High-pressure, high-temperature molecular doping of nanodiamond
Abstract
The development of color centers in diamond as the basis for emerging quantum technologies has been limited by the need for ion implantation to create the appropriate defects. We present a versatile method to dope diamond without ion implantation by synthesis of a doped amorphous carbon precursor and transformation at high temperatures and high pressures. To explore this bottom-up method for color center generation, we rationally create silicon vacancy defects in nanodiamond and investigate them for optical pressure metrology. In addition, we show that this process can generate noble gas defects within diamond from the typically inactive argon pressure medium, which may explain the hysteresis effects observed in other high-pressure experiments and the presence of noble gases in some meteoritic nanodiamonds. Our results illustrate a general method to produce color centers in diamond and may enable the controlled generation of designer defects.
- Authors:
-
[1];
[1];
[1];
[1];
[1];
[2];
- Univ. of Washington, Seattle, WA (United States)
- Naval Research Lab, Washington, D.C. (United States)
- Univ. of Washington, Seattle, WA (United States); Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
- Publication Date:
- Research Org.:
- Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1557733
- Report Number(s):
- PNNL-SA-145794
Journal ID: ISSN 2375-2548
- Grant/Contract Number:
- AC05-76RL01830
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Science Advances
- Additional Journal Information:
- Journal Volume: 5; Journal Issue: 5; Journal ID: ISSN 2375-2548
- Publisher:
- AAAS
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE
Citation Formats
Crane, Matthew J., Petrone, Alessio, Beck, Ryan A., Lim, Matthew B., Zhou, Xiaoyuan, Li, Xiaosong, Stroud, Rhonda M., and Pauzauskie, Peter J. High-pressure, high-temperature molecular doping of nanodiamond. United States: N. p., 2019.
Web. doi:10.1126/sciadv.aau6073.
Crane, Matthew J., Petrone, Alessio, Beck, Ryan A., Lim, Matthew B., Zhou, Xiaoyuan, Li, Xiaosong, Stroud, Rhonda M., & Pauzauskie, Peter J. High-pressure, high-temperature molecular doping of nanodiamond. United States. https://doi.org/10.1126/sciadv.aau6073
Crane, Matthew J., Petrone, Alessio, Beck, Ryan A., Lim, Matthew B., Zhou, Xiaoyuan, Li, Xiaosong, Stroud, Rhonda M., and Pauzauskie, Peter J. Fri .
"High-pressure, high-temperature molecular doping of nanodiamond". United States. https://doi.org/10.1126/sciadv.aau6073. https://www.osti.gov/servlets/purl/1557733.
@article{osti_1557733,
title = {High-pressure, high-temperature molecular doping of nanodiamond},
author = {Crane, Matthew J. and Petrone, Alessio and Beck, Ryan A. and Lim, Matthew B. and Zhou, Xiaoyuan and Li, Xiaosong and Stroud, Rhonda M. and Pauzauskie, Peter J.},
abstractNote = {The development of color centers in diamond as the basis for emerging quantum technologies has been limited by the need for ion implantation to create the appropriate defects. We present a versatile method to dope diamond without ion implantation by synthesis of a doped amorphous carbon precursor and transformation at high temperatures and high pressures. To explore this bottom-up method for color center generation, we rationally create silicon vacancy defects in nanodiamond and investigate them for optical pressure metrology. In addition, we show that this process can generate noble gas defects within diamond from the typically inactive argon pressure medium, which may explain the hysteresis effects observed in other high-pressure experiments and the presence of noble gases in some meteoritic nanodiamonds. Our results illustrate a general method to produce color centers in diamond and may enable the controlled generation of designer defects.},
doi = {10.1126/sciadv.aau6073},
journal = {Science Advances},
number = 5,
volume = 5,
place = {United States},
year = {Fri May 03 00:00:00 EDT 2019},
month = {Fri May 03 00:00:00 EDT 2019}
}
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Works referenced in this record:
Electronic structures and spectroscopic signatures of silicon-vacancy containing nanodiamonds
journal, November 2018
- Petrone, Alessio; Beck, Ryan A.; Kasper, Joseph M.
- Physical Review B, Vol. 98, Issue 20
Electronic Properties and Metrology Applications of the Diamond Center under Pressure
journal, January 2014
- Doherty, Marcus W.; Struzhkin, Viktor V.; Simpson, David A.
- Physical Review Letters, Vol. 112, Issue 4
Characteristics and origin of the 1.681 eV luminescence center in chemical‐vapor‐deposited diamond films
journal, February 1993
- Feng, Tom; Schwartz, Bradley D.
- Journal of Applied Physics, Vol. 73, Issue 3
Ice-VII inclusions in diamonds: Evidence for aqueous fluid in Earth’s deep mantle
journal, March 2018
- Tschauner, O.; Huang, S.; Greenberg, E.
- Science, Vol. 359, Issue 6380
Effect of helium on structure and compression behavior of SiO2 glass
journal, March 2011
- Shen, G.; Mei, Q.; Prakapenka, V. B.
- Proceedings of the National Academy of Sciences, Vol. 108, Issue 15
Structure, Bonding, and Geochemistry of Xenon at High Pressures
journal, August 1997
- Caldwell, W. A.
- Science, Vol. 277, Issue 5328
Coherent control of a strongly driven silicon vacancy optical transition in diamond
journal, February 2017
- Zhou, Yu; Rasmita, Abdullah; Li, Ke
- Nature Communications, Vol. 8, Issue 1
Molecular-sized fluorescent nanodiamonds
journal, December 2013
- Vlasov, Igor I.; Shiryaev, Andrey A.; Rendler, Torsten
- Nature Nanotechnology, Vol. 9, Issue 1
Interstellar diamonds in meteorites
journal, March 1987
- Lewis, Roy S.; Ming, Tang; Wacker, John F.
- Nature, Vol. 326, Issue 6109
Shear-Induced Isostructural Phase Transition and Metallization of Layered Tungsten Disulfide under Nonhydrostatic Compression
journal, February 2016
- Duwal, Sakun; Yoo, Choong-Shik
- The Journal of Physical Chemistry C, Vol. 120, Issue 9
Optical signatures of silicon-vacancy spins in diamond
journal, February 2014
- Müller, Tina; Hepp, Christian; Pingault, Benjamin
- Nature Communications, Vol. 5, Issue 1
Varying temperature and silicon content in nanodiamond growth: effects on silicon-vacancy centres
journal, February 2018
- Choi, Sumin; Leong, Victor; Davydov, Valery A.
- Scientific Reports, Vol. 8, Issue 1
Results obtained with the correlation energy density functionals of becke and Lee, Yang and Parr
journal, May 1989
- Miehlich, Burkhard; Savin, Andreas; Stoll, Hermann
- Chemical Physics Letters, Vol. 157, Issue 3
Experimental measurement of the diamond nucleation landscape reveals classical and nonclassical features
journal, August 2018
- Gebbie, Matthew A.; Ishiwata, Hitoshi; McQuade, Patrick J.
- Proceedings of the National Academy of Sciences, Vol. 115, Issue 33
Isotopic anomalies in organic nanoglobules from Comet 81P/Wild 2: Comparison to Murchison nanoglobules and isotopic anomalies induced in terrestrial organics by electron irradiation
journal, August 2010
- De Gregorio, Bradley T.; Stroud, Rhonda M.; Nittler, Larry R.
- Geochimica et Cosmochimica Acta, Vol. 74, Issue 15
An efficient implementation of time-dependent density-functional theory for the calculation of excitation energies of large molecules
journal, November 1998
- Stratmann, R. Eric; Scuseria, Gustavo E.; Frisch, Michael J.
- The Journal of Chemical Physics, Vol. 109, Issue 19
Proper Surface Termination for Luminescent Near-Surface NV Centers in Diamond
journal, July 2014
- Kaviani, Moloud; Deák, Peter; Aradi, Bálint
- Nano Letters, Vol. 14, Issue 8
Silicon-Vacancy Spin Qubit in Diamond: A Quantum Memory Exceeding 10 ms with Single-Shot State Readout
journal, November 2017
- Sukachev, D. D.; Sipahigil, A.; Nguyen, C. T.
- Physical Review Letters, Vol. 119, Issue 22
Ab initio study of the split silicon-vacancy defect in diamond: Electronic structure and related properties
journal, December 2013
- Gali, Adam; Maze, Jeronimo R.
- Physical Review B, Vol. 88, Issue 23
Raman spectroscopy of amorphous, nanostructured, diamond–like carbon, and nanodiamond
journal, September 2004
- Ferrari, Andrea Carlo; Robertson, John
- Philosophical Transactions of the Royal Society of London. Series A: Mathematical, Physical and Engineering Sciences, Vol. 362, Issue 1824
Size tunable synthesis of solution processable diamond nanocrystals
journal, January 2014
- Mandal, Manik; Haso, Fadi; Liu, Tianbo
- Chem. Commun., Vol. 50, Issue 77
Nanoscale nuclear magnetic resonance with chemical resolution
journal, June 2017
- Aslam, Nabeel; Pfender, Matthias; Neumann, Philipp
- Science, Vol. 357, Issue 6346
Complexes of silicon, vacancy, and hydrogen in diamond: A density functional study
journal, October 2015
- Thiering, Gergő; Gali, Adam
- Physical Review B, Vol. 92, Issue 16
The properties and applications of nanodiamonds
journal, December 2011
- Mochalin, Vadym N.; Shenderova, Olga; Ho, Dean
- Nature Nanotechnology, Vol. 7, Issue 1
Calibration of the ruby pressure gauge to 800 kbar under quasi-hydrostatic conditions
journal, January 1986
- Mao, H. K.; Xu, J.; Bell, P. M.
- Journal of Geophysical Research, Vol. 91, Issue B5, p. 4673-4676
C, N, and Noble Gas Isotopes in Grain Size Separates of Presolar Diamonds from Efremovka
journal, August 1998
- Verchovsky, A. B.
- Science, Vol. 281, Issue 5380
Effect of Surface Passivation on Nanodiamond Crystallinity
journal, March 2018
- Beck, Ryan A.; Petrone, Alessio; Kasper, Joseph M.
- The Journal of Physical Chemistry C, Vol. 122, Issue 15
Supernova Shock-Wave-Induced Co-Formation of Glassy Carbon and Nanodiamond
journal, August 2011
- Stroud, Rhonda M.; Chisholm, Matthew F.; Heck, Philipp R.
- The Astrophysical Journal, Vol. 738, Issue 2
The Twelve-Line 1.682 eV Luminescence Center in Diamond and the Vacancy-Silicon Complex
journal, September 1996
- Goss, J. P.; Jones, R.; Breuer, S. J.
- Physical Review Letters, Vol. 77, Issue 14
Synthesis and characterization of a nanocrystalline diamond aerogel
journal, May 2011
- Pauzauskie, P. J.; Crowhurst, J. C.; Worsley, M. A.
- Proceedings of the National Academy of Sciences, Vol. 108, Issue 21, p. 8550-8553
Density‐functional thermochemistry. III. The role of exact exchange
journal, April 1993
- Becke, Axel D.
- The Journal of Chemical Physics, Vol. 98, Issue 7, p. 5648-5652
Single-Reference ab Initio Methods for the Calculation of Excited States of Large Molecules
journal, November 2005
- Dreuw, Andreas; Head-Gordon, Martin
- Chemical Reviews, Vol. 105, Issue 11
Nanoscale Detection of a Single Fundamental Charge in Ambient Conditions Using the Center in Diamond
journal, March 2014
- Dolde, Florian; Doherty, Marcus W.; Michl, Julia
- Physical Review Letters, Vol. 112, Issue 9
An overview of noble gas (He, Ne, Ar, Xe) contents and isotope signals in terrestrial diamond
journal, November 2013
- Basu, S.; Jones, A. P.; Verchovsky, A. B.
- Earth-Science Reviews, Vol. 126
Development of the Colle-Salvetti correlation-energy formula into a functional of the electron density
journal, January 1988
- Lee, Chengteh; Yang, Weitao; Parr, Robert G.
- Physical Review B, Vol. 37, Issue 2
Pressure-induced transition in titanium metal a systematic study of the effects of uniaxial stress
journal, January 2005
- Errandonea, Daniel; Meng, Y.; Somayazulu, M.
- Physica B: Condensed Matter, Vol. 355, Issue 1-4, p. 116-125
Quantum confinement effects on optical transitions in nanodiamonds containing nitrogen vacancies
journal, October 2016
- Petrone, Alessio; Goings, Joshua J.; Li, Xiaosong
- Physical Review B, Vol. 94, Issue 16
Properties of diamond under hydrostatic pressures up to 140 GPa
journal, February 2003
- Occelli, Florent; Loubeyre, Paul; LeToullec, René
- Nature Materials, Vol. 2, Issue 3
Creation and nature of optical centres in diamond for single-photon emission—overview and critical remarks
journal, March 2011
- Pezzagna, Sébastien; Rogalla, Detlef; Wildanger, Dominik
- New Journal of Physics, Vol. 13, Issue 3
Electronic structure of the negatively charged silicon-vacancy center in diamond
journal, June 2014
- Rogers, Lachlan J.; Jahnke, Kay D.; Doherty, Marcus W.
- Physical Review B, Vol. 89, Issue 23
Terapascal static pressure generation with ultrahigh yield strength nanodiamond
text, January 2016
- Dubrovinskaia, Natalia; Dubrovinsky, Leonid; Solopova, Natalia A.
- Karlsruhe
Organic aerogels from the polycondensation of resorcinol with formaldehyde
journal, September 1989
- Pekala, R. W.
- Journal of Materials Science, Vol. 24, Issue 9
Optical signatures of silicon-vacancy spins in diamond
text, January 2014
- Muller, T.; Hepp, C.; Pingault, Benjamin
- Apollo - University of Cambridge Repository
Transformation of the state of nitrogen in diamond
journal, November 1977
- Chrenko, R. M.; Tuft, R. E.; Strong, H. M.
- Nature, Vol. 270, Issue 5633
Electronic structure of neutral silicon-vacancy complex in diamond
journal, November 2003
- Moliver, S. S.
- Technical Physics, Vol. 48, Issue 11
History of trace gases in presolar diamonds inferred from ion-implantation experiments
journal, August 2001
- Koscheev, A. P.; Gromov, M. D.; Mohapatra, R. K.
- Nature, Vol. 412, Issue 6847
The Mechanism of Diamond Nucleation from Energetic Species
journal, August 2002
- Lifshitz, Y.
- Science, Vol. 297, Issue 5586
Photothermal effects during nanodiamond synthesis from a carbon aerogel in a laser-heated diamond anvil cell
journal, August 2018
- Crane, Matthew J.; Smith, Bennett E.; Meisenheimer, Peter B.
- Diamond and Related Materials, Vol. 87
High-pressure structural and electronic properties of carbon
journal, August 1987
- Fahy, S.; Louie, Steven G.
- Physical Review B, Vol. 36, Issue 6
Single-Reference ab initio Methods for the Calculation of Excited States of Large Molecules
journal, January 2006
- Dreuw, Andreas; Head-Gordon, Martin
- ChemInform, Vol. 37, Issue 5
Terapascal static pressure generation with ultrahigh yield strength nanodiamond
journal, July 2016
- Dubrovinskaia, Natalia; Dubrovinsky, Leonid; Solopova, Natalia A.
- Science Advances, Vol. 2, Issue 7
Optical properties of implanted Xe color centers in diamond
journal, March 2018
- Sandstrom, Russell; Ke, Li; Martin, Aiden
- Optics Communications, Vol. 411
Production of activated carbons from a washington lignite using phosphoric acid activation
journal, January 1996
- Toles, C.; Rimmer, S.; Hower, J. C.
- Carbon, Vol. 34, Issue 11
Noble-gas enrichment in vapour-growth diamonds and the origin of diamonds in ureilites
journal, July 1987
- Fukunaga, Kazuya; Matsuda, Jun-ichi; Nagao, Keisuke
- Nature, Vol. 328, Issue 6126
CaSiO3 perovskite in diamond indicates the recycling of oceanic crust into the lower mantle
journal, March 2018
- Nestola, F.; Korolev, N.; Kopylova, M.
- Nature, Vol. 555, Issue 7695
Electronic Structure of the Silicon Vacancy Color Center in Diamond
journal, January 2014
- Hepp, Christian; Müller, Tina; Waselowski, Victor
- Physical Review Letters, Vol. 112, Issue 3
Density functional simulations of silicon-containing point defects in diamond
journal, August 2007
- Goss, J. P.; Briddon, P. R.; Shaw, M. J.
- Physical Review B, Vol. 76, Issue 7
The pressure-temperature phase and transformation diagram for carbon; updated through 1994
journal, January 1996
- Bundy, F. P.; Bassett, W. A.; Weathers, M. S.
- Carbon, Vol. 34, Issue 2
Development of the Colle-Salvetti correlation-energy formula into a functional of the electron density
text, January 1988
- Robert, Parr,; Chengteh, Lee,; Weitao, Yang,
- The University of North Carolina at Chapel Hill University Libraries
Electronic structure of the negatively-charged silicon-vacancy center in diamond
text, January 2013
- Rogers, Lachlan J.; Jahnke, Kay D.; Doherty, Marcus W.
- arXiv
Coherent control of a strongly driven silicon vacancy optical transition in diamond
text, January 2016
- Zhou, Yu; Rasmita, Abdullah; Li, Ke
- arXiv
Silicon-Vacancy Spin Qubit in Diamond: A Quantum Memory Exceeding 10 ms with Single-Shot State Readout
text, January 2017
- Sukachev, Denis D.; Sipahigil, Alp; Nguyen, Christian T.
- arXiv
Varying temperature and silicon content in nanodiamond growth: effects on silicon-vacancy centers
text, January 2017
- Choi, Sumin; Leong, Victor; Davydov, Valery A.
- arXiv
Single-Reference ab initio Methods for the Calculation of Excited States of Large Molecules
journal, January 2006
- Dreuw, Andreas; Head-Gordon, Martin
- ChemInform, Vol. 37, Issue 5
Shear-Induced Isostructural Phase Transition and Metallization of Layered Tungsten Disulfide under Nonhydrostatic Compression
journal, February 2016
- Duwal, Sakun; Yoo, Choong-Shik
- The Journal of Physical Chemistry C, Vol. 120, Issue 9
Effect of Surface Passivation on Nanodiamond Crystallinity
journal, March 2018
- Beck, Ryan A.; Petrone, Alessio; Kasper, Joseph M.
- The Journal of Physical Chemistry C, Vol. 122, Issue 15
Proper Surface Termination for Luminescent Near-Surface NV Centers in Diamond
journal, July 2014
- Kaviani, Moloud; Deák, Peter; Aradi, Bálint
- Nano Letters, Vol. 14, Issue 8
History of trace gases in presolar diamonds inferred from ion-implantation experiments
journal, August 2001
- Koscheev, A. P.; Gromov, M. D.; Mohapatra, R. K.
- Nature, Vol. 412, Issue 6847
CaSiO3 perovskite in diamond indicates the recycling of oceanic crust into the lower mantle
journal, March 2018
- Nestola, F.; Korolev, N.; Kopylova, M.
- Nature, Vol. 555, Issue 7695
Coherent control of a strongly driven silicon vacancy optical transition in diamond
journal, February 2017
- Zhou, Yu; Rasmita, Abdullah; Li, Ke
- Nature Communications, Vol. 8, Issue 1
Properties of diamond under hydrostatic pressures up to 140 GPa
journal, February 2003
- Occelli, Florent; Loubeyre, Paul; LeToullec, René
- Nature Materials, Vol. 2, Issue 3
Varying temperature and silicon content in nanodiamond growth: effects on silicon-vacancy centres
journal, February 2018
- Choi, Sumin; Leong, Victor; Davydov, Valery A.
- Scientific Reports, Vol. 8, Issue 1
Synthesis and characterization of a nanocrystalline diamond aerogel
journal, May 2011
- Pauzauskie, P. J.; Crowhurst, J. C.; Worsley, M. A.
- Proceedings of the National Academy of Sciences, Vol. 108, Issue 21, p. 8550-8553
Effect of helium on structure and compression behavior of SiO2 glass
journal, March 2011
- Shen, G.; Mei, Q.; Prakapenka, V. B.
- Proceedings of the National Academy of Sciences, Vol. 108, Issue 15
Experimental measurement of the diamond nucleation landscape reveals classical and nonclassical features
journal, August 2018
- Gebbie, Matthew A.; Ishiwata, Hitoshi; McQuade, Patrick J.
- Proceedings of the National Academy of Sciences, Vol. 115, Issue 33
Electronic structure of the N- V center in diamond: Theory
journal, May 1996
- Lenef, A.; Rand, S. C.
- Physical Review B, Vol. 53, Issue 20
Terapascal static pressure generation with ultrahigh yield strength nanodiamond
journal, July 2016
- Dubrovinskaia, Natalia; Dubrovinsky, Leonid; Solopova, Natalia A.
- Science Advances, Vol. 2, Issue 7
The Mechanism of Diamond Nucleation from Energetic Species
journal, August 2002
- Lifshitz, Y.
- Science, Vol. 297, Issue 5586
Observing chemical shifts from nanosamples
journal, July 2017
- Bar-Gill, Nir; Retzker, Alex
- Science, Vol. 357, Issue 6346
Optical signatures of silicon-vacancy spins in diamond
text, January 2013
- Muller, Tina; Hepp, Christian; Pingault, Benjamin
- arXiv
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- Nature Communications, Vol. 10, Issue 1
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- De Feudis, Mary; Tallaire, Alexandre; Nicolas, Louis
- Advanced Materials Interfaces, Vol. 7, Issue 2
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- arXiv
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