Effects of Salinity-Induced Chemical Reactions on Biotite Wettability Changes under Geologic CO2 Sequestration Conditions

Zhang, Lijie; Kim, Yongman; Jung, Haesung; Wan, Jiamin; Jun, Young-Shin

doi:10.1021/acs.estlett.5b00359

Title: Effects of Salinity-Induced Chemical Reactions on Biotite Wettability Changes under Geologic CO₂ Sequestration Conditions

Abstract

The wettability of rocks and minerals significantly affects the safety and efficiency of energy-related subsurface operations. Salinity is an important controlling factor in terms of wettability but has received limited attention. We studied the effects of salinity-induced chemical reactions on biotite's wettability changes under relevant subsurface conditions. Biotite was reacted at 95 °C and 102 atm of CO₂ for 70 h in solutions with salinities of 0, 0.1, 0.5, and 1.0 M NaCl. Then, static and dynamic water contact angles on reacted biotite basal surfaces were measured using a captive drop method. As a result of enhanced biotite dissolution at higher salinities, increased roughness, more negatively charged surfaces, and higher densities of hydroxyl groups on the biotite surfaces made biotite basal surface more hydrophilic. These results provide new information about the interplay of chemical reactions and wettability alterations of minerals, providing a better understanding of CO₂ transport in subsurface environments.

Authors:

Zhang, Lijie ^[1]; Kim, Yongman ^[2]; Jung, Haesung ^[1]; Wan, Jiamin ^[2]; Jun, Young-Shin ^[1]

Washington Univ., St. Louis, MO (United States). Dept. of Energy, Environmental and Chemical Engineering
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Energy Geosciences Division

Publication Date:: Wed Feb 10 00:00:00 EST 2016

Research Org.:: Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States); Energy Frontier Research Centers (EFRC) (United States). Center for Nanoscale Control of Geologic CO2 (NCGC)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI Identifier:: 1506253

Grant/Contract Number:: AC02-05CH11231

Resource Type:: Accepted Manuscript

Journal Name:: Environmental Science & Technology Letters (Online)

Additional Journal Information:: Journal Name: Environmental Science & Technology Letters (Online); Journal Volume: 3; Journal Issue: 3; Journal ID: ISSN 2328-8930

Publisher:: American Chemical Society (ACS)

Country of Publication:: United States

Language:: English

Subject:: 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 58 GEOSCIENCES

Citation Formats


                    Zhang, Lijie, Kim, Yongman, Jung, Haesung, Wan, Jiamin, and Jun, Young-Shin. Effects of Salinity-Induced Chemical Reactions on Biotite Wettability Changes under Geologic CO2 Sequestration Conditions.  United States: N. p., 2016. 
Web.  doi:10.1021/acs.estlett.5b00359.

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                    Zhang, Lijie, Kim, Yongman, Jung, Haesung, Wan, Jiamin, & Jun, Young-Shin. Effects of Salinity-Induced Chemical Reactions on Biotite Wettability Changes under Geologic CO2 Sequestration Conditions.  United States.  https://doi.org/10.1021/acs.estlett.5b00359

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                    Zhang, Lijie, Kim, Yongman, Jung, Haesung, Wan, Jiamin, and Jun, Young-Shin. Wed .  
"Effects of Salinity-Induced Chemical Reactions on Biotite Wettability Changes under Geologic CO2 Sequestration Conditions".  United States.  https://doi.org/10.1021/acs.estlett.5b00359.  https://www.osti.gov/servlets/purl/1506253.

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@article{osti_1506253,

  title        = {Effects of Salinity-Induced Chemical Reactions on Biotite Wettability Changes under Geologic CO2 Sequestration Conditions},

  author       = {Zhang, Lijie and Kim, Yongman and Jung, Haesung and Wan, Jiamin and Jun, Young-Shin},

  abstractNote = {The wettability of rocks and minerals significantly affects the safety and efficiency of energy-related subsurface operations. Salinity is an important controlling factor in terms of wettability but has received limited attention. We studied the effects of salinity-induced chemical reactions on biotite's wettability changes under relevant subsurface conditions. Biotite was reacted at 95 °C and 102 atm of CO2 for 70 h in solutions with salinities of 0, 0.1, 0.5, and 1.0 M NaCl. Then, static and dynamic water contact angles on reacted biotite basal surfaces were measured using a captive drop method. As a result of enhanced biotite dissolution at higher salinities, increased roughness, more negatively charged surfaces, and higher densities of hydroxyl groups on the biotite surfaces made biotite basal surface more hydrophilic. These results provide new information about the interplay of chemical reactions and wettability alterations of minerals, providing a better understanding of CO2 transport in subsurface environments.},

  doi          = {10.1021/acs.estlett.5b00359},

  journal      = {Environmental Science & Technology Letters (Online)},

  number       = 3,

  volume       = 3,

  place        = {United States},

  year         = {Wed Feb 10 00:00:00 EST 2016},

  month        = {Wed Feb 10 00:00:00 EST 2016}

}

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Figures / Tables:

Figure 1: Aqueous concentrations of K, Si, Al, Fe, and Mg from the dissolution of biotite flakes (A) and biotite powders (B) after 70 h in solutions with different salinities (0, 0.1, 0.5, and 1.0 M NaCl) at 102 atm of CO₂ and 95 °C.

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Works referencing / citing this record:

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journal, January 2019

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Title: Effects of Salinity-Induced Chemical Reactions on Biotite Wettability Changes under Geologic CO2 Sequestration Conditions

Abstract

Citation Formats

Figures / Tables:

CO 2 wettability of seal and reservoir rocks and the implications for carbon geo-sequestration journal, January 2015

Capillary Pressure and Mineral Wettability Influences on Reservoir CO2 Capacity journal, January 2013

Wettability alteration of caprock minerals by carbon dioxide journal, May 2007

Wettability of Supercritical Carbon Dioxide/Water/Quartz Systems: Simultaneous Measurement of Contact Angle and Interfacial Tension at Reservoir Conditions journal, May 2013

Contact angle measurements of CO2–water–quartz/calcite systems in the perspective of carbon sequestration journal, September 2011

Molecular Simulation of Carbon Dioxide, Brine, and Clay Mineral Interactions and Determination of Contact Angles journal, January 2014

Molecular Dynamics Simulation of Water/CO2-quartz Interfacial Properties: Application to Subsurface Gas Injection journal, January 2013

Supercritical CO 2 and Ionic Strength Effects on Wettability of Silica Surfaces: Equilibrium Contact Angle Measurements journal, August 2012

Wettability Phenomena at the CO 2 –Brine–Mineral Interface: Implications for Geologic Carbon Sequestration journal, August 2012

Water-CO 2 -mineral systems: Interfacial tension, contact angle, and diffusion-Implications to CO 2 geological storage : WATER CO journal, July 2010

Contact angle measurement ambiguity in supercritical CO2–water–mineral systems: Mica as an example journal, December 2014

Beyond the Lotus Effect: Roughness Influences on Wetting over a Wide Surface-Energy Range journal, April 2008

Contamination of silica surfaces: Impact on water–CO2–quartz and glass contact angle measurements journal, March 2014

Biotite–Brine Interactions under Acidic Hydrothermal Conditions: Fibrous Illite, Goethite, and Kaolinite Formation and Biotite Surface Cracking journal, July 2011

Na + , Ca 2+ , and Mg 2+ in Brines Affect Supercritical CO 2 –Brine–Biotite Interactions: Ion Exchange, Biotite Dissolution, and Illite Precipitation journal, May 2012

Experimental study on water–rock interactions during CO2 flooding in the Tensleep Formation, Wyoming, USA journal, March 2000

The effects of initial acetate concentration on CO2–brine-anorthite interactions under geologic CO2 sequestration conditions journal, January 2011

Structure-Dependent Interactions between Alkali Feldspars and Organic Compounds: Implications for Reactions in Geologic Carbon Sequestration journal, August 2012

Plagioclase Dissolution during CO 2 –SO 2 Cosequestration: Effects of Sulfate journal, January 2015

DLVO-Based Estimates of Adsorbed Water Film Thicknesses in Geologic CO 2 Reservoirs journal, May 2012

Sequestration of CO2 in geological media in response to climate change: capacity of deep saline aquifers to sequester CO2 in solution journal, December 2003

Separation and Capture of CO 2 from Large Stationary Sources and Sequestration in Geological Formations—Coalbeds and Deep Saline Aquifers journal, June 2003

CO2 Sequestration in Deep Sedimentary Formations journal, October 2008

Monitoring of fluid–rock interaction and CO2 storage through produced fluid sampling at the Weyburn CO2-injection enhanced oil recovery site, Saskatchewan, Canada journal, June 2005

Paleohydrology of the Gulf of Mexico basin journal, February 1991

Potential environmental issues of CO2 storage in deep saline aquifers: Geochemical results from the Frio-I Brine Pilot test, Texas, USA journal, June 2009

Effects of Salinity and the Extent of Water on Supercritical CO 2 -Induced Phlogopite Dissolution and Secondary Mineral Formation journal, February 2011

Biotite Dissolution in Brine at Varied Temperatures and CO 2 Pressures: Its Activation Energy and Potential CO 2 Intercalation journal, October 2012

Distinctive Reactivities at Biotite Edge and Basal Planes in the Presence of Organic Ligands: Implications for Organic-Rich Geologic CO 2 Sequestration journal, August 2015

Geological Sequestration of Carbon Dioxide journal, September 2001

Biotite surface chemistry as a function of aqueous fluid composition journal, March 2014

In Situ Infrared Spectroscopic Study of Forsterite Carbonation in Wet Supercritical CO 2 journal, July 2011

Molecular Simulation of CO2- and CO3-Brine-Mineral Systems journal, January 2013

Thickness measurements of nanoscale brine films on silica surfaces under geologic CO 2 sequestration conditions using synchrotron X-ray fluorescence : MEASUREMENTS OF NANOSCALE BRINE FILMS ON SILICA SURFACES journal, September 2012

Some effects of substrate roughness on wettability journal, March 1981

Effects of surface roughness on wettability journal, April 1998

Wetting and Roughness journal, August 2008

Rough ideas on wetting journal, October 2002

Resistance Of Solid Surfaces To Wetting By Water journal, August 1936

The effects of substrate roughness on ultrathin water films journal, June 1989

Adsorption and capillary condensation on rough surfaces journal, June 1978

Brine film thicknesses on mica surfaces under geologic CO 2 sequestration conditions and controlled capillary pressures : BRINE FILM THICKNESSES ON MICA SURFACES UNDER GCC journal, August 2013

The surface chemistry of amorphous silica. Zhuravlev model journal, November 2000

Ab initio quantum mechanical studies of the kinetics and mechanisms of silicate dissolution: H+(H3O+) catalysis journal, December 1994

Water Contact Angle Dependence with Hydroxyl Functional Groups on Silica Surfaces under CO 2 Sequestration Conditions journal, November 2015

Kinetics of Water-Rock Interaction book, January 2008

Adhesion: Molecules and Mechanics journal, March 1994

Adhesion between metal surfaces: The effect of surface roughness journal, February 1981

Adhesion between Nanoscale Rough Surfaces journal, December 2000

CO 2 Adhesion on Hydrated Mineral Surfaces journal, September 2013

Contact Angle Hysteresis Explained journal, July 2006

Anomalous Contact Angle Hysteresis of a Captive Bubble: Advancing Contact Line Pinning journal, June 2011

Are rocks still water-wet in the presence of dense CO 2 or H 2 S? : Wettability alteration of rocks by acid gases journal, July 2012

Impacts of Geochemical Reactions on Geologic Carbon Sequestration journal, August 2012

Modeling geologic storage of carbon dioxide: Comparison of non-hysteretic and hysteretic characteristic curves journal, June 2007

Hysteretic trapping and relative permeability of CO2 in sandstone at reservoir conditions journal, August 2014

Molecular Simulation of CO2- and CO3-Brine-Mineral Systems journal, January 2013

Interrelationship between water film thicknesses and contact angles and a model for CO 2 adhesion journal, April 2019

Effects of sulfate on biotite interfacial reactions under high temperature and high CO 2 pressure journal, January 2019

Title: Effects of Salinity-Induced Chemical Reactions on Biotite Wettability Changes under Geologic CO₂ Sequestration Conditions

CO ₂ wettability of seal and reservoir rocks and the implications for carbon geo-sequestration
journal, January 2015

Capillary Pressure and Mineral Wettability Influences on Reservoir CO2 Capacity
journal, January 2013

Wettability alteration of caprock minerals by carbon dioxide
journal, May 2007

Wettability of Supercritical Carbon Dioxide/Water/Quartz Systems: Simultaneous Measurement of Contact Angle and Interfacial Tension at Reservoir Conditions
journal, May 2013

Contact angle measurements of CO2–water–quartz/calcite systems in the perspective of carbon sequestration
journal, September 2011

Molecular Simulation of Carbon Dioxide, Brine, and Clay Mineral Interactions and Determination of Contact Angles
journal, January 2014

Molecular Dynamics Simulation of Water/CO2-quartz Interfacial Properties: Application to Subsurface Gas Injection
journal, January 2013

Supercritical CO ₂ and Ionic Strength Effects on Wettability of Silica Surfaces: Equilibrium Contact Angle Measurements
journal, August 2012

Wettability Phenomena at the CO ₂ –Brine–Mineral Interface: Implications for Geologic Carbon Sequestration
journal, August 2012

Water-CO ₂ -mineral systems: Interfacial tension, contact angle, and diffusion-Implications to CO ₂ geological storage : WATER CO
journal, July 2010

Contact angle measurement ambiguity in supercritical CO2–water–mineral systems: Mica as an example
journal, December 2014

Beyond the Lotus Effect: Roughness Influences on Wetting over a Wide Surface-Energy Range
journal, April 2008

Contamination of silica surfaces: Impact on water–CO2–quartz and glass contact angle measurements
journal, March 2014

Biotite–Brine Interactions under Acidic Hydrothermal Conditions: Fibrous Illite, Goethite, and Kaolinite Formation and Biotite Surface Cracking
journal, July 2011

Na ⁺ , Ca ²⁺ , and Mg ²⁺ in Brines Affect Supercritical CO ₂ –Brine–Biotite Interactions: Ion Exchange, Biotite Dissolution, and Illite Precipitation
journal, May 2012

Experimental study on water–rock interactions during CO2 flooding in the Tensleep Formation, Wyoming, USA
journal, March 2000

The effects of initial acetate concentration on CO2–brine-anorthite interactions under geologic CO2 sequestration conditions
journal, January 2011

Structure-Dependent Interactions between Alkali Feldspars and Organic Compounds: Implications for Reactions in Geologic Carbon Sequestration
journal, August 2012

Plagioclase Dissolution during CO ₂ –SO ₂ Cosequestration: Effects of Sulfate
journal, January 2015

DLVO-Based Estimates of Adsorbed Water Film Thicknesses in Geologic CO ₂ Reservoirs
journal, May 2012

Sequestration of CO2 in geological media in response to climate change: capacity of deep saline aquifers to sequester CO2 in solution
journal, December 2003

Separation and Capture of CO ₂ from Large Stationary Sources and Sequestration in Geological Formations—Coalbeds and Deep Saline Aquifers
journal, June 2003

CO2 Sequestration in Deep Sedimentary Formations
journal, October 2008

Monitoring of fluid–rock interaction and CO₂ storage through produced fluid sampling at the Weyburn CO₂-injection enhanced oil recovery site, Saskatchewan, Canada
journal, June 2005

Paleohydrology of the Gulf of Mexico basin
journal, February 1991

Potential environmental issues of CO2 storage in deep saline aquifers: Geochemical results from the Frio-I Brine Pilot test, Texas, USA
journal, June 2009

Effects of Salinity and the Extent of Water on Supercritical CO ₂ -Induced Phlogopite Dissolution and Secondary Mineral Formation
journal, February 2011

Biotite Dissolution in Brine at Varied Temperatures and CO ₂ Pressures: Its Activation Energy and Potential CO ₂ Intercalation
journal, October 2012

Distinctive Reactivities at Biotite Edge and Basal Planes in the Presence of Organic Ligands: Implications for Organic-Rich Geologic CO ₂ Sequestration
journal, August 2015

Geological Sequestration of Carbon Dioxide
journal, September 2001

Biotite surface chemistry as a function of aqueous fluid composition
journal, March 2014

In Situ Infrared Spectroscopic Study of Forsterite Carbonation in Wet Supercritical CO ₂
journal, July 2011

Molecular Simulation of CO2- and CO3-Brine-Mineral Systems
journal, January 2013

Thickness measurements of nanoscale brine films on silica surfaces under geologic CO ₂ sequestration conditions using synchrotron X-ray fluorescence : MEASUREMENTS OF NANOSCALE BRINE FILMS ON SILICA SURFACES
journal, September 2012

Some effects of substrate roughness on wettability
journal, March 1981

Effects of surface roughness on wettability
journal, April 1998

Wetting and Roughness
journal, August 2008

Rough ideas on wetting
journal, October 2002

Resistance Of Solid Surfaces To Wetting By Water
journal, August 1936

The effects of substrate roughness on ultrathin water films
journal, June 1989

Adsorption and capillary condensation on rough surfaces
journal, June 1978

Brine film thicknesses on mica surfaces under geologic CO ₂ sequestration conditions and controlled capillary pressures : BRINE FILM THICKNESSES ON MICA SURFACES UNDER GCC
journal, August 2013

The surface chemistry of amorphous silica. Zhuravlev model
journal, November 2000

Ab initio quantum mechanical studies of the kinetics and mechanisms of silicate dissolution: H+(H3O+) catalysis
journal, December 1994

Water Contact Angle Dependence with Hydroxyl Functional Groups on Silica Surfaces under CO ₂ Sequestration Conditions
journal, November 2015

Kinetics of Water-Rock Interaction
book, January 2008

Adhesion: Molecules and Mechanics
journal, March 1994

Adhesion between metal surfaces: The effect of surface roughness
journal, February 1981

Adhesion between Nanoscale Rough Surfaces
journal, December 2000

CO ₂ Adhesion on Hydrated Mineral Surfaces
journal, September 2013

Contact Angle Hysteresis Explained
journal, July 2006

Anomalous Contact Angle Hysteresis of a Captive Bubble: Advancing Contact Line Pinning
journal, June 2011

Are rocks still water-wet in the presence of dense CO ₂ or H ₂ S? : Wettability alteration of rocks by acid gases
journal, July 2012

Impacts of Geochemical Reactions on Geologic Carbon Sequestration
journal, August 2012

Modeling geologic storage of carbon dioxide: Comparison of non-hysteretic and hysteretic characteristic curves
journal, June 2007

Hysteretic trapping and relative permeability of CO2 in sandstone at reservoir conditions
journal, August 2014

Molecular Simulation of CO2- and CO3-Brine-Mineral Systems
journal, January 2013

Interrelationship between water film thicknesses and contact angles and a model for CO ₂ adhesion
journal, April 2019

Effects of sulfate on biotite interfacial reactions under high temperature and high CO ₂ pressure
journal, January 2019