In Situ Raman Study of Nickel Oxide and Gold-Supported Nickel Oxide Catalysts for the Electrochemical Evolution of Oxygen
Abstract
An in situ Raman spectroscopic investigation has been carried out to identify the composition of the active phase present on the surface of nickel electrodes used for the electrochemical evolution of oxygen. The electrolyte in all cases was 0.1 M KOH. A freshly polished Ni electrode oxidized upon immersion in the electrolyte and at potentials approaching the evolution of oxygen developed a layer of γ-NiOOH. Electrochemical cycling of this film transformed it into β-NiOOH, which was observed to be three times more active than γ-NiOOH. The higher activity of β-NiOOH is attributed to an unidentified Ni oxide formed at a potential above 0.52 V (vs Hg/HgO reference). We have also observed that a submonolayer of Ni oxide deposited on Au exhibits a turnover frequency (TOF) for oxygen evolution that is an order of magnitude higher than that for a freshly prepared γ-NiOOH surface and more than 2-fold higher than that for a β-NiOOH surface. By contrast, a similar film deposited on Pd exhibits a TOF that is similar to that of bulk γ-NiOOH. Furthermore it is proposed that the high activity of submonolayer deposits of Ni oxide on Au is due to charge transfer from the oxide to the highlymore »
- Authors:
-
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Univ. of California, Berkeley, CA (United States)
- Publication Date:
- Research Org.:
- Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences, and Biosciences Division
- OSTI Identifier:
- 1511336
- Grant/Contract Number:
- AC02-05CH11231
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of Physical Chemistry. C
- Additional Journal Information:
- Journal Volume: 116; Journal Issue: 15; Journal ID: ISSN 1932-7447
- Publisher:
- American Chemical Society
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Yeo, Boon Siang, and Bell, Alexis T. In Situ Raman Study of Nickel Oxide and Gold-Supported Nickel Oxide Catalysts for the Electrochemical Evolution of Oxygen. United States: N. p., 2012.
Web. doi:10.1021/jp3007415.
Yeo, Boon Siang, & Bell, Alexis T. In Situ Raman Study of Nickel Oxide and Gold-Supported Nickel Oxide Catalysts for the Electrochemical Evolution of Oxygen. United States. https://doi.org/10.1021/jp3007415
Yeo, Boon Siang, and Bell, Alexis T. Wed .
"In Situ Raman Study of Nickel Oxide and Gold-Supported Nickel Oxide Catalysts for the Electrochemical Evolution of Oxygen". United States. https://doi.org/10.1021/jp3007415. https://www.osti.gov/servlets/purl/1511336.
@article{osti_1511336,
title = {In Situ Raman Study of Nickel Oxide and Gold-Supported Nickel Oxide Catalysts for the Electrochemical Evolution of Oxygen},
author = {Yeo, Boon Siang and Bell, Alexis T.},
abstractNote = {An in situ Raman spectroscopic investigation has been carried out to identify the composition of the active phase present on the surface of nickel electrodes used for the electrochemical evolution of oxygen. The electrolyte in all cases was 0.1 M KOH. A freshly polished Ni electrode oxidized upon immersion in the electrolyte and at potentials approaching the evolution of oxygen developed a layer of γ-NiOOH. Electrochemical cycling of this film transformed it into β-NiOOH, which was observed to be three times more active than γ-NiOOH. The higher activity of β-NiOOH is attributed to an unidentified Ni oxide formed at a potential above 0.52 V (vs Hg/HgO reference). We have also observed that a submonolayer of Ni oxide deposited on Au exhibits a turnover frequency (TOF) for oxygen evolution that is an order of magnitude higher than that for a freshly prepared γ-NiOOH surface and more than 2-fold higher than that for a β-NiOOH surface. By contrast, a similar film deposited on Pd exhibits a TOF that is similar to that of bulk γ-NiOOH. Furthermore it is proposed that the high activity of submonolayer deposits of Ni oxide on Au is due to charge transfer from the oxide to the highly electronegative Au, leading to the possible formation of a mixed Ni/Au surface oxide.},
doi = {10.1021/jp3007415},
journal = {Journal of Physical Chemistry. C},
number = 15,
volume = 116,
place = {United States},
year = {Wed Apr 11 00:00:00 EDT 2012},
month = {Wed Apr 11 00:00:00 EDT 2012}
}
Free Publicly Available Full Text
Publisher's Version of Record
Other availability
Search WorldCat to find libraries that may hold this journal
Cited by: 539 works
Citation information provided by
Web of Science
Web of Science
Figures / Tables:
Figure 1: (a) Cyclic voltammograms and (b) linear sweep voltammograms of Ni $α$/$γ$ (red trace) and Ni $β$/$β$ (black trace) electrodes. In situ Raman spectra collected during linear sweep voltammetry from (c) Ni $α$/$γ$ and (d) Ni $β$/$β$ electrodes. The 735 cm−1 peak in panel c originates from the Teflonmore »
All figures and tables
(5 total)
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Renewable hydrogen production
journal, January 2008
- Turner, John; Sverdrup, George; Mann, Margaret K.
- International Journal of Energy Research, Vol. 32, Issue 5
Electrocatalysis in the anodic evolution of oxygen and chlorine
journal, November 1984
- Trasatti, S.
- Electrochimica Acta, Vol. 29, Issue 11, p. 1503-1512
Ni ( OH ) 2 ‐ Impregnated Anodes for Alkaline Water Electrolysis
journal, February 1983
- Hall, D. E.
- Journal of The Electrochemical Society, Vol. 130, Issue 2
Electrochemical-Ellipsometric Studies of Oxide Film Formed on Nickel during Oxygen Evolution
journal, January 1978
- Lu, P. W. T.
- Journal of The Electrochemical Society, Vol. 125, Issue 9
Oxygen evolution at nickel anodes in concentrated alkaline solution
journal, August 1994
- Cappadonia, Marcella; Divisek, Jiri; von der Heyden, Thomas
- Electrochimica Acta, Vol. 39, Issue 11-12
Revised Pourbaix diagrams for nickel at 25–300 °C
journal, May 1997
- Beverskog, B.; Puigdomenech, I.
- Corrosion Science, Vol. 39, Issue 5
Zur kenntnis der nickelhydroxidelektrode—I.Über das nickel (II)-hydroxidhydrat
journal, August 1966
- Bode, H.; Dehmelt, K.; Witte, J.
- Electrochimica Acta, Vol. 11, Issue 8
Nickel surface anodic oxidation and electrocatalysis of oxygen evolution
journal, January 2008
- Juodkazis, K.; Juodkazytė, J.; Vilkauskaitė, R.
- Journal of Solid State Electrochemistry, Vol. 12, Issue 11
Review of the structure and the electrochemistry of nickel hydroxides and oxy-hydroxides
journal, January 1982
- Oliva, P.; Leonardi, J.; Laurent, J. F.
- Journal of Power Sources, Vol. 8, Issue 2
Characterization of Redox States of Nickel Hydroxide Film Electrodes by In Situ Surface Raman Spectroscopy
journal, January 1988
- Desilvestro, Johann
- Journal of The Electrochemical Society, Vol. 135, Issue 4
In situ X-ray absorption fine structure and optical reflectance studies of electrodeposited nickel hydrous oxide films in alkaline electrolytes
journal, November 1997
- Hu, Yining; Bae, In Tae; Mo, Yibo
- Canadian Journal of Chemistry, Vol. 75, Issue 11
X-ray photoelectron spectroscopic chemical state quantification of mixed nickel metal, oxide and hydroxide systems
journal, April 2009
- Biesinger, Mark C.; Payne, Brad P.; Lau, Leo W. M.
- Surface and Interface Analysis, Vol. 41, Issue 4
Enhanced Activity of Gold-Supported Cobalt Oxide for the Electrochemical Evolution of Oxygen
journal, April 2011
- Yeo, Boon Siang; Bell, Alexis T.
- Journal of the American Chemical Society, Vol. 133, Issue 14
A comparative study of the oxygen evolution reaction on oxidised nickel, cobalt and iron electrodes in base
journal, March 2010
- Lyons, Michael E. G.; Brandon, Michael P.
- Journal of Electroanalytical Chemistry, Vol. 641, Issue 1-2
Mechanism of Water Oxidation by Single-Site Ruthenium Complex Catalysts
journal, February 2010
- Concepcion, Javier J.; Tsai, Ming-Kang; Muckerman, James T.
- Journal of the American Chemical Society, Vol. 132, Issue 5, p. 1545-1557
Structural and textural investigations of the nickel hydroxide electrode
journal, April 1996
- Delahaye-Vidal, A.
- Solid State Ionics, Vol. 84, Issue 3-4
Spectroelectrochemistry of thin nickel hydroxide films on gold using surface-enhanced Raman spectroscopy
journal, November 1986
- Desilvestro, Johann; Corrigan, Dennis A.; Weaver, Michael J.
- The Journal of Physical Chemistry, Vol. 90, Issue 24
Electrochemical and In Situ Raman Spectroscopic Characterization of Nickel Hydroxide Electrodes
journal, January 1997
- Kostecki, Robert
- Journal of The Electrochemical Society, Vol. 144, Issue 2
Oxygen evolution reaction on thick hydrous nickel oxide electrodes
journal, June 1988
- Gennero de Chialvo, M. R.; Chialvo, A. C.
- Electrochimica Acta, Vol. 33, Issue 6
Structural comparison of nickel electrodes and precursor phases
journal, February 1990
- Cornilsen, Bahne C.; Shan, Xiaoyin; Loyselle, Patricia L.
- Journal of Power Sources, Vol. 29, Issue 3-4
In situ uv visible reflectance spectroscopic investigation of the nickel electrode-alkaline solution interface
journal, March 1986
- Hahn, F.; Beden, B.; Croissant, M. J.
- Electrochimica Acta, Vol. 31, Issue 3
In Situ Raman Studies on Cathodically Deposited Nickel Hydroxide Films and Electroless Ni−P Electrodes in 1 M KOH Solution
journal, February 1998
- Lo, Yi Ling; Hwang, Bing Joe
- Langmuir, Vol. 14, Issue 4
In Situ Spectroelectrochemical Studies on the Anodic Oxidation of Nickel Hydroxide in Alkaline Media
journal, November 1989
- Zhang, Chaojiong; Park, Su‐Moon
- Journal of The Electrochemical Society, Vol. 136, Issue 11
Surface structural changes during oxidation of gold electrodes in aqueous media as detected using surface-enhanced Raman spectroscopy
journal, September 1986
- Desilvestro, Johann; Weaver, Michael J.
- Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 209, Issue 2
Photoelectron spectroscopy study of surface alloying in the Au/Ni (s) 5(0 0 1) × (1 1 1) system
journal, March 2001
- Zafeiratos, S.; Kennou, S.
- Applied Surface Science, Vol. 173, Issue 1-2
Structural models for nickel electrode active mass
journal, March 1988
- Cornilsen, B. C.; Karjala, P. J.; Loyselle, P. L.
- Journal of Power Sources, Vol. 22, Issue 3-4
Structural and morphological characterization of gold–nickel electrocatalyst synthesized by taking advantage of the AuNi phase separation mechanism
journal, March 2010
- Yang, Tao; Zhang, Lijuan; Li, Xiang
- Journal of Alloys and Compounds, Vol. 492, Issue 1-2
Voltammetric and XPS investigations of nickel hydroxide electrochemically dispersed on gold surface electrodes
journal, February 1999
- Casella, Innocenzo G.; Guascito, Maria R.; Sannazzaro, Maria G.
- Journal of Electroanalytical Chemistry, Vol. 462, Issue 2
Electronegativity and electron binding in gold alloys
journal, October 1976
- Chou, T. S.; Perlman, M. L.; Watson, R. E.
- Physical Review B, Vol. 14, Issue 8
Effects of Ligand Composition on the Oxidative Carbonylation of Toluene to Toluic Acid Catalyzed by Rh(III) Complexes
journal, July 2009
- Zakzeski, Joseph; Behn, Andrew; Head-Gordon, Martin
- Journal of the American Chemical Society, Vol. 131, Issue 31
Electronegativity scale for metals
journal, April 1979
- Alonso, J. A.; Girifalco, L. A.
- Physical Review B, Vol. 19, Issue 8
Origin of ohmic losses at Co3O4/Ti electrodes
journal, March 1994
- Baronetto, D.; Kodintsev, I. M.; Trasatti, S.
- Journal of Applied Electrochemistry, Vol. 24, Issue 3
Characterization of sputtered NiO thin films
journal, August 2005
- Chen, Hao-Long; Lu, Yang-Ming; Hwang, Weng-Sing
- Surface and Coatings Technology, Vol. 198, Issue 1-3
Works referencing / citing this record:
NiFe Layered Double Hydroxide Nanoparticles on Co,N-Codoped Carbon Nanoframes as Efficient Bifunctional Catalysts for Rechargeable Zinc-Air Batteries
journal, July 2017
- Wang, Qing; Shang, Lu; Shi, Run
- Advanced Energy Materials, Vol. 7, Issue 21
NiFe Oxalate Nanomesh Array with Homogenous Doping of Fe for Electrocatalytic Water Oxidation
journal, October 2019
- Gao, Xueqing; Chen, Dandan; Qi, Jing
- Small, Vol. 15, Issue 46
Facile synthesis of sponge-like Ni 3 N/NC for electrocatalytic water oxidation
journal, January 2017
- Chen, Mingxing; Qi, Jing; Guo, Dingyi
- Chemical Communications, Vol. 53, Issue 69
Hierarchically Structured 3D Integrated Electrodes by Galvanic Replacement Reaction for Highly Efficient Water Splitting
journal, March 2017
- Wang, Jianying; Ji, Lvlv; Zuo, Shangshang
- Advanced Energy Materials, Vol. 7, Issue 14
Ni(OH)2 nanoflakes supported on 3D hierarchically nanoporous gold/Ni foam as superior electrodes for supercapacitors
journal, December 2017
- Ke, Xi; Zhang, Zouxin; Cheng, Yifeng
- Science China Materials, Vol. 61, Issue 3
Nickel oxide–polypyrrole nanocomposite electrode materials for electrocatalytic water oxidation
journal, January 2018
- Morales, Daniela V.; Astudillo, Catalina N.; Lattach, Youssef
- Catalysis Science & Technology, Vol. 8, Issue 16
Creating Highly Active Atomic Layer Deposited NiO Electrocatalysts for the Oxygen Evolution Reaction
journal, June 2015
- Nardi, Katie L.; Yang, Nuoya; Dickens, Colin F.
- Advanced Energy Materials, Vol. 5, Issue 17
Prussian blue analogue-derived Ni and Co bimetallic oxide nanoplate arrays block-built from porous and hollow nanocubes for the efficient oxygen evolution reaction
journal, January 2019
- Shen, Yan; Guo, Shu-Guang; Du, Feng
- Nanoscale, Vol. 11, Issue 24
Electrocatalytic Oxygen Evolution Reaction in Acidic Environments - Reaction Mechanisms and Catalysts
journal, October 2016
- Reier, Tobias; Nong, Hong Nhan; Teschner, Detre
- Advanced Energy Materials, Vol. 7, Issue 1
Water Oxidation at Electrodes Modified with Earth-Abundant Transition-Metal Catalysts
journal, October 2014
- Galán-Mascarós, José Ramón
- ChemElectroChem, Vol. 2, Issue 1
Direct storage of holes in ultrathin Ni(OH) 2 on Fe 2 O 3 photoelectrodes for integrated solar charging battery-type supercapacitors
journal, January 2018
- Zhu, Kaijian; Zhu, Guoxiang; Wang, Jun
- Journal of Materials Chemistry A, Vol. 6, Issue 43
Laser processed Ni-Fe alloys as electrocatalyst toward oxygen evolution reaction
journal, June 2018
- Cui, Xiaodan; Zhang, Boliang; Zeng, Congyuan
- Materials Research Express, Vol. 5, Issue 6
Transition-Metal (Co, Ni, and Fe)-Based Electrocatalysts for the Water Oxidation Reaction
journal, August 2016
- Han, Lei; Dong, Shaojun; Wang, Erkang
- Advanced Materials, Vol. 28, Issue 42
NiFe-Based (Oxy)hydroxide Catalysts for Oxygen Evolution Reaction in Non-Acidic Electrolytes
journal, July 2016
- Dionigi, Fabio; Strasser, Peter
- Advanced Energy Materials, Vol. 6, Issue 23
Reliable electrochemical phase diagrams of magnetic transition metals and related compounds from high-throughput ab initio calculations
journal, June 2019
- Huang, Liang-Feng; Rondinelli, James M.
- npj Materials Degradation, Vol. 3, Issue 1
Oxygen Evolution Reaction on Ni‐based Two‐dimensional (2D) Titanate Nanosheets: Investigation on Effect of Fe Co‐doping and Fe Incorporation from Electrolyte on the Activity
journal, May 2018
- Ramesh, Rahul; Lee, Seonggyu; Kim, Seongbeen
- ChemistrySelect, Vol. 3, Issue 18
Understanding the Role of Gold Nanoparticles in Enhancing the Catalytic Activity of Manganese Oxides in Water Oxidation Reactions
journal, October 2014
- Kuo, Chung-Hao; Li, Weikun; Pahalagedara, Lakshitha
- Angewandte Chemie, Vol. 127, Issue 8
Electrochemical Water Splitting by Pseudo-spinel, Disordered and Layered Lithium Nickel Oxides: Correlation between Structural Motifs and Catalytic Properties
journal, May 2018
- Wu, Jian; Wang, Guofu; Du, Juan
- ChemCatChem, Vol. 10, Issue 12
Value added transformation of ubiquitous substrates into highly efficient and flexible electrodes for water splitting
journal, May 2018
- Sahasrabudhe, Atharva; Dixit, Harsha; Majee, Rahul
- Nature Communications, Vol. 9, Issue 1
Investigation of mixed-metal (oxy)fluorides as a new class of water oxidation electrocatalysts
journal, January 2019
- Lemoine, Kévin; Lhoste, Jérôme; Hémon-Ribaud, Annie
- Chemical Science, Vol. 10, Issue 40
An advanced and efficient Co 3 O 4 /C nanocomposite for the oxygen evolution reaction in alkaline media
journal, January 2019
- Mugheri, Abdul Qayoom; Tahira, Aneela; Aftab, Umair
- RSC Advances, Vol. 9, Issue 59
Direct observation of active catalyst surface phases and the effect of dynamic self-optimization in NiFe-layered double hydroxides for alkaline water splitting
journal, January 2019
- Qiu, Zhen; Tai, Cheuk-Wai; Niklasson, Gunnar A.
- Energy & Environmental Science, Vol. 12, Issue 2
Towards Versatile and Sustainable Hydrogen Production through Electrocatalytic Water Splitting: Electrolyte Engineering
journal, March 2017
- Shinagawa, Tatsuya; Takanabe, Kazuhiro
- ChemSusChem, Vol. 10, Issue 7
Gold-supported cerium-doped NiOx catalysts for water oxidation
journal, April 2016
- Ng, Jia Wei Desmond; García-Melchor, Max; Bajdich, Michal
- Nature Energy, Vol. 1, Issue 5
Atomic-level insight into super-efficient electrocatalytic oxygen evolution on iron and vanadium co-doped nickel (oxy)hydroxide
journal, July 2018
- Jiang, Jian; Sun, Fanfei; Zhou, Si
- Nature Communications, Vol. 9, Issue 1
Recent Progress on Multimetal Oxide Catalysts for the Oxygen Evolution Reaction
journal, January 2018
- Kim, Ju Seong; Kim, Byunghoon; Kim, Hyunah
- Advanced Energy Materials, Vol. 8, Issue 11
Synergistic Effect between Metal-Nitrogen-Carbon Sheets and NiO Nanoparticles for Enhanced Electrochemical Water-Oxidation Performance
journal, July 2015
- Wang, Jun; Li, Kai; Zhong, Hai-xia
- Angewandte Chemie, Vol. 127, Issue 36
Synergistic Effect between Metal-Nitrogen-Carbon Sheets and NiO Nanoparticles for Enhanced Electrochemical Water-Oxidation Performance
journal, July 2015
- Wang, Jun; Li, Kai; Zhong, Hai-xia
- Angewandte Chemie International Edition, Vol. 54, Issue 36
Metal organic frameworks for electrochemical applications
journal, January 2012
- Morozan, Adina; Jaouen, Frédéric
- Energy & Environmental Science, Vol. 5, Issue 11
Effects of Metal Electrode Support on the Catalytic Activity of Fe(oxy)hydroxide for the Oxygen Evolution Reaction in Alkaline Media
journal, August 2019
- Enman, Lisa J.; Vise, Ashlee E.; Burke Stevens, Michaela
- ChemPhysChem, Vol. 20, Issue 22
Identification of Key Reversible Intermediates in Self‐Reconstructed Nickel‐Based Hybrid Electrocatalysts for Oxygen Evolution
journal, November 2019
- Huang, Jianwen; Li, Yaoyao; Zhang, Yadong
- Angewandte Chemie International Edition, Vol. 58, Issue 48
A nanostructured nickel/carbon matrix as an efficient oxygen evolution reaction electrocatalyst for rechargeable zinc–air batteries
journal, January 2019
- Cui, Chengqiang; Ge, Xiaoming; An, Tao
- Inorganic Chemistry Frontiers, Vol. 6, Issue 7
Photoelectrochemical water splitting at low applied potential using a NiOOH coated codoped (Sn, Zr) α-Fe 2 O 3 photoanode
journal, January 2015
- Tamirat, Andebet Gedamu; Su, Wei-Nien; Dubale, Amare Aregahegn
- Journal of Materials Chemistry A, Vol. 3, Issue 11
Amorphous NiO electrocatalyst overcoated ZnO nanorod photoanodes for enhanced photoelectrochemical performance
journal, January 2016
- Mao, Yanchao; Cheng, Yongguang; Wang, Junqiao
- New Journal of Chemistry, Vol. 40, Issue 1
Ultrasmall Dispersible Crystalline Nickel Oxide Nanoparticles as High-Performance Catalysts for Electrochemical Water Splitting
journal, March 2014
- Fominykh, Ksenia; Feckl, Johann M.; Sicklinger, Johannes
- Advanced Functional Materials, Vol. 24, Issue 21
Enhancement of Oxygen Evolution Activity of Nickel Oxyhydroxide by Electrolyte Alkali Cations
journal, July 2019
- Garcia, Amanda C.; Touzalin, Thomas; Nieuwland, Celine
- Angewandte Chemie, Vol. 131, Issue 37
Accelerated Durability Test for High‐Surface‐Area Oxyhydroxide Nickel Supported on Raney Nickel as Catalyst for the Alkaline Oxygen Evolution Reaction
journal, June 2019
- Delgado, Dario; Bizzotto, Francesco; Zana, Alessandro
- ChemPhysChem, Vol. 20, Issue 22
Identification of Key Reversible Intermediates in Self‐Reconstructed Nickel‐Based Hybrid Electrocatalysts for Oxygen Evolution
journal, November 2019
- Huang, Jianwen; Li, Yaoyao; Zhang, Yadong
- Angewandte Chemie, Vol. 131, Issue 48
Single-crystalline Ni(OH) 2 nanosheets vertically aligned on a three-dimensional nanoporous metal for high-performance asymmetric supercapacitors
journal, January 2015
- Hou, Chao; Lang, Xing-You; Wen, Zi
- Journal of Materials Chemistry A, Vol. 3, Issue 46
Active Site Identification and Evaluation Criteria of In Situ Grown CoTe and NiTe Nanoarrays for Hydrogen Evolution and Oxygen Evolution Reactions
journal, January 2019
- Yang, Liu; Xu, Haoxiang; Liu, Huibing
- Small Methods, Vol. 3, Issue 5
Intensification of anodic charge transfer by contaminant degradation for efficient H 2 production
journal, January 2018
- Zhang, Kai; Zhang, Gong; Qu, Jiuhui
- Journal of Materials Chemistry A, Vol. 6, Issue 22
A Comparative Study on Gold and Platinum Dissolution in Acidic and Alkaline Media
journal, January 2014
- Cherevko, Serhiy; Zeradjanin, Aleksandar R.; Keeley, Gareth P.
- Journal of The Electrochemical Society, Vol. 161, Issue 12
Facile efficient earth abundant NiO/C composite electrocatalyst for the oxygen evolution reaction
journal, January 2019
- Mugheri, Abdul Qayoom; Tahira, Aneela; Aftab, Umair
- RSC Advances, Vol. 9, Issue 10
Magnetic bipolar transistor based on ZnO/NiO/Si heterostructure using pulsed laser deposition
journal, January 2020
- Kaur, Harsimrat; Sharma, Monika; Ghosh, RamKrishna
- AIP Advances, Vol. 10, Issue 1
An Efficient Three-Dimensional Oxygen Evolution Electrode
journal, April 2013
- Wang, Jun; Zhong, Hai-xia; Qin, Yu-ling
- Angewandte Chemie International Edition, Vol. 52, Issue 20
Enhancement of Oxygen Evolution Activity of Nickel Oxyhydroxide by Electrolyte Alkali Cations
journal, July 2019
- Garcia, Amanda C.; Touzalin, Thomas; Nieuwland, Celine
- Angewandte Chemie International Edition, Vol. 58, Issue 37
Roles of soluble species in the alkaline oxygen evolution reaction on a nickel anode
journal, January 2018
- Ye, Jia-Ming; He, Ding-Hong; Li, Fang
- Chemical Communications, Vol. 54, Issue 72
Engineering of ZnCo-layered double hydroxide nanowalls toward high-efficiency electrochemical water oxidation
journal, January 2014
- Li, Ying; Zhang, Lu; Xiang, Xu
- Journal of Materials Chemistry A, Vol. 2, Issue 33
Glycerol Electro-Oxidation in Alkaline Media and Alkaline Direct Glycerol Fuel Cells
journal, November 2019
- Antolini, Ermete
- Catalysts, Vol. 9, Issue 12
Ternary NiCoP nanosheet arrays: An excellent bifunctional catalyst for alkaline overall water splitting
journal, June 2016
- Li, Yingjie; Zhang, Haichuan; Jiang, Ming
- Nano Research, Vol. 9, Issue 8
Paired Electrocatalytic Oxygenation and Hydrogenation of Organic Substrates with Water as the Oxygen and Hydrogen Source
journal, May 2019
- Zhang, Peili; Sheng, Xia; Chen, Xiaoyu
- Angewandte Chemie, Vol. 131, Issue 27
Nickel Cysteine Complexes as Anodic Electrocatalysts for Fuel Cells
journal, January 2014
- Chen, Dayi; Giroud, Fabien; Minteer, Shelley D.
- Journal of The Electrochemical Society, Vol. 161, Issue 9
In situ autologous growth of self-supporting NiFe-based nanosheets on nickel foam as an efficient electrocatalyst for the oxygen evolution reaction
journal, January 2019
- Wang, Jianying; Teng, Xue; Niu, Yanli
- RSC Advances, Vol. 9, Issue 38
Enhancing Activity for the Oxygen Evolution Reaction: The Beneficial Interaction of Gold with Manganese and Cobalt Oxides
journal, November 2014
- Frydendal, Rasmus; Busch, Michael; Halck, Niels B.
- ChemCatChem, Vol. 7, Issue 1
Redox and electrochemical water splitting catalytic properties of hydrated metal oxide modified electrodes
journal, January 2013
- Doyle, Richard L.; Godwin, Ian J.; Brandon, Michael P.
- Physical Chemistry Chemical Physics, Vol. 15, Issue 33
In Situ Raman Study of Amorphous and Crystalline Ni-Co Alloys for the Alkaline Oxygen Evolution Reaction
journal, January 2018
- Cole, K. M.; Kirk, D. W.; Thorpe, S. J.
- Journal of The Electrochemical Society, Vol. 165, Issue 15
Efficient Water Splitting Using a Simple Ni/N/C Paper Electrocatalyst
journal, December 2014
- Ren, Jiawen; Antonietti, Markus; Fellinger, Tim-Patrick
- Advanced Energy Materials, Vol. 5, Issue 6
Expansion of the urea electrocatalytic oxidation window by adsorbed nickel ions
journal, July 2019
- Baker, David R.; Lundgren, Cynthia A.
- Journal of Applied Electrochemistry, Vol. 49, Issue 9
Surface Oxidation of AuNi Heterodimers to Achieve High Activities toward Hydrogen/Oxygen Evolution and Oxygen Reduction Reactions
journal, February 2018
- Ni, Bing; He, Peng; Liao, Wenxin
- Small, Vol. 14, Issue 14
Anodic deposition of NiOx water oxidation catalysts from macrocyclic nickel(ii) complexes
journal, January 2013
- Singh, Archana; Chang, Shery L. Y.; Hocking, Rosalie K.
- Catalysis Science & Technology, Vol. 3, Issue 7
Dendritic core-shell nickel-iron-copper metal/metal oxide electrode for efficient electrocatalytic water oxidation
journal, January 2018
- Zhang, Peili; Li, Lin; Nordlund, Dennis
- Nature Communications, Vol. 9, Issue 1
An Efficient Three-Dimensional Oxygen Evolution Electrode
journal, April 2013
- Wang, Jun; Zhong, Hai-xia; Qin, Yu-ling
- Angewandte Chemie, Vol. 125, Issue 20
Understanding the Role of Gold Nanoparticles in Enhancing the Catalytic Activity of Manganese Oxides in Water Oxidation Reactions
journal, October 2014
- Kuo, Chung-Hao; Li, Weikun; Pahalagedara, Lakshitha
- Angewandte Chemie International Edition, Vol. 54, Issue 8
Accelerated Durability Test for High‐Surface‐Area Oxyhydroxide Nickel Supported on Raney Nickel as Catalyst for the Alkaline Oxygen Evolution Reaction
text, January 2019
- Delgado, Dario; Bizzotto, Francesco; Zana, Alessandro
- Wiley-VCH
Paired Electrocatalytic Oxygenation and Hydrogenation of Organic Substrates with Water as the Oxygen and Hydrogen Source
journal, May 2019
- Zhang, Peili; Sheng, Xia; Chen, Xiaoyu
- Angewandte Chemie International Edition, Vol. 58, Issue 27
Figures / Tables found in this record:
Figures/Tables have been extracted from DOE-funded journal article accepted manuscripts.