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Title: Large moments in bcc FexCoyMnz ternary alloy thin films

Abstract

The elemental magnetic moments and the average atomic moment of 10-20 nm thick single crystal bcc (bct) FexCoyMnz films deposited on MgO(001) have been determined as a function of a broad range of compositions. Thin film epitaxy stabilized the bcc structure for 80% of the available ternary compositional space compared to only a 23% stability region for the bulk. The films that display ferromagnetism represent 60% of the available compositional possibilities compared to 25% for the bulk. A maximum average atomic moment of 3.25 ± 0.3 μB/atom was observed for a bcc Fe9Co62Mn29 film (well above the limit of the Slater-Pauling binary alloy curve of 2.45 μB/atom). Furthermore, the FexCoyMnz ternary alloys that exhibit high moments can only be synthesized as ultrathin films since the bcc structure is not stable in the bulk for those compositions.

Authors:
 [1];  [1]; ORCiD logo [2];  [2]; ORCiD logo [1]
  1. Montana State Univ., Bozeman, MT (United States)
  2. Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
Publication Date:
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
Sponsoring Org.:
USDOE Office of Science (SC)
OSTI Identifier:
1530335
Alternate Identifier(s):
OSTI ID: 1420355
Grant/Contract Number:  
AC02-05CH11231
Resource Type:
Accepted Manuscript
Journal Name:
Applied Physics Letters
Additional Journal Information:
Journal Volume: 112; Journal Issue: 7; Journal ID: ISSN 0003-6951
Publisher:
American Institute of Physics (AIP)
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE

Citation Formats

Snow, R. J., Bhatkar, H., N'Diaye, A. T., Arenholz, E., and Idzerda, Y. U. Large moments in bcc FexCoyMnz ternary alloy thin films. United States: N. p., 2018. Web. doi:10.1063/1.5006347.
Snow, R. J., Bhatkar, H., N'Diaye, A. T., Arenholz, E., & Idzerda, Y. U. Large moments in bcc FexCoyMnz ternary alloy thin films. United States. https://doi.org/10.1063/1.5006347
Snow, R. J., Bhatkar, H., N'Diaye, A. T., Arenholz, E., and Idzerda, Y. U. Mon . "Large moments in bcc FexCoyMnz ternary alloy thin films". United States. https://doi.org/10.1063/1.5006347. https://www.osti.gov/servlets/purl/1530335.
@article{osti_1530335,
title = {Large moments in bcc FexCoyMnz ternary alloy thin films},
author = {Snow, R. J. and Bhatkar, H. and N'Diaye, A. T. and Arenholz, E. and Idzerda, Y. U.},
abstractNote = {The elemental magnetic moments and the average atomic moment of 10-20 nm thick single crystal bcc (bct) FexCoyMnz films deposited on MgO(001) have been determined as a function of a broad range of compositions. Thin film epitaxy stabilized the bcc structure for 80% of the available ternary compositional space compared to only a 23% stability region for the bulk. The films that display ferromagnetism represent 60% of the available compositional possibilities compared to 25% for the bulk. A maximum average atomic moment of 3.25 ± 0.3 μB/atom was observed for a bcc Fe9Co62Mn29 film (well above the limit of the Slater-Pauling binary alloy curve of 2.45 μB/atom). Furthermore, the FexCoyMnz ternary alloys that exhibit high moments can only be synthesized as ultrathin films since the bcc structure is not stable in the bulk for those compositions.},
doi = {10.1063/1.5006347},
journal = {Applied Physics Letters},
number = 7,
volume = 112,
place = {United States},
year = {Mon Feb 12 00:00:00 EST 2018},
month = {Mon Feb 12 00:00:00 EST 2018}
}

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Free Publicly Available Full Text
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Cited by: 9 works
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Figures / Tables:

Fig. 1 Fig. 1: The average total atomic moment (independent of atom type) for 10 nm FexCoyMnz films on MgO(001) as a function of composition. The green crosses represent the measured data points.

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Works referenced in this record:

Epitaxial bcc Fe x Co 1− x alloy films on ZnSe(001)
journal, November 1992

  • Gutierrez, C. J.; Krebs, J. J.; Prinz, G. A.
  • Applied Physics Letters, Vol. 61, Issue 20
  • DOI: 10.1063/1.108157

In-plane magnetic anisotropy of bcc Co on GaAs(001)
journal, May 1998


On the structural changes accompanying the fcc/hcp martensitic transformation in Fe–Mn–Co alloys
journal, June 2002


Generalized Slater-Pauling curve for transition-metal magnets
journal, September 1983


Molecular beam epitaxial growth of single‐crystal Fe films on GaAs
journal, September 1981

  • Prinz, G. A.; Krebs, J. J.
  • Applied Physics Letters, Vol. 39, Issue 5
  • DOI: 10.1063/1.92750

Probing the spinor nature of electronic states in nanosize non-collinear magnets
journal, October 2016

  • Fischer, Jeison A.; Sandratskii, Leonid M.; Phark, Soo-Hyon
  • Nature Communications, Vol. 7, Issue 1
  • DOI: 10.1038/ncomms13000

Elastic instability of bcc cobalt
journal, April 1993


Spin transfer torques
journal, April 2008


Les moments ferro-magnétiques des éléments et le système périodique
journal, January 1932


The behaviour of nanostructured magnetic materials produced by depositing gas-phase nanoparticles
journal, November 2005


Ab-initio calculations of the electronic structure of impurities and alloys of ferromagnetic transition metals
journal, November 1991


Magnetic Properties of fcc γ-Phase in the Ternary Co-Mn-Fe System
journal, August 1973

  • Matsui, Masaaki; Sato, Kiyoo; Adachi, Kengo
  • Journal of the Physical Society of Japan, Vol. 35, Issue 2
  • DOI: 10.1143/JPSJ.35.419

Electronic properties of Fe, Co, and Mn ultrathin films at the interface with MgO(001)
journal, October 2005


La saturation absolue des ferromagnétiques et les lois d'approche en fonction du champ et de la température
journal, January 1929


Future Options for HDD Storage
journal, October 2009


How to Define and Calculate the Degree of Spin Polarization in Ferromagnets
journal, August 1999


A review of high magnetic moment thin films for microscale and nanotechnology applications
journal, February 2016

  • Scheunert, G.; Heinonen, O.; Hardeman, R.
  • Applied Physics Reviews, Vol. 3, Issue 1
  • DOI: 10.1063/1.4941311

Effect of Mn content on the austenite–martensite phases and magnetic properties in Fe–Mn–Co alloys
journal, October 2011


Probing interfacial properties of ferromagnetic/insulator bilayers with X-ray spectroscopies: Application to Fe, Co, Mn/MgO(001) interfaces
journal, January 2006

  • Sicot, M.; Andrieu, Stéphane; Bertran, F.
  • Materials Science and Engineering: B, Vol. 126, Issue 2-3
  • DOI: 10.1016/j.mseb.2005.09.058

Enhanced moments in bcc Co1−Mn on MgO(001)
journal, December 2016


Stabilization of bcc Co via Epitaxial Growth on GaAs
journal, March 1985


Elemental moment variation of bcc FexMn1−x on MgO(001)
journal, February 2017


Magnetic structure of Co 1 x Mn x alloys
journal, April 2001


Electronic structure and magnetism of metastable bcc Co(001)
journal, November 1986


bcc cobalt: Metastable phase or forced structure?
journal, May 1993

  • Liu, Amy Y.; Singh, David J.
  • Journal of Applied Physics, Vol. 73, Issue 10
  • DOI: 10.1063/1.352693

Thermodynamics of the Co-Fe-Mn System
journal, January 1990


Transition between fundamental magnetic behaviors revealed by generalized Slater–Pauling construction
journal, March 1984

  • Williams, A. R.; Malozemoff, A. P.; Moruzzi, V. L.
  • Journal of Applied Physics, Vol. 55, Issue 6
  • DOI: 10.1063/1.333662

Moment mapping of body-centered-cubic Fe x Mn 1−x alloy films on MgO(001)
journal, May 2015

  • Idzerda, Y. U.; Bhatkar, H.; Arenholz, E.
  • Journal of Applied Physics, Vol. 117, Issue 17
  • DOI: 10.1063/1.4914127

Electronic Structure of Alloys
journal, June 1937


The Nature of the Interatomic Forces in Metals
journal, December 1938


Magnetization of ultrathin bcc Fe films on MgO
journal, January 1993


Exchange-spring behavior in epitaxial hard/soft magnetic bilayers
journal, November 1998


Magnetic moments and short-range order in CoMn and NiMn alloys
journal, February 1995


Exchange-Spring Behavior in Epitaxial Hard/Soft Magnetic Bilayers
conference, January 1998

  • Jiang, J. S.; Fullerton, E. E.; Grimsditch, M.
  • 7th Joint MMM-Intermag Conference. Abstracts (Cat. No.98CH36275)
  • DOI: 10.1109/intmag.1998.735488

Figures/Tables have been extracted from DOE-funded journal article accepted manuscripts.