Crystal-Field Tuning of Photoluminescence in Two-Dimensional Materials with Embedded Lanthanide Ions
Abstract
Lanthanide (Ln) group elements have been attracting considerable attention owing to the distinct optical properties. The crystal-field surroundings of Ln ions in the host materials can determine their energy level splitting, which is of vital importance to tailor their optical properties. 2D MoS2 single crystals were utilized as the host material to embed Eu3+ and energy-level splitting was achieved for tuning its photoluminescence (PL). The high anisotropy of the 2D host materials makes them distort the degenerate orbitals of the Ln ions more efficiently than the symmetrical bulk host materials. A significant red-shift of the PL peak for Eu3+ was observed. The strategy for tailoring the energy level splitting of Ln ions by the highly designable 2D material crystal field provides a new method to extend their optical properties.
- Authors:
-
- Wuhan Univ., Wuhan (China). College of Chemistry and Molecular Sciences, Inst. for Advanced Studies
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Science (CNMS)
- Publication Date:
- Research Org.:
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1528738
- Grant/Contract Number:
- AC05-00OR22725
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Angewandte Chemie (International Edition)
- Additional Journal Information:
- Journal Name: Angewandte Chemie (International Edition); Journal Volume: 57; Journal Issue: 3; Journal ID: ISSN 1433-7851
- Publisher:
- Wiley
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE
Citation Formats
Xu, Ding, Chen, Weiyin, Zeng, Mengqi, Xue, Haifeng, Chen, Yunxu, Sang, Xiahan, Xiao, Yao, Zhang, Tao, Unocic, Raymond R., Xiao, Kai, and Fu, Lei. Crystal-Field Tuning of Photoluminescence in Two-Dimensional Materials with Embedded Lanthanide Ions. United States: N. p., 2017.
Web. doi:10.1002/anie.201711071.
Xu, Ding, Chen, Weiyin, Zeng, Mengqi, Xue, Haifeng, Chen, Yunxu, Sang, Xiahan, Xiao, Yao, Zhang, Tao, Unocic, Raymond R., Xiao, Kai, & Fu, Lei. Crystal-Field Tuning of Photoluminescence in Two-Dimensional Materials with Embedded Lanthanide Ions. United States. https://doi.org/10.1002/anie.201711071
Xu, Ding, Chen, Weiyin, Zeng, Mengqi, Xue, Haifeng, Chen, Yunxu, Sang, Xiahan, Xiao, Yao, Zhang, Tao, Unocic, Raymond R., Xiao, Kai, and Fu, Lei. Fri .
"Crystal-Field Tuning of Photoluminescence in Two-Dimensional Materials with Embedded Lanthanide Ions". United States. https://doi.org/10.1002/anie.201711071. https://www.osti.gov/servlets/purl/1528738.
@article{osti_1528738,
title = {Crystal-Field Tuning of Photoluminescence in Two-Dimensional Materials with Embedded Lanthanide Ions},
author = {Xu, Ding and Chen, Weiyin and Zeng, Mengqi and Xue, Haifeng and Chen, Yunxu and Sang, Xiahan and Xiao, Yao and Zhang, Tao and Unocic, Raymond R. and Xiao, Kai and Fu, Lei},
abstractNote = {Lanthanide (Ln) group elements have been attracting considerable attention owing to the distinct optical properties. The crystal-field surroundings of Ln ions in the host materials can determine their energy level splitting, which is of vital importance to tailor their optical properties. 2D MoS2 single crystals were utilized as the host material to embed Eu3+ and energy-level splitting was achieved for tuning its photoluminescence (PL). The high anisotropy of the 2D host materials makes them distort the degenerate orbitals of the Ln ions more efficiently than the symmetrical bulk host materials. A significant red-shift of the PL peak for Eu3+ was observed. The strategy for tailoring the energy level splitting of Ln ions by the highly designable 2D material crystal field provides a new method to extend their optical properties.},
doi = {10.1002/anie.201711071},
journal = {Angewandte Chemie (International Edition)},
number = 3,
volume = 57,
place = {United States},
year = {Fri Dec 15 00:00:00 EST 2017},
month = {Fri Dec 15 00:00:00 EST 2017}
}
Web of Science
Works referenced in this record:
A density functional theory study of electronic and magnetic properties of rare earth doped monolayered molybdenum disulphide
journal, October 2016
- Majid, Abdul; Imtiaz, Anum; Yoshiya, Masato
- Journal of Applied Physics, Vol. 120, Issue 14
Lanthanide-doped semiconductor nanocrystals: electronic structures and optical properties
journal, October 2015
- Luo, Wenqin; Liu, Yongsheng; Chen, Xueyuan
- Science China Materials, Vol. 58, Issue 10
Energy transfer in lanthanide upconversion studies for extended optical applications
journal, January 2015
- Dong, Hao; Sun, Ling-Dong; Yan, Chun-Hua
- Chemical Society Reviews, Vol. 44, Issue 6
Some Rules of Spectral Structure*
journal, January 1925
- Laporte, Otto; Meggers, William F.
- Journal of the Optical Society of America, Vol. 11, Issue 5
Chemical vapour deposition of group-VIB metal dichalcogenide monolayers: engineered substrates from amorphous to single crystalline
journal, January 2015
- Ji, Qingqing; Zhang, Yu; Zhang, Yanfeng
- Chemical Society Reviews, Vol. 44, Issue 9
Lanthanide-Doped Upconversion Nanoparticles: Emerging Intelligent Light-Activated Drug Delivery Systems
journal, March 2016
- Bagheri, Ali; Arandiyan, Hamidreza; Boyer, Cyrille
- Advanced Science, Vol. 3, Issue 7
Strong photoluminescence emission of Eu:TiO2 nanotubes
journal, November 2007
- Zeng, Q. G.; Zhang, Z. M.; Ding, Z. J.
- Scripta Materialia, Vol. 57, Issue 10
The enhanced performance of MnOx catalyst for NH3-SCR reaction by the modification with Eu
journal, February 2017
- Sun, Peng; Guo, Rui-tang; Liu, Shu-ming
- Applied Catalysis A: General, Vol. 531
Strain-engineered growth of two-dimensional materials
journal, September 2017
- Ahn, Geun Ho; Amani, Matin; Rasool, Haider
- Nature Communications, Vol. 8, Issue 1
Increase in external quantum efficiency of encapsulated silicon solar cells from a luminescent down-shifting layer
journal, May 2009
- McIntosh, Keith R.; Lau, Gay; Cotsell, James N.
- Progress in Photovoltaics: Research and Applications, Vol. 17, Issue 3
Ultrathin S-doped MoSe 2 nanosheets for efficient hydrogen evolution
journal, January 2014
- Xu, Chen; Peng, Shengjie; Tan, Chaoliang
- J. Mater. Chem. A, Vol. 2, Issue 16
UV-Vis-NIR luminescence properties and energy transfer mechanism of LiSrPO_4:Eu^2+, Pr^3+ suitable for solar spectral convertor
journal, January 2013
- Chen, Yan; Wang, Jing; Liu, Chunmeng
- Optics Express, Vol. 21, Issue 3
Long-Term Real-Time Tracking of Lanthanide Ion Doped Upconverting Nanoparticles in Living Cells
journal, May 2011
- Nam, Sang Hwan; Bae, Yun Mi; Park, Yong Il
- Angewandte Chemie International Edition, Vol. 50, Issue 27
Full-Color Emission from In 2 S 3 and In 2 S 3 :Eu 3+ Nanoparticles
journal, August 2004
- Chen, Wei; Bovin, Jan-Olov; Joly, Alan G.
- The Journal of Physical Chemistry B, Vol. 108, Issue 32
Long-Term Real-Time Tracking of Lanthanide Ion Doped Upconverting Nanoparticles in Living Cells
journal, May 2011
- Nam, Sang Hwan; Bae, Yun Mi; Park, Yong Il
- Angewandte Chemie, Vol. 123, Issue 27
Lanthanide-doped luminescent nanoprobes: controlled synthesis, optical spectroscopy, and bioapplications
journal, January 2013
- Liu, Yongsheng; Tu, Datao; Zhu, Haomiao
- Chemical Society Reviews, Vol. 42, Issue 16
Nanoparticle Luminescence Thermometry
journal, October 2002
- Wang, Shaopeng; Westcott, Sarah; Chen, Wei
- The Journal of Physical Chemistry B, Vol. 106, Issue 43
Works referencing / citing this record:
Integrating Properties Modification in the Synthesis of Metal Halide Perovskites
journal, November 2018
- Huang, Ke; Liu, Jinxin; Chang, Xuejiao
- Advanced Materials Technologies, Vol. 4, Issue 2
Atomic-Scale Structural Modification of 2D Materials
journal, January 2019
- Xiao, Yao; Zhou, Mengyue; Zeng, Mengqi
- Advanced Science, Vol. 6, Issue 5
Properties Design: Prediction and Experimental Validation of the Luminescence Properties of a New Eu II -Based Phosphor
journal, October 2018
- García-Fuente, Amador; Baur, Florian; Cimpoesu, Fanica
- Chemistry - A European Journal, Vol. 24, Issue 61
Rare‐earth‐incorporated low‐dimensional chalcogenides: Dry‐method syntheses and applications
journal, February 2020
- Zhang, Zheshan; Zhao, Hongyang; Zhang, Chao
- InfoMat, Vol. 2, Issue 3
Salt-assisted chemical vapor deposition of two-dimensional materials
journal, August 2019
- Han, Wei; Liu, Kailang; Yang, Sanjun
- Science China Chemistry, Vol. 62, Issue 10
Engineering of transition metal dichalcogenide-based 2D nanomaterials through doping for environmental applications
journal, January 2019
- Balasubramaniam, Bhuvaneshwari; Singh, Narendra; Kar, Prasenjit
- Molecular Systems Design & Engineering, Vol. 4, Issue 4