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Title: Simultaneous determination of high-temperature crystal structure and texture of synthetic porous cordierite

Abstract

The evolution of the crystal structure and crystallographic texture of porous synthetic cordierite was studied by in situ high-temperature neutron diffraction up to 1373 K, providing the first in situ high-temperature texture measurement of this technologically important material. It was observed that the crystal texture slightly weakens with increasing temperature, concurrently with subtle changes in the crystal structure. These changes are in agreement with previous work, leading the authors to the conclusion that high-temperature neutron diffraction allows reliable crystallographic characterization of materials with moderate texture. It was also demonstrated that structural changes occur at about the glass transition temperature of the cordierite glass (between 973 and 1073 K). Crystal structure refinements were conducted with and without quantitative texture analysis being part of the Rietveld refinement, and a critical comparison of the results is presented, contributing to the sparse body of literature on combined texture and crystal structure refinements.

Authors:
ORCiD logo [1]; ORCiD logo [2]
+ Show Author Affiliations
  1. Federal Inst. for Materials Research and Testing (BAM), Berlin (Germany); Univ. of Potsdam (Germany)
  2. Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
Publication Date:
Research Org.:
Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)
Sponsoring Org.:
USDOE National Nuclear Security Administration (NNSA)
OSTI Identifier:
1525816
Report Number(s):
LA-UR-18-21169
Journal ID: ISSN 1600-5767; JACGAR
Grant/Contract Number:  
89233218CNA000001; AC52-06NA25396
Resource Type:
Accepted Manuscript
Journal Name:
Journal of Applied Crystallography (Online)
Additional Journal Information:
Journal Name: Journal of Applied Crystallography (Online); Journal Volume: 50; Journal Issue: 3; Journal ID: ISSN 1600-5767
Publisher:
International Union of Crystallography
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; synthetic extruded cordierite; crystal texture; high temperature; atomic distances; atomic displacement parameters; neutron diffraction

Citation Formats

Bruno, Giovanni, and Vogel, Sven C. Simultaneous determination of high-temperature crystal structure and texture of synthetic porous cordierite. United States: N. p., 2017. Web. doi:10.1107/S160057671700406X.
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Bruno, Giovanni, & Vogel, Sven C. Simultaneous determination of high-temperature crystal structure and texture of synthetic porous cordierite. United States. https://doi.org/10.1107/S160057671700406X
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Bruno, Giovanni, and Vogel, Sven C. Thu . "Simultaneous determination of high-temperature crystal structure and texture of synthetic porous cordierite". United States. https://doi.org/10.1107/S160057671700406X. https://www.osti.gov/servlets/purl/1525816.
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@article{osti_1525816,
title = {Simultaneous determination of high-temperature crystal structure and texture of synthetic porous cordierite},
author = {Bruno, Giovanni and Vogel, Sven C.},
abstractNote = {The evolution of the crystal structure and crystallographic texture of porous synthetic cordierite was studied by in situ high-temperature neutron diffraction up to 1373 K, providing the first in situ high-temperature texture measurement of this technologically important material. It was observed that the crystal texture slightly weakens with increasing temperature, concurrently with subtle changes in the crystal structure. These changes are in agreement with previous work, leading the authors to the conclusion that high-temperature neutron diffraction allows reliable crystallographic characterization of materials with moderate texture. It was also demonstrated that structural changes occur at about the glass transition temperature of the cordierite glass (between 973 and 1073 K). Crystal structure refinements were conducted with and without quantitative texture analysis being part of the Rietveld refinement, and a critical comparison of the results is presented, contributing to the sparse body of literature on combined texture and crystal structure refinements.},
doi = {10.1107/S160057671700406X},
journal = {Journal of Applied Crystallography (Online)},
number = 3,
volume = 50,
place = {United States},
year = {Thu Apr 13 00:00:00 EDT 2017},
month = {Thu Apr 13 00:00:00 EDT 2017}
}
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Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
https://doi.org/10.1107/S160057671700406X
Copyright Statement
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Citation Metrics:
Cited by: 10 works
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Figures / Tables:

Figure 1 Figure 1: Pole figure coverage of the 96 selected histograms for the four sample orientations.
All figures and tables (18 total)
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    Works referencing / citing this record:

    Crystal Structure and Thermal Expansion Coefficient of Cordierite Honeycomb Ceramics
    journal, January 2019

    • Son, Min-A; Chae, Ki-Woong; Kim, Jeong Seog
    • physica status solidi (a), Vol. 216, Issue 4
    • DOI: 10.1002/pssa.201700994
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      Figures / Tables found in this record:

      Figure 1 (p. 5)figure
      Table 1 (p. 5)table
      Table 2 (p. 5)table
      Figure 2 (p. 6)figure
      Figure 3 (p. 7)figure
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      Figure 11 (p. 12)figure
      Figure 12 (p. 14)figure
      Table 3 (p. 14)table
      Figure 13 (p. 15)figure
      Figure 14 (p. 15)figure
      Figure 15 (p. 16)figure
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