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Title: High-entropy alloys

Abstract

We present that alloying has long been used to confer desirable properties to materials. Typically, it involves the addition of relatively small amounts of secondary elements to a primary element. For the past decade and a half, however, a new alloying strategy that involves the combination of multiple principal elements in high concentrations to create new materials called high-entropy alloys has been in vogue. The multi-dimensional compositional space that can be tackled with this approach is practically limitless, and only tiny regions have been investigated so far. Nevertheless, a few high-entropy alloys have already been shown to possess exceptional properties, exceeding those of conventional alloys, and other outstanding high-entropy alloys are likely to be discovered in the future. In this paper, we review recent progress in understanding the salient features of high-entropy alloys. Model alloys whose behaviour has been carefully investigated are highlighted and their fundamental properties and underlying elementary mechanisms discussed. Finally, we also address the vast compositional space that remains to be explored and outline fruitful ways to identify regions within this space where high-entropy alloys with potentially interesting properties may be lurking.

Authors:
ORCiD logo [1];  [2]; ORCiD logo [3]
  1. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Univ. of Tennessee, Knoxville, TN (United States)
  2. Max-Planck-Institut für Eisenforschung, Düsseldorf (Germany)
  3. Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Univ. of California, Berkeley, CA (United States)
Publication Date:
Research Org.:
Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Materials Sciences & Engineering Division
OSTI Identifier:
1550755
Grant/Contract Number:  
AC05-00OR22725
Resource Type:
Accepted Manuscript
Journal Name:
Nature Reviews. Materials
Additional Journal Information:
Journal Volume: 4; Journal Issue: 8; Journal ID: ISSN 2058-8437
Publisher:
Nature Publishing Group
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE

Citation Formats

George, Easo P., Raabe, Dierk, and Ritchie, Robert O. High-entropy alloys. United States: N. p., 2019. Web. doi:10.1038/s41578-019-0121-4.
George, Easo P., Raabe, Dierk, & Ritchie, Robert O. High-entropy alloys. United States. https://doi.org/10.1038/s41578-019-0121-4
George, Easo P., Raabe, Dierk, and Ritchie, Robert O. Tue . "High-entropy alloys". United States. https://doi.org/10.1038/s41578-019-0121-4. https://www.osti.gov/servlets/purl/1550755.
@article{osti_1550755,
title = {High-entropy alloys},
author = {George, Easo P. and Raabe, Dierk and Ritchie, Robert O.},
abstractNote = {We present that alloying has long been used to confer desirable properties to materials. Typically, it involves the addition of relatively small amounts of secondary elements to a primary element. For the past decade and a half, however, a new alloying strategy that involves the combination of multiple principal elements in high concentrations to create new materials called high-entropy alloys has been in vogue. The multi-dimensional compositional space that can be tackled with this approach is practically limitless, and only tiny regions have been investigated so far. Nevertheless, a few high-entropy alloys have already been shown to possess exceptional properties, exceeding those of conventional alloys, and other outstanding high-entropy alloys are likely to be discovered in the future. In this paper, we review recent progress in understanding the salient features of high-entropy alloys. Model alloys whose behaviour has been carefully investigated are highlighted and their fundamental properties and underlying elementary mechanisms discussed. Finally, we also address the vast compositional space that remains to be explored and outline fruitful ways to identify regions within this space where high-entropy alloys with potentially interesting properties may be lurking.},
doi = {10.1038/s41578-019-0121-4},
journal = {Nature Reviews. Materials},
number = 8,
volume = 4,
place = {United States},
year = {Tue Jun 18 00:00:00 EDT 2019},
month = {Tue Jun 18 00:00:00 EDT 2019}
}

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Transition from high-entropy to Cu-based (TiZrNbNi) 1− x Cu x metallic glasses
journal, October 2019

  • Ristić, Ramir; Figueroa, Ignacio A.; Lachová, Andrea
  • Journal of Applied Physics, Vol. 126, Issue 15
  • DOI: 10.1063/1.5119373

Sintering mechanism of CoCrFeMnNi high-entropy alloy powders
journal, February 2018


Microstructure and properties of laser clad high-entropy alloy coating on aluminium
journal, January 2018


Microstructure stability and oxidation behaviour of (FeCoNiMo) 90 (Al/Cr) 10 high-entropy alloys
journal, August 2019


High-entropy alloys: a critical assessment of their founding principles and future prospects
journal, April 2016


Effect of microalloying with silicon on high temperature oxidation resistance of novel refractory high-entropy alloy Ta-Mo-Cr-Ti-Al
journal, October 2017


Strong grain-size effect on deformation twinning of an Al 0.1 CoCrFeNi high-entropy alloy
journal, November 2016


Microstructures and properties of high-entropy alloy films and coatings: a review
journal, February 2018


Structural and thermal properties of nanocrystalline Al x (SiFeCoNi) 100-x medium entropy alloys
journal, August 2019

  • Hana, Amina; Janjua, Naveed Kausar; Subhani, Tayyab
  • Materials Research Express, Vol. 6, Issue 10
  • DOI: 10.1088/2053-1591/ab3bd6

Outstanding radiation resistance of tungsten-based high-entropy alloys
journal, March 2019


Current and emerging practices of CALPHAD toward the development of high entropy alloys and complex concentrated alloys
journal, June 2018

  • Gorsse, Stéphane; Tancret, Franck
  • Journal of Materials Research, Vol. 33, Issue 19
  • DOI: 10.1557/jmr.2018.152

Model interatomic potentials and lattice strain in a high-entropy alloy
journal, August 2018

  • Farkas, Diana; Caro, Alfredo
  • Journal of Materials Research, Vol. 33, Issue 19
  • DOI: 10.1557/jmr.2018.245

Wear behavior of Al 0.6 CoCrFeNi high-entropy alloys: Effect of environments
journal, September 2018

  • Chen, Ming; Shi, Xiao Hui; Yang, Huijun
  • Journal of Materials Research, Vol. 33, Issue 19
  • DOI: 10.1557/jmr.2018.279

Size effects on plasticity in high-entropy alloys
journal, August 2018

  • Basu, Indranil; Ocelík, Václav; De Hosson, Jeff Th. M.
  • Journal of Materials Research, Vol. 33, Issue 19
  • DOI: 10.1557/jmr.2018.282

First report on cold-sprayed AlCoCrFeNi high-entropy alloy and its isothermal oxidation
journal, March 2019

  • Anupam, Ameey; Kumar, S.; Chavan, Naveen M.
  • Journal of Materials Research, Vol. 34, Issue 5
  • DOI: 10.1557/jmr.2019.38

Multicomponent equiatomic rare earth oxides
text, January 2016


High-entropy alloys fabricated via powder metallurgy. A critical review
text, January 2019


Enhancing the mechanical properties of casting eutectic high entropy alloys with Mo addition
journal, February 2019


Preparation of nanocrystalline high-entropy alloys via cryomilling of cast ingots
journal, May 2018

  • Kumar, Nirmal; Tiwary, C. S.; Biswas, Krishanu
  • Journal of Materials Science, Vol. 53, Issue 19
  • DOI: 10.1007/s10853-018-2485-z

Lightweight AlCrTiV high-entropy alloys with dual-phase microstructure via microalloying
journal, October 2018


Senary Refractory High-Entropy Alloy HfNbTaTiVZr
journal, September 2015

  • Gao, M. C.; Zhang, B.; Yang, S.
  • Metallurgical and Materials Transactions A, Vol. 47, Issue 7
  • DOI: 10.1007/s11661-015-3105-z

Electrosynthesis of high-entropy metallic glass nanoparticles for designer, multi-functional electrocatalysis
journal, June 2019

  • Glasscott, Matthew W.; Pendergast, Andrew D.; Goines, Sondrica
  • Nature Communications, Vol. 10, Issue 1
  • DOI: 10.1038/s41467-019-10303-z

Tailoring heterogeneities in high-entropy alloys to promote strength–ductility synergy
journal, December 2019


A high-entropy B 4 (HfMo 2 TaTi)C and SiC ceramic composite
journal, January 2019

  • Zhang, Hanzhu; Hedman, Daniel; Feng, Peizhong
  • Dalton Transactions, Vol. 48, Issue 16
  • DOI: 10.1039/c8dt04555k

“Treasure maps” for magnetic high-entropy-alloys from theory and experiment
journal, October 2015

  • Körmann, F.; Ma, D.; Belyea, D. D.
  • Applied Physics Letters, Vol. 107, Issue 14
  • DOI: 10.1063/1.4932571

Multielemental single–atom-thick A layers in nanolaminated V 2 (Sn, A ) C ( A = Fe, Co, Ni, Mn) for tailoring magnetic properties
journal, December 2019

  • Li, Youbing; Lu, Jun; Li, Mian
  • Proceedings of the National Academy of Sciences, Vol. 117, Issue 2
  • DOI: 10.1073/pnas.1916256117

Evolution of the microstructure and properties of laser-clad FeCrNiCoB x high-entropy alloy coatings
journal, January 2016


Multicomponent equiatomic rare earth oxides
journal, August 2016


Superplastic-like flow in a fine-grained equiatomic CoCrFeMnNi high-entropy alloy
journal, March 2017


Computational characterization of the structural and mechanical properties of Al x CoCrFeNiTi 1− x high entropy alloys
journal, July 2019


Microstructure characterization of AlCoCrFeNiTi high-entropy alloy coating produced by atmospheric plasma spraying
journal, September 2019


Phase evolution and thermal stability of mechanically alloyed CoCrCuFeNi high entropy alloy
journal, December 2019

  • Pandey, Vivek Kumar; Shivam, Vikas; Sarma, B. Nageswara
  • Materials Research Express, Vol. 6, Issue 12
  • DOI: 10.1088/2053-1591/ab618f

Unveiling the mechanism of abnormal magnetic behavior of FeNiCoMnCu high-entropy alloys through a joint experimental-theoretical study
journal, January 2020


High‐entropy, phase‐constrained, lanthanide sesquioxide
journal, July 2019

  • Tseng, Kuo‐Pin; Yang, Qun; McCormack, Scott J.
  • Journal of the American Ceramic Society, Vol. 103, Issue 1
  • DOI: 10.1111/jace.16689

High‐entropy transparent fluoride laser ceramics
journal, September 2019

  • Chen, Xianqiang; Wu, Yiquan
  • Journal of the American Ceramic Society, Vol. 103, Issue 2
  • DOI: 10.1111/jace.16842

Nanomechanical studies of high-entropy alloys
journal, June 2018


Effect of Ti substitution for Al on the cuboidal nanoprecipitates in Al 0.7 NiCoFeCr 2 high-entropy alloys
journal, August 2018

  • Li, Chunling; Ma, Yue; Hao, Jiamiao
  • Journal of Materials Research, Vol. 33, Issue 19
  • DOI: 10.1557/jmr.2018.213

Materials-structure-property correlation study of spark plasma sintered AlCuCrFeMnW x ( x = 0, 0.05, 0.1, 0.5) high-entropy alloys
journal, March 2019

  • Kumar, Devesh; Sharma, Vishnu K.; Prasad, Y. V. S. S.
  • Journal of Materials Research, Vol. 34, Issue 5
  • DOI: 10.1557/jmr.2019.18

A Short Review on Welding and Joining of High Entropy Alloys
journal, February 2020


The Poly-Substituted M-Type Hexaferrite Crystals Growth
journal, February 2019


Polymorphism and superconductivity in the V-Nb-Mo-Al-Ga high-entropy alloys
journal, January 2020


High Strain Rate Response of Al0.7CoCrFeNi High Entropy Alloy: Dynamic Strength Over 2 GPa from Thermomechanical Processing and Hierarchical Microstructure
journal, December 2018

  • Gangireddy, S.; Gwalani, B.; Banerjee, R.
  • Journal of Dynamic Behavior of Materials, Vol. 5, Issue 1
  • DOI: 10.1007/s40870-018-00178-4

High-entropy high-hardness metal carbides discovered by entropy descriptors
journal, November 2018


Reactive nanotemplates for synthesis of highly efficient electrocatalysts: beyond simple morphology transfer
journal, January 2019


An as-cast high-entropy alloy with remarkable mechanical properties strengthened by nanometer precipitates
journal, January 2020

  • Qin, Gang; Chen, Ruirun; Liaw, Peter K.
  • Nanoscale, Vol. 12, Issue 6
  • DOI: 10.1039/c9nr08338c

Review of high entropy ceramics: design, synthesis, structure and properties
journal, January 2019

  • Zhang, Rui-Zhi; Reece, Michael J.
  • Journal of Materials Chemistry A, Vol. 7, Issue 39
  • DOI: 10.1039/c9ta05698j

Rare-earth high entropy alloys with hexagonal close-packed structure
journal, November 2018

  • Qiao, J. W.; Bao, M. L.; Zhao, Y. J.
  • Journal of Applied Physics, Vol. 124, Issue 19
  • DOI: 10.1063/1.5051514

Structure and properties of lightweight high entropy alloys: a brief review
journal, May 2018


Microstructure and elastic constants of AlTiVMoNb refractory high-entropy alloy coating on Ti6Al4V by laser cladding
journal, September 2019


A possibility of Pd based high entropy alloy for hydrogen gas sensing applications
journal, September 2019


Modeling the structure and thermodynamics of high-entropy alloys
journal, July 2018


Dissimilar welding of Al 0.1 CoCrFeNi high-entropy alloy and AISI304 stainless steel
journal, June 2019

  • Sokkalingam, Rathinavelu; Muthupandi, Veerappan; Sivaprasad, Katakam
  • Journal of Materials Research, Vol. 34, Issue 15
  • DOI: 10.1557/jmr.2019.186

High entropy oxides for reversible energy storage
text, January 2018


Critical evaluation of glass forming ability criteria
text, January 2016


The scandium effect in multicomponent alloys
text, January 2016


Additive Manufacturing of Advanced Multi-Component Alloys: Bulk Metallic Glasses and High Entropy Alloys
journal, December 2017


Discovery of a FeCoNiPdCu High‐Entropy Alloy with Excellent Magnetic Softness
journal, February 2019

  • Koželj, Primož; Vrtnik, Stanislav; Jelen, Andreja
  • Advanced Engineering Materials, Vol. 21, Issue 5
  • DOI: 10.1002/adem.201801055

Plasma-Sprayed High Entropy Alloys: Microstructure and Properties of AlCoCrFeNi and MnCoCrFeNi
journal, November 2014

  • Ang, Andrew Siao Ming; Berndt, Christopher C.; Sesso, Mitchell L.
  • Metallurgical and Materials Transactions A, Vol. 46, Issue 2
  • DOI: 10.1007/s11661-014-2644-z

Nano-/Ultrafine Eutectic in CoCrFeNi(Nb/Ta) High-Entropy Alloys
journal, September 2018

  • Chanda, Barnasree; Verma, Abhilash; Das, Jayanta
  • Transactions of the Indian Institute of Metals, Vol. 71, Issue 11
  • DOI: 10.1007/s12666-018-1408-7

Accelerated exploration of multi-principal element alloys with solid solution phases
journal, March 2015

  • Senkov, O. N.; Miller, J. D.; Miracle, D. B.
  • Nature Communications, Vol. 6, Issue 1
  • DOI: 10.1038/ncomms7529

Comparison of the structure and properties of equiatomic and non-equiatomic multicomponent alloys
journal, January 2018


Synthesis of a single phase of high-entropy Laves intermetallics in the Ti–Zr–V–Cr–Ni equiatomic alloy
journal, December 2017


The scandium effect in multicomponent alloys
journal, April 2016


Nanomechanical behavior and structural stability of a nanocrystalline CoCrFeNiMn high-entropy alloy processed by high-pressure torsion
journal, August 2015

  • Lee, Dong-Hyun; Choi, In-Chul; Seok, Moo-Young
  • Journal of Materials Research, Vol. 30, Issue 18
  • DOI: 10.1557/jmr.2015.239

Breakthrough applications of high-entropy materials
journal, August 2018

  • Yeh, Jien-Wei; Lin, Su-Jien
  • Journal of Materials Research, Vol. 33, Issue 19
  • DOI: 10.1557/jmr.2018.283

Influence of Ti on the Tensile Properties of the High-Strength Powder Metallurgy High Entropy Alloys
journal, January 2020

  • Moravcik, Igor; Gamanov, Stepan; Moravcikova-Gouvea, Larissa
  • Materials, Vol. 13, Issue 3
  • DOI: 10.3390/ma13030578

Phase Evolution and Mechanical Behaviour of Co–Fe–Mn–Ni–Ti Eutectic High Entropy Alloys
journal, October 2018

  • Jain, Reliance; Rahul, M. R.; Jain, Sandeep
  • Transactions of the Indian Institute of Metals, Vol. 71, Issue 11
  • DOI: 10.1007/s12666-018-1437-2

Microstructure and Mechanical Properties of NiTiCuFe Multi-component Alloy
journal, September 2018

  • Sekhar, R. Anand; Nayan, Niraj; Bakshi, Srinivasa Rao
  • Transactions of the Indian Institute of Metals, Vol. 71, Issue 11
  • DOI: 10.1007/s12666-018-1444-3

Hierarchical nanostructured aluminum alloy with ultrahigh strength and large plasticity
journal, November 2019


High-Entropy Oxides: Fundamental Aspects and Electrochemical Properties
text, January 2019


High-entropy alloys fabricated via powder metallurgy. A critical review
text, January 2019


Hierarchical nanostructured aluminum alloy with ultrahigh strength and large plasticity
journal, November 2019


Influence of Ti on the Tensile Properties of the High-Strength Powder Metallurgy High Entropy Alloys
journal, January 2020

  • Moravcik, Igor; Gamanov, Stepan; Moravcikova-Gouvea, Larissa
  • Materials, Vol. 13, Issue 3
  • DOI: 10.3390/ma13030578