Dichotomy between frustrated local spins and conjugated electrons in a two-dimensional metal–organic framework
Abstract
Dichotomy between local spins and conjugated electrons spawns various exotic physical phenomena, however, it has mostly been reported in three-dimensional (3D) inorganic systems. We demonstrate, for the first time, that a rare 2D metal–organic framework exhibits intriguing dichotomy behavior, which can be directly identified through scanning tunneling microscopy/spectroscopy (STM/STS). In a newly synthesized Cu-hexaiminobenzene [Cu3(HAB)2], on the one hand, the Cu2+ ions form an ideal S–1/2 antiferromagnetic (AFM) kagome lattice; on the other hand, the conjugated-electrons from the organic ligands produce a frustrated πx,y model on a honeycomb lattice, giving rise to completely dispersionless energy bands around the Fermi level that favour the ferromagnetic (FM) state. Remarkably, the frustrated local spins and conjugated electrons interact through a strong FM Hund's coupling, giving rise to a wide range of intriguing quantum phases. Furthermore, we propose that this dichotomy can be directly characterized through STM/STS measurements due to its special 2D nature, which provides a unique exciting platform to investigate the dichotomy of frustrated spins and electrons in a single lattice.
- Authors:
-
[1];
[4];
- Univ. of Utah, Salt Lake City, UT (United States); Univ. of Minnesota, Minneapolis, MN (United States)
- Tsinghua Univ., Beijing (China)
- Southern Univ. of Science and Technology, Shenzhen (China)
- Shandong Univ., Jinan (China)
- Univ. of Utah, Salt Lake City, UT (United States)
- Publication Date:
- Research Org.:
- Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States). National Energy Research Scientific Computing Center (NERSC); Univ. of Utah, Salt Lake City, UT (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES); National Science Foundation (NSF); National Natural Science Foundation of China (NSFC)
- OSTI Identifier:
- 1543815
- Alternate Identifier(s):
- OSTI ID: 1487170
- Grant/Contract Number:
- FG02-04ER46148; DMR-1121252; 11774196
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Nanoscale
- Additional Journal Information:
- Journal Volume: 11; Journal Issue: 3; Journal ID: ISSN 2040-3364
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 42 ENGINEERING; Chemistry; Science & Technology - Other Topics; Materials Science; Physics
Citation Formats
Jiang, Wei, Liu, Zheng, Mei, Jia-Wei, Cui, Bin, and Liu, Feng. Dichotomy between frustrated local spins and conjugated electrons in a two-dimensional metal–organic framework. United States: N. p., 2018.
Web. doi:10.1039/c8nr08479c.
Jiang, Wei, Liu, Zheng, Mei, Jia-Wei, Cui, Bin, & Liu, Feng. Dichotomy between frustrated local spins and conjugated electrons in a two-dimensional metal–organic framework. United States. https://doi.org/10.1039/c8nr08479c
Jiang, Wei, Liu, Zheng, Mei, Jia-Wei, Cui, Bin, and Liu, Feng. Fri .
"Dichotomy between frustrated local spins and conjugated electrons in a two-dimensional metal–organic framework". United States. https://doi.org/10.1039/c8nr08479c. https://www.osti.gov/servlets/purl/1543815.
@article{osti_1543815,
title = {Dichotomy between frustrated local spins and conjugated electrons in a two-dimensional metal–organic framework},
author = {Jiang, Wei and Liu, Zheng and Mei, Jia-Wei and Cui, Bin and Liu, Feng},
abstractNote = {Dichotomy between local spins and conjugated electrons spawns various exotic physical phenomena, however, it has mostly been reported in three-dimensional (3D) inorganic systems. We demonstrate, for the first time, that a rare 2D metal–organic framework exhibits intriguing dichotomy behavior, which can be directly identified through scanning tunneling microscopy/spectroscopy (STM/STS). In a newly synthesized Cu-hexaiminobenzene [Cu3(HAB)2], on the one hand, the Cu2+ ions form an ideal S–1/2 antiferromagnetic (AFM) kagome lattice; on the other hand, the conjugated-electrons from the organic ligands produce a frustrated πx,y model on a honeycomb lattice, giving rise to completely dispersionless energy bands around the Fermi level that favour the ferromagnetic (FM) state. Remarkably, the frustrated local spins and conjugated electrons interact through a strong FM Hund's coupling, giving rise to a wide range of intriguing quantum phases. Furthermore, we propose that this dichotomy can be directly characterized through STM/STS measurements due to its special 2D nature, which provides a unique exciting platform to investigate the dichotomy of frustrated spins and electrons in a single lattice.},
doi = {10.1039/c8nr08479c},
journal = {Nanoscale},
number = 3,
volume = 11,
place = {United States},
year = {Fri Nov 23 00:00:00 EST 2018},
month = {Fri Nov 23 00:00:00 EST 2018}
}
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