High-quality mesoporous graphene particles as high-energy and fast-charging anodes for lithium-ion batteries
Abstract
The application of graphene for electrochemical energy storage has received tremendous attention; however, challenges remain in synthesis and other aspects. Here we report the synthesis of high-quality, nitrogen-doped, mesoporous graphene particles through chemical vapor deposition with magnesium-oxide particles as the catalyst and template. Such particles possess excellent structural and electrochemical stability, electronic and ionic conductivity, enabling their use as high-performance anodes with high reversible capacity, outstanding rate performance (e.g., 1,138 mA h g-1 at 0.2 C or 440 mA h g-1 at 60 C with a mass loading of 1 mg cm-2), and excellent cycling stability (e.g., >99% capacity retention for 500 cycles at 2 C with a mass loading of 1 mg cm-2). Interestingly, thick electrodes could be fabricated with high areal capacity and current density (e.g., 6.1 mA h cm-2 at 0.9 mA cm-2), providing an intriguing class of materials for lithium-ion batteries with high energy and power performance.
- Authors:
-
[4];
- Univ. of California, Los Angeles, CA (United States)
- Jilin Univ., Changchun (China)
- General Motors Research and Development Center, Warren, MI (United States)
- Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
- ENN Group, Hebei (China)
- Univ. of Science and Technology Beijing, Beijing (China)
- Publication Date:
- Research Org.:
- Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1518474
- Report Number(s):
- PNNL-SA-143544
Journal ID: ISSN 2041-1723
- Grant/Contract Number:
- AC05-76RL01830
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Nature Communications
- Additional Journal Information:
- Journal Volume: 10; Journal Issue: 1; Journal ID: ISSN 2041-1723
- Publisher:
- Nature Publishing Group
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE
Citation Formats
Mo, Runwei, Li, Fan, Tan, Xinyi, Xu, Pengcheng, Tao, Ran, Shen, Gurong, Lu, Xing, Liu, Fang, Shen, Li, Xu, Bin, Xiao, Qiangfeng, Wang, Xiang, Wang, Chongmin, Li, Jinlai, Wang, Ge, and Lu, Yunfeng. High-quality mesoporous graphene particles as high-energy and fast-charging anodes for lithium-ion batteries. United States: N. p., 2019.
Web. doi:10.1038/s41467-019-09274-y.
Mo, Runwei, Li, Fan, Tan, Xinyi, Xu, Pengcheng, Tao, Ran, Shen, Gurong, Lu, Xing, Liu, Fang, Shen, Li, Xu, Bin, Xiao, Qiangfeng, Wang, Xiang, Wang, Chongmin, Li, Jinlai, Wang, Ge, & Lu, Yunfeng. High-quality mesoporous graphene particles as high-energy and fast-charging anodes for lithium-ion batteries. United States. https://doi.org/10.1038/s41467-019-09274-y
Mo, Runwei, Li, Fan, Tan, Xinyi, Xu, Pengcheng, Tao, Ran, Shen, Gurong, Lu, Xing, Liu, Fang, Shen, Li, Xu, Bin, Xiao, Qiangfeng, Wang, Xiang, Wang, Chongmin, Li, Jinlai, Wang, Ge, and Lu, Yunfeng. Mon .
"High-quality mesoporous graphene particles as high-energy and fast-charging anodes for lithium-ion batteries". United States. https://doi.org/10.1038/s41467-019-09274-y. https://www.osti.gov/servlets/purl/1518474.
@article{osti_1518474,
title = {High-quality mesoporous graphene particles as high-energy and fast-charging anodes for lithium-ion batteries},
author = {Mo, Runwei and Li, Fan and Tan, Xinyi and Xu, Pengcheng and Tao, Ran and Shen, Gurong and Lu, Xing and Liu, Fang and Shen, Li and Xu, Bin and Xiao, Qiangfeng and Wang, Xiang and Wang, Chongmin and Li, Jinlai and Wang, Ge and Lu, Yunfeng},
abstractNote = {The application of graphene for electrochemical energy storage has received tremendous attention; however, challenges remain in synthesis and other aspects. Here we report the synthesis of high-quality, nitrogen-doped, mesoporous graphene particles through chemical vapor deposition with magnesium-oxide particles as the catalyst and template. Such particles possess excellent structural and electrochemical stability, electronic and ionic conductivity, enabling their use as high-performance anodes with high reversible capacity, outstanding rate performance (e.g., 1,138 mA h g-1 at 0.2 C or 440 mA h g-1 at 60 C with a mass loading of 1 mg cm-2), and excellent cycling stability (e.g., >99% capacity retention for 500 cycles at 2 C with a mass loading of 1 mg cm-2). Interestingly, thick electrodes could be fabricated with high areal capacity and current density (e.g., 6.1 mA h cm-2 at 0.9 mA cm-2), providing an intriguing class of materials for lithium-ion batteries with high energy and power performance.},
doi = {10.1038/s41467-019-09274-y},
journal = {Nature Communications},
number = 1,
volume = 10,
place = {United States},
year = {Mon Apr 01 00:00:00 EDT 2019},
month = {Mon Apr 01 00:00:00 EDT 2019}
}
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Fig. 1: A schematic illustrating the synthesis of high-quality, nitrogen-doped, mesoporous graphene (HNMG) particles
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N-Doped Graphene with Low Intrinsic Defect Densities via a Solid Source Doping Technique
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- Chemical Communications, Vol. 55, Issue 70
Multi-functional stretchable sensors based on a 3D-rGO wrinkled microarchitecture
journal, January 2019
- Jia, Jin; Huang, Guotao; Wang, Mingti
- Nanoscale Advances, Vol. 1, Issue 11
Exploring high-performance anodes of Li-ion batteries based on the rules of pore-size dependent band gaps in porous carbon foams
journal, January 2019
- Chen, Shi-Zhang; Deng, Yuan-Xiang; Cao, Xuan-Hao
- Journal of Materials Chemistry A, Vol. 7, Issue 38
Figures / Tables found in this record:
Figures/Tables have been extracted from DOE-funded journal article accepted manuscripts.