Analysis of Plant Leaves Using Laser Ablation Inductively Coupled Plasma Optical Emission Spectrometry: Use of Carbon to Compensate for Matrix Effects

Chirinos, José; Oropeza, Dayana; González, Jhanis; Zorba, Vassilia; Russo, Richard E.

doi:10.1177/0003702816683686

Title: Analysis of Plant Leaves Using Laser Ablation Inductively Coupled Plasma Optical Emission Spectrometry: Use of Carbon to Compensate for Matrix Effects

Abstract

Direct solid sampling by laser ablation into an inductively coupled plasma synchronous vertical dual view optical emission spectroscope (LA-SVDV-ICP-OES) was used for the elemental analysis of nutrient elements Ca, B, Mn, Mg, K, and Zn and essential (non-metallic) elements P and S in plant materials. The samples were mixed with paraffin as a binder, an approach that provides better cohesion of the particles in the pellets in addition to supplying carbon to serve as an internal standard (atomic line C I 193.027 nm) as a way to compensate for matrix effects, and/or variations in the ablation process. Precision was in the range of 1-8% relative standard deviation (RSD) with limit of detection in the range of 0.4^-1 mg/kg^-1 and 25-640 mg/kg^-1 for metallic and non-metallic elements, respectively.

Authors:

Chirinos, José ^[1]; Oropeza, Dayana ^[2]; González, Jhanis ^[3]; Zorba, Vassilia ^[2]; Russo, Richard E. ^[3]

Univ. Central de Venezuela, Caracas (Venezuela); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Applied Spectra, Inc., Fremont, CA (United States)

Publication Date:: Thu Dec 22 00:00:00 EST 2016

Research Org.:: Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI Identifier:: 1532241

Grant/Contract Number:: AC02-05CH11231

Resource Type:: Accepted Manuscript

Journal Name:: Applied Spectroscopy

Additional Journal Information:: Journal Volume: 71; Journal Issue: 4; Journal ID: ISSN 0003-7028

Publisher:: Society for Applied Spectroscopy

Country of Publication:: United States

Language:: English

Subject:: 59 BASIC BIOLOGICAL SCIENCES; 54 ENVIRONMENTAL SCIENCES

Citation Formats


                    Chirinos, José, Oropeza, Dayana, González, Jhanis, Zorba, Vassilia, and Russo, Richard E. Analysis of Plant Leaves Using Laser Ablation Inductively Coupled Plasma Optical Emission Spectrometry: Use of Carbon to Compensate for Matrix Effects.  United States: N. p., 2016. 
Web.  doi:10.1177/0003702816683686.

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                    Chirinos, José, Oropeza, Dayana, González, Jhanis, Zorba, Vassilia, & Russo, Richard E. Analysis of Plant Leaves Using Laser Ablation Inductively Coupled Plasma Optical Emission Spectrometry: Use of Carbon to Compensate for Matrix Effects.  United States.  https://doi.org/10.1177/0003702816683686

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                    Chirinos, José, Oropeza, Dayana, González, Jhanis, Zorba, Vassilia, and Russo, Richard E. Thu .  
"Analysis of Plant Leaves Using Laser Ablation Inductively Coupled Plasma Optical Emission Spectrometry: Use of Carbon to Compensate for Matrix Effects".  United States.  https://doi.org/10.1177/0003702816683686.  https://www.osti.gov/servlets/purl/1532241.

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@article{osti_1532241,

  title        = {Analysis of Plant Leaves Using Laser Ablation Inductively Coupled Plasma Optical Emission Spectrometry: Use of Carbon to Compensate for Matrix Effects},

  author       = {Chirinos, José and Oropeza, Dayana and González, Jhanis and Zorba, Vassilia and Russo, Richard E.},

  abstractNote = {Direct solid sampling by laser ablation into an inductively coupled plasma synchronous vertical dual view optical emission spectroscope (LA-SVDV-ICP-OES) was used for the elemental analysis of nutrient elements Ca, B, Mn, Mg, K, and Zn and essential (non-metallic) elements P and S in plant materials. The samples were mixed with paraffin as a binder, an approach that provides better cohesion of the particles in the pellets in addition to supplying carbon to serve as an internal standard (atomic line C I 193.027 nm) as a way to compensate for matrix effects, and/or variations in the ablation process. Precision was in the range of 1-8% relative standard deviation (RSD) with limit of detection in the range of 0.4-1 mg/kg-1 and 25-640 mg/kg-1 for metallic and non-metallic elements, respectively.},

  doi          = {10.1177/0003702816683686},

  journal      = {Applied Spectroscopy},

  number       = 4,

  volume       = 71,

  place        = {United States},

  year         = {Thu Dec 22 00:00:00 EST 2016},

  month        = {Thu Dec 22 00:00:00 EST 2016}

}

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Works referencing / citing this record:

Atomic Spectrometry Update – a review of advances in environmental analysis
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Bacon, Jeffrey R.; Butler, Owen T.; Cairns, Warren R. L.
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journal, January 2019

Oropeza, Dayana; González, Jhanis; Chirinos, José
Applied Spectroscopy, Vol. 73, Issue 5
DOI: 10.1177/0003702818819497

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Similar Records

Title: Analysis of Plant Leaves Using Laser Ablation Inductively Coupled Plasma Optical Emission Spectrometry: Use of Carbon to Compensate for Matrix Effects

Abstract

Citation Formats

Comparison of ionic line-based internal standardization with axially and radially viewed inductively coupled plasma atomic emission spectrometry to compensate for sodium effects on accuracy journal, January 1998

Rapid Nitric Acid Digestion of Plant Material with an Open-Vessel Microwave System journal, December 2004

Elemental fractionation effects in high repetition rate IR femtosecond laser ablation ICP-MS analysis of glasses journal, January 2009

Laser Ablation in Analytical Chemistry journal, May 2013

Selection of internal standards in inductively coupled plasma atomic emission spectrometry by principal component analysis journal, February 2003

Laser ablation in analytical chemistry—a review journal, May 2002

External calibration strategy for trace element quantification in botanical samples by LA-ICP-MS using filter paper journal, January 2016

Review of the State-of-the-Art of Laser Ablation Inductively Coupled Plasma Mass Spectrometry journal, May 2011

Laser-Induced Breakdown Spectroscopy (LIBS), Part II: Review of Instrumental and Methodological Approaches to Material Analysis and Applications to Different Fields journal, April 2012

Slurry Sampling—An Analytical Strategy for the Determination of Metals and Metalloids by Spectroanalytical Techniques journal, January 2010

Recent Progress in Electrothermal Vaporization–Inductively Coupled Plasma Atomic Emission Spectrometry and Inductively Coupled Plasma Mass Spectrometry journal, March 2007

Microwave-assisted digestion using diluted acid and base solutions for plant analysis by ICP OES journal, January 2016

Laser assisted plasma spectrochemistry: laser ablation journal, January 2004

Fundamental studies on the ablation behaviour of carbon in LA-ICP-MS with respect to the suitability as internal standard journal, January 2012

Elemental analysis of coal by tandem laser induced breakdown spectroscopy and laser ablation inductively coupled plasma time of flight mass spectrometry journal, July 2015

A review of normalization techniques in analytical atomic spectrometry with laser sampling: From single to multivariate correction journal, August 2010

A matrix effect and accuracy evaluation for the determination of elements in milk powder LIBS and laser ablation/ICP-OES spectrometry journal, May 2011

Study of polymer ablation products obtained by ultraviolet laser ablation — inductively coupled plasma atomic emission spectrometry journal, October 1998

Direct determination of the nutrient profile in plant materials by femtosecond laser-induced breakdown spectroscopy journal, May 2015

A novel strategy for preparing calibration standards for the analysis of plant materials by laser-induced breakdown spectroscopy: A case study with pellets of sugar cane leaves journal, August 2013

Detection of Nutrient Elements and Contamination by Pesticides in Spinach and Rice Samples Using Laser-Induced Breakdown Spectroscopy (LIBS) journal, January 2012

Nomenclature in evaluation of analytical methods including detection and quantification capabilities (IUPAC Recommendations 1995) journal, January 1995

Rapid, Wet Oxidation Procedure for the Estimation of Silicon in Plant Tissue journal, June 2006

Laser ablation inductively coupled plasma optical emission spectrometry for analysis of pellets of plant materials journal, April 2014

Microwave digestion of plant and grain standard reference materials in nitric and hydrofluoric acids for multi-elemental determination by inductively coupled plasma mass spectrometry journal, January 1999

Comparison of ICP OES and LIBS Analysis of Medicinal Herbs Rich in Flavonoids from Eastern Europe journal, January 2016

Determination of silicon in plant materials by laser-induced breakdown spectroscopy journal, May 2013

Experimental evaluation of elemental behavior during LA-ICP-MS: influences of plasma conditions and limits of plasma robustness journal, January 2016

Review: The role of atomic spectrometry in plant science journal, January 2011

Determination of macro- and micronutrients in plant leaves by high-resolution continuum source flame atomic absorption spectrometry combining instrumental and sample preparation strategies journal, April 2010

Elemental fractionation and matrix effects in laser sampling based spectrometry journal, January 2016

Imaging techniques for elements and element species in plant science journal, January 2012

Comparison of univariate and multivariate calibration for the determination of micronutrients in pellets of plant materials by laser induced breakdown spectrometry journal, January 2010

Comparative Investigation of Concentrations of Major and Trace Elements in Organic and Conventional Danish Agricultural Crops. 1. Onions ( Allium c epa Hysam) and Peas ( Pisum s ativum Ping Pong) journal, December 2000

Atomic Spectrometry Update – a review of advances in environmental analysis journal, January 2019

Multi-energy calibration and sample fusion as alternatives for quantitative analysis of high silicon content samples by laser-induced breakdown spectrometry journal, January 2019

Elemental Analysis of Asphaltenes Using Simultaneous Laser-Induced Breakdown Spectroscopy (LIBS)–Laser Ablation Inductively Coupled Plasma Optical Emission Spectrometry (LA-ICP-OES) journal, January 2019

Comparison of ionic line-based internal standardization with axially and radially viewed inductively coupled plasma atomic emission spectrometry to compensate for sodium effects on accuracy
journal, January 1998

Rapid Nitric Acid Digestion of Plant Material with an Open-Vessel Microwave System
journal, December 2004

Elemental fractionation effects in high repetition rate IR femtosecond laser ablation ICP-MS analysis of glasses
journal, January 2009

Laser Ablation in Analytical Chemistry
journal, May 2013

Selection of internal standards in inductively coupled plasma atomic emission spectrometry by principal component analysis
journal, February 2003

Laser ablation in analytical chemistry—a review
journal, May 2002

External calibration strategy for trace element quantification in botanical samples by LA-ICP-MS using filter paper
journal, January 2016

Review of the State-of-the-Art of Laser Ablation Inductively Coupled Plasma Mass Spectrometry
journal, May 2011

Laser-Induced Breakdown Spectroscopy (LIBS), Part II: Review of Instrumental and Methodological Approaches to Material Analysis and Applications to Different Fields
journal, April 2012

Slurry Sampling—An Analytical Strategy for the Determination of Metals and Metalloids by Spectroanalytical Techniques
journal, January 2010

Recent Progress in Electrothermal Vaporization–Inductively Coupled Plasma Atomic Emission Spectrometry and Inductively Coupled Plasma Mass Spectrometry
journal, March 2007

Microwave-assisted digestion using diluted acid and base solutions for plant analysis by ICP OES
journal, January 2016

Laser assisted plasma spectrochemistry: laser ablation
journal, January 2004

Fundamental studies on the ablation behaviour of carbon in LA-ICP-MS with respect to the suitability as internal standard
journal, January 2012

Elemental analysis of coal by tandem laser induced breakdown spectroscopy and laser ablation inductively coupled plasma time of flight mass spectrometry
journal, July 2015

A review of normalization techniques in analytical atomic spectrometry with laser sampling: From single to multivariate correction
journal, August 2010

A matrix effect and accuracy evaluation for the determination of elements in milk powder LIBS and laser ablation/ICP-OES spectrometry
journal, May 2011

Study of polymer ablation products obtained by ultraviolet laser ablation — inductively coupled plasma atomic emission spectrometry
journal, October 1998

Direct determination of the nutrient profile in plant materials by femtosecond laser-induced breakdown spectroscopy
journal, May 2015

A novel strategy for preparing calibration standards for the analysis of plant materials by laser-induced breakdown spectroscopy: A case study with pellets of sugar cane leaves
journal, August 2013

Detection of Nutrient Elements and Contamination by Pesticides in Spinach and Rice Samples Using Laser-Induced Breakdown Spectroscopy (LIBS)
journal, January 2012

Nomenclature in evaluation of analytical methods including detection and quantification capabilities (IUPAC Recommendations 1995)
journal, January 1995

Rapid, Wet Oxidation Procedure for the Estimation of Silicon in Plant Tissue
journal, June 2006

Laser ablation inductively coupled plasma optical emission spectrometry for analysis of pellets of plant materials
journal, April 2014

Microwave digestion of plant and grain standard reference materials in nitric and hydrofluoric acids for multi-elemental determination by inductively coupled plasma mass spectrometry
journal, January 1999

Comparison of ICP OES and LIBS Analysis of Medicinal Herbs Rich in Flavonoids from Eastern Europe
journal, January 2016

Determination of silicon in plant materials by laser-induced breakdown spectroscopy
journal, May 2013

Experimental evaluation of elemental behavior during LA-ICP-MS: influences of plasma conditions and limits of plasma robustness
journal, January 2016

Review: The role of atomic spectrometry in plant science
journal, January 2011

Determination of macro- and micronutrients in plant leaves by high-resolution continuum source flame atomic absorption spectrometry combining instrumental and sample preparation strategies
journal, April 2010

Elemental fractionation and matrix effects in laser sampling based spectrometry
journal, January 2016

Imaging techniques for elements and element species in plant science
journal, January 2012

Comparison of univariate and multivariate calibration for the determination of micronutrients in pellets of plant materials by laser induced breakdown spectrometry
journal, January 2010

Comparative Investigation of Concentrations of Major and Trace Elements in Organic and Conventional Danish Agricultural Crops. 1. Onions ( Allium c epa Hysam) and Peas ( Pisum s ativum Ping Pong)
journal, December 2000

Atomic Spectrometry Update – a review of advances in environmental analysis
journal, January 2019

Multi-energy calibration and sample fusion as alternatives for quantitative analysis of high silicon content samples by laser-induced breakdown spectrometry
journal, January 2019

Elemental Analysis of Asphaltenes Using Simultaneous Laser-Induced Breakdown Spectroscopy (LIBS)–Laser Ablation Inductively Coupled Plasma Optical Emission Spectrometry (LA-ICP-OES)
journal, January 2019