Sacrificial template synthesis of hollow C@MoS2@PPy nanocomposites as anodes for enhanced sodium storage performance
Abstract
Molybdenum disulfide (MoS2) has become a potential anode material for sodium-ion batteries (SIBs) by showing decent cell performance but it suffers poor electronic conductivity and large volume expansion during sodiation. Here we design a nanocomposite with hollow nitrogen doped carbon and polypyrrole modified MoS2 for improving the performance for SIBs. The designed nanocomposite shows a much-improved electronic conductivity and the design of the architecture provides sufficient channels for mass transport and accommodates large volume change. This C@MoS2@PPy anode delivers a high specific capacity of 713 mAh g-1 at 0.1 A g-1 for 100 cycles, and an excellent rate capacity of 294 mAh g-1 at 5 A g-1 for 500 cycles. This specific architecture of C@MoS2@PPy could guide the future design of the electrode material in SIBs and its superior electrochemical performance indicates the great potential application for SIBs.
- Authors:
-
- Ludong Univ., Yantai (China)
- Argonne National Lab. (ANL), Argonne, IL (United States)
- Publication Date:
- Research Org.:
- Argonne National Lab. (ANL), Argonne, IL (United States)
- Sponsoring Org.:
- National Natural Science Foundation of China (NSFC); USDOE Office of Energy Efficiency and Renewable Energy (EERE) - Office of Vehicle Technologies (VTO)
- OSTI Identifier:
- 1523650
- Grant/Contract Number:
- AC02-06CH11357
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Nano Energy
- Additional Journal Information:
- Journal Volume: 60; Journal Issue: C; Journal ID: ISSN 2211-2855
- Publisher:
- Elsevier
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE; anode; molybdenum disulfide; polymerization; polypyrrole; sodium ion batteries
Citation Formats
Wang, Guangming, Bi, Xuanxuan, Yue, Hailong, Jin, Rencheng, Wang, Qingyao, Gao, Shanmin, and Lu, Jun. Sacrificial template synthesis of hollow C@MoS2@PPy nanocomposites as anodes for enhanced sodium storage performance. United States: N. p., 2019.
Web. doi:10.1016/j.nanoen.2019.03.065.
Wang, Guangming, Bi, Xuanxuan, Yue, Hailong, Jin, Rencheng, Wang, Qingyao, Gao, Shanmin, & Lu, Jun. Sacrificial template synthesis of hollow C@MoS2@PPy nanocomposites as anodes for enhanced sodium storage performance. United States. https://doi.org/10.1016/j.nanoen.2019.03.065
Wang, Guangming, Bi, Xuanxuan, Yue, Hailong, Jin, Rencheng, Wang, Qingyao, Gao, Shanmin, and Lu, Jun. Sat .
"Sacrificial template synthesis of hollow C@MoS2@PPy nanocomposites as anodes for enhanced sodium storage performance". United States. https://doi.org/10.1016/j.nanoen.2019.03.065. https://www.osti.gov/servlets/purl/1523650.
@article{osti_1523650,
title = {Sacrificial template synthesis of hollow C@MoS2@PPy nanocomposites as anodes for enhanced sodium storage performance},
author = {Wang, Guangming and Bi, Xuanxuan and Yue, Hailong and Jin, Rencheng and Wang, Qingyao and Gao, Shanmin and Lu, Jun},
abstractNote = {Molybdenum disulfide (MoS2) has become a potential anode material for sodium-ion batteries (SIBs) by showing decent cell performance but it suffers poor electronic conductivity and large volume expansion during sodiation. Here we design a nanocomposite with hollow nitrogen doped carbon and polypyrrole modified MoS2 for improving the performance for SIBs. The designed nanocomposite shows a much-improved electronic conductivity and the design of the architecture provides sufficient channels for mass transport and accommodates large volume change. This C@MoS2@PPy anode delivers a high specific capacity of 713 mAh g-1 at 0.1 A g-1 for 100 cycles, and an excellent rate capacity of 294 mAh g-1 at 5 A g-1 for 500 cycles. This specific architecture of C@MoS2@PPy could guide the future design of the electrode material in SIBs and its superior electrochemical performance indicates the great potential application for SIBs.},
doi = {10.1016/j.nanoen.2019.03.065},
journal = {Nano Energy},
number = C,
volume = 60,
place = {United States},
year = {Sat Mar 23 00:00:00 EDT 2019},
month = {Sat Mar 23 00:00:00 EDT 2019}
}
Free Publicly Available Full Text
Publisher's Version of Record
Other availability
Search WorldCat to find libraries that may hold this journal
Cited by: 81 works
Citation information provided by
Web of Science
Web of Science
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Research Development on Sodium-Ion Batteries
journal, October 2014
- Yabuuchi, Naoaki; Kubota, Kei; Dahbi, Mouad
- Chemical Reviews, Vol. 114, Issue 23
Array of nanosheets render ultrafast and high-capacity Na-ion storage by tunable pseudocapacitance
journal, June 2016
- Chao, Dongliang; Zhu, Changrong; Yang, Peihua
- Nature Communications, Vol. 7, Issue 1
Ultrathin MoS 2 Nanosheets@Metal Organic Framework-Derived N-Doped Carbon Nanowall Arrays as Sodium Ion Battery Anode with Superior Cycling Life and Rate Capability
journal, July 2017
- Ren, Weina; Zhang, Haifeng; Guan, Cao
- Advanced Functional Materials, Vol. 27, Issue 32
Ice Templated Free-Standing Hierarchically WS 2 /CNT-rGO Aerogel for High-Performance Rechargeable Lithium and Sodium Ion Batteries
journal, August 2016
- Wang, Ye; Kong, Dezhi; Shi, Wenhui
- Advanced Energy Materials, Vol. 6, Issue 21
Graphene, related two-dimensional crystals, and hybrid systems for energy conversion and storage
journal, January 2015
- Bonaccorso, Francesco; Colombo, Luigi; Yu, Guihua
- Science, Vol. 347, Issue 6217
Electrochemical Na Insertion and Solid Electrolyte Interphase for Hard-Carbon Electrodes and Application to Na-Ion Batteries
journal, August 2011
- Komaba, Shinichi; Murata, Wataru; Ishikawa, Toru
- Advanced Functional Materials, Vol. 21, Issue 20
Sodium Storage Behavior in Natural Graphite using Ether-based Electrolyte Systems
journal, November 2014
- Kim, Haegyeom; Hong, Jihyun; Park, Young-Uk
- Advanced Functional Materials, Vol. 25, Issue 4
Lithium-Pretreated Hard Carbon as High-Performance Sodium-Ion Battery Anodes
journal, July 2018
- Xiao, Biwei; Soto, Fernando A.; Gu, Meng
- Advanced Energy Materials, Vol. 8, Issue 24
MoS 2 /Graphene Composite Paper for Sodium-Ion Battery Electrodes
journal, January 2014
- David, Lamuel; Bhandavat, Romil; Singh, Gurpreet
- ACS Nano, Vol. 8, Issue 2
MoS 2 Nanoflowers with Expanded Interlayers as High-Performance Anodes for Sodium-Ion Batteries
journal, September 2014
- Hu, Zhe; Wang, Lixiu; Zhang, Kai
- Angewandte Chemie International Edition, Vol. 53, Issue 47
Effective Liquid-Phase Exfoliation and Sodium Ion Battery Application of MoS 2 Nanosheets
journal, May 2014
- Bang, Gyeong Sook; Nam, Kwan Woo; Kim, Jong Yun
- ACS Applied Materials & Interfaces, Vol. 6, Issue 10
WS 2 Nanowires as a High-Performance Anode for Sodium-Ion Batteries
journal, June 2015
- Liu, Yongchang; Zhang, Ning; Kang, Hongyan
- Chemistry - A European Journal, Vol. 21, Issue 33
Engineering nanostructured electrode materials for high performance sodium ion batteries: a case study of a 3D porous interconnected WS 2 /C nanocomposite
journal, January 2015
- Zhu, Changbao; Kopold, Peter; Li, Weihan
- Journal of Materials Chemistry A, Vol. 3, Issue 41
WS2@graphene nanocomposites as anode materials for Na-ion batteries with enhanced electrochemical performances
journal, January 2014
- Su, Dawei; Dou, Shixue; Wang, Guoxiu
- Chemical Communications, Vol. 50, Issue 32
Enhanced Sodium-Ion Battery Performance by Structural Phase Transition from Two-Dimensional Hexagonal-SnS 2 to Orthorhombic-SnS
journal, July 2014
- Zhou, Tengfei; Pang, Wei Kong; Zhang, Chaofeng
- ACS Nano, Vol. 8, Issue 8
Few-Layered SnS 2 on Few-Layered Reduced Graphene Oxide as Na-Ion Battery Anode with Ultralong Cycle Life and Superior Rate Capability
journal, November 2014
- Zhang, Yandong; Zhu, Peiyi; Huang, Liliang
- Advanced Functional Materials, Vol. 25, Issue 3
SnS nanoparticles electrostatically anchored on three-dimensional N-doped graphene as an active and durable anode for sodium-ion batteries
journal, January 2017
- Xiong, Xunhui; Yang, Chenghao; Wang, Guanhua
- Energy & Environmental Science, Vol. 10, Issue 8
Aerosol-assisted rapid synthesis of SnS-C composite microspheres as anode material for Na-ion batteries
journal, April 2015
- Choi, Seung Ho; Kang, Yun Chan
- Nano Research, Vol. 8, Issue 5
Fe 3 O 4 quantum dot decorated MoS 2 nanosheet arrays on graphite paper as free-standing sodium-ion battery anodes
journal, January 2017
- Kong, Dezhi; Cheng, Chuanwei; Wang, Ye
- Journal of Materials Chemistry A, Vol. 5, Issue 19
High-Performance Sodium-Ion Batteries and Sodium-Ion Pseudocapacitors Based on MoS 2 /Graphene Composites
journal, July 2014
- Wang, Yun-Xiao; Chou, Shu-Lei; Wexler, David
- Chemistry - A European Journal, Vol. 20, Issue 31
Ultrathin MoS 2 Nanosheets as Anode Materials for Sodium-Ion Batteries with Superior Performance
journal, December 2014
- Su, Dawei; Dou, Shixue; Wang, Guoxiu
- Advanced Energy Materials, Vol. 5, Issue 6
Liquid Phase Exfoliated MoS 2 Nanosheets Percolated with Carbon Nanotubes for High Volumetric/Areal Capacity Sodium-Ion Batteries
journal, August 2016
- Liu, Yuping; He, Xiaoyun; Hanlon, Damien
- ACS Nano, Vol. 10, Issue 9
Growth of Ultrathin MoS 2 Nanosheets with Expanded Spacing of (002) Plane on Carbon Nanotubes for High-Performance Sodium-Ion Battery Anodes
journal, December 2014
- Zhang, Shen; Yu, Xianbo; Yu, Hailong
- ACS Applied Materials & Interfaces, Vol. 6, Issue 24
MoS 2 /Graphene Composite Anodes with Enhanced Performance for Sodium-Ion Batteries: The Role of the Two-Dimensional Heterointerface
journal, January 2015
- Xie, Xiuqiang; Ao, Zhimin; Su, Dawei
- Advanced Functional Materials, Vol. 25, Issue 9
3D MoS 2 -Graphene Microspheres Consisting of Multiple Nanospheres with Superior Sodium Ion Storage Properties
journal, February 2015
- Choi, Seung Ho; Ko, You Na; Lee, Jung-Kul
- Advanced Functional Materials, Vol. 25, Issue 12
Exfoliated MoS 2 nanosheets confined in 3-D hierarchical carbon nanotube@graphene architecture with superior sodium-ion storage
journal, January 2017
- Sahu, Tuhin Subhra; Li, Qianqian; Wu, Jinsong
- Journal of Materials Chemistry A, Vol. 5, Issue 1
Synthesis of MoS 2 @C Nanotubes Via the Kirkendall Effect with Enhanced Electrochemical Performance for Lithium Ion and Sodium Ion Batteries
journal, March 2016
- Zhang, Xueqian; Li, Xiaona; Liang, Jianwen
- Small, Vol. 12, Issue 18
MoS 2 Nanosheets Vertically Aligned on Carbon Paper: A Freestanding Electrode for Highly Reversible Sodium-Ion Batteries
journal, December 2015
- Xie, Xiuqiang; Makaryan, Taron; Zhao, Mengqiang
- Advanced Energy Materials, Vol. 6, Issue 5
An Advanced MoS 2 /Carbon Anode for High-Performance Sodium-Ion Batteries
journal, September 2014
- Wang, Jingjing; Luo, Chao; Gao, Tao
- Small, Vol. 11, Issue 4
ALD TiO 2 -Coated Flower-like MoS 2 Nanosheets on Carbon Cloth as Sodium Ion Battery Anode with Enhanced Cycling Stability and Rate Capability
journal, December 2016
- Ren, Weina; Zhou, Weiwei; Zhang, Haifeng
- ACS Applied Materials & Interfaces, Vol. 9, Issue 1
3D Interconnected and Multiwalled Carbon@MoS 2 @Carbon Hollow Nanocables as Outstanding Anodes for Na-Ion Batteries
journal, September 2016
- Wang, Yan; Qu, Qunting; Li, Guangchao
- Small, Vol. 12, Issue 43
Construction of a Hierarchical NiCo 2 S 4 @PPy Core–Shell Heterostructure Nanotube Array on Ni Foam for a High-Performance Asymmetric Supercapacitor
journal, September 2016
- Yan, Minglei; Yao, Yadong; Wen, Jiqiu
- ACS Applied Materials & Interfaces, Vol. 8, Issue 37
Construction of High-Capacitance 3D CoO@Polypyrrole Nanowire Array Electrode for Aqueous Asymmetric Supercapacitor
journal, April 2013
- Zhou, Cheng; Zhang, Yangwei; Li, Yuanyuan
- Nano Letters, Vol. 13, Issue 5
Nanoengineered Polypyrrole-Coated Fe 2 O 3 @C Multifunctional Composites with an Improved Cycle Stability as Lithium-Ion Anodes
journal, October 2012
- Han, Fei; Li, Duo; Li, Wen-Cui
- Advanced Functional Materials, Vol. 23, Issue 13
Controllable Disorder Engineering in Oxygen-Incorporated MoS 2 Ultrathin Nanosheets for Efficient Hydrogen Evolution
journal, November 2013
- Xie, Junfeng; Zhang, Jiajia; Li, Shuang
- Journal of the American Chemical Society, Vol. 135, Issue 47
Fabrication of 3D Hierarchical MoS 2 /Polyaniline and MoS 2 /C Architectures for Lithium-Ion Battery Applications
journal, August 2014
- Hu, Lianren; Ren, Yumei; Yang, Hongxia
- ACS Applied Materials & Interfaces, Vol. 6, Issue 16
N-doped graphene/porous g-C3N4 nanosheets supported layered-MoS2 hybrid as robust anode materials for lithium-ion batteries
journal, September 2014
- Hou, Yang; Li, Jianyang; Wen, Zhenhai
- Nano Energy, Vol. 8
MoS 2 Nanosheets Vertically Grown on Graphene Sheets for Lithium-Ion Battery Anodes
journal, August 2016
- Teng, Yongqiang; Zhao, Hailei; Zhang, Zijia
- ACS Nano, Vol. 10, Issue 9
A Honeycomb-like Co@N–C Composite for Ultrahigh Sulfur Loading Li–S Batteries
journal, September 2017
- Li, Yijuan; Fan, Jingmin; Zhang, Jinhua
- ACS Nano, Vol. 11, Issue 11
Ultrathin MoS 2 /Nitrogen-Doped Graphene Nanosheets with Highly Reversible Lithium Storage
journal, April 2013
- Chang, Kun; Geng, Dongsheng; Li, Xifei
- Advanced Energy Materials, Vol. 3, Issue 7
Metal-Organic-Framework-Derived N-Doped Hierarchically Porous Carbon Polyhedrons Anchored on Crumpled Graphene Balls as Efficient Selenium Hosts for High-Performance Lithium–Selenium Batteries
journal, April 2018
- Park, Seung-Keun; Park, Jin-Sung; Kang, Yun Chan
- ACS Applied Materials & Interfaces, Vol. 10, Issue 19
Hierarchical nanotubes assembled from MoS 2 -carbon monolayer sandwiched superstructure nanosheets for high-performance sodium ion batteries
journal, April 2016
- Shi, Zheng-Tian; Kang, Wenpei; Xu, Jun
- Nano Energy, Vol. 22
Nitrogen-Doped Carbon Embedded MoS 2 Microspheres as Advanced Anodes for Lithium- and Sodium-Ion Batteries
journal, June 2016
- Xie, Dong; Xia, Xinhui; Wang, Yadong
- Chemistry - A European Journal, Vol. 22, Issue 33
Facile Spraying Synthesis and High-Performance Sodium Storage of Mesoporous MoS 2 /C Microspheres
journal, December 2015
- Lu, Yanying; Zhao, Qing; Zhang, Ning
- Advanced Functional Materials, Vol. 26, Issue 6
Chemical vapor deposited MoS2/electrospun carbon nanofiber composite as anode material for high-performance sodium-ion batteries
journal, December 2016
- Chen, Chen; Li, Guoqing; Lu, Yao
- Electrochimica Acta, Vol. 222
MoS2 nanosheets vertically grown on reduced graphene oxide via oxygen bonds with carbon coating as ultrafast sodium ion batteries anodes
journal, August 2017
- Teng, Yongqiang; Zhao, Hailei; Zhang, Zijia
- Carbon, Vol. 119
Hierarchical MoS2@RGO nanosheets for high performance sodium storage
journal, November 2016
- Che, Zongzhou; Li, Yafeng; Chen, Kaixiang
- Journal of Power Sources, Vol. 331
Works referencing / citing this record:
The Advances of Metal Sulfides and In Situ Characterization Methods beyond Li Ion Batteries: Sodium, Potassium, and Aluminum Ion Batteries
journal, November 2019
- Chen, Jingwei; Chua, Daniel H. C.; Lee, Pooi See
- Small Methods, Vol. 4, Issue 1
Construction of hierarchical V 4 C 3 -MXene/MoS 2 /C nanohybrids for high rate lithium-ion batteries
journal, January 2020
- Bai, Jin; Zhao, Bangchuan; Lin, Shuai
- Nanoscale, Vol. 12, Issue 2
Bimetallic phosphosulfide Zn–Ni–P–S nanosheets as binder-free electrodes for aqueous asymmetric supercapacitors with impressive performance
journal, January 2019
- Lei, Xueyan; Ge, Shicheng; Tan, Yihong
- Journal of Materials Chemistry A, Vol. 7, Issue 43
Metal Chalcogenides: Paving the Way for High‐Performance Sodium/Potassium‐Ion Batteries
journal, October 2019
- Tan, Huiteng; Feng, Yuezhan; Rui, Xianhong
- Small Methods, Vol. 4, Issue 1
Layer-by-layer stacked nanohybrids of N,S-co-doped carbon film modified atomic MoS 2 nanosheets for advanced sodium dual-ion batteries
journal, January 2019
- Liu, YangJie; Hu, Xiang; Zhong, Guobao
- Journal of Materials Chemistry A, Vol. 7, Issue 42
Facile Synthesis of Copper Sulfide Nanosheet@Graphene Oxide for the Anode of Potassium‐Ion Batteries
journal, September 2019
- Jia, Xinxin; Zhang, Erjin; Yu, Xinzhi
- Energy Technology, Vol. 8, Issue 1