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Title: Pressure-induced reentrant transition in NbS3 phases: Combined Raman scattering and x-ray diffraction study

Abstract

In this paper we report the evolution of charge density wave states under pressure for two NbS3 phases: triclinic (phase I) and monoclinic (phase II) at room temperature. Raman and x-ray diffraction (XRD) techniques are applied. The x-ray studies on the monoclinic phase under pressure show a compression of the lattice at different rates below and above ~7 GPa but without a change in space group symmetry. The Raman spectra of the two phases evolve similarly with pressure; all peaks almost disappear in the ~6–8 GPa range, indicating a transition from an insulating to a metallic state, and peaks at new positions appear above 8 GPa. The results suggest suppression of the ambient charge-density waves and their subsequent recovery with new orderings above 8 GPa.

Authors:
 [1];  [2];  [3];  [3];  [3];  [4];  [5];  [6];  [6];  [6];  [6];  [7];  [2];  [8]
+ Show Author Affiliations
  1. Center for High Pressure Science and Technology Advanced Research, Shanghai (China); Harvard Univ., Cambridge, MA (United States); National Univ. of Science and Technology (MISiS), Moscow (Russia); Uppsala Univ. (Sweden)
  2. Center for High Pressure Science and Technology Advanced Research, Shanghai (China)
  3. Uppsala Univ. (Sweden)
  4. National Univ. of Science and Technology (MISiS), Moscow (Russia); National Research South Ural State Univ., Chelyabinsk (Russia); Moscow State Univ., Moscow (Russia)
  5. Imam Abdulrahman Bin Faisal Univ., Dammam (Saudi Arabia)
  6. Russian Academy of Sciences (RAS), Moscow (Russia). Inst. of Radioengineering and Electronics
  7. National Taiwan Univ., Taipei (Taiwan)
  8. Russian Academy of Sciences (RAS), Moscow (Russia). Inst. of Solid State Physics
Publication Date:
Research Org.:
Argonne National Laboratory (ANL), Argonne, IL (United States). Advanced Photon Source (APS)
Sponsoring Org.:
National Natural Science Foundation of China (NSFC); Ministry of Education and Science of the Russian Federation; Russian Foundation for Basic Research (RFBR); Russian Science Foundation; Taiwan Ministry of Science and Technology (MOST); National Taiwan University; USDOE National Nuclear Security Administration (NNSA); USDOE Office of Science (SC), Basic Energy Sciences (BES); National Science Foundation (NSF)
OSTI Identifier:
1542986
Alternate Identifier(s):
OSTI ID: 1546240
Grant/Contract Number:  
51527801; U1530402; K2- 2017-084; 02.A03.21.0004; 02.A03.21.0011; 17-02-01343; 17-12-01519; NA0001974; FG02-99ER45775; AC02-06CH11357
Resource Type:
Accepted Manuscript
Journal Name:
Physical Review B
Additional Journal Information:
Journal Volume: 99; Journal Issue: 23; Journal ID: ISSN 2469-9950
Publisher:
American Physical Society (APS)
Country of Publication:
United States
Language:
ENGLISH
Subject:
75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; 36 MATERIALS SCIENCE

Citation Formats

Abdel-Hafiez, M., Thiyagarajan, R., Majumdar, A., Ahuja, R., Luo, W., Vasiliev, A. N., Maarouf, A. A., Zybtsev, S. G., Pokrovskii, V. Ya., Zaitsev-Zotov, S. V., Pavlovskiy, V. V., Pai, Woei Wu, Yang, W., and Kulik, L. V. Pressure-induced reentrant transition in NbS3 phases: Combined Raman scattering and x-ray diffraction study. United States: N. p., 2019. Web. doi:10.1103/PhysRevB.99.235126.
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Abdel-Hafiez, M., Thiyagarajan, R., Majumdar, A., Ahuja, R., Luo, W., Vasiliev, A. N., Maarouf, A. A., Zybtsev, S. G., Pokrovskii, V. Ya., Zaitsev-Zotov, S. V., Pavlovskiy, V. V., Pai, Woei Wu, Yang, W., & Kulik, L. V. Pressure-induced reentrant transition in NbS3 phases: Combined Raman scattering and x-ray diffraction study. United States. https://doi.org/10.1103/PhysRevB.99.235126
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Abdel-Hafiez, M., Thiyagarajan, R., Majumdar, A., Ahuja, R., Luo, W., Vasiliev, A. N., Maarouf, A. A., Zybtsev, S. G., Pokrovskii, V. Ya., Zaitsev-Zotov, S. V., Pavlovskiy, V. V., Pai, Woei Wu, Yang, W., and Kulik, L. V. Wed . "Pressure-induced reentrant transition in NbS3 phases: Combined Raman scattering and x-ray diffraction study". United States. https://doi.org/10.1103/PhysRevB.99.235126. https://www.osti.gov/servlets/purl/1542986.
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@article{osti_1542986,
title = {Pressure-induced reentrant transition in NbS3 phases: Combined Raman scattering and x-ray diffraction study},
author = {Abdel-Hafiez, M. and Thiyagarajan, R. and Majumdar, A. and Ahuja, R. and Luo, W. and Vasiliev, A. N. and Maarouf, A. A. and Zybtsev, S. G. and Pokrovskii, V. Ya. and Zaitsev-Zotov, S. V. and Pavlovskiy, V. V. and Pai, Woei Wu and Yang, W. and Kulik, L. V.},
abstractNote = {In this paper we report the evolution of charge density wave states under pressure for two NbS3 phases: triclinic (phase I) and monoclinic (phase II) at room temperature. Raman and x-ray diffraction (XRD) techniques are applied. The x-ray studies on the monoclinic phase under pressure show a compression of the lattice at different rates below and above ~7 GPa but without a change in space group symmetry. The Raman spectra of the two phases evolve similarly with pressure; all peaks almost disappear in the ~6–8 GPa range, indicating a transition from an insulating to a metallic state, and peaks at new positions appear above 8 GPa. The results suggest suppression of the ambient charge-density waves and their subsequent recovery with new orderings above 8 GPa.},
doi = {10.1103/PhysRevB.99.235126},
journal = {Physical Review B},
number = 23,
volume = 99,
place = {United States},
year = {Wed Jun 12 00:00:00 EDT 2019},
month = {Wed Jun 12 00:00:00 EDT 2019}
}
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https://doi.org/10.1103/PhysRevB.99.235126
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