Title: Techno-economic analysis and life-cycle greenhouse gas mitigation cost of five routes to bio-jet fuel blendstocks

Abstract

Decarbonizing the air transportation sector remains one of the most challenging hurdles to mitigating climate change. Lignocellulosic biomass-derived jet fuel blendstocks can contribute to the shift toward renewable, low-carbon energy sources for aircrafts. Producing these renewable jet fuel molecules from biomass requires advanced pathways with the potential for efficient and affordable conversion routes. Here, this paper presents a detailed techno-economic analysis and sensitivity analysis, including estimated minimum selling price (MSP), and life-cycle greenhouse gas (GHG) mitigation costs for five routes to four potential bio-jet fuel molecules – limonane via limonene, limonane via 1,8-cineole, tetrahydromethylcyclopentadiene dimer (RJ-4), bisabolane, and epi-isozizaane. The simulated biorefineries utilize biomass sorghum and an integrated high-gravity ionic liquid-based biomass deconstruction process. We present results reflecting the current state of the technology and potential future scenarios with improved yields. Among the conversion pathways and the fuel molecules evaluated in this study, limonane, bisabolane, and epi-isozizaane could reach an MSP of 0.73–0.91 dollars per L-Jet A (2.75–3.45 dollars per gal-Jet A) in optimized future cases, without a hypothetical lignin-derived co-product. RJ-4 requires a more costly upgrading process and catalysts, resulting in a comparatively higher MSP (1.33 dollars per L-Jet A or 5.04 dollars per gal-jet A). Based on themore » GHG footprints of each fuel, the minimum achievable carbon mitigation cost relative to conventional Jet-A is 29 dollars per metric ton CO_2e, which is just under double the current cap-and-trade market price in California. In the absence of any policy support, the economics could be improved through high-value uses for lignin. To reach a target selling price of 0.66 dollars per L-Jet A (2.50 dollars per gal), lignin-derived products would need to be sold for at least 1.9 dollars per kg. However, the higher energy density of these bio-based blendstocks offers valuable improvements in aircraft efficiency/range; we find that commercial airlines may be willing to pay a 4–14 cent per L premium for these bio-jet fuels. In conclusion, our results highlight the need for improvements beyond currently-reported yields for the biologically produced intermediates, identification of ideal microbial hosts, selection of metabolic pathways to achieve competitive production costs, and a focus on fuels with attractive properties that increase their value.« less

Authors:

Baral, Nawa Raj  ^[1];

• Search DOE PAGES for author "Baral, Nawa Raj"
• Search DOE PAGES for ORCID "0000-0002-0942-9183"

Kavvada, Olga  ^[1];

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• Search DOE PAGES for ORCID "0000-0002-9801-144X"

Mendez-Perez, Daniel ^[1]; Mukhopadhyay, Aindrila  ^[1];

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• Search DOE PAGES for ORCID "0000-0002-6513-7425"

Lee, Taek Soon  ^[1];

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• Search DOE PAGES for ORCID "0000-0002-0764-2626"

Simmons, Blake A.  ^[1];

• Search DOE PAGES for author "Simmons, Blake A."
• Search DOE PAGES for ORCID "0000-0002-1332-1810"

Scown, Corinne D.  ^[1]

• Search DOE PAGES for author "Scown, Corinne D."
• Search DOE PAGES for ORCID "0000-0003-2078-1126"

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+ Show Author Affiliations

1. Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)

Publication Date:

Tue Feb 05 00:00:00 EST 2019

Research Org.:

Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)

Sponsoring Org.:

USDOE Office of Science (SC), Biological and Environmental Research (BER)

OSTI Identifier:

1528903

Alternate Identifier(s):

OSTI ID: 1494643

Grant/Contract Number:  

AC02-05CH11231

Resource Type:

Accepted Manuscript

Journal Name:

Energy & Environmental Science

Additional Journal Information:

Journal Volume: 12; Journal Issue: 3; Journal ID: ISSN 1754-5692

Publisher:

Royal Society of Chemistry

Country of Publication:

United States

Language:

English

Subject:

09 BIOMASS FUELS; 54 ENVIRONMENTAL SCIENCES