Communication—O3-Type Layered Oxide with a Quaternary Transition Metal Composition for Na-Ion Battery Cathodes: NaTi0.25Fe0.25Co0.25Ni0.25O2

Vassilaras, Plousia; Dacek, Stephen T.; Kim, Haegyeom; Fister, Timothy T.; Kim, Soojeong; Ceder, Gerbrand; Kim, Jae Chul

doi:10.1149/2.0271714jes

Title: Communication—O3-Type Layered Oxide with a Quaternary Transition Metal Composition for Na-Ion Battery Cathodes: NaTi_0.25Fe_0.25Co_0.25Ni_0.25O₂

Abstract

NaTi_0.25Fe_0.25Co_0.25Ni_0.25O₂ is explored as a cathode material for Na-ion batteries. Synthesized by a solid-state reaction, the compound is phase-pure with the O3-type layered structure and consists of Ti⁴⁺, Fe³⁺, Co³⁺, and Ni²⁺ according to X-ray absorption spectroscopy. The cathode delivers 163 mAh/g and 504 Wh/kg at C/20 in the first discharge with 89% capacity retention after 20 cycles and demonstrates superior rate capability with micron sized particles, in which discharge capacity at 30 C is 80mAh/g. Our results indicate that the Ti-containing quaternary material can be a potential cathode composition for Na-ion batteries.

Authors:

Vassilaras, Plousia ^[1]; Dacek, Stephen T. ^[1]; Kim, Haegyeom ^[2]; Fister, Timothy T. ^[3]; Kim, Soojeong ^[3]; Ceder, Gerbrand ^[4]; Kim, Jae Chul ^[2]

Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States)
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
Argonne National Lab. (ANL), Argonne, IL (United States)
Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)

Publication Date:: Sat Nov 11 00:00:00 EST 2017

Research Org.:: Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)

Sponsoring Org.:: USDOE Office of Science (SC)

OSTI Identifier:: 1530275

Grant/Contract Number:: AC02-05CH11231; AC02-06CH11357; FG02-94ER14466

Resource Type:: Accepted Manuscript

Journal Name:: Journal of the Electrochemical Society

Additional Journal Information:: Journal Volume: 164; Journal Issue: 14; Journal ID: ISSN 0013-4651

Publisher:: The Electrochemical Society

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE; 25 ENERGY STORAGE; Cathode; Na-ion batteries; O3-type

Citation Formats


                    Vassilaras, Plousia, Dacek, Stephen T., Kim, Haegyeom, Fister, Timothy T., Kim, Soojeong, Ceder, Gerbrand, and Kim, Jae Chul. Communication—O3-Type Layered Oxide with a Quaternary Transition Metal Composition for Na-Ion Battery Cathodes: NaTi0.25Fe0.25Co0.25Ni0.25O2.  United States: N. p., 2017. 
Web.  doi:10.1149/2.0271714jes.

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                    Vassilaras, Plousia, Dacek, Stephen T., Kim, Haegyeom, Fister, Timothy T., Kim, Soojeong, Ceder, Gerbrand, & Kim, Jae Chul. Communication—O3-Type Layered Oxide with a Quaternary Transition Metal Composition for Na-Ion Battery Cathodes: NaTi0.25Fe0.25Co0.25Ni0.25O2.  United States.  https://doi.org/10.1149/2.0271714jes

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                    Vassilaras, Plousia, Dacek, Stephen T., Kim, Haegyeom, Fister, Timothy T., Kim, Soojeong, Ceder, Gerbrand, and Kim, Jae Chul. Sat .  
"Communication—O3-Type Layered Oxide with a Quaternary Transition Metal Composition for Na-Ion Battery Cathodes: NaTi0.25Fe0.25Co0.25Ni0.25O2".  United States.  https://doi.org/10.1149/2.0271714jes.  https://www.osti.gov/servlets/purl/1530275.

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@article{osti_1530275,

  title        = {Communication—O3-Type Layered Oxide with a Quaternary Transition Metal Composition for Na-Ion Battery Cathodes: NaTi0.25Fe0.25Co0.25Ni0.25O2},

  author       = {Vassilaras, Plousia and Dacek, Stephen T. and Kim, Haegyeom and Fister, Timothy T. and Kim, Soojeong and Ceder, Gerbrand and Kim, Jae Chul},

  abstractNote = {NaTi0.25Fe0.25Co0.25Ni0.25O2 is explored as a cathode material for Na-ion batteries. Synthesized by a solid-state reaction, the compound is phase-pure with the O3-type layered structure and consists of Ti4+, Fe3+, Co3+, and Ni2+ according to X-ray absorption spectroscopy. The cathode delivers 163 mAh/g and 504 Wh/kg at C/20 in the first discharge with 89% capacity retention after 20 cycles and demonstrates superior rate capability with micron sized particles, in which discharge capacity at 30 C is 80mAh/g. Our results indicate that the Ti-containing quaternary material can be a potential cathode composition for Na-ion batteries.},

  doi          = {10.1149/2.0271714jes},

  journal      = {Journal of the Electrochemical Society},

  number       = 14,

  volume       = 164,

  place        = {United States},

  year         = {Sat Nov 11 00:00:00 EST 2017},

  month        = {Sat Nov 11 00:00:00 EST 2017}

}

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https://doi.org/10.1149/2.0271714jes

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Cited by: 11 works

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Figures / Tables:

Figure 1: Rietveld-refined XRD pattern and SEM image (inset, scale bar: 2 μm) obtained from as-prepared TFCN. Background humps are due to a sealing Kapton film. R_wp = 2.6967, R_p = 1.6841, χ² = 5.9666.

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Works referenced in this record:

A comparison of destabilization mechanisms of the layered NaxMO2 and LixMO2 compounds upon alkali de-intercalation
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Kim, Sangtae; Ma, Xiaohua; Ong, Shyue Ping
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Electrochemistry, Vol. 80, Issue 10
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Synthesis and Electrode Performance of O3-Type NaFeO ₂ -NaNi _1/2 Mn _1/2 O ₂ Solid Solution for Rechargeable Sodium Batteries
journal, January 2013

Yabuuchi, Naoaki; Yano, Masaya; Yoshida, Hiroaki
Journal of The Electrochemical Society, Vol. 160, Issue 5
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Air-Stable Copper-Based P2-Na _7/9 Cu _2/9 Fe _1/9 Mn _2/3 O ₂ as a New Positive Electrode Material for Sodium-Ion Batteries
journal, May 2015

Li, Yunming; Yang, Zhenzhong; Xu, Shuyin
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Structure and Electrochemistry of Na _x Fe _x Ti _1-x O ₂ (1.0 ≥ x ≥ 0.75) for Na-Ion Battery Positive Electrodes
journal, January 2014

Thorne, J. S.; Chowdhury, S.; Dunlap, R. A.
Journal of The Electrochemical Society, Vol. 161, Issue 12
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Structure and Electrochemistry of Na _x Fe _x Mn _1-x O ₂ (1.0 ≤ x ≤ 0.5) for Na-Ion Battery Positive Electrodes
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Thorne, J. S.; Dunlap, R. A.; Obrovac, M. N.
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Stability of Prismatic and Octahedral Coordination in Layered Oxides and Sulfides Intercalated with Alkali and Alkaline-Earth Metals
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Works referencing / citing this record:

Readiness Level of Sodium-Ion Battery Technology: A Materials Review
journal, January 2018

Chen, Lin; Fiore, Michele; Wang, Ji Eun
Advanced Sustainable Systems, Vol. 2, Issue 3
DOI: 10.1002/adsu.201700153

A New Strategy for High-Voltage Cathodes for K-Ion Batteries: Stoichiometric KVPO ₄ F
journal, July 2018

Kim, Haegyeom; Seo, Dong-Hwa; Bianchini, Matteo
Advanced Energy Materials, Vol. 8, Issue 26
DOI: 10.1002/aenm.201801591

Sodium-based batteries: from critical materials to battery systems
journal, January 2019

Li, Fang; Wei, Zengxi; Manthiram, Arumugam
Journal of Materials Chemistry A, Vol. 7, Issue 16
DOI: 10.1039/c8ta11999f

Nickel Oxide Nano-Particles on 3D Nickel Foam Substrate as a Non-Enzymatic Glucose Sensor
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Journal of The Electrochemical Society, Vol. 166, Issue 15
DOI: 10.1149/2.0491915jes

Water-Processable P2-Na _0.67 Ni _0.22 Cu _0.11 Mn _0.56 Ti _0.11 O ₂ Cathode Material for Sodium Ion Batteries
journal, January 2019

Mu, Linqin; Hou, Qingping; Yang, Zhenzhong
Journal of The Electrochemical Society, Vol. 166, Issue 2
DOI: 10.1149/2.0881902jes

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Similar Records

Title: Communication—O3-Type Layered Oxide with a Quaternary Transition Metal Composition for Na-Ion Battery Cathodes: NaTi0.25Fe0.25Co0.25Ni0.25O2

Abstract

Citation Formats

Figures / Tables:

A comparison of destabilization mechanisms of the layered NaxMO2 and LixMO2 compounds upon alkali de-intercalation journal, January 2012

Crystal Structures and Electrode Performance of Alpha-NaFeO2 for Rechargeable Sodium Batteries journal, January 2012

Synthesis and Electrode Performance of O3-Type NaFeO 2 -NaNi 1/2 Mn 1/2 O 2 Solid Solution for Rechargeable Sodium Batteries journal, January 2013

Air-Stable Copper-Based P2-Na 7/9 Cu 2/9 Fe 1/9 Mn 2/3 O 2 as a New Positive Electrode Material for Sodium-Ion Batteries journal, May 2015

Structural classification and properties of the layered oxides journal, January 1980

Structure and Electrochemistry of Na x Fe x Ti 1-x O 2 (1.0 ≥ x ≥ 0.75) for Na-Ion Battery Positive Electrodes journal, January 2014

Structure and Electrochemistry of Na x Fe x Mn 1-x O 2 (1.0 ≤ x ≤ 0.5) for Na-Ion Battery Positive Electrodes journal, December 2012

Stability of Prismatic and Octahedral Coordination in Layered Oxides and Sulfides Intercalated with Alkali and Alkaline-Earth Metals journal, October 2016

Readiness Level of Sodium-Ion Battery Technology: A Materials Review journal, January 2018

A New Strategy for High-Voltage Cathodes for K-Ion Batteries: Stoichiometric KVPO 4 F journal, July 2018

Sodium-based batteries: from critical materials to battery systems journal, January 2019

Nickel Oxide Nano-Particles on 3D Nickel Foam Substrate as a Non-Enzymatic Glucose Sensor journal, January 2019

Water-Processable P2-Na 0.67 Ni 0.22 Cu 0.11 Mn 0.56 Ti 0.11 O 2 Cathode Material for Sodium Ion Batteries journal, January 2019

Title: Communication—O3-Type Layered Oxide with a Quaternary Transition Metal Composition for Na-Ion Battery Cathodes: NaTi_0.25Fe_0.25Co_0.25Ni_0.25O₂

A comparison of destabilization mechanisms of the layered NaxMO2 and LixMO2 compounds upon alkali de-intercalation
journal, January 2012

Crystal Structures and Electrode Performance of Alpha-NaFeO2 for Rechargeable Sodium Batteries
journal, January 2012

Synthesis and Electrode Performance of O3-Type NaFeO ₂ -NaNi _1/2 Mn _1/2 O ₂ Solid Solution for Rechargeable Sodium Batteries
journal, January 2013

Air-Stable Copper-Based P2-Na _7/9 Cu _2/9 Fe _1/9 Mn _2/3 O ₂ as a New Positive Electrode Material for Sodium-Ion Batteries
journal, May 2015

Structural classification and properties of the layered oxides
journal, January 1980

Structure and Electrochemistry of Na _x Fe _x Ti _1-x O ₂ (1.0 ≥ x ≥ 0.75) for Na-Ion Battery Positive Electrodes
journal, January 2014

Structure and Electrochemistry of Na _x Fe _x Mn _1-x O ₂ (1.0 ≤ x ≤ 0.5) for Na-Ion Battery Positive Electrodes
journal, December 2012

Stability of Prismatic and Octahedral Coordination in Layered Oxides and Sulfides Intercalated with Alkali and Alkaline-Earth Metals
journal, October 2016

Readiness Level of Sodium-Ion Battery Technology: A Materials Review
journal, January 2018

A New Strategy for High-Voltage Cathodes for K-Ion Batteries: Stoichiometric KVPO ₄ F
journal, July 2018

Sodium-based batteries: from critical materials to battery systems
journal, January 2019

Nickel Oxide Nano-Particles on 3D Nickel Foam Substrate as a Non-Enzymatic Glucose Sensor
journal, January 2019

Water-Processable P2-Na _0.67 Ni _0.22 Cu _0.11 Mn _0.56 Ti _0.11 O ₂ Cathode Material for Sodium Ion Batteries
journal, January 2019