Uniform High Ionic Conducting Lithium Sulfide Protection Layer for Stable Lithium Metal Anode
Abstract
Abstract Artificial solid‐electrolyte interphase (SEI) is one of the key approaches in addressing the low reversibility and dendritic growth problems of lithium metal anode, yet its current effect is still insufficient due to insufficient stability. Here, a new principle of “simultaneous high ionic conductivity and homogeneity” is proposed for stabilizing SEI and lithium metal anodes. Fabricated by a facile, environmentally friendly, and low‐cost lithium solid‐sulfur vapor reaction at elevated temperature, a designed lithium sulfide protective layer successfully maintains its protection function during cycling, which is confirmed by both simulations and experiments. Stable dendrite‐free cycling of lithium metal anode is realized even at a high areal capacity of 5 mAh cm −2 , and prototype Li–Li 4 Ti 5 O 12 cell with limited lithium also achieves 900 stable cycles. These findings give new insight into the ideal SEI composition and structure and provide new design strategies for stable lithium metal batteries.
- Authors:
-
[1];
[1];
[1];
[1];
[1];
[1];
- Stanford Univ., CA (United States). Dept. of Materials Science and Engineering
- SLAC National Accelerator Lab., Menlo Park, CA (United States). Stanford Institute for Materials and Energy Science (SIMES)
- Publication Date:
- Research Org.:
- SLAC National Accelerator Laboratory (SLAC), Menlo Park, CA (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1532475
- Alternate Identifier(s):
- OSTI ID: 1510099
- Grant/Contract Number:
- AC02-76SF00515
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Advanced Energy Materials
- Additional Journal Information:
- Journal Volume: 9; Journal Issue: 22; Journal ID: ISSN 1614-6832
- Publisher:
- Wiley
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE; artificial SEI; compositional homogeneity; high ionic conductivity; lithium metal batteries
Citation Formats
Chen, Hao, Pei, Allen, Lin, Dingchang, Xie, Jin, Yang, Ankun, Xu, Jinwei, Lin, Kaixiang, Wang, Jiangyan, Wang, Hansen, Shi, Feifei, Boyle, David, and Cui, Yi. Uniform High Ionic Conducting Lithium Sulfide Protection Layer for Stable Lithium Metal Anode. United States: N. p., 2019.
Web. doi:10.1002/aenm.201900858.
Chen, Hao, Pei, Allen, Lin, Dingchang, Xie, Jin, Yang, Ankun, Xu, Jinwei, Lin, Kaixiang, Wang, Jiangyan, Wang, Hansen, Shi, Feifei, Boyle, David, & Cui, Yi. Uniform High Ionic Conducting Lithium Sulfide Protection Layer for Stable Lithium Metal Anode. United States. https://doi.org/10.1002/aenm.201900858
Chen, Hao, Pei, Allen, Lin, Dingchang, Xie, Jin, Yang, Ankun, Xu, Jinwei, Lin, Kaixiang, Wang, Jiangyan, Wang, Hansen, Shi, Feifei, Boyle, David, and Cui, Yi. Tue .
"Uniform High Ionic Conducting Lithium Sulfide Protection Layer for Stable Lithium Metal Anode". United States. https://doi.org/10.1002/aenm.201900858. https://www.osti.gov/servlets/purl/1532475.
@article{osti_1532475,
title = {Uniform High Ionic Conducting Lithium Sulfide Protection Layer for Stable Lithium Metal Anode},
author = {Chen, Hao and Pei, Allen and Lin, Dingchang and Xie, Jin and Yang, Ankun and Xu, Jinwei and Lin, Kaixiang and Wang, Jiangyan and Wang, Hansen and Shi, Feifei and Boyle, David and Cui, Yi},
abstractNote = {Abstract Artificial solid‐electrolyte interphase (SEI) is one of the key approaches in addressing the low reversibility and dendritic growth problems of lithium metal anode, yet its current effect is still insufficient due to insufficient stability. Here, a new principle of “simultaneous high ionic conductivity and homogeneity” is proposed for stabilizing SEI and lithium metal anodes. Fabricated by a facile, environmentally friendly, and low‐cost lithium solid‐sulfur vapor reaction at elevated temperature, a designed lithium sulfide protective layer successfully maintains its protection function during cycling, which is confirmed by both simulations and experiments. Stable dendrite‐free cycling of lithium metal anode is realized even at a high areal capacity of 5 mAh cm −2 , and prototype Li–Li 4 Ti 5 O 12 cell with limited lithium also achieves 900 stable cycles. These findings give new insight into the ideal SEI composition and structure and provide new design strategies for stable lithium metal batteries.},
doi = {10.1002/aenm.201900858},
journal = {Advanced Energy Materials},
number = 22,
volume = 9,
place = {United States},
year = {Tue Apr 30 00:00:00 EDT 2019},
month = {Tue Apr 30 00:00:00 EDT 2019}
}
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