Atomically engineering activation sites onto metallic 1T-MoS2 catalysts for enhanced electrochemical hydrogen evolution
Abstract
Engineering catalytic sites at the atomic level provides an opportunity to understand the catalyst’s active sites, which is vital to the development of improved catalysts. Here we show a reliable and tunable polyoxometalate template-based synthetic strategy to atomically engineer metal doping sites onto metallic 1T-MoS2, using Anderson-type polyoxometalates as precursors. Benefiting from engineering nickel and oxygen atoms, the optimized electrocatalyst shows great enhancement in the hydrogen evolution reaction with a positive onset potential of ~ 0 V and a low overpotential of –46 mV in alkaline electrolyte, comparable to platinum-based catalysts. First-principles calculations reveal co-doping nickel and oxygen into 1T-MoS2 assists the process of water dissociation and hydrogen generation from their intermediate states. This research will expand on the ability to improve the activities of various catalysts by precisely engineering atomic activation sites to achieve significant electronic modulations and improve atomic utilization efficiencies.
- Authors:
-
- Tsinghua Univ., Beijing (People's Republic of China); San Diego State Univ., San Diego, CA (United States)
- Jilin Univ., Changchun (People's Republic of China)
- Stanford Univ., Stanford, CA (United States)
- Univ. of California, Irvine, CA (United States)
- Marquette Univ., Milwaukee, WI (United States)
- Tsinghua Univ., Beijing (People's Republic of China)
- San Diego State Univ., San Diego, CA (United States)
- Publication Date:
- Research Org.:
- SLAC National Accelerator Laboratory (SLAC), Menlo Park, CA (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1506174
- Grant/Contract Number:
- AC02-76SF00515
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Nature Communications
- Additional Journal Information:
- Journal Volume: 10; Journal Issue: 1; Journal ID: ISSN 2041-1723
- Publisher:
- Nature Publishing Group
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Huang, Yichao, Sun, Yuanhui, Zheng, Xueli, Aoki, Toshihiro, Pattengale, Brian, Huang, Jier, He, Xin, Bian, Wei, Younan, Sabrina, Williams, Nicholas, Hu, Jun, Ge, Jingxuan, Pu, Ning, Yan, Xingxu, Pan, Xiaoqing, Zhang, Lijun, Wei, Yongge, and Gu, Jing. Atomically engineering activation sites onto metallic 1T-MoS2 catalysts for enhanced electrochemical hydrogen evolution. United States: N. p., 2019.
Web. doi:10.1038/s41467-019-08877-9.
Huang, Yichao, Sun, Yuanhui, Zheng, Xueli, Aoki, Toshihiro, Pattengale, Brian, Huang, Jier, He, Xin, Bian, Wei, Younan, Sabrina, Williams, Nicholas, Hu, Jun, Ge, Jingxuan, Pu, Ning, Yan, Xingxu, Pan, Xiaoqing, Zhang, Lijun, Wei, Yongge, & Gu, Jing. Atomically engineering activation sites onto metallic 1T-MoS2 catalysts for enhanced electrochemical hydrogen evolution. United States. https://doi.org/10.1038/s41467-019-08877-9
Huang, Yichao, Sun, Yuanhui, Zheng, Xueli, Aoki, Toshihiro, Pattengale, Brian, Huang, Jier, He, Xin, Bian, Wei, Younan, Sabrina, Williams, Nicholas, Hu, Jun, Ge, Jingxuan, Pu, Ning, Yan, Xingxu, Pan, Xiaoqing, Zhang, Lijun, Wei, Yongge, and Gu, Jing. Thu .
"Atomically engineering activation sites onto metallic 1T-MoS2 catalysts for enhanced electrochemical hydrogen evolution". United States. https://doi.org/10.1038/s41467-019-08877-9. https://www.osti.gov/servlets/purl/1506174.
@article{osti_1506174,
title = {Atomically engineering activation sites onto metallic 1T-MoS2 catalysts for enhanced electrochemical hydrogen evolution},
author = {Huang, Yichao and Sun, Yuanhui and Zheng, Xueli and Aoki, Toshihiro and Pattengale, Brian and Huang, Jier and He, Xin and Bian, Wei and Younan, Sabrina and Williams, Nicholas and Hu, Jun and Ge, Jingxuan and Pu, Ning and Yan, Xingxu and Pan, Xiaoqing and Zhang, Lijun and Wei, Yongge and Gu, Jing},
abstractNote = {Engineering catalytic sites at the atomic level provides an opportunity to understand the catalyst’s active sites, which is vital to the development of improved catalysts. Here we show a reliable and tunable polyoxometalate template-based synthetic strategy to atomically engineer metal doping sites onto metallic 1T-MoS2, using Anderson-type polyoxometalates as precursors. Benefiting from engineering nickel and oxygen atoms, the optimized electrocatalyst shows great enhancement in the hydrogen evolution reaction with a positive onset potential of ~ 0 V and a low overpotential of –46 mV in alkaline electrolyte, comparable to platinum-based catalysts. First-principles calculations reveal co-doping nickel and oxygen into 1T-MoS2 assists the process of water dissociation and hydrogen generation from their intermediate states. This research will expand on the ability to improve the activities of various catalysts by precisely engineering atomic activation sites to achieve significant electronic modulations and improve atomic utilization efficiencies.},
doi = {10.1038/s41467-019-08877-9},
journal = {Nature Communications},
number = 1,
volume = 10,
place = {United States},
year = {Thu Feb 28 00:00:00 EST 2019},
month = {Thu Feb 28 00:00:00 EST 2019}
}
Web of Science
Figures / Tables:
Works referenced in this record:
Surface and Interface Engineering of Noble-Metal-Free Electrocatalysts for Efficient Energy Conversion Processes
journal, February 2017
- Zhu, Yun Pei; Guo, Chunxian; Zheng, Yao
- Accounts of Chemical Research, Vol. 50, Issue 4
ATHENA , ARTEMIS , HEPHAESTUS : data analysis for X-ray absorption spectroscopy using IFEFFIT
journal, June 2005
- Ravel, B.; Newville, M.
- Journal of Synchrotron Radiation, Vol. 12, Issue 4
Enhanced Hydrogen Evolution Catalysis from Chemically Exfoliated Metallic MoS 2 Nanosheets
journal, May 2013
- Lukowski, Mark A.; Daniel, Andrew S.; Meng, Fei
- Journal of the American Chemical Society, Vol. 135, Issue 28
Formation of Ni-Co-MoS 2 Nanoboxes with Enhanced Electrocatalytic Activity for Hydrogen Evolution
journal, August 2016
- Yu, Xin-Yao; Feng, Yi; Jeon, Yeryung
- Advanced Materials, Vol. 28, Issue 40
Computational high-throughput screening of electrocatalytic materials for hydrogen evolution
journal, October 2006
- Greeley, Jeff; Jaramillo, Thomas F.; Bonde, Jacob
- Nature Materials, Vol. 5, Issue 11, p. 909-913
MoS2 Nanoparticles Grown on Graphene An Advanced Catalyst for the Hydrogen Evolution Reaction
journal, May 2011
- Li, Yanguang; Wang, Hailiang; Xie, Liming
- Journal of the American Chemical Society, Vol. 133, Issue 19, p. 7296-7299
Ultrathin two-dimensional materials for photo- and electrocatalytic hydrogen evolution
journal, September 2018
- Di, Jun; Yan, Cheng; Handoko, Albertus D.
- Materials Today, Vol. 21, Issue 7
Transition-metal doped edge sites in vertically aligned MoS2 catalysts for enhanced hydrogen evolution
journal, January 2015
- Wang, Haotian; Tsai, Charlie; Kong, Desheng
- Nano Research, Vol. 8, Issue 2
Hydrogen production through sorption-enhanced steam methane reforming and membrane technology: A review
journal, April 2008
- Barelli, L.; Bidini, G.; Gallorini, F.
- Energy, Vol. 33, Issue 4
The Crystal Structure of Molybdenite
journal, June 1923
- Dickinson, Roscoe G.; Pauling, Linus
- Journal of the American Chemical Society, Vol. 45, Issue 6
Theoretical insights into the hydrogen evolution activity of layered transition metal dichalcogenides
journal, October 2015
- Tsai, Charlie; Chan, Karen; Nørskov, Jens K.
- Surface Science, Vol. 640
Vertically Aligned Oxygenated-CoS 2 –MoS 2 Heteronanosheet Architecture from Polyoxometalate for Efficient and Stable Overall Water Splitting
journal, April 2018
- Hou, Jungang; Zhang, Bo; Li, Zhuwei
- ACS Catalysis, Vol. 8, Issue 5
Bifunctional non-noble metal oxide nanoparticle electrocatalysts through lithium-induced conversion for overall water splitting
journal, June 2015
- Wang, Haotian; Lee, Hyun-Wook; Deng, Yong
- Nature Communications, Vol. 6, Issue 1
Recent advances in alkoxylation chemistry of polyoxometalates: From synthetic strategies, structural overviews to functional applications
journal, January 2019
- Zhang, Jiangwei; Huang, Yichao; Li, Gao
- Coordination Chemistry Reviews, Vol. 378
Prediction of structural and metal-to-semiconductor phase transitions in nanoscale , , and other transition metal dichalcogenide zigzag ribbons
journal, February 2015
- Güller, F.; Llois, A. M.; Goniakowski, J.
- Physical Review B, Vol. 91, Issue 7
In Situ X-Ray Absorption Spectroscopic Studies of Nickel Oxide Electrodes
journal, January 1990
- Pandya, K. I.
- Journal of The Electrochemical Society, Vol. 137, Issue 2
Phosphorus-Modified Tungsten Nitride/Reduced Graphene Oxide as a High-Performance, Non-Noble-Metal Electrocatalyst for the Hydrogen Evolution Reaction
journal, March 2015
- Yan, Haijing; Tian, Chungui; Wang, Lei
- Angewandte Chemie International Edition, Vol. 54, Issue 21
Novel porous molybdenum tungsten phosphide hybrid nanosheets on carbon cloth for efficient hydrogen evolution
journal, January 2016
- Wang, Xu-Dong; Xu, Yang-Fan; Rao, Hua-Shang
- Energy & Environmental Science, Vol. 9, Issue 4
Alternative energy technologies
journal, November 2001
- Dresselhaus, M. S.; Thomas, I. L.
- Nature, Vol. 414, Issue 6861
Current Status of Hydrogen Production Techniques by Steam Reforming of Ethanol: A Review
journal, September 2005
- Haryanto, Agus; Fernando, Sandun; Murali, Naveen
- Energy & Fuels, Vol. 19, Issue 5
Conducting MoS 2 Nanosheets as Catalysts for Hydrogen Evolution Reaction
journal, November 2013
- Voiry, Damien; Salehi, Maryam; Silva, Rafael
- Nano Letters, Vol. 13, Issue 12
Understanding Structure-Dependent Catalytic Performance of Nickel Selenides for Electrochemical Water Oxidation
journal, December 2016
- Xu, Kun; Ding, Hui; Lv, Haifeng
- ACS Catalysis, Vol. 7, Issue 1
Porous MoO 2 Nanosheets as Non-noble Bifunctional Electrocatalysts for Overall Water Splitting
journal, March 2016
- Jin, Yanshuo; Wang, Haotian; Li, Junjie
- Advanced Materials, Vol. 28, Issue 19
Self-optimizing, highly surface-active layered metal dichalcogenide catalysts for hydrogen evolution
journal, July 2017
- Liu, Yuanyue; Wu, Jingjie; Hackenberg, Ken P.
- Nature Energy, Vol. 2, Issue 9
Recent developments in transition metal carbides and nitrides as hydrogen evolution electrocatalysts
journal, January 2013
- Chen, Wei-Fu; Muckerman, James T.; Fujita, Etsuko
- Chemical Communications, Vol. 49, Issue 79
The role of electronic coupling between substrate and 2D MoS2 nanosheets in electrocatalytic production of hydrogen
journal, June 2016
- Voiry, Damien; Fullon, Raymond; Yang, Jieun
- Nature Materials, Vol. 15, Issue 9
Structure Re-determination and Superconductivity Observation of Bulk 1T MoS 2
journal, January 2018
- Fang, Yuqiang; Pan, Jie; He, Jianqiao
- Angewandte Chemie International Edition, Vol. 57, Issue 5
Gram-Scale Aqueous Synthesis of Stable Few-Layered 1T-MoS 2 : Applications for Visible-Light-Driven Photocatalytic Hydrogen Evolution
journal, August 2015
- Liu, Qin; Li, Xiuling; He, Qun
- Small, Vol. 11, Issue 41
Resolving surface chemical states in XPS analysis of first row transition metals, oxides and hydroxides: Cr, Mn, Fe, Co and Ni
journal, January 2011
- Biesinger, Mark C.; Payne, Brad P.; Grosvenor, Andrew P.
- Applied Surface Science, Vol. 257, Issue 7, p. 2717-2730
Biomimetic Hydrogen Evolution: MoS 2 Nanoparticles as Catalyst for Hydrogen Evolution
journal, April 2005
- Hinnemann, Berit; Moses, Poul Georg; Bonde, Jacob
- Journal of the American Chemical Society, Vol. 127, Issue 15
The Synthesis of Nanostructured Ni 5 P 4 Films and their Use as a Non-Noble Bifunctional Electrocatalyst for Full Water Splitting
journal, June 2015
- Ledendecker, Marc; Krick Calderón, Sandra; Papp, Christian
- Angewandte Chemie International Edition, Vol. 54, Issue 42
Hydrogen as an energy carrier: Prospects and challenges
journal, June 2012
- Mazloomi, Kaveh; Gomes, Chandima
- Renewable and Sustainable Energy Reviews, Vol. 16, Issue 5
Kinetic Study of Hydrogen Evolution Reaction over Strained MoS 2 with Sulfur Vacancies Using Scanning Electrochemical Microscopy
journal, April 2016
- Li, Hong; Du, Minshu; Mleczko, Michal J.
- Journal of the American Chemical Society, Vol. 138, Issue 15
Interface engineering: The Ni(OH) 2 /MoS 2 heterostructure for highly efficient alkaline hydrogen evolution
journal, July 2017
- Zhang, Bao; Liu, Jia; Wang, Jinsong
- Nano Energy, Vol. 37
Engineering the surface structure of MoS2 to preferentially expose active edge sites for electrocatalysis
journal, October 2012
- Kibsgaard, Jakob; Chen, Zhebo; Reinecke, Benjamin N.
- Nature Materials, Vol. 11, Issue 11, p. 963-969
Controllable Disorder Engineering in Oxygen-Incorporated MoS 2 Ultrathin Nanosheets for Efficient Hydrogen Evolution
journal, November 2013
- Xie, Junfeng; Zhang, Jiajia; Li, Shuang
- Journal of the American Chemical Society, Vol. 135, Issue 47
Unprecedented Replacement of Bridging Oxygen Atoms in Polyoxometalates with Organic Imido Ligands
journal, March 2008
- Hao, Jian; Xia, Yun; Wang, Longsheng
- Angewandte Chemie International Edition, Vol. 47, Issue 14
Phosphorus-Mo 2 C@carbon nanowires toward efficient electrochemical hydrogen evolution: composition, structural and electronic regulation
journal, January 2017
- Shi, Zhangping; Nie, Kaiqi; Shao, Zheng-Jiang
- Energy & Environmental Science, Vol. 10, Issue 5
Pure and stable metallic phase molybdenum disulfide nanosheets for hydrogen evolution reaction
journal, February 2016
- Geng, Xiumei; Sun, Weiwei; Wu, Wei
- Nature Communications, Vol. 7, Issue 1
Raman study and lattice dynamics of single molecular layers of
journal, August 1991
- Jiménez Sandoval, S.; Yang, D.; Frindt, R. F.
- Physical Review B, Vol. 44, Issue 8
High-Performance Hydrogen Evolution from MoS 2(1- x ) P x Solid Solution
journal, December 2015
- Ye, Ruquan; del Angel-Vicente, Paz; Liu, Yuanyue
- Advanced Materials, Vol. 28, Issue 7
Hydrogen evolution by a metal-free electrocatalyst
journal, April 2014
- Zheng, Yao; Jiao, Yan; Zhu, Yihan
- Nature Communications, Vol. 5, Issue 1
Engineering water dissociation sites in MoS 2 nanosheets for accelerated electrocatalytic hydrogen production
journal, January 2016
- Zhang, Jian; Wang, Tao; Liu, Pan
- Energy & Environmental Science, Vol. 9, Issue 9
A Fast Soluble Carbon-Free Molecular Water Oxidation Catalyst Based on Abundant Metals
journal, March 2010
- Yin, Q.; Tan, J. M.; Besson, C.
- Science, Vol. 328, Issue 5976, p. 342-345
Self-Assembled Hierarchical MoO 2 /Graphene Nanoarchitectures and Their Application as a High-Performance Anode Material for Lithium-Ion Batteries
journal, August 2011
- Sun, Yongming; Hu, Xianluo; Luo, Wei
- ACS Nano, Vol. 5, Issue 9
All The Catalytic Active Sites of MoS 2 for Hydrogen Evolution
journal, December 2016
- Li, Guoqing; Zhang, Du; Qiao, Qiao
- Journal of the American Chemical Society, Vol. 138, Issue 51
Coherent Atomic and Electronic Heterostructures of Single-Layer MoS2
journal, July 2012
- Eda, Goki; Fujita, Takeshi; Yamaguchi, Hisato
- ACS Nano, Vol. 6, Issue 8, p. 7311-7317
Polyoxometalate water oxidation catalysts and the production of green fuel
journal, January 2012
- Lv, Hongjin; Geletii, Yurii V.; Zhao, Chongchao
- Chemical Society Reviews, Vol. 41, Issue 22, p. 7572-7589
3D Nitrogen-Anion-Decorated Nickel Sulfides for Highly Efficient Overall Water Splitting
journal, June 2017
- Chen, Pengzuo; Zhou, Tianpei; Zhang, Mengxing
- Advanced Materials, Vol. 29, Issue 30
Highly efficient hydrogen evolution from seawater by a low-cost and stable CoMoP@C electrocatalyst superior to Pt/C
journal, January 2017
- Ma, Yuan-Yuan; Wu, Cai-Xia; Feng, Xiao-Jia
- Energy & Environmental Science, Vol. 10, Issue 3
Interface Engineering of MoS 2 /Ni 3 S 2 Heterostructures for Highly Enhanced Electrochemical Overall-Water-Splitting Activity
journal, April 2016
- Zhang, Jian; Wang, Tao; Pohl, Darius
- Angewandte Chemie International Edition, Vol. 55, Issue 23
Carbon-based metal-free catalysts
journal, September 2016
- Liu, Xien; Dai, Liming
- Nature Reviews Materials, Vol. 1, Issue 11
Electrochemical generation of sulfur vacancies in the basal plane of MoS2 for hydrogen evolution
journal, April 2017
- Tsai, Charlie; Li, Hong; Park, Sangwook
- Nature Communications, Vol. 8, Issue 1
Ab Initio Study of the H2–H2S/MoS2 Gas–Solid Interface: The Nature of the Catalytically Active Sites
journal, January 2000
- Raybaud, P.; Hafner, J.; Kresse, G.
- Journal of Catalysis, Vol. 189, Issue 1
Tuning the MoS 2 Edge-Site Activity for Hydrogen Evolution via Support Interactions
journal, February 2014
- Tsai, Charlie; Abild-Pedersen, Frank; Nørskov, Jens K.
- Nano Letters, Vol. 14, Issue 3
Anderson-type heteropolyanions of molybdenum(VI) and tungsten(VI)
journal, January 1987
- Nomiya, Kenji; Takahashi, Takeo; Shirai, Takahiro
- Polyhedron, Vol. 6, Issue 2
Precise tuning in platinum-nickel/nickel sulfide interface nanowires for synergistic hydrogen evolution catalysis
journal, February 2017
- Wang, Pengtang; Zhang, Xu; Zhang, Jin
- Nature Communications, Vol. 8, Issue 1
The chemistry of two-dimensional layered transition metal dichalcogenide nanosheets
journal, April 2013
- Chhowalla, Manish; Shin, Hyeon Suk; Eda, Goki
- Nature Chemistry, Vol. 5, Issue 4, p. 263-275
Chemically exfoliated single-layer : Stability, lattice dynamics, and catalytic adsorption from first principles
journal, December 2013
- Calandra, Matteo
- Physical Review B, Vol. 88, Issue 24
A Molecular MoS2 Edge Site Mimic for Catalytic Hydrogen Generation
journal, February 2012
- Karunadasa, H. I.; Montalvo, E.; Sun, Y.
- Science, Vol. 335, Issue 6069
Hydrogen evolution: Guiding principles
journal, September 2016
- Xia, Zhenhai
- Nature Energy, Vol. 1, Issue 10
Identification of Active Edge Sites for Electrochemical H2 Evolution from MoS2 Nanocatalysts
journal, July 2007
- Jaramillo, T. F.; Jorgensen, K. P.; Bonde, J.
- Science, Vol. 317, Issue 5834, p. 100-102
Energy Level Engineering of MoS 2 by Transition-Metal Doping for Accelerating Hydrogen Evolution Reaction
journal, October 2017
- Shi, Yi; Zhou, Yue; Yang, Dong-Rui
- Journal of the American Chemical Society, Vol. 139, Issue 43
Design of active and stable Co–Mo–Sx chalcogels as pH-universal catalysts for the hydrogen evolution reaction
journal, November 2015
- Staszak-Jirkovský, Jakub; Malliakas, Christos D.; Lopes, Pietro P.
- Nature Materials, Vol. 15, Issue 2
A graded catalytic–protective layer for an efficient and stable water-splitting photocathode
journal, January 2017
- Gu, Jing; Aguiar, Jeffery A.; Ferrere, Suzanne
- Nature Energy, Vol. 2, Issue 2
Unprecedented Replacement of Bridging Oxygen Atoms in Polyoxometalates with Organic Imido Ligands
journal, March 2008
- Hao, Jian; Xia, Yun; Wang, Longsheng
- Angewandte Chemie, Vol. 120, Issue 14
Alternative energy technologies
journal, January 2000
- Kolar, James L.
- Environmental Quality Management, Vol. 10, Issue 2
Phosphorus-Modified Tungsten Nitride/Reduced Graphene Oxide as a High-Performance, Non-Noble-Metal Electrocatalyst for the Hydrogen Evolution Reaction
journal, March 2015
- Yan, Haijing; Tian, Chungui; Wang, Lei
- Angewandte Chemie, Vol. 127, Issue 21
The Synthesis of Nanostructured Ni 5 P 4 Films and their Use as a Non-Noble Bifunctional Electrocatalyst for Full Water Splitting
journal, June 2015
- Ledendecker, Marc; Krick Calderón, Sandra; Papp, Christian
- Angewandte Chemie, Vol. 127, Issue 42
Biomimetic Hydrogen Evolution: MoS2 Nanoparticles as Catalyst for Hydrogen Evolution
journal, June 2005
- Hinnemann, Berit; Moses, Poul Georg; Bonde, Jacob
- ChemInform, Vol. 36, Issue 25
Interface Engineering of MoS 2 /Ni 3 S 2 Heterostructures for Highly Enhanced Electrochemical Overall-Water-Splitting Activity
journal, April 2016
- Zhang, Jian; Wang, Tao; Pohl, Darius
- Angewandte Chemie, Vol. 128, Issue 23
Porous MoO 2 Nanosheets as Non-noble Bifunctional Electrocatalysts for Overall Water Splitting
journal, March 2016
- Jin, Yanshuo; Wang, Haotian; Li, Junjie
- Advanced Materials, Vol. 28, Issue 19
Formation of Ni-Co-MoS 2 Nanoboxes with Enhanced Electrocatalytic Activity for Hydrogen Evolution
journal, August 2016
- Yu, Xin-Yao; Feng, Yi; Jeon, Yeryung
- Advanced Materials, Vol. 28, Issue 40
3D Nitrogen-Anion-Decorated Nickel Sulfides for Highly Efficient Overall Water Splitting
journal, June 2017
- Chen, Pengzuo; Zhou, Tianpei; Zhang, Mengxing
- Advanced Materials, Vol. 29, Issue 30
Phosphorus-Modified Tungsten Nitride/Reduced Graphene Oxide as a High-Performance, Non-Noble-Metal Electrocatalyst for the Hydrogen Evolution Reaction
journal, March 2015
- Yan, Haijing; Tian, Chungui; Wang, Lei
- Angewandte Chemie, Vol. 127, Issue 21
The Synthesis of Nanostructured Ni 5 P 4 Films and their Use as a Non-Noble Bifunctional Electrocatalyst for Full Water Splitting
journal, June 2015
- Ledendecker, Marc; Krick Calderón, Sandra; Papp, Christian
- Angewandte Chemie, Vol. 127, Issue 42
Interface Engineering of MoS 2 /Ni 3 S 2 Heterostructures for Highly Enhanced Electrochemical Overall-Water-Splitting Activity
journal, April 2016
- Zhang, Jian; Wang, Tao; Pohl, Darius
- Angewandte Chemie International Edition, Vol. 55, Issue 23
Gram-Scale Aqueous Synthesis of Stable Few-Layered 1T-MoS 2 : Applications for Visible-Light-Driven Photocatalytic Hydrogen Evolution
journal, August 2015
- Liu, Qin; Li, Xiuling; He, Qun
- Small, Vol. 11, Issue 41
Ab Initio Study of the H2–H2S/MoS2 Gas–Solid Interface: The Nature of the Catalytically Active Sites
journal, January 2000
- Raybaud, P.; Hafner, J.; Kresse, G.
- Journal of Catalysis, Vol. 189, Issue 1
A critical review of research progress for metal alloy materials in hydrogen evolution and oxygen evolution reaction
journal, December 2022
- Xu, Yuling; Zhang, Xinyi; Liu, Yanyan
- Environmental Science and Pollution Research, Vol. 30, Issue 5
Transition-metal doped edge sites in vertically aligned MoS2 catalysts for enhanced hydrogen evolution
journal, January 2015
- Wang, Haotian; Tsai, Charlie; Kong, Desheng
- Nano Research, Vol. 8, Issue 2
Resolving surface chemical states in XPS analysis of first row transition metals, oxides and hydroxides: Cr, Mn, Fe, Co and Ni
journal, January 2011
- Biesinger, Mark C.; Payne, Brad P.; Grosvenor, Andrew P.
- Applied Surface Science, Vol. 257, Issue 7, p. 2717-2730
Hydrogen production through sorption-enhanced steam methane reforming and membrane technology: A review
journal, April 2008
- Barelli, L.; Bidini, G.; Gallorini, F.
- Energy, Vol. 33, Issue 4
Interface engineering: The Ni(OH) 2 /MoS 2 heterostructure for highly efficient alkaline hydrogen evolution
journal, July 2017
- Zhang, Bao; Liu, Jia; Wang, Jinsong
- Nano Energy, Vol. 37
Hydrogen as an energy carrier: Prospects and challenges
journal, June 2012
- Mazloomi, Kaveh; Gomes, Chandima
- Renewable and Sustainable Energy Reviews, Vol. 16, Issue 5
Understanding Structure-Dependent Catalytic Performance of Nickel Selenides for Electrochemical Water Oxidation
journal, December 2016
- Xu, Kun; Ding, Hui; Lv, Haifeng
- ACS Catalysis, Vol. 7, Issue 1
Vertically Aligned Oxygenated-CoS 2 –MoS 2 Heteronanosheet Architecture from Polyoxometalate for Efficient and Stable Overall Water Splitting
journal, April 2018
- Hou, Jungang; Zhang, Bo; Li, Zhuwei
- ACS Catalysis, Vol. 8, Issue 5
Current Status of Hydrogen Production Techniques by Steam Reforming of Ethanol: A Review
journal, September 2005
- Haryanto, Agus; Fernando, Sandun; Murali, Naveen
- Energy & Fuels, Vol. 19, Issue 5
The Crystal Structure of Molybdenite
journal, June 1923
- Dickinson, Roscoe G.; Pauling, Linus
- Journal of the American Chemical Society, Vol. 45, Issue 6
Biomimetic Hydrogen Evolution: MoS 2 Nanoparticles as Catalyst for Hydrogen Evolution
journal, April 2005
- Hinnemann, Berit; Moses, Poul Georg; Bonde, Jacob
- Journal of the American Chemical Society, Vol. 127, Issue 15
MoS2 Nanoparticles Grown on Graphene An Advanced Catalyst for the Hydrogen Evolution Reaction
journal, May 2011
- Li, Yanguang; Wang, Hailiang; Xie, Liming
- Journal of the American Chemical Society, Vol. 133, Issue 19, p. 7296-7299
Controllable Disorder Engineering in Oxygen-Incorporated MoS 2 Ultrathin Nanosheets for Efficient Hydrogen Evolution
journal, November 2013
- Xie, Junfeng; Zhang, Jiajia; Li, Shuang
- Journal of the American Chemical Society, Vol. 135, Issue 47
Kinetic Study of Hydrogen Evolution Reaction over Strained MoS 2 with Sulfur Vacancies Using Scanning Electrochemical Microscopy
journal, April 2016
- Li, Hong; Du, Minshu; Mleczko, Michal J.
- Journal of the American Chemical Society, Vol. 138, Issue 15
All The Catalytic Active Sites of MoS 2 for Hydrogen Evolution
journal, December 2016
- Li, Guoqing; Zhang, Du; Qiao, Qiao
- Journal of the American Chemical Society, Vol. 138, Issue 51
Tuning the MoS 2 Edge-Site Activity for Hydrogen Evolution via Support Interactions
journal, February 2014
- Tsai, Charlie; Abild-Pedersen, Frank; Nørskov, Jens K.
- Nano Letters, Vol. 14, Issue 3
Self-Assembled Hierarchical MoO 2 /Graphene Nanoarchitectures and Their Application as a High-Performance Anode Material for Lithium-Ion Batteries
journal, August 2011
- Sun, Yongming; Hu, Xianluo; Luo, Wei
- ACS Nano, Vol. 5, Issue 9
Coherent Atomic and Electronic Heterostructures of Single-Layer MoS2
journal, July 2012
- Eda, Goki; Fujita, Takeshi; Yamaguchi, Hisato
- ACS Nano, Vol. 6, Issue 8, p. 7311-7317
The chemistry of two-dimensional layered transition metal dichalcogenide nanosheets
journal, April 2013
- Chhowalla, Manish; Shin, Hyeon Suk; Eda, Goki
- Nature Chemistry, Vol. 5, Issue 4, p. 263-275
Pure and stable metallic phase molybdenum disulfide nanosheets for hydrogen evolution reaction
journal, February 2016
- Geng, Xiumei; Sun, Weiwei; Wu, Wei
- Nature Communications, Vol. 7, Issue 1
Precise tuning in platinum-nickel/nickel sulfide interface nanowires for synergistic hydrogen evolution catalysis
journal, February 2017
- Wang, Pengtang; Zhang, Xu; Zhang, Jin
- Nature Communications, Vol. 8, Issue 1
Electrochemical generation of sulfur vacancies in the basal plane of MoS2 for hydrogen evolution
journal, April 2017
- Tsai, Charlie; Li, Hong; Park, Sangwook
- Nature Communications, Vol. 8, Issue 1
Bifunctional non-noble metal oxide nanoparticle electrocatalysts through lithium-induced conversion for overall water splitting
journal, June 2015
- Wang, Haotian; Lee, Hyun-Wook; Deng, Yong
- Nature Communications, Vol. 6, Issue 1
Hydrogen evolution: Guiding principles
journal, September 2016
- Xia, Zhenhai
- Nature Energy, Vol. 1, Issue 10
A graded catalytic–protective layer for an efficient and stable water-splitting photocathode
journal, January 2017
- Gu, Jing; Aguiar, Jeffery A.; Ferrere, Suzanne
- Nature Energy, Vol. 2, Issue 2
Design of active and stable Co–Mo–Sx chalcogels as pH-universal catalysts for the hydrogen evolution reaction
journal, November 2015
- Staszak-Jirkovský, Jakub; Malliakas, Christos D.; Lopes, Pietro P.
- Nature Materials, Vol. 15, Issue 2
The role of electronic coupling between substrate and 2D MoS2 nanosheets in electrocatalytic production of hydrogen
journal, June 2016
- Voiry, Damien; Fullon, Raymond; Yang, Jieun
- Nature Materials, Vol. 15, Issue 9
Polyoxometalate water oxidation catalysts and the production of green fuel
journal, January 2012
- Lv, Hongjin; Geletii, Yurii V.; Zhao, Chongchao
- Chemical Society Reviews, Vol. 41, Issue 22, p. 7572-7589
Recent developments in transition metal carbides and nitrides as hydrogen evolution electrocatalysts
journal, January 2013
- Chen, Wei-Fu; Muckerman, James T.; Fujita, Etsuko
- Chemical Communications, Vol. 49, Issue 79
Metal-free carbonaceous electrocatalysts and photocatalysts for water splitting
journal, January 2016
- Xu, You; Kraft, Markus; Xu, Rong
- Chemical Society Reviews, Vol. 45, Issue 11
Polyoxometalate precursors for precisely controlled synthesis of bimetallic sulfide heterostructure through nucleation-doping competition
journal, January 2018
- Tang, Yu-Jia; Zhang, A-Man; Zhu, Hong-Jing
- Nanoscale, Vol. 10, Issue 18
A Molecular MoS2 Edge Site Mimic for Catalytic Hydrogen Generation
journal, February 2012
- Karunadasa, H. I.; Montalvo, E.; Sun, Y.
- Science, Vol. 335, Issue 6069
In Situ X-Ray Absorption Spectroscopic Studies of Nickel Oxide Electrodes
journal, January 1990
- Pandya, K. I.
- Journal of The Electrochemical Society, Vol. 137, Issue 2
Self-optimizing layered hydrogen evolution catalyst with high basal-plane activity
text, January 2016
- Liu, Yuanyue; Wu, Jingjie; Hackenberg, Ken P.
- arXiv
Works referencing / citing this record:
Theoretical Analysis of Surface Active Sites in Defective 2H and 1T′ MoS 2 Polymorphs for Hydrogen Evolution Reaction: Quantifying the Total Activity of Point Defects
journal, January 2020
- Ekspong, Joakim; Gracia‐Espino, Eduardo
- Advanced Theory and Simulations, Vol. 3, Issue 3
Defect‐Rich Heterogeneous MoS 2 /NiS 2 Nanosheets Electrocatalysts for Efficient Overall Water Splitting
journal, May 2019
- Lin, Jinghuang; Wang, Pengcheng; Wang, Haohan
- Advanced Science, Vol. 6, Issue 14
Surface Engineering of MoS 2 via Laser‐Induced Exfoliation in Protic Solvents
journal, September 2019
- Gao, Zhi‐Wen; Liu, Mengjie; Zheng, Weiran
- Small, Vol. 15, Issue 44
Single‐Atom Ru Doping Induced Phase Transition of MoS 2 and S Vacancy for Hydrogen Evolution Reaction
journal, August 2019
- Zhang, Junmeng; Xu, Xiaopei; Yang, Liu
- Small Methods, Vol. 3, Issue 12
Overcoming the barrier of conventional electrochemical deposition of inorganic composites
journal, January 2020
- Geuli, Ori; Mandler, Daniel
- Chemical Communications, Vol. 56, Issue 3
Ta 3 N 5 nanorods encapsulated into 3D hydrangea-like MoS 2 for enhanced photocatalytic hydrogen evolution under visible light irradiation
journal, January 2019
- Pei, Lang; Yuan, Yongjun; Zhong, Jiasong
- Dalton Transactions, Vol. 48, Issue 35
A facile alkali metal hydroxide-assisted controlled and targeted synthesis of 1T MoS 2 single-crystal nanosheets for lithium ion battery anodes
journal, January 2019
- Li, Zhao; Zhan, Xun; Qi, Shuhua
- Nanoscale, Vol. 11, Issue 31
[MW 12 O 44 ] clusters: unprecedented central heteroatoms atomically dispersed in the eight coordination state bridging the 1 : 12 polyoxometalate family of Keggin and Silverton
journal, January 2019
- Chen, Yongdong; Tian, Shanli; Qin, Zhaoxian
- Nanoscale, Vol. 11, Issue 46
An in-plane Co 9 S 8 @MoS 2 heterostructure for the hydrogen evolution reaction in alkaline media
journal, January 2019
- Diao, Lechen; Zhang, Biao; Sun, Qiaozhi
- Nanoscale, Vol. 11, Issue 44
Self-supported MoP nanocrystals embedded in N,P-codoped carbon nanofibers via a polymer-confinement route for electrocatalytic hydrogen production
journal, January 2019
- Ren, Jin-Tao; Chen, Lei; Weng, Chen-Chen
- Materials Chemistry Frontiers, Vol. 3, Issue 9
Visualizing spatial potential and charge distribution in Ru/N-doped carbon electrocatalysts for superior hydrogen evolution reaction
journal, January 2019
- Liu, Jiwei; Ding, Guangzhou; Yu, Jieyi
- Journal of Materials Chemistry A, Vol. 7, Issue 30
FeP 3 monolayer as a high-efficiency catalyst for hydrogen evolution reaction
journal, January 2019
- Zheng, Shuang; Yu, Tong; Lin, Jianyan
- Journal of Materials Chemistry A, Vol. 7, Issue 44
Nickel nanograins anchored on a carbon framework for an efficient hydrogen evolution electrocatalyst and a flexible electrode
journal, January 2020
- Zhang, Zhiwei; Deng, Linjie; Zhao, Zhe
- Journal of Materials Chemistry A, Vol. 8, Issue 6
Heterometallic multinuclear nodes directing MOF electronic behavior
journal, January 2020
- Ejegbavwo, Otega A.; Berseneva, Anna A.; Martin, Corey R.
- Chemical Science, Vol. 11, Issue 28
Defect‐Rich Heterogeneous MoS 2 /NiS 2 Nanosheets Electrocatalysts for Efficient Overall Water Splitting
journal, May 2019
- Lin, Jinghuang; Wang, Pengcheng; Wang, Haohan
- Advanced Science, Vol. 6, Issue 14
Advanced Ultrathin RuPdM (M = Ni, Co, Fe) Nanosheets Electrocatalyst Boosts Hydrogen Evolution
journal, December 2019
- Zhang, Dan; Zhao, Huan; Huang, Bolong
- ACS Central Science, Vol. 5, Issue 12
Effect of Structural Phases on Mechanical Properties of Molybdenum Disulfide
journal, March 2020
- Imani Yengejeh, Sadegh; Liu, Junxian; Kazemi, Seyedeh Alieh
- ACS Omega, Vol. 5, Issue 11
Figures / Tables found in this record: