Bio-mimetic oxygen separation via a hollow fiber membrane contactor with O2 carrier solutions

Fathizadeh, Mahdi; Khivantsev, Konstantin; Pyrzynski, Travis J.; Klinghoffer, Naomi B.; Shakouri, Abolfazl (Nabi); Yu, Miao; Li, Shiguang

doi:10.1039/c8cc01457d

Title: Bio-mimetic oxygen separation via a hollow fiber membrane contactor with O₂ carrier solutions

Abstract

A low-cost poly(ethyleneimine)–cobalt (PEI–Co) complex solution with high O₂ absorption capacity (as high as 1.5 L O₂ (STP)/L solution) was developed and used in a bio-mimetic system to produce high-purity O₂ from air. Here, an oxygen concentration greater than 99.6% was demonstrated.

Authors:

^[1]; Khivantsev, Konstantin ^[1]; Pyrzynski, Travis J. ^[2]; Klinghoffer, Naomi B. ^[2]; Shakouri, Abolfazl ^[3]; Yu, Miao ^[1];

^[2]

Univ. of South Carolina, Columbia, SC (United States)
Gas Technology Institute (GTI), Des Plaines, IL (United States)
(Nabi) [Univ. of South Carolina, Columbia, SC (United States)

Publication Date:: Thu Aug 02 00:00:00 EDT 2018

Research Org.:: Gas Technology Institute (GTI), Des Plaines, IL (United States)

Sponsoring Org.:: USDOE Office of Fossil Energy (FE)

OSTI Identifier:: 1512038

Grant/Contract Number:: FE0024080

Resource Type:: Accepted Manuscript

Journal Name:: ChemComm

Additional Journal Information:: Journal Volume: 54; Journal Issue: 68; Journal ID: ISSN 1359-7345

Publisher:: Royal Society of Chemistry

Country of Publication:: United States

Language:: English

Subject:: 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats


                    Fathizadeh, Mahdi, Khivantsev, Konstantin, Pyrzynski, Travis J., Klinghoffer, Naomi B., Shakouri, Abolfazl, Yu, Miao, and Li, Shiguang. Bio-mimetic oxygen separation via a hollow fiber membrane contactor with O2 carrier solutions.  United States: N. p., 2018. 
Web.  doi:10.1039/c8cc01457d.

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                    Fathizadeh, Mahdi, Khivantsev, Konstantin, Pyrzynski, Travis J., Klinghoffer, Naomi B., Shakouri, Abolfazl, Yu, Miao, & Li, Shiguang. Bio-mimetic oxygen separation via a hollow fiber membrane contactor with O2 carrier solutions.  United States.  https://doi.org/10.1039/c8cc01457d

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                    Fathizadeh, Mahdi, Khivantsev, Konstantin, Pyrzynski, Travis J., Klinghoffer, Naomi B., Shakouri, Abolfazl, Yu, Miao, and Li, Shiguang. Thu .  
"Bio-mimetic oxygen separation via a hollow fiber membrane contactor with O2 carrier solutions".  United States.  https://doi.org/10.1039/c8cc01457d.  https://www.osti.gov/servlets/purl/1512038.

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@article{osti_1512038,

  title        = {Bio-mimetic oxygen separation via a hollow fiber membrane contactor with O2 carrier solutions},

  author       = {Fathizadeh, Mahdi and Khivantsev, Konstantin and Pyrzynski, Travis J. and Klinghoffer, Naomi B. and Shakouri, Abolfazl and Yu, Miao and Li, Shiguang},

  abstractNote = {A low-cost poly(ethyleneimine)–cobalt (PEI–Co) complex solution with high O2 absorption capacity (as high as 1.5 L O2 (STP)/L solution) was developed and used in a bio-mimetic system to produce high-purity O2 from air. Here, an oxygen concentration greater than 99.6% was demonstrated.},

  doi          = {10.1039/c8cc01457d},

  journal      = {ChemComm},

  number       = 68,

  volume       = 54,

  place        = {United States},

  year         = {Thu Aug 02 00:00:00 EDT 2018},

  month        = {Thu Aug 02 00:00:00 EDT 2018}

}

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Title: Bio-mimetic oxygen separation via a hollow fiber membrane contactor with O2 carrier solutions

Abstract

Citation Formats

Surface dioxygen adducts on MgO-CoO solid solutions: Analogy with cobalt-based homogeneous oxygen carriers journal, March 1982

Selective Binding of O 2 over N 2 in a Redox–Active Metal–Organic Framework with Open Iron(II) Coordination Sites journal, September 2011

Facilitated oxygen transport in liquid membranes: review and new concepts journal, January 2001

Oxygen separation from air using ceramic-based membrane technology for sustainable fuel production and power generation journal, February 2011

A review of air separation technologies and their integration with energy conversion processes journal, May 2001

Exergy analysis of two cryogenic air separation processes journal, December 2010

Complexes of cobalt(II). IV. Electron paramagnetic resonance spectra of some magnetically anomalous complexes of cobalt(II) journal, February 1967

Oxygen Transport through Hemoglobin Solutions journal, February 1960

Synthesis, Characterization, and Applications of Dendrimer-Encapsulated Nanoparticles journal, January 2005

Highly-Selective and Reversible O2 Binding in Cr3(1,3,5-benzenetricarboxylate)2 journal, June 2010

Reactivity of a Cobalt(III)–Hydroperoxo Complex in Electrophilic Reactions journal, November 2016

Complex formation of polyethyleneimine with copper(II), nickel(II), and cobalt(II) ions journal, February 2002

Highly Selective Oxygen Permeation through a Poly(vinylidene dichloride)−Cobalt Porphyrin Membrane: Hopping Transport of Oxygen via the Fixed Cobalt Porphyrin Carrier journal, October 1998

Separation of Oxygen from Air Using Coordination Complexes: A Review journal, April 1994

Catalytic N−H Bond Activation and Breaking by a Well-Defined Co II 1 O 4 Site of a Heterogeneous Catalyst journal, January 2018

The effect of oxygen carriers on gas transport through polysiloxane and ethylcellulose membranes journal, July 1998

Selective, Tunable O 2 Binding in Cobalt(II)–Triazolate/Pyrazolate Metal–Organic Frameworks journal, May 2016

Title: Bio-mimetic oxygen separation via a hollow fiber membrane contactor with O₂ carrier solutions

Surface dioxygen adducts on MgO-CoO solid solutions: Analogy with cobalt-based homogeneous oxygen carriers
journal, March 1982

Selective Binding of O ₂ over N ₂ in a Redox–Active Metal–Organic Framework with Open Iron(II) Coordination Sites
journal, September 2011

Facilitated oxygen transport in liquid membranes: review and new concepts
journal, January 2001

Oxygen separation from air using ceramic-based membrane technology for sustainable fuel production and power generation
journal, February 2011

A review of air separation technologies and their integration with energy conversion processes
journal, May 2001

Exergy analysis of two cryogenic air separation processes
journal, December 2010

Complexes of cobalt(II). IV. Electron paramagnetic resonance spectra of some magnetically anomalous complexes of cobalt(II)
journal, February 1967

Oxygen Transport through Hemoglobin Solutions
journal, February 1960

Synthesis, Characterization, and Applications of Dendrimer-Encapsulated Nanoparticles
journal, January 2005

Highly-Selective and Reversible O₂ Binding in Cr₃(1,3,5-benzenetricarboxylate)₂
journal, June 2010

Reactivity of a Cobalt(III)–Hydroperoxo Complex in Electrophilic Reactions
journal, November 2016

Complex formation of polyethyleneimine with copper(II), nickel(II), and cobalt(II) ions
journal, February 2002

Highly Selective Oxygen Permeation through a Poly(vinylidene dichloride)−Cobalt Porphyrin Membrane: Hopping Transport of Oxygen via the Fixed Cobalt Porphyrin Carrier
journal, October 1998

Separation of Oxygen from Air Using Coordination Complexes: A Review
journal, April 1994

Catalytic N−H Bond Activation and Breaking by a Well-Defined Co ^II ₁ O ₄ Site of a Heterogeneous Catalyst
journal, January 2018

The effect of oxygen carriers on gas transport through polysiloxane and ethylcellulose membranes
journal, July 1998

Selective, Tunable O ₂ Binding in Cobalt(II)–Triazolate/Pyrazolate Metal–Organic Frameworks
journal, May 2016