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Title: Rate mechanism of vanadium oxide coated tin dioxide nanowire electrode for lithium ion battery

Abstract

Correlating composition and structures with battery performance is key aspect of electrode material design and improvement. Here utilizing in situ open cell transmission electron microscopy, we studied the in situ cycling rate performance of vanadium oxide coated tin dioxide nanowire electrode by tuning the lithiation/delithiation current. In situ results show that the good rate performance of such high capacity compositional material lies in the layered vanadium oxide coating strategy. For cycling at high rate, the layered vanadium oxide also serves as fast ions and electrons transportation route while tin nanoparticles aggregate to the surface with sizes controlled by the coating layer, cycle induced volume change is released to the surface and excellent mechanical tolerance of tin nanoparticle and inner nanowire ensure improved cyclability of the electrode.

Authors:
 [1];  [2];  [3];  [3];  [4];  [3]
+ Show Author Affiliations
  1. Chinese Academy of Sciences (CAS), Beijing (China). Beijing National Lab. for Condensed Matter Physics and Inst. of Physics; Argonne National Lab. (ANL), Argonne, IL (United States). Center for Nanoscale Materials, Nanoscience and Technology Division
  2. Hefei Univ. of Technology (China). School of Materials Science and Engineering
  3. Chinese Academy of Sciences (CAS), Beijing (China). Beijing National Lab. for Condensed Matter Physics and Inst. of Physics
  4. Argonne National Lab. (ANL), Argonne, IL (United States). Center for Nanoscale Materials, Nanoscience and Technology Division
Publication Date:
Research Org.:
Argonne National Laboratory (ANL), Argonne, IL (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES); Chinese Academy of Sciences (CAS); National Natural Science Foundation of China (NSFC)
OSTI Identifier:
1509821
Alternate Identifier(s):
OSTI ID: 1549527
Grant/Contract Number:  
AC02-06CH11357
Resource Type:
Accepted Manuscript
Journal Name:
Nano Energy
Additional Journal Information:
Journal Volume: 42; Journal Issue: C; Journal ID: ISSN 2211-2855
Publisher:
Elsevier
Country of Publication:
United States
Language:
English
Subject:
25 ENERGY STORAGE; Composite structures; In Situ TEM; Lithium ion batteries; V2O5 coated SnO2 nanowire

Citation Formats

Wang, Lifen, Yan, Jian, Xu, Zhi, Wang, Wenlong, Wen, Jianguo, and Bai, Xuedong. Rate mechanism of vanadium oxide coated tin dioxide nanowire electrode for lithium ion battery. United States: N. p., 2017. Web. doi:10.1016/j.nanoen.2017.10.059.
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Wang, Lifen, Yan, Jian, Xu, Zhi, Wang, Wenlong, Wen, Jianguo, & Bai, Xuedong. Rate mechanism of vanadium oxide coated tin dioxide nanowire electrode for lithium ion battery. United States. https://doi.org/10.1016/j.nanoen.2017.10.059
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Wang, Lifen, Yan, Jian, Xu, Zhi, Wang, Wenlong, Wen, Jianguo, and Bai, Xuedong. Fri . "Rate mechanism of vanadium oxide coated tin dioxide nanowire electrode for lithium ion battery". United States. https://doi.org/10.1016/j.nanoen.2017.10.059. https://www.osti.gov/servlets/purl/1509821.
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@article{osti_1509821,
title = {Rate mechanism of vanadium oxide coated tin dioxide nanowire electrode for lithium ion battery},
author = {Wang, Lifen and Yan, Jian and Xu, Zhi and Wang, Wenlong and Wen, Jianguo and Bai, Xuedong},
abstractNote = {Correlating composition and structures with battery performance is key aspect of electrode material design and improvement. Here utilizing in situ open cell transmission electron microscopy, we studied the in situ cycling rate performance of vanadium oxide coated tin dioxide nanowire electrode by tuning the lithiation/delithiation current. In situ results show that the good rate performance of such high capacity compositional material lies in the layered vanadium oxide coating strategy. For cycling at high rate, the layered vanadium oxide also serves as fast ions and electrons transportation route while tin nanoparticles aggregate to the surface with sizes controlled by the coating layer, cycle induced volume change is released to the surface and excellent mechanical tolerance of tin nanoparticle and inner nanowire ensure improved cyclability of the electrode.},
doi = {10.1016/j.nanoen.2017.10.059},
journal = {Nano Energy},
number = C,
volume = 42,
place = {United States},
year = {Fri Nov 03 00:00:00 EDT 2017},
month = {Fri Nov 03 00:00:00 EDT 2017}
}
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Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
https://doi.org/10.1016/j.nanoen.2017.10.059
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Citation Metrics:
Cited by: 15 works
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Figures / Tables:

Fig. 1 Fig. 1: Comparison of nanowires during the first lithiation process with and without V2O5 coated on the surface. a, Pristine SnO2 nanowire in an open cell before lithiation started. Lithium foil adhered to a tungsten wire serving as counter electrode, the thin oxide layer covered on the foil formed whenmore » transferring from glove box to TEM column serves as electrolyte, and SnO2 nanowire attached to a gold wire serves as the working electrode. e, f Selected area diffraction pattern (SADP) and corresponding high resolution TEM (HRTEM) image of the pristine nanowire marked by red tangle in a showing single crystalline feature. b, c, Time sequenced TEM images of SnO2 nanowire during the first lithiation process when a constant current of −100 PA applied to the nanowire with respect to lithium. Lithiation front started from the near lithium end with enormous morphology changes of swelling and tangle introduced by lithiation. d, Thermal runaway cause breakdown of the first lithiation process. g, h SADP and corresponding HRTEM image of the area marked by dashed circle in d show lithiated phase of Li13Sn5 embedded in Li2O matrix. i Pristine V2O5 loaded SnO2 nanowire in an open cell. m, n SADP and corresponding HRTEM image of the area marked by red tangle in i show crystalline V2O5 covering single crystal SnO2 nanowire on the surface. j-l Time sequenced TEM image of the first lithiation process show elongation of the nanowire confined in the longitude direction. o, p SADP and corresponding HRTEM image of the nanowire marked by dashed red circle in l after the first lithiation process.« less
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    Works referencing / citing this record:

    Fluffy carbon-coated red phosphorus as a highly stable and high-rate anode for lithium-ion batteries
    journal, January 2019

    • Liu, Huan; Zhang, Shixue; Zhu, Qizhen
    • Journal of Materials Chemistry A, Vol. 7, Issue 18
    • DOI: 10.1039/c9ta02030f

    Using Peanut Shells to Construct a Porous MnO/C Composite Material with Highly Improved Lithium Storage Performance
    journal, December 2019

    Facile Approach for Synthesizing High-Performance MnO/C Electrodes from Rice Husk
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