Exploring reaction dynamics in lithium–sulfur batteries by time-resolved operando sulfur K-edge X-ray absorption spectroscopy
Abstract
A time-resolved operando X-ray absorption spectroscopy experiment was successfully designed to explore the sulfur reaction dynamics in lithium–sulfur (Li–S) batteries. It presents direct real-time experimental evidence for the distinct sulfur dynamics at different discharge rates, deepening the understanding of reaction mechanisms in Li–S batteries.
- Authors:
-
- Chinese Academy of Sciences (CAS), Beijing (China). Beijing National Lab. for Condensed Matter Physics, Inst. of Physics; Univ. of Chinese Academy of Sciences, Beijing (China); Songshan Lake Materials Lab., Dongguan, Guangdong (China)
- Chinese Academy of Sciences (CAS), Shenyang (China). Advanced Carbon Division, Shenyang National Lab. for Materials Science, Inst. of Metal Research
- Chinese Academy of Sciences, Shanghai (China). Shanghai Synchrotron Radiation Facility, Shanghai Inst. of Applied Physics
- Brookhaven National Lab. (BNL), Upton, NY (United States). Chemistry Division
- Publication Date:
- Research Org.:
- Brookhaven National Laboratory (BNL), Upton, NY (United States)
- Sponsoring Org.:
- USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V); USDOE
- OSTI Identifier:
- 1507701
- Alternate Identifier(s):
- OSTI ID: 1506138
- Report Number(s):
- BNL-211559-2019-JAAM
Journal ID: ISSN 1359-7345; CHCOFS
- Grant/Contract Number:
- SC0012704; 11675255; 51502334; 51822211
- Resource Type:
- Accepted Manuscript
- Journal Name:
- ChemComm
- Additional Journal Information:
- Journal Volume: 55; Journal Issue: 34; Journal ID: ISSN 1359-7345
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE; Li-Sulfur cathode; Li batteries
Citation Formats
Zhao, Enyue, Wang, Junyang, Li, Feng, Jiang, Zheng, Yang, Xiao-Qing, Wang, Fangwei, Li, Hong, and Yu, Xiqian. Exploring reaction dynamics in lithium–sulfur batteries by time-resolved operando sulfur K-edge X-ray absorption spectroscopy. United States: N. p., 2019.
Web. doi:10.1039/C9CC00485H.
Zhao, Enyue, Wang, Junyang, Li, Feng, Jiang, Zheng, Yang, Xiao-Qing, Wang, Fangwei, Li, Hong, & Yu, Xiqian. Exploring reaction dynamics in lithium–sulfur batteries by time-resolved operando sulfur K-edge X-ray absorption spectroscopy. United States. https://doi.org/10.1039/C9CC00485H
Zhao, Enyue, Wang, Junyang, Li, Feng, Jiang, Zheng, Yang, Xiao-Qing, Wang, Fangwei, Li, Hong, and Yu, Xiqian. Mon .
"Exploring reaction dynamics in lithium–sulfur batteries by time-resolved operando sulfur K-edge X-ray absorption spectroscopy". United States. https://doi.org/10.1039/C9CC00485H. https://www.osti.gov/servlets/purl/1507701.
@article{osti_1507701,
title = {Exploring reaction dynamics in lithium–sulfur batteries by time-resolved operando sulfur K-edge X-ray absorption spectroscopy},
author = {Zhao, Enyue and Wang, Junyang and Li, Feng and Jiang, Zheng and Yang, Xiao-Qing and Wang, Fangwei and Li, Hong and Yu, Xiqian},
abstractNote = {A time-resolved operando X-ray absorption spectroscopy experiment was successfully designed to explore the sulfur reaction dynamics in lithium–sulfur (Li–S) batteries. It presents direct real-time experimental evidence for the distinct sulfur dynamics at different discharge rates, deepening the understanding of reaction mechanisms in Li–S batteries.},
doi = {10.1039/C9CC00485H},
journal = {ChemComm},
number = 34,
volume = 55,
place = {United States},
year = {Mon Apr 01 00:00:00 EDT 2019},
month = {Mon Apr 01 00:00:00 EDT 2019}
}
Free Publicly Available Full Text
Publisher's Version of Record
Other availability
Cited by: 9 works
Citation information provided by
Web of Science
Web of Science
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
In situ / operando characterization techniques for rechargeable lithium–sulfur batteries: a review
journal, January 2017
- Tan, Jian; Liu, Dongna; Xu, Xu
- Nanoscale, Vol. 9, Issue 48
Synchrotron X-ray Analytical Techniques for Studying Materials Electrochemistry in Rechargeable Batteries
journal, September 2017
- Lin, Feng; Liu, Yijin; Yu, Xiqian
- Chemical Reviews, Vol. 117, Issue 21
Revealing the Electrochemical Charging Mechanism of Nanosized Li 2 S by in Situ and Operando X-ray Absorption Spectroscopy
journal, July 2017
- Zhang, Liang; Sun, Dan; Feng, Jun
- Nano Letters, Vol. 17, Issue 8
Kinetically Enhanced Electrochemical Redox of Polysulfides on Polymeric Carbon Nitrides for Improved Lithium–Sulfur Batteries
journal, September 2016
- Liang, Ji; Yin, Lichang; Tang, Xiaonan
- ACS Applied Materials & Interfaces, Vol. 8, Issue 38
Anode Improvement in Rechargeable Lithium-Sulfur Batteries
journal, June 2017
- Tao, Tao; Lu, Shengguo; Fan, Ye
- Advanced Materials, Vol. 29, Issue 48
In Operando X-ray Diffraction and Transmission X-ray Microscopy of Lithium Sulfur Batteries
journal, March 2012
- Nelson, Johanna; Misra, Sumohan; Yang, Yuan
- Journal of the American Chemical Society, Vol. 134, Issue 14
Fingerprinting Lithium-Sulfur Battery Reaction Products by X-ray Absorption Spectroscopy
journal, January 2014
- Wujcik, Kevin H.; Velasco-Velez, Juan; Wu, Cheng Hao
- Journal of The Electrochemical Society, Vol. 161, Issue 6
Lithium-Sulfur Batteries: Progress and Prospects
journal, February 2015
- Manthiram, Arumugam; Chung, Sheng-Heng; Zu, Chenxi
- Advanced Materials, Vol. 27, Issue 12
Operando Resonant Inelastic X-ray Scattering: An Appropriate Tool to Characterize Sulfur in Li–S Batteries
journal, October 2016
- Kavčič, M.; Bučar, K.; Petric, M.
- The Journal of Physical Chemistry C, Vol. 120, Issue 43
In Situ X-ray Absorption Spectroscopy Studies of Discharge Reactions in a Thick Cathode of a Lithium Sulfur Battery
journal, December 2016
- Wujcik, Kevin H.; Wang, Dunyang Rita; Pascal, Tod A.
- Journal of The Electrochemical Society, Vol. 164, Issue 2
Enhancing lithium–sulphur battery performance by strongly binding the discharge products on amino-functionalized reduced graphene oxide
journal, September 2014
- Wang, Zhiyu; Dong, Yanfeng; Li, Hongjiang
- Nature Communications, Vol. 5, Issue 1
Lithium sulfur batteries, a mechanistic review
journal, January 2015
- Wild, M.; O'Neill, L.; Zhang, T.
- Energy & Environmental Science, Vol. 8, Issue 12
Carbon–sulfur composites for Li–S batteries: status and prospects
journal, January 2013
- Wang, Da-Wei; Zeng, Qingcong; Zhou, Guangmin
- Journal of Materials Chemistry A, Vol. 1, Issue 33
High capacity vertical aligned carbon nanotube/sulfur composite cathodes for lithium–sulfur batteries
journal, January 2012
- Dörfler, Susanne; Hagen, Markus; Althues, Holger
- Chemical Communications, Vol. 48, Issue 34
Challenges and Prospects of Lithium–Sulfur Batteries
journal, June 2012
- Manthiram, Arumugam; Fu, Yongzhu; Su, Yu-Sheng
- Accounts of Chemical Research, Vol. 46, Issue 5
A Flexible Sulfur-Graphene-Polypropylene Separator Integrated Electrode for Advanced Li-S Batteries
journal, November 2014
- Zhou, Guangmin; Li, Lu; Wang, Da-Wei
- Advanced Materials, Vol. 27, Issue 4
Revisit Carbon/Sulfur Composite for Li-S Batteries
journal, January 2013
- Zheng, Jianming; Gu, Meng; Wagner, Michael J.
- Journal of The Electrochemical Society, Vol. 160, Issue 10
More Reliable Lithium-Sulfur Batteries: Status, Solutions and Prospects
journal, April 2017
- Fang, Ruopian; Zhao, Shiyong; Sun, Zhenhua
- Advanced Materials, Vol. 29, Issue 48
Polysulfide immobilization and conversion on a conductive polar MoC@MoOx material for lithium-sulfur batteries
journal, January 2018
- Fang, Ruopian; Zhao, Shiyong; Sun, Zhenhua
- Energy Storage Materials, Vol. 10
Unique behaviour of nonsolvents for polysulphides in lithium–sulphur batteries
journal, January 2014
- Cuisinier, M.; Cabelguen, P. -E.; Adams, B. D.
- Energy Environ. Sci., Vol. 7, Issue 8
Porous Hollow Carbon@Sulfur Composites for High-Power Lithium-Sulfur Batteries
journal, May 2011
- Jayaprakash, N.; Shen, J.; Moganty, Surya S.
- Angewandte Chemie International Edition, Vol. 50, Issue 26, p. 5904-5908
Mechanistic insights into operational lithium–sulfur batteries by in situ X-ray diffraction and absorption spectroscopy
journal, January 2014
- Lowe, Michael A.; Gao, Jie; Abruña, Héctor D.
- RSC Advances, Vol. 4, Issue 35
Rechargeable Lithium–Sulfur Batteries
journal, July 2014
- Manthiram, Arumugam; Fu, Yongzhu; Chung, Sheng-Heng
- Chemical Reviews, Vol. 114, Issue 23
Ionic shield for polysulfides towards highly-stable lithium–sulfur batteries
journal, January 2014
- Huang, Jia-Qi; Zhang, Qiang; Peng, Hong-Jie
- Energy Environ. Sci., Vol. 7, Issue 1
Understanding the Charging Mechanism of Lithium-Sulfur Batteries Using Spatially Resolved Operando X-Ray Absorption Spectroscopy
journal, January 2016
- Gorlin, Yelena; Patel, Manu U. M.; Freiberg, Anna
- Journal of The Electrochemical Society, Vol. 163, Issue 6
In situ/operando synchrotron-based X-ray techniques for lithium-ion battery research
journal, July 2018
- Bak, Seong-Min; Shadike, Zulipiya; Lin, Ruoqian
- NPG Asia Materials, Vol. 10, Issue 7
Designing high-energy lithium–sulfur batteries
journal, January 2016
- Seh, Zhi Wei; Sun, Yongming; Zhang, Qianfan
- Chemical Society Reviews, Vol. 45, Issue 20
Conductive porous vanadium nitride/graphene composite as chemical anchor of polysulfides for lithium-sulfur batteries
journal, March 2017
- Sun, Zhenhua; Zhang, Jingqi; Yin, Lichang
- Nature Communications, Vol. 8, Issue 1
Characterization of Polysulfide Radicals Present in an Ether-Based Electrolyte of a Lithium-Sulfur Battery During Initial Discharge Using In Situ X-Ray Absorption Spectroscopy Experiments and First-Principles Calculations
journal, June 2015
- Wujcik, Kevin H.; Pascal, Tod A.; Pemmaraju, C. D.
- Advanced Energy Materials, Vol. 5, Issue 16
Stabilizing sulfur cathodes using nitrogen-doped graphene as a chemical immobilizer for Li S batteries
journal, November 2016
- Li, Lu; Zhou, Guangmin; Yin, Lichang
- Carbon, Vol. 108
A new insight into the lithium storage mechanism of sulfurized polyacrylonitrile with no soluble intermediates
journal, September 2018
- Jin, Zhao-Qing; Liu, Yong-Gang; Wang, Wei-Kun
- Energy Storage Materials, Vol. 14
Carbon materials for Li–S batteries: Functional evolution and performance improvement
journal, January 2016
- Liang, Ji; Sun, Zhen-Hua; Li, Feng
- Energy Storage Materials, Vol. 2
Advanced Characterization Techniques in Promoting Mechanism Understanding for Lithium-Sulfur Batteries
journal, March 2018
- Zhao, Enyue; Nie, Kaihui; Yu, Xiqian
- Advanced Functional Materials, Vol. 28, Issue 38
A highly ordered nanostructured carbon–sulphur cathode for lithium–sulphur batteries
journal, May 2009
- Ji, Xiulei; Lee, Kyu Tae; Nazar, Linda F.
- Nature Materials, Vol. 8, Issue 6, p. 500-506
High-rate lithium–sulfur batteries promoted by reduced graphene oxide coating
journal, January 2012
- Li, Nianwu; Zheng, Mingbo; Lu, Hongling
- Chemical Communications, Vol. 48, Issue 34
Porous Hollow Carbon@Sulfur Composites for High-Power Lithium-Sulfur Batteries
journal, May 2011
- Jayaprakash, N.; Shen, J.; Moganty, Surya S.
- Angewandte Chemie, Vol. 123, Issue 26, p. 6026-6030