journal, June 2007

Ultra-Wideline Solid-State NMR Spectroscopy
journal, June 2013

  • Schurko, Robert W.
  • Accounts of Chemical Research, Vol. 46, Issue 9
  • DOI: 10.1021/ar400045t

Broadband solid-state MAS NMR of paramagnetic systems
journal, February 2015

2 H and 27 Al Solid-State NMR Study of the Local Environments in Al-Doped 2-Line Ferrihydrite, Goethite, and Lepidocrocite
journal, May 2015

Controlling the Mechanism of Excitonic Splitting in In 2 O 3 Nanocrystals by Carrier Delocalization
journal, October 2018

Three-dimensional imaging of localized surface plasmon resonances of metal nanoparticles
journal, October 2013

  • Nicoletti, Olivia; de la Peña, Francisco; Leary, Rowan K.
  • Nature, Vol. 502, Issue 7469
  • DOI: 10.1038/nature12469

Plasmonic resonances and hot spots in Ag octopods
journal, January 2010

  • Naumov, Ivan I.; Li, Zhiyong; Bratkovsky, Alexander M.
  • Applied Physics Letters, Vol. 96, Issue 3
  • DOI: 10.1063/1.3273859

Anisotropic Etching of Silver Nanoparticles for Plasmonic Structures Capable of Single-Particle SERS
journal, January 2010

  • Mulvihill, Martin J.; Ling, Xing Yi; Henzie, Joel
  • Journal of the American Chemical Society, Vol. 132, Issue 1
  • DOI: 10.1021/ja906954f

Optical excitations in electron microscopy
journal, February 2010

Exploring the capabilities of monochromated electron energy loss spectroscopy in the infrared regime
journal, April 2018

Spatially Mapping Energy Transfer from Single Plasmonic Particles to Semiconductor Substrates via STEM/EELS
journal, April 2015

Resonances of nanoparticles with poor plasmonic metal tips
journal, November 2015

  • Ringe, Emilie; DeSantis, Christopher J.; Collins, Sean M.
  • Scientific Reports, Vol. 5, Issue 1
  • DOI: 10.1038/srep17431

Direct observation of narrow mid-infrared plasmon linewidths of single metal oxide nanocrystals
journal, May 2016

  • Johns, Robert W.; Bechtel, Hans A.; Runnerstrom, Evan L.
  • Nature Communications, Vol. 7, Issue 1
  • DOI: 10.1038/ncomms11583

Efficient Nanosecond Photoluminescence from Infrared PbS Quantum Dots Coupled to Plasmonic Nanoantennas
journal, September 2016

    Sort by:
    [ × clear filter / sort ]

    Works referencing / citing this record:

    Spectrally tunable infrared plasmonic F,Sn:In 2 O 3 nanocrystal cubes
    journal, January 2020

    • Cho, Shin Hum; Roccapriore, Kevin M.; Dass, Chandriker Kavir
    • The Journal of Chemical Physics, Vol. 152, Issue 1
    • DOI: 10.1063/1.5139050

    Emerging Electron Microscopy Techniques for Probing Functional Interfaces in Energy Materials
    journal, January 2020

    • Zachman, Michael J.; Hachtel, Jordan A.; Idrobo, Juan Carlos
    • Angewandte Chemie International Edition, Vol. 59, Issue 4
    • DOI: 10.1002/anie.201902993
      Sort by:
      [ × clear filter / sort ]

      Similar Records in DOE PAGES and OSTI.GOV collections: