(CH3NH3) AuX4·H2O (X=Cl, Br) and (CH3NH3) AuCl4: Low-Band Gap Lead-Free Layered Gold Halide Perovskite Materials
Abstract
Perovskite solar cells have recently enabled power conversion efficiency comparable to established technologies such as silicon and cadmium telluride. Ongoing efforts to improve the stability of halide perovskites in ambient air has yielded promising results. However, the presence of toxic heavy element lead (Pb) remains a major concern requiring further attention. Herein, we report three new Pb-free hybrid organic–inorganic perovskite-type halides based on gold (Au), (CH3NH3)AuBr4·H2O (1), (CH3NH3)AuCl4·H2O (2), and (CH3NH3)AuCl4 (3). Hydrated compounds 1 and 2 crystallize in a brand-new structure type featuring perovskite-derived 2D layers and 1D chains based on pseudo-octahedral AuX6 building blocks. In contrast, the novel crystal structure of the solvent-free compound 3 shows an exotic non-perovskite quasi-2D layered structure containing edge- and corner-shared AuCl6 octahedra. The use of Au metal instead of Pb results in unprecedented low band gaps below 2.5 eV for single-layered metal chlorides and bromides. Moreover, at room temperature the three compounds show a weak blue emission due to the electronic transition between Au-6s and Au-5d, in agreement with the density function theory (DFT) calculation results. These findings are discussed in the context of viability of Au-based halides as alternatives for Pb-based halides for optoelectronic applications.
- Authors:
-
[1];
[1]
- Univ. of Oklahoma, Norman, OK (United States). Dept. of Chemistry and Biochemistry
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Materials Science & Technology Division
- Publication Date:
- Research Org.:
- Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1545209
- Alternate Identifier(s):
- OSTI ID: 1530632
- Grant/Contract Number:
- AC05-00OR22725
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Chemistry - A European Journal
- Additional Journal Information:
- Journal Volume: 25; Journal Issue: 42; Journal ID: ISSN 0947-6539
- Publisher:
- ChemPubSoc Europe
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 13 HYDRO ENERGY; 30 DIRECT ENERGY CONVERSION; density functional calculations; diffuse reflectance; halides; low-band gap; perovskite phases
Citation Formats
Worley, Chris, Yangui, Aymen, Roccanova, Rachel, Du, Mao‐Hua, and Saparov, Bayrammurad. (CH3NH3) AuX4·H2O (X=Cl, Br) and (CH3NH3) AuCl4: Low-Band Gap Lead-Free Layered Gold Halide Perovskite Materials. United States: N. p., 2019.
Web. doi:10.1002/chem.201901112.
Worley, Chris, Yangui, Aymen, Roccanova, Rachel, Du, Mao‐Hua, & Saparov, Bayrammurad. (CH3NH3) AuX4·H2O (X=Cl, Br) and (CH3NH3) AuCl4: Low-Band Gap Lead-Free Layered Gold Halide Perovskite Materials. United States. https://doi.org/10.1002/chem.201901112
Worley, Chris, Yangui, Aymen, Roccanova, Rachel, Du, Mao‐Hua, and Saparov, Bayrammurad. Tue .
"(CH3NH3) AuX4·H2O (X=Cl, Br) and (CH3NH3) AuCl4: Low-Band Gap Lead-Free Layered Gold Halide Perovskite Materials". United States. https://doi.org/10.1002/chem.201901112. https://www.osti.gov/servlets/purl/1545209.
@article{osti_1545209,
title = {(CH3NH3) AuX4·H2O (X=Cl, Br) and (CH3NH3) AuCl4: Low-Band Gap Lead-Free Layered Gold Halide Perovskite Materials},
author = {Worley, Chris and Yangui, Aymen and Roccanova, Rachel and Du, Mao‐Hua and Saparov, Bayrammurad},
abstractNote = {Perovskite solar cells have recently enabled power conversion efficiency comparable to established technologies such as silicon and cadmium telluride. Ongoing efforts to improve the stability of halide perovskites in ambient air has yielded promising results. However, the presence of toxic heavy element lead (Pb) remains a major concern requiring further attention. Herein, we report three new Pb-free hybrid organic–inorganic perovskite-type halides based on gold (Au), (CH3NH3)AuBr4·H2O (1), (CH3NH3)AuCl4·H2O (2), and (CH3NH3)AuCl4 (3). Hydrated compounds 1 and 2 crystallize in a brand-new structure type featuring perovskite-derived 2D layers and 1D chains based on pseudo-octahedral AuX6 building blocks. In contrast, the novel crystal structure of the solvent-free compound 3 shows an exotic non-perovskite quasi-2D layered structure containing edge- and corner-shared AuCl6 octahedra. The use of Au metal instead of Pb results in unprecedented low band gaps below 2.5 eV for single-layered metal chlorides and bromides. Moreover, at room temperature the three compounds show a weak blue emission due to the electronic transition between Au-6s and Au-5d, in agreement with the density function theory (DFT) calculation results. These findings are discussed in the context of viability of Au-based halides as alternatives for Pb-based halides for optoelectronic applications.},
doi = {10.1002/chem.201901112},
journal = {Chemistry - A European Journal},
number = 42,
volume = 25,
place = {United States},
year = {Tue Jul 02 00:00:00 EDT 2019},
month = {Tue Jul 02 00:00:00 EDT 2019}
}
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Figure 1: Polyhedral representation of the crystal structure of 1 and 2 demonstrating (a) the 2D layering of alternating perovskite and non-perovskite layers, (b) the corner-sharing octahedra of the perovskite layer and (c) the edge-sharing octahedra of the non-perovskite layer. Green spheres denote Cl/Br; Au, C, N, and O atomsmore »
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Works referenced in this record:
Computational Design of Two-Dimensional Perovskites with Functional Organic Cations
journal, March 2018
- Maheshwari, Sudeep; Savenije, Tom J.; Renaud, Nicolas
- The Journal of Physical Chemistry C, Vol. 122, Issue 30
Synthesis and Properties of a Lead-Free Hybrid Double Perovskite: (CH 3 NH 3 ) 2 AgBiBr 6
journal, January 2017
- Wei, Fengxia; Deng, Zeyu; Sun, Shijing
- Chemistry of Materials, Vol. 29, Issue 3
Mixed Dimensional 2D/3D Hybrid Perovskite Absorbers: The Future of Perovskite Solar Cells?
journal, December 2018
- Krishna, Anurag; Gottis, Sébastien; Nazeeruddin, Mohammad Khaja
- Advanced Functional Materials, Vol. 29, Issue 8
Two-Dimensional Hybrid Halide Perovskites: Principles and Promises
journal, November 2018
- Mao, Lingling; Stoumpos, Constantinos C.; Kanatzidis, Mercouri G.
- Journal of the American Chemical Society, Vol. 141, Issue 3
Organic–Inorganic Perovskites: Structural Versatility for Functional Materials Design
journal, March 2016
- Saparov, Bayrammurad; Mitzi, David B.
- Chemical Reviews, Vol. 116, Issue 7
Synthesis, Crystal and Electronic Structures, and Optical Properties of (CH 3 NH 3 ) 2 CdX 4 (X = Cl, Br, I)
journal, November 2017
- Roccanova, Rachel; Ming, Wenmei; Whiteside, Vincent R.
- Inorganic Chemistry, Vol. 56, Issue 22
Cs 2 InAgCl 6 : A New Lead-Free Halide Double Perovskite with Direct Band Gap
journal, January 2017
- Volonakis, George; Haghighirad, Amir Abbas; Milot, Rebecca L.
- The Journal of Physical Chemistry Letters, Vol. 8, Issue 4
Synthesis, characterization and phase transitions of the inorganic–organic layered perovskite-type hybrids [(C n H 2n+1 NH 3 ) 2 PbI 4 ], n = 7, 8, 9 and 10
journal, January 2012
- Lemmerer, Andreas; Billing, David G.
- Dalton Trans., Vol. 41, Issue 4
Organic-inorganic electronics
journal, January 2001
- Mitzi, D. B.; Chondroudis, K.; Kagan, C. R.
- IBM Journal of Research and Development, Vol. 45, Issue 1
Highly Stable, New, Organic-Inorganic Perovskite (CH 3 NH 3 ) 2 PdBr 4 : Synthesis, Structure, and Physical Properties
journal, March 2018
- Liu, Xixia; Huang, Tang Jiao; Zhang, Liuyang
- Chemistry - A European Journal, Vol. 24, Issue 19
Fabrication of Lead-Free (CH 3 NH 3 ) 3 Bi 2 I 9 Perovskite Photovoltaics in Ethanol Solvent
journal, September 2017
- Li, Haijin; Wu, Congcong; Yan, Yongke
- ChemSusChem, Vol. 10, Issue 20
Solution-processed hybrid perovskite photodetectors with high detectivity
journal, November 2014
- Dou, Letian; Yang, Yang (Micheal); You, Jingbi
- Nature Communications, Vol. 5, Issue 1
Laser cooling of organic–inorganic lead halide perovskites
journal, December 2015
- Ha, Son-Tung; Shen, Chao; Zhang, Jun
- Nature Photonics, Vol. 10, Issue 2
Hybrid Perovskites for Photovoltaics: Charge-Carrier Recombination, Diffusion, and Radiative Efficiencies
journal, December 2015
- Johnston, Michael B.; Herz, Laura M.
- Accounts of Chemical Research, Vol. 49, Issue 1
Bandgap Narrowing in Bi-Doped CH 3 NH 3 PbCl 3 Perovskite Single Crystals and Thin Films
journal, August 2017
- Zhang, Zhan; Ren, Lixia; Yan, Hong
- The Journal of Physical Chemistry C, Vol. 121, Issue 32
Solar cell efficiency tables (version 52)
journal, June 2018
- Green, Martin A.; Hishikawa, Yoshihiro; Dunlop, Ewan D.
- Progress in Photovoltaics: Research and Applications, Vol. 26, Issue 7
Ultralarge All-Inorganic Perovskite Bulk Single Crystal for High-Performance Visible-Infrared Dual-Modal Photodetectors
journal, May 2017
- Song, Jizhong; Cui, Qingzhi; Li, Jianhai
- Advanced Optical Materials, Vol. 5, Issue 12
Chemistry and structure in Acta Crystallographica Section C
journal, January 2015
- Linden, Anthony
- Acta Crystallographica Section C Structural Chemistry, Vol. 71, Issue 1
Broadband Emission in a New Two-Dimensional Cd-Based Hybrid Perovskite
journal, January 2018
- Yangui, Aymen; Pillet, Sebastien; Bendeif, El-Eulmi
- ACS Photonics, Vol. 5, Issue 4
Properties of CH 3 NH 3 PbX 3 (X = I, Br, Cl) Powders as Precursors for Organic/Inorganic Solar Cells
journal, November 2014
- Dimesso, L.; Dimamay, M.; Hamburger, M.
- Chemistry of Materials, Vol. 26, Issue 23
Under the spotlight: The organic–inorganic hybrid halide perovskite for optoelectronic applications
journal, June 2015
- Chen, Qi; De Marco, Nicholas; Yang, Yang (Michael)
- Nano Today, Vol. 10, Issue 3
Perovskite photonic sources
journal, April 2016
- Sutherland, Brandon R.; Sargent, Edward H.
- Nature Photonics, Vol. 10, Issue 5
Broadband Emission with a Massive Stokes Shift from Sulfonium Pb–Br Hybrids
journal, August 2017
- Smith, Matthew D.; Watson, Brian L.; Dauskardt, Reinhold H.
- Chemistry of Materials, Vol. 29, Issue 17
Cs2AgBiBr6 single-crystal X-ray detectors with a low detection limit
journal, October 2017
- Pan, Weicheng; Wu, Haodi; Luo, Jiajun
- Nature Photonics, Vol. 11, Issue 11
Two‐Step Structure Phase Transition, Dielectric Anomalies, and Thermochromic Luminescence Behavior in a Direct Band Gap 2D Corrugated Layer Lead Chloride Hybrid of [(CH 3 ) 4 N ] 4 Pb 3 Cl 10
journal, March 2019
- Xue, Chen; Wang, Shu; Liu, Wen‐Long
- Chemistry – A European Journal, Vol. 25, Issue 20
Degradation in perovskite solar cells stored under different environmental conditions
journal, July 2017
- Chauhan, Abhishek K.; Kumar, Pankaj
- Journal of Physics D: Applied Physics, Vol. 50, Issue 32
Bismuth Based Hybrid Perovskites A 3 Bi 2 I 9 (A: Methylammonium or Cesium) for Solar Cell Application
journal, September 2015
- Park, Byung-Wook; Philippe, Bertrand; Zhang, Xiaoliang
- Advanced Materials, Vol. 27, Issue 43
The one-dimensional organic–inorganic hybrid: catena -poly[bis[1-(3-ammoniopropyl)-1 H -imidazolium] [[iodidoplumbate(II)]-tri-μ-iodido-plumbate(II)-tri-μ-iodido-[iodidoplumbate(II)]-di-μ-iodido]]
journal, March 2011
- Trigui, A.; Boughzala, H.; Driss, A.
- Acta Crystallographica Section E Structure Reports Online, Vol. 67, Issue 4
Attaining High Photovoltaic Efficiency and Stability with Multidimensional Perovskites
journal, November 2018
- Kosasih, Felix Utama; Ducati, Caterina
- ChemSusChem, Vol. 11, Issue 24
High Detectivity and Rapid Response in Perovskite CsPbBr 3 Single-Crystal Photodetector
journal, February 2017
- Ding, Jianxu; Du, Songjie; Zuo, Zhiyuan
- The Journal of Physical Chemistry C, Vol. 121, Issue 9
Fabrication of self-assembled palladium nanosheets using layered organic/inorganic hybrid as the template
journal, December 2005
- Cheng, Ziyong; Pan, Daocheng; Wang, Hanfu
- Nanotechnology, Vol. 17, Issue 2
Efficient room temperature aqueous Sb 2 S 3 synthesis for inorganic–organic sensitized solar cells with 5.1% efficiencies
journal, January 2015
- Gödel, Karl C.; Choi, Yong Chan; Roose, Bart
- Chemical Communications, Vol. 51, Issue 41
Thin-Film Preparation and Characterization of Cs 3 Sb 2 I 9 : A Lead-Free Layered Perovskite Semiconductor
journal, August 2015
- Saparov, Bayrammurad; Hong, Feng; Sun, Jon-Paul
- Chemistry of Materials, Vol. 27, Issue 16
Band Gaps of the Lead-Free Halide Double Perovskites Cs 2 BiAgCl 6 and Cs 2 BiAgBr 6 from Theory and Experiment
journal, June 2016
- Filip, Marina R.; Hillman, Samuel; Haghighirad, Amir Abbas
- The Journal of Physical Chemistry Letters, Vol. 7, Issue 13
Yellowish White-Light Emission Involving Resonant Energy Transfer in a New One-Dimensional Hybrid Material: (C 9 H 10 N 2 )PbCl 4
journal, September 2018
- Barkaoui, H.; Abid, H.; Yangui, A.
- The Journal of Physical Chemistry C, Vol. 122, Issue 42
Electronic structure of the gold complexes =I, Br, and Cl)
journal, March 1999
- Liu, X. J.; Matsuda, K.; Moritomo, Y.
- Physical Review B, Vol. 59, Issue 12
Perovskite Solar Cells and Devices at EPFL Valais Wallis
journal, September 2016
- Nazeeruddin, Mohammad Khaja
- ChemSusChem, Vol. 9, Issue 18
Structural characterization, vibrational, optical properties and DFT investigation of a new luminescent organic–inorganic material: (C6H14N)3Bi2I9
journal, May 2015
- Dammak, Hajer; Yangui, Aymen; Triki, Smail
- Journal of Luminescence, Vol. 161
Structural diversity and retro-crystal engineering analysis of iodometalate hybrids
journal, January 2009
- Mercier, Nicolas; Louvain, Nicolas; Bi, Wenhua
- CrystEngComm, Vol. 11, Issue 5, p. 720-734
High Chloride Doping Levels Stabilize the Perovskite Phase of Cesium Lead Iodide
journal, May 2016
- Dastidar, Subham; Egger, David A.; Tan, Liang Z.
- Nano Letters, Vol. 16, Issue 6
Mixed Valence Perovskite Cs 2 Au 2 I 6 : A Potential Material for Thin-Film Pb-Free Photovoltaic Cells with Ultrahigh Efficiency
journal, February 2018
- Debbichi, Lamjed; Lee, Songju; Cho, Hyunyoung
- Advanced Materials, Vol. 30, Issue 12
Rb 4 Ag 2 BiBr 9 : A Lead-Free Visible Light Absorbing Halide Semiconductor with Improved Stability
journal, February 2019
- Sharma, Manila; Yangui, Aymen; Whiteside, Vincent R.
- Inorganic Chemistry, Vol. 58, Issue 7
Lead-free solid-state organic–inorganic halide perovskite solar cells
journal, May 2014
- Hao, Feng; Stoumpos, Constantinos C.; Cao, Duyen Hanh
- Nature Photonics, Vol. 8, Issue 6
Air-Stable Molecular Semiconducting Iodosalts for Solar Cell Applications: Cs2SnI6 as a Hole Conductor
journal, October 2014
- Lee, Byunghong; Stoumpos, Constantinos C.; Zhou, Nanjia
- Journal of the American Chemical Society, Vol. 136, Issue 43, p. 15379-15385
Generalized Gradient Approximation Made Simple
journal, October 1996
- Perdew, John P.; Burke, Kieron; Ernzerhof, Matthias
- Physical Review Letters, Vol. 77, Issue 18, p. 3865-3868
High spectral resolution of gamma-rays at room temperature by perovskite CsPbBr3 single crystals
journal, April 2018
- He, Yihui; Matei, Liviu; Jung, Hee Joon
- Nature Communications, Vol. 9, Issue 1
Strained hybrid perovskite thin films and their impact on the intrinsic stability of perovskite solar cells
journal, November 2017
- Zhao, Jingjing; Deng, Yehao; Wei, Haotong
- Science Advances, Vol. 3, Issue 11
Recombination in Perovskite Solar Cells: Significance of Grain Boundaries, Interface Traps, and Defect Ions
journal, April 2017
- Sherkar, Tejas S.; Momblona, Cristina; Gil-Escrig, Lidón
- ACS Energy Letters, Vol. 2, Issue 5
Iodide management in formamidinium-lead-halide–based perovskite layers for efficient solar cells
journal, June 2017
- Yang, Woon Seok; Park, Byung-Wook; Jung, Eui Hyuk
- Science, Vol. 356, Issue 6345
Recycling Perovskite Solar Cells To Avoid Lead Waste
journal, May 2016
- Binek, Andreas; Petrus, Michiel L.; Huber, Niklas
- ACS Applied Materials & Interfaces, Vol. 8, Issue 20
Evidence and detailed study of a second-order phase transition in the (C 6 H 11 NH 3 ) 2 [PbI 4 ] organic-inorganic hybrid material
journal, March 2015
- Yangui, A.; Pillet, S.; Garrot, D.
- Journal of Applied Physics, Vol. 117, Issue 11
New Contributions to the Optics of Intensely Light-Scattering Materials Part I
journal, January 1948
- Kubelka, Paul
- Journal of the Optical Society of America, Vol. 38, Issue 5
From ultrasoft pseudopotentials to the projector augmented-wave method
journal, January 1999
- Kresse, G.; Joubert, D.
- Physical Review B, Vol. 59, Issue 3, p. 1758-1775
Optical Properties and Electronic Structure of Amorphous Germanium
journal, January 1966
- Tauc, J.; Grigorovici, R.; Vancu, A.
- physica status solidi (b), Vol. 15, Issue 2
Single-crystalline layered metal-halide perovskite nanowires for ultrasensitive photodetectors
journal, July 2018
- Feng, Jiangang; Gong, Cheng; Gao, Hanfei
- Nature Electronics, Vol. 1, Issue 7
High-performance direct conversion X-ray detectors based on sintered hybrid lead triiodide perovskite wafers
journal, June 2017
- Shrestha, Shreetu; Fischer, René; Matt, Gebhard J.
- Nature Photonics, Vol. 11, Issue 7
SHELXT – Integrated space-group and crystal-structure determination
journal, January 2015
- Sheldrick, George M.
- Acta Crystallographica Section A Foundations and Advances, Vol. 71, Issue 1, p. 3-8
Toward Lead-Free Perovskite Solar Cells
journal, November 2016
- Giustino, Feliciano; Snaith, Henry J.
- ACS Energy Letters, Vol. 1, Issue 6
How transport layer properties affect perovskite solar cell performance: insights from a coupled charge transport/ion migration model
journal, January 2019
- Courtier, Nicola E.; Cave, James M.; Foster, Jamie M.
- Energy & Environmental Science, Vol. 12, Issue 1
Dimensionality engineering of hybrid halide perovskite light absorbers
journal, November 2018
- Gao, Peng; Bin Mohd Yusoff, Abd Rashid; Nazeeruddin, Mohammad Khaja
- Nature Communications, Vol. 9, Issue 1
Low-temperature solution-processed wavelength-tunable perovskites for lasing
journal, March 2014
- Xing, Guichuan; Mathews, Nripan; Lim, Swee Sien
- Nature Materials, Vol. 13, Issue 5
Efficiency of ab-initio total energy calculations for metals and semiconductors using a plane-wave basis set
journal, July 1996
- Kresse, G.; Furthmüller, J.
- Computational Materials Science, Vol. 6, Issue 1, p. 15-50
Hybrid Organic–Inorganic Halides (C 5 H 7 N 2 ) 2 MBr 4 (M = Hg, Zn) with High Color Rendering Index and High-Efficiency White-Light Emission
journal, March 2019
- Yangui, Aymen; Roccanova, Rachel; McWhorter, Timothy M.
- Chemistry of Materials, Vol. 31, Issue 8
Beyond methylammonium lead iodide: prospects for the emergent field of ns 2 containing solar absorbers
journal, January 2017
- Ganose, Alex M.; Savory, Christopher N.; Scanlon, David O.
- Chemical Communications, Vol. 53, Issue 1
Quantifying the Potential for Lead Pollution from Halide Perovskite Photovoltaics
journal, August 2015
- Fabini, Douglas
- The Journal of Physical Chemistry Letters, Vol. 6, Issue 18
Perovskite Solar Cells: Beyond Methylammonium Lead Iodide
journal, February 2015
- Boix, Pablo P.; Agarwala, Shweta; Koh, Teck Ming
- The Journal of Physical Chemistry Letters, Vol. 6, Issue 5
Electronegativity values from thermochemical data
journal, June 1961
- Allred, A. L.
- Journal of Inorganic and Nuclear Chemistry, Vol. 17, Issue 3-4
Toxicity of organometal halide perovskite solar cells
journal, February 2016
- Babayigit, Aslihan; Ethirajan, Anitha; Muller, Marc
- Nature Materials, Vol. 15, Issue 3
Lead-free germanium iodide perovskite materials for photovoltaic applications
journal, January 2015
- Krishnamoorthy, Thirumal; Ding, Hong; Yan, Chen
- Journal of Materials Chemistry A, Vol. 3, Issue 47
Rapid and robust spatiotemporal dynamics of the first-order phase transition in crystals of the organic-inorganic perovskite (C12H25NH3)2PbI4
journal, November 2015
- Yangui, Aymen; Sy, Mouhamadou; Li, Liang
- Scientific Reports, Vol. 5, Issue 1
A critical review on tin halide perovskite solar cells
journal, January 2017
- Konstantakou, Maria; Stergiopoulos, Thomas
- Journal of Materials Chemistry A, Vol. 5, Issue 23
Structural phase transition causing anomalous photoluminescence behavior in perovskite (C 6 H 11 NH 3 ) 2 [PbI 4 ]
journal, December 2015
- Yangui, A.; Pillet, S.; Mlayah, A.
- The Journal of Chemical Physics, Vol. 143, Issue 22
Color-stable highly luminescent sky-blue perovskite light-emitting diodes
journal, August 2018
- Xing, Jun; Zhao, Yongbiao; Askerka, Mikhail
- Nature Communications, Vol. 9, Issue 1
(CH 3 NH 3 ) 2 PdCl 4 : A Compound with Two-Dimensional Organic-Inorganic Layered Perovskite Structure
journal, January 2016
- Huang, Tang Jiao; Thiang, Zhang Xian; Yin, Xuesong
- Chemistry - A European Journal, Vol. 22, Issue 6
Bulk crystal growth of hybrid perovskite material CH 3 NH 3 PbI 3
journal, January 2015
- Dang, Yangyang; Liu, Yang; Sun, Youxuan
- CrystEngComm, Vol. 17, Issue 3
Structural Diversity in White-Light-Emitting Hybrid Lead Bromide Perovskites
journal, September 2018
- Mao, Lingling; Guo, Peijun; Kepenekian, Mikaël
- Journal of the American Chemical Society, Vol. 140, Issue 40
Structural Phase Transitions of the Polymorphs of CsSnI3 by Means of Rietveld Analysis of the X-Ray Diffraction
journal, May 1991
- Yamada, Koji; Funabiki, Shinya; Horimoto, Hiromi
- Chemistry Letters, Vol. 20, Issue 5, p. 801-804
Solvent engineering for high-performance inorganic–organic hybrid perovskite solar cells
journal, July 2014
- Jeon, Nam Joong; Noh, Jun Hong; Kim, Young Chan
- Nature Materials, Vol. 13, Issue 9, p. 897-903
Organic-Inorganic Hybrid Materials as Semiconducting Channels in Thin-Film Field-Effect Transistors
journal, October 1999
- Kagan, C. R.; Mitzi, D. B.; Dimitrakopoulos, C. D.
- Science, Vol. 286, Issue 5441, p. 945-947
Broadband Emission in Hybrid Organic–Inorganic Halides of Group 12 Metals
journal, December 2018
- Roccanova, Rachel; Houck, Matthew; Yangui, Aymen
- ACS Omega, Vol. 3, Issue 12
Thin Films and Solar Cells Based on Semiconducting Two-Dimensional Ruddlesden–Popper (CH 3 (CH 2 ) 3 NH 3 ) 2 (CH 3 NH 3 ) n −1 Sn n I 3 n +1 Perovskites
journal, April 2017
- Cao, Duyen H.; Stoumpos, Constantinos C.; Yokoyama, Takamichi
- ACS Energy Letters, Vol. 2, Issue 5
(C 6 H 5 C 2 H 4 NH 3 ) 2 GeI 4 : A Layered Two-Dimensional Perovskite with Potential for Photovoltaic Applications
journal, September 2017
- Cheng, Pengfei; Wu, Tao; Zhang, Jiangwei
- The Journal of Physical Chemistry Letters, Vol. 8, Issue 18
High-efficiency perovskite–polymer bulk heterostructure light-emitting diodes
journal, November 2018
- Zhao, Baodan; Bai, Sai; Kim, Vincent
- Nature Photonics, Vol. 12, Issue 12
All-inorganic perovskite nanocrystal scintillators
journal, August 2018
- Chen, Qiushui; Wu, Jing; Ou, Xiangyu
- Nature, Vol. 561, Issue 7721
Recent progress in organometal halide perovskite photodetectors
journal, January 2018
- Wang, Xingguang; Li, Mingming; Zhang, Biao
- Organic Electronics, Vol. 52
Optical Investigation of Broadband White-Light Emission in Self-Assembled Organic–Inorganic Perovskite (C 6 H 11 NH 3 ) 2 PbBr 4
journal, October 2015
- Yangui, A.; Garrot, D.; Lauret, J. S.
- The Journal of Physical Chemistry C, Vol. 119, Issue 41
Nanocrystalline Perovskite Hybrid Photodetectors with High Performance in Almost Every Figure of Merit
journal, December 2017
- Lin, Yuanwei; Lin, Guoming; Sun, Baoyun
- Advanced Functional Materials, Vol. 28, Issue 7
Synthesis and crystal structures of iodoplumbate chains, ribbons and rods with new structural types
journal, January 2001
- Krautscheid, Harald; Lode, Christine; Vielsack, Frieder
- Journal of the Chemical Society, Dalton Transactions, Issue 7
Synthesis, crystal structure, absorption properties, photoelectric behavior of organic-inorganic hybrid (CH 3 NH 3 ) 2 CoCl 4 : Photoelectric Behavior of (CH3NH3)2CoCl4
journal, February 2019
- Yin, Jie; Liu, Xuejing; Fan, Lin
- Applied Organometallic Chemistry, Vol. 33, Issue 4
Bis(pentane-1,5-diammonium) decaiodotriplumbate(II)
journal, April 2004
- Billing, David G.; Lemmerer, Andreas
- Acta Crystallographica Section C Crystal Structure Communications, Vol. 60, Issue 5
Control of the white-light emission in the mixed two-dimensional hybrid perovskites (C 6 H 11 NH 3 ) 2 [PbBr 4−x I x ]
journal, March 2017
- Yangui, Aymen; Pillet, Sebastien; Lusson, Alain
- Journal of Alloys and Compounds, Vol. 699
Graphdiyne as a Host Active Material for Perovskite Solar Cell Application
journal, October 2018
- Li, Jiangsheng; Jiu, Tonggang; Chen, Siqi
- Nano Letters, Vol. 18, Issue 11
Molecular engineering of perovskite photodetectors: recent advances in materials and devices
journal, January 2018
- Yao, Fang; Gui, Pengbin; Zhang, Qi
- Molecular Systems Design & Engineering, Vol. 3, Issue 5
Perovskite-based low-cost and high-efficiency hybrid halide solar cells
journal, January 2014
- Fan, Jiandong; Jia, Baohua; Gu, Min
- Photonics Research, Vol. 2, Issue 5
The resistivity of mixed valence compound Cs2Au2Cl6 at high pressure and low temperatures
journal, October 1974
- Keller, R.; Fenner, J.; Holzapfel, W. B.
- Materials Research Bulletin, Vol. 9, Issue 10
Progress on lead-free metal halide perovskites for photovoltaic applications: a review
journal, March 2017
- Hoefler, Sebastian F.; Trimmel, Gregor; Rath, Thomas
- Monatshefte für Chemie - Chemical Monthly, Vol. 148, Issue 5
Near-Unity Photoluminescence Quantum Yield in Blue-Emitting Cs 3 Cu 2 Br 5– x I x (0 ≤ x ≤ 5)
journal, February 2019
- Roccanova, Rachel; Yangui, Aymen; Nhalil, Hariharan
- ACS Applied Electronic Materials, Vol. 1, Issue 3
Stability of Metal Halide Perovskite Solar Cells
journal, September 2015
- Leijtens, Tomas; Eperon, Giles E.; Noel, Nakita K.
- Advanced Energy Materials, Vol. 5, Issue 20
Reducing Dzyaloshinskii-Moriya interaction and field-free spin-orbit torque switching in synthetic antiferromagnets
journal, May 2021
- Chen, Ruyi; Cui, Qirui; Liao, Liyang
- Nature Communications, Vol. 12, Issue 1
High-resolution X-ray luminescence extension imaging
journal, February 2021
- Ou, Xiangyu; Qin, Xian; Huang, Bolong
- Nature, Vol. 590, Issue 7846
Strained hybrid perovskite thin films and their impact on the intrinsic stability of perovskite solar cells
text, January 2017
- Jinsong, Huang,; Haotong, Wei,; E., Shield, Jeffrey
- The University of North Carolina at Chapel Hill University Libraries
Attaining High Photovoltaic Efficiency and Stability with Multidimensional Perovskites.
text, January 2018
- Kosasih, Felix; Ducati, Caterina
- Apollo - University of Cambridge Repository
High-efficiency perovskite–polymer bulk heterostructure light-emitting diodes
text, January 2018
- Zhao, Baodan; Bai, S.; Kim, Vincent
- Apollo - University of Cambridge Repository
Chemistry and structure in Acta Crystallographica Section C
text, January 2015
- Linden, Anthony
- Wiley-Blackwell Publishing, Inc.
High-efficiency perovskite-polymer bulk heterostructure light-emitting diodes
text, January 2018
- Zhao, Baodan; Bai, Sai; Kim, Vincent
- arXiv
Works referencing / citing this record:
Additive-assisted synthesis and optoelectronic properties of (CH 3 NH 3 ) 4 Bi 6 I 22
journal, January 2020
- Sharma, Manila; Yangui, Aymen; Lusson, Alain
- Inorganic Chemistry Frontiers, Vol. 7, Issue 7
Lead-Free Perovskites for Lighting and Lasing Applications: A Minireview
journal, November 2019
- Ushakova, Elena V.; Cherevkov, Sergei A.; Kuznetsova, Vera A.
- Materials, Vol. 12, Issue 23
Lead-Free Perovskites for Lighting and Lasing Applications: A Minireview
journal, November 2019
- Ushakova, Elena V.; Cherevkov, Sergei A.; Kuznetsova, Vera A.
- Materials, Vol. 12, Issue 23
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