Measurement–model comparison of stabilized Criegee intermediate and highly oxygenated molecule production in the CLOUD chamber
Abstract
Abstract. Atmospheric oxidation is an important phenomenon which produces large quantities of low-volatility compounds such as sulfuric acid and oxidized organic compounds. Such species may be involved in the nucleation of particles and enhance their subsequent growth to reach the size of cloud condensation nuclei (CCN). In this study, we investigate α-pinene, the most abundant monoterpene globally, and its oxidation products formed through ozonolysis in the Cosmic Leaving Outdoor Droplets (CLOUD) chamber at CERN(the European Organization for Nuclear Research). By scavenging hydroxyl radicals (OH) with hydrogen (H2), we were able to investigate the formation of highly oxygenated molecules (HOMs) purely driven by ozonolysis and study the oxidation of sulfur dioxide (SO2) driven by stabilized Criegee intermediates (sCIs). We measured the concentrations of HOM and sulfuric acid with a chemical ionization atmospheric-pressure interface time-of-flight (CI-APi-TOF) mass spectrometer and compared the measured concentrations with simulated concentrations calculated with a kinetic model.We found molar yields in the range of 3.5–6.5% for HOM formation and 22–32% for the formation of stabilized Criegee intermediates by fitting our model to the measured sulfuric acid concentrations. The simulated time evolution of the ozonolysis products was in good agreement with measured concentrations except that in some of themore »
- Authors:
-
[1];
[1];
[2];
[1];
[3];
[6];
[1];
[1];
more »
- Univ. of Helsinki, Helsinki (Finland)
- Univ. of Eastern Finland, Kuopio (Finland)
- Univ. of Helsinki, Helsinki (Finland); Univ. of Eastern Finland, Kuopio (Finland); Univ. of Washington, Seattle, WA (United States)
- Goethe Univ. Frankfurt, Frankfurt am Main (Germany)
- Goethe Univ. Frankfurt, Frankfurt am Main (Germany); Max-Planck Institute of Chemistry, Mainz (Germany)
- Univ. of Helsinki, Helsinki (Finland); Paul Scherrer Inst. (PSI), Villigen (Switzerland)
- Paul Scherrer Inst. (PSI), Villigen (Switzerland)
- Univ. of Innsbruck, Innsbruck (Austria)
- Univ. of California, Irvine, CA (United States)
- Finnish Meteorological Institute, Helsinki (Finland)
- CENTRA, Lisbon (Portugal)
- Tofwerk AG, Thun (Switzerland)
- Goethe Univ. Frankfurt, Frankfurt am Main (Germany); European Organization for Nuclear Research (CERN), Geneva (Switzerland)
- Univ. of Helsinki, Helsinki (Finland); Aerodyne Research Inc., Billerica, MA (United States)
- Univ. of Helsinki, Helsinki (Finland); Carnegie Mellon Univ., Pittsburgh, PA (United States)
- Publication Date:
- Research Org.:
- Univ. of California, Irvine, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1505587
- Grant/Contract Number:
- SC0014469
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Atmospheric Chemistry and Physics (Online)
- Additional Journal Information:
- Journal Name: Atmospheric Chemistry and Physics (Online); Journal Volume: 18; Journal Issue: 4; Journal ID: ISSN 1680-7324
- Publisher:
- European Geosciences Union
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 54 ENVIRONMENTAL SCIENCES
Citation Formats
Sarnela, Nina, Jokinen, Tuija, Duplissy, Jonathan, Yan, Chao, Nieminen, Tuomo, Ehn, Mikael, Schobesberger, Siegfried, Heinritzi, Martin, Ehrhart, Sebastian, Lehtipalo, Katrianne, Tröstl, Jasmin, Simon, Mario, Kürten, Andreas, Leiminger, Markus, Lawler, Michael J., Rissanen, Matti P., Bianchi, Federico, Praplan, Arnaud P., Hakala, Jani, Amorim, Antonio, Gonin, Marc, Hansel, Armin, Kirkby, Jasper, Dommen, Josef, Curtius, Joachim, Smith, James N., Petäjä, Tuukka, Worsnop, Douglas R., Kulmala, Markku, Donahue, Neil M., and Sipilä, Mikko. Measurement–model comparison of stabilized Criegee intermediate and highly oxygenated molecule production in the CLOUD chamber. United States: N. p., 2018.
Web. doi:10.5194/acp-18-2363-2018.
Sarnela, Nina, Jokinen, Tuija, Duplissy, Jonathan, Yan, Chao, Nieminen, Tuomo, Ehn, Mikael, Schobesberger, Siegfried, Heinritzi, Martin, Ehrhart, Sebastian, Lehtipalo, Katrianne, Tröstl, Jasmin, Simon, Mario, Kürten, Andreas, Leiminger, Markus, Lawler, Michael J., Rissanen, Matti P., Bianchi, Federico, Praplan, Arnaud P., Hakala, Jani, Amorim, Antonio, Gonin, Marc, Hansel, Armin, Kirkby, Jasper, Dommen, Josef, Curtius, Joachim, Smith, James N., Petäjä, Tuukka, Worsnop, Douglas R., Kulmala, Markku, Donahue, Neil M., & Sipilä, Mikko. Measurement–model comparison of stabilized Criegee intermediate and highly oxygenated molecule production in the CLOUD chamber. United States. https://doi.org/10.5194/acp-18-2363-2018
Sarnela, Nina, Jokinen, Tuija, Duplissy, Jonathan, Yan, Chao, Nieminen, Tuomo, Ehn, Mikael, Schobesberger, Siegfried, Heinritzi, Martin, Ehrhart, Sebastian, Lehtipalo, Katrianne, Tröstl, Jasmin, Simon, Mario, Kürten, Andreas, Leiminger, Markus, Lawler, Michael J., Rissanen, Matti P., Bianchi, Federico, Praplan, Arnaud P., Hakala, Jani, Amorim, Antonio, Gonin, Marc, Hansel, Armin, Kirkby, Jasper, Dommen, Josef, Curtius, Joachim, Smith, James N., Petäjä, Tuukka, Worsnop, Douglas R., Kulmala, Markku, Donahue, Neil M., and Sipilä, Mikko. Mon .
"Measurement–model comparison of stabilized Criegee intermediate and highly oxygenated molecule production in the CLOUD chamber". United States. https://doi.org/10.5194/acp-18-2363-2018. https://www.osti.gov/servlets/purl/1505587.
@article{osti_1505587,
title = {Measurement–model comparison of stabilized Criegee intermediate and highly oxygenated molecule production in the CLOUD chamber},
author = {Sarnela, Nina and Jokinen, Tuija and Duplissy, Jonathan and Yan, Chao and Nieminen, Tuomo and Ehn, Mikael and Schobesberger, Siegfried and Heinritzi, Martin and Ehrhart, Sebastian and Lehtipalo, Katrianne and Tröstl, Jasmin and Simon, Mario and Kürten, Andreas and Leiminger, Markus and Lawler, Michael J. and Rissanen, Matti P. and Bianchi, Federico and Praplan, Arnaud P. and Hakala, Jani and Amorim, Antonio and Gonin, Marc and Hansel, Armin and Kirkby, Jasper and Dommen, Josef and Curtius, Joachim and Smith, James N. and Petäjä, Tuukka and Worsnop, Douglas R. and Kulmala, Markku and Donahue, Neil M. and Sipilä, Mikko},
abstractNote = {Abstract. Atmospheric oxidation is an important phenomenon which produces large quantities of low-volatility compounds such as sulfuric acid and oxidized organic compounds. Such species may be involved in the nucleation of particles and enhance their subsequent growth to reach the size of cloud condensation nuclei (CCN). In this study, we investigate α-pinene, the most abundant monoterpene globally, and its oxidation products formed through ozonolysis in the Cosmic Leaving Outdoor Droplets (CLOUD) chamber at CERN(the European Organization for Nuclear Research). By scavenging hydroxyl radicals (OH) with hydrogen (H2), we were able to investigate the formation of highly oxygenated molecules (HOMs) purely driven by ozonolysis and study the oxidation of sulfur dioxide (SO2) driven by stabilized Criegee intermediates (sCIs). We measured the concentrations of HOM and sulfuric acid with a chemical ionization atmospheric-pressure interface time-of-flight (CI-APi-TOF) mass spectrometer and compared the measured concentrations with simulated concentrations calculated with a kinetic model.We found molar yields in the range of 3.5–6.5% for HOM formation and 22–32% for the formation of stabilized Criegee intermediates by fitting our model to the measured sulfuric acid concentrations. The simulated time evolution of the ozonolysis products was in good agreement with measured concentrations except that in some of the experiments sulfuric acid formation was faster than simulated. In those experiments the simulated and measured concentrations met when the concentration reached a plateau but the plateau was reached 20–50min later in the simulations. The results shown here are consistent with the recently published yields for HOM formation from different laboratory experiments. Together with the sCI yields, these results help us to understand atmospheric oxidation processes better and make there action parameters more comprehensive for broader use.},
doi = {10.5194/acp-18-2363-2018},
journal = {Atmospheric Chemistry and Physics (Online)},
number = 4,
volume = 18,
place = {United States},
year = {Mon Feb 19 00:00:00 EST 2018},
month = {Mon Feb 19 00:00:00 EST 2018}
}
Free Publicly Available Full Text
Publisher's Version of Record
Other availability
Search WorldCat to find libraries that may hold this journal
Cited by: 14 works
Citation information provided by
Web of Science
Web of Science
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Gas-Phase Ozonolysis of Selected Olefins: The Yield of Stabilized Criegee Intermediate and the Reactivity toward SO 2
journal, September 2012
- Berndt, Torsten; Jokinen, Tuija; Mauldin, Roy L.
- The Journal of Physical Chemistry Letters, Vol. 3, Issue 19
The reaction of Criegee intermediates with NO, RO2, and SO2, and their fate in the atmosphere
journal, January 2012
- Vereecken, L.; Harder, H.; Novelli, A.
- Physical Chemistry Chemical Physics, Vol. 14, Issue 42
Sulfuric acid and OH concentrations in a boreal forest site
journal, January 2009
- Petäjä, T.; Mauldin, III, R. L.; Kosciuch, E.
- Atmospheric Chemistry and Physics, Vol. 9, Issue 19
Competing atmospheric reactions of CH 2 OO with SO 2 and water vapour
journal, January 2014
- Berndt, Torsten; Voigtländer, Jens; Stratmann, Frank
- Physical Chemistry Chemical Physics, Vol. 16, Issue 36
The reactions of Criegee intermediates with alkenes, ozone, and carbonyl oxides
journal, January 2014
- Vereecken, L.; Harder, H.; Novelli, A.
- Physical Chemistry Chemical Physics, Vol. 16, Issue 9
Organic condensation: a vital link connecting aerosol formation to cloud condensation nuclei (CCN) concentrations
journal, January 2011
- Riipinen, I.; Pierce, J. R.; Yli-Juuti, T.
- Atmospheric Chemistry and Physics, Vol. 11, Issue 8
Molecular-scale evidence of aerosol particle formation via sequential addition of HIO3
journal, August 2016
- Sipilä, Mikko; Sarnela, Nina; Jokinen, Tuija
- Nature, Vol. 537, Issue 7621
Parametric sensitivity and uncertainty analysis of dimethylsulfide oxidation in the clear-sky remote marine boundary layer
journal, January 2005
- Lucas, D. D.; Prinn, R. G.
- Atmospheric Chemistry and Physics, Vol. 5, Issue 6
New particle formation in the free troposphere: A question of chemistry and timing
journal, May 2016
- Bianchi, F.; Trostl, J.; Junninen, H.
- Science, Vol. 352, Issue 6289
Numerical simulations of mixing conditions and aerosol dynamics in the CERN CLOUD chamber
journal, January 2012
- Voigtländer, J.; Duplissy, J.; Rondo, L.
- Atmospheric Chemistry and Physics, Vol. 12, Issue 4
Evaluated kinetic and photochemical data for atmospheric chemistry: Volume II – gas phase reactions of organic species
journal, January 2006
- Atkinson, R.; Baulch, D. L.; Cox, R. A.
- Atmospheric Chemistry and Physics, Vol. 6, Issue 11
Mechanism of Ozonolysis
journal, November 1975
- Criegee, Rudolf
- Angewandte Chemie International Edition in English, Vol. 14, Issue 11
Laboratory studies of particle nucleation: Initial results for H 2 SO 4 , H 2 O, and NH 3 vapors
journal, October 1999
- Ball, S. M.; Hanson, D. R.; Eisele, F. L.
- Journal of Geophysical Research: Atmospheres, Vol. 104, Issue D19
Oxidation of Atmospheric SO2 by Products of the Ozone–Olefin Reaction
journal, April 1971
- Cox, R. A.; Penkett, S. A.
- Nature, Vol. 230, Issue 5292
Measurement of the gas phase concentration of H 2 SO 4 and methane sulfonic acid and estimates of H 2 SO 4 production and loss in the atmosphere
journal, May 1993
- Eisele, F. L.; Tanner, D. J.
- Journal of Geophysical Research: Atmospheres, Vol. 98, Issue D5
The role of low-volatility organic compounds in initial particle growth in the atmosphere
journal, May 2016
- Tröstl, Jasmin; Chuang, Wayne K.; Gordon, Hamish
- Nature, Vol. 533, Issue 7604
A global model of natural volatile organic compound emissions
journal, January 1995
- Guenther, Alex; Hewitt, C. Nicholas; Erickson, David
- Journal of Geophysical Research, Vol. 100, Issue D5
Amines are likely to enhance neutral and ion-induced sulfuric acid-water nucleation in the atmosphere more effectively than ammonia
journal, January 2008
- Kurtén, T.; Loukonen, V.; Vehkamäki, H.
- Atmospheric Chemistry and Physics, Vol. 8, Issue 14
Oxidation Products of Biogenic Emissions Contribute to Nucleation of Atmospheric Particles
journal, May 2014
- Riccobono, F.; Schobesberger, S.; Scott, C. E.
- Science, Vol. 344, Issue 6185
Rapid Autoxidation Forms Highly Oxidized RO 2 Radicals in the Atmosphere
journal, October 2014
- Jokinen, Tuija; Sipilä, Mikko; Richters, Stefanie
- Angewandte Chemie International Edition, Vol. 53, Issue 52
Neutral molecular cluster formation of sulfuric acid–dimethylamine observed in real time under atmospheric conditions
journal, October 2014
- Kürten, Andreas; Jokinen, Tuija; Simon, Mario
- Proceedings of the National Academy of Sciences, Vol. 111, Issue 42
On-line monitoring of volatile organic compounds at pptv levels by means of proton-transfer-reaction mass spectrometry (PTR-MS) medical applications, food control and environmental research
journal, February 1998
- Lindinger, W.; Hansel, A.; Jordan, A.
- International Journal of Mass Spectrometry and Ion Processes, Vol. 173, Issue 3
Role of sulphuric acid, ammonia and galactic cosmic rays in atmospheric aerosol nucleation
journal, August 2011
- Kirkby, Jasper; Curtius, Joachim; Almeida, João
- Nature, Vol. 476, Issue 7361
A new atmospherically relevant oxidant of sulphur dioxide
journal, August 2012
- Mauldin III, R. L.; Berndt, T.; Sipilä, M.
- Nature, Vol. 488, Issue 7410
Photochemical production of aerosols from real plant emissions
journal, January 2009
- Mentel, Th. F.; Wildt, J.; Kiendler-Scharr, A.
- Atmospheric Chemistry and Physics, Vol. 9, Issue 13
Cycloalkene Ozonolysis: Collisionally Mediated Mechanistic Branching
journal, October 2004
- Chuong, Bao; Zhang, Jieyuan; Donahue, Neil M.
- Journal of the American Chemical Society, Vol. 126, Issue 39
Sulphuric acid and aerosol particle production in the vicinity of an oil refinery
journal, October 2015
- Sarnela, Nina; Jokinen, Tuija; Nieminen, Tuomo
- Atmospheric Environment, Vol. 119
A two-dimensional volatility basis set – Part 2: Diagnostics of organic-aerosol evolution
journal, January 2012
- Donahue, N. M.; Kroll, J. H.; Pandis, S. N.
- Atmospheric Chemistry and Physics, Vol. 12, Issue 2
O RGANIC A TMOSPHERIC P ARTICULATE M ATERIAL
journal, October 2003
- Seinfeld, John H.; Pankow, James F.
- Annual Review of Physical Chemistry, Vol. 54, Issue 1
Role of stabilized Criegee Intermediate in secondary organic aerosol formation from the ozonolysis of α-cedrene
journal, September 2014
- Yao, Lei; Ma, Yan; Wang, Lin
- Atmospheric Environment, Vol. 94
Effect of ions on sulfuric acid-water binary particle formation: 2. Experimental data and comparison with QC-normalized classical nucleation theory: BINARY PARTICLE FORMATION EXPERIMENTS
journal, February 2016
- Duplissy, J.; Merikanto, J.; Franchin, A.
- Journal of Geophysical Research: Atmospheres, Vol. 121, Issue 4
The gas-phase ozonolysis of unsaturated volatile organic compounds in the troposphere
journal, January 2008
- Johnson, David; Marston, George
- Chemical Society Reviews, Vol. 37, Issue 4
Direct Kinetic Measurements of Criegee Intermediate (CH2OO) Formed by Reaction of CH2I with O2
journal, January 2012
- Welz, O.; Savee, J. D.; Osborn, D. L.
- Science, Vol. 335, Issue 6065
Formation and growth rates of ultrafine atmospheric particles: a review of observations
journal, March 2004
- Kulmala, M.; Vehkamäki, H.; Petäjä, T.
- Journal of Aerosol Science, Vol. 35, Issue 2
Oxidation of SO 2 by stabilized Criegee intermediate (sCI) radicals as a crucial source for atmospheric sulfuric acid concentrations
journal, January 2013
- Boy, M.; Mogensen, D.; Smolander, S.
- Atmospheric Chemistry and Physics, Vol. 13, Issue 7
Elemental composition and clustering behaviour of α-pinene oxidation products for different oxidation conditions
journal, January 2015
- Praplan, A. P.; Schobesberger, S.; Bianchi, F.
- Atmospheric Chemistry and Physics, Vol. 15, Issue 8
A Medium Flow, High-Resolution Vienna DMA Running in Recirculating Mode
journal, February 2010
- Steiner, G.; Attoui, M.; Wimmer, D.
- Aerosol Science and Technology, Vol. 44, Issue 4
A statistical proxy for sulphuric acid concentration
journal, January 2011
- Mikkonen, S.; Romakkaniemi, S.; Smith, J. N.
- Atmospheric Chemistry and Physics, Vol. 11, Issue 21
Measurements of new particle formation and ultrafine particle growth rates at a clean continental site
journal, February 1997
- Weber, R. J.; Marti, J. J.; McMurry, P. H.
- Journal of Geophysical Research: Atmospheres, Vol. 102, Issue D4
H2SO4 formation from the gas-phase reaction of stabilized Criegee Intermediates with SO2: Influence of water vapour content and temperature
journal, June 2014
- Berndt, Torsten; Jokinen, Tuija; Sipilä, Mikko
- Atmospheric Environment, Vol. 89
Enhancement of atmospheric H 2 SO 4 / H 2 O nucleation: organic oxidation products versus amines
journal, January 2014
- Berndt, T.; Sipilä, M.; Stratmann, F.
- Atmospheric Chemistry and Physics, Vol. 14, Issue 2
A high-resolution mass spectrometer to measure atmospheric ion composition
journal, January 2010
- Junninen, H.; Ehn, M.; Petäjä, T.
- Atmospheric Measurement Techniques, Vol. 3, Issue 4
Kinetics and energetics of the criegee intermediate in the gas phase. I. The criegee intermediate in ozone-alkene reactions
journal, March 1982
- Herron, John T.; Martinez, Richard I.; Huie, Robert E.
- International Journal of Chemical Kinetics, Vol. 14, Issue 3
On the formation of sulphuric acid – amine clusters in varying atmospheric conditions and its influence on atmospheric new particle formation
journal, January 2012
- Paasonen, P.; Olenius, T.; Kupiainen, O.
- Atmospheric Chemistry and Physics, Vol. 12, Issue 19
Gas phase formation of extremely oxidized pinene reaction products in chamber and ambient air
journal, January 2012
- Ehn, M.; Kleist, E.; Junninen, H.
- Atmospheric Chemistry and Physics, Vol. 12, Issue 11
Pressure Dependence of Stabilized Criegee Intermediate Formation from a Sequence of Alkenes
journal, May 2011
- Drozd, Greg T.; Donahue, Neil M.
- The Journal of Physical Chemistry A, Vol. 115, Issue 17
Performance of a corona ion source for measurement of sulfuric acid by chemical ionization mass spectrometry
journal, January 2011
- Kürten, A.; Rondo, L.; Ehrhart, S.
- Atmospheric Measurement Techniques, Vol. 4, Issue 3
Organic aerosol formation from the oxidation of biogenic hydrocarbons
journal, February 1999
- Griffin, Robert J.; Cocker, David R.; Flagan, Richard C.
- Journal of Geophysical Research: Atmospheres, Vol. 104, Issue D3
Modeling the Charging of Highly Oxidized Cyclohexene Ozonolysis Products Using Nitrate-Based Chemical Ionization
journal, May 2015
- Hyttinen, Noora; Kupiainen-Määttä, Oona; Rissanen, Matti P.
- The Journal of Physical Chemistry A, Vol. 119, Issue 24
A large source of low-volatility secondary organic aerosol
journal, February 2014
- Ehn, Mikael; Thornton, Joel A.; Kleist, Einhard
- Nature, Vol. 506, Issue 7489
Laboratory study on new particle formation from the reaction OH + SO 2 : influence of experimental conditions, H 2 O vapour, NH 3 and the amine tert-butylamine on the overall process
journal, January 2010
- Berndt, T.; Stratmann, F.; Sipilä, M.
- Atmospheric Chemistry and Physics, Vol. 10, Issue 15
The contribution of sulfuric acid and non-volatile compounds on the growth of freshly formed atmospheric aerosols: GROWTH OF FRESHLY FORMED AEROSOLS
journal, September 2005
- Wehner, B.; Petäjä, T.; Boy, M.
- Geophysical Research Letters, Vol. 32, Issue 17
Adventures in ozoneland: down the rabbit-hole
journal, January 2011
- Donahue, Neil M.; Drozd, Greg T.; Epstein, Scott A.
- Physical Chemistry Chemical Physics, Vol. 13, Issue 23
Thermal stability of carbonyl radicals Part I. Straight-chain and branched C4 and C5 acyl radicals
journal, January 2000
- Jagiella, S.; Libuda, H. G.; Zabel, F.
- Physical Chemistry Chemical Physics, Vol. 2, Issue 6
Source characterization of highly oxidized multifunctional compounds in a boreal forest environment using positive matrix factorization
journal, January 2016
- Yan, Chao; Nie, Wei; Äijälä, Mikko
- Atmospheric Chemistry and Physics, Vol. 16, Issue 19
Reactivity of stabilized Criegee intermediates (sCIs) from isoprene and monoterpene ozonolysis toward SO 2 and organic acids
journal, January 2014
- Sipilä, M.; Jokinen, T.; Berndt, T.
- Atmospheric Chemistry and Physics, Vol. 14, Issue 22
On the formation, growth and composition of nucleation mode particles
journal, January 2001
- Kulmala, M.; Maso, M. Dal; Mäkelä, J. M.
- Tellus B: Chemical and Physical Meteorology, Vol. 53, Issue 4
Kinetics of a Criegee intermediate that would survive high humidity and may oxidize atmospheric SO 2
journal, August 2015
- Huang, Hao-Li; Chao, Wen; Lin, Jim Jr-Min
- Proceedings of the National Academy of Sciences, Vol. 112, Issue 35
Rapid Formation of Sulfuric Acid Particles at Near-Atmospheric Conditions
journal, February 2005
- Berndt, T.
- Science, Vol. 307, Issue 5710
Toward Reconciling Measurements of Atmospherically Relevant Clusters by Chemical Ionization Mass Spectrometry and Mobility Classification/Vapor Condensation
journal, December 2014
- Jen, Coty N.; Hanson, David R.; McMurry, Peter H.
- Aerosol Science and Technology, Vol. 49, Issue 1
Molecular understanding of sulphuric acid–amine particle nucleation in the atmosphere
journal, October 2013
- Almeida, João; Schobesberger, Siegfried; Kürten, Andreas
- Nature, Vol. 502, Issue 7471
The Formation of Highly Oxidized Multifunctional Products in the Ozonolysis of Cyclohexene
journal, October 2014
- Rissanen, Matti P.; Kurtén, Theo; Sipilä, Mikko
- Journal of the American Chemical Society, Vol. 136, Issue 44
Direct Measurements of Conformer-Dependent Reactivity of the Criegee Intermediate CH3CHOO
journal, April 2013
- Taatjes, C. A.; Welz, O.; Eskola, A. J.
- Science, Vol. 340, Issue 6129
Ion-induced nucleation of pure biogenic particles
journal, May 2016
- Kirkby, Jasper; Duplissy, Jonathan; Sengupta, Kamalika
- Nature, Vol. 533, Issue 7604
The mathematical principles and design of the NAIS – a spectrometer for the measurement of cluster ion and nanometer aerosol size distributions
journal, January 2013
- Mirme, S.; Mirme, A.
- Atmospheric Measurement Techniques, Vol. 6, Issue 4
Effect of ions on the measurement of sulfuric acid in the CLOUD experiment at CERN
journal, January 2014
- Rondo, L.; Kürten, A.; Ehrhart, S.
- Atmospheric Measurement Techniques, Vol. 7, Issue 11
Atmospheric sulphuric acid and aerosol formation: implications from atmospheric measurements for nucleation and early growth mechanisms
journal, January 2006
- Sihto, S. -L.; Kulmala, M.; Kerminen, V. -M.
- Atmospheric Chemistry and Physics, Vol. 6, Issue 12
Secondary aerosol formation from atmospheric reactions of aliphatic amines
journal, January 2007
- Murphy, S. M.; Sorooshian, A.; Kroll, J. H.
- Atmospheric Chemistry and Physics, Vol. 7, Issue 9
Marine aerosol formation from biogenic iodine emissions
journal, June 2002
- O'Dowd, Colin D.; Jimenez, Jose L.; Bahreini, Roya
- Nature, Vol. 417, Issue 6889
Scanning Electrical Mobility Spectrometer
journal, January 1990
- Wang, Shih Chen; Flagan, Richard C.
- Aerosol Science and Technology, Vol. 13, Issue 2
Calibration of a Chemical Ionization Mass Spectrometer for the Measurement of Gaseous Sulfuric Acid
journal, February 2012
- Kürten, Andreas; Rondo, Linda; Ehrhart, Sebastian
- The Journal of Physical Chemistry A, Vol. 116, Issue 24
Atmospheric sulphuric acid and neutral cluster measurements using CI-APi-TOF
journal, January 2012
- Jokinen, T.; Sipilä, M.; Junninen, H.
- Atmospheric Chemistry and Physics, Vol. 12, Issue 9
Production of extremely low volatile organic compounds from biogenic emissions: Measured yields and atmospheric implications
journal, May 2015
- Jokinen, Tuija; Berndt, Torsten; Makkonen, Risto
- Proceedings of the National Academy of Sciences, Vol. 112, Issue 23
Measured Atmospheric new Particle Formation Rates: Implications for Nucleation Mechanisms
journal, September 1996
- Weber, R. J.; Marti, J. J.; McMURRY, P. H.
- Chemical Engineering Communications, Vol. 151, Issue 1
Ion-polar molecule collisions. Effect of molecular size on ion-polar molecule rate constants
journal, November 1973
- Su, Timothy.; Bowers, Michael T.
- Journal of the American Chemical Society, Vol. 95, Issue 23
Mechanism of ozonolysis
journal, October 1968
- Murray, Robert W.
- Accounts of Chemical Research, Vol. 1, Issue 10
Toward Reconciling Measurements of Atmospherically Relevant Clusters by Chemical Ionization Mass Spectrometry and Mobility Classification/Vapor Condensation
text, January 2015
- Jen, Coty N.; Hanson, David R.; McMurry, Peter H.
- Taylor & Francis
A two-dimensional volatility basis set – Part 2: Diagnostics of organic-aerosol evolution
text, January 2012
- Donahue, Neil; Kroll, J. H.; Pandis, Spyros N.
- Carnegie Mellon University
Organic condensation: a vital link connecting aerosol formation to cloud condensation nuclei (CCN) concentrations
text, January 2011
- Riipinen, I.; Pierce, J. R.; Yli-Juuti, T.
- Carnegie Mellon University
Numerical simulations of mixing conditions and aerosol dynamics in the CERN CLOUD chamber
other, January 2012
- Voigtländer, J.; Duplissy, J.; Rondo, L.
- München : European Geopyhsical Union
Elemental composition and clustering behaviour of α-pinene oxidation products for different oxidation conditions
text, January 2015
- Praplan, Arnaud P.; Schobesberger, Siegfried; Bianchi, Frederico
- ETH Zurich
Towards Reconciling Measurements of Atmospherically Relevant Clusters by Chemical Ionization Mass Spectrometry and Mobility Classification/Vapor Condensation
text, January 2015
- Jen, Coty N.; Hanson, David R.; McMurry, Peter H.
- Taylor & Francis
On the formation, growth and composition of nucleation mode particles
journal, September 2001
- Kulmala, M.; Maso, M. Dal; MÄKelÄ, J. M.
- Tellus B, Vol. 53, Issue 4
Toward Reconciling Measurements of Atmospherically Relevant Clusters by Chemical Ionization Mass Spectrometry and Mobility Classification/Vapor Condensation
text, January 2015
- Jen, Coty N.; Hanson, David R.; McMurry, Peter H.
- Taylor & Francis
Ion-induced nucleation of pure biogenic particles
text, January 2016
- Kirkby, Jasper; Frege, Carla; Tröstl, Jasmin
- ETH Zurich
Toward Reconciling Measurements of Atmospherically Relevant Clusters by Chemical Ionization Mass Spectrometry and Mobility Classification/Vapor Condensation
text, January 2015
- Jen, Coty N.; Hanson, David R.; McMurry, Peter H.
- Taylor & Francis
A two-dimensional volatility basis set – Part 2: Diagnostics of organic-aerosol evolution
text, January 2012
- Donahue, Neil; Kroll, J. H.; Pandis, Spyros N.
- Carnegie Mellon University
Effect of dimethylamine on the gas phase sulfuric acid concentration measured by Chemical Ionization Mass Spectrometry
journal, March 2016
- Rondo, L.; Ehrhart, S.; Kürten, A.
- Journal of Geophysical Research: Atmospheres, Vol. 121, Issue 6
Sulphuric acid and aerosol particle production in the vicinity of an oil refinery
journal, October 2015
- Sarnela, Nina; Jokinen, Tuija; Nieminen, Tuomo
- Atmospheric Environment, Vol. 119
Comment on “Electrostatic Sampler for Semivolatile Aerosols: Chemical Artifacts” and “Filter and Electrostatic Samplers for Semivolatile Aerosols: Physical Artifacts”
journal, April 2003
- Pankow, James F.
- Environmental Science & Technology, Vol. 37, Issue 9
A new atmospherically relevant oxidant of sulphur dioxide
journal, August 2012
- Mauldin III, R. L.; Berndt, T.; Sipilä, M.
- Nature, Vol. 488, Issue 7410
A large source of low-volatility secondary organic aerosol
journal, February 2014
- Ehn, Mikael; Thornton, Joel A.; Kleist, Einhard
- Nature, Vol. 506, Issue 7489
The role of low-volatility organic compounds in initial particle growth in the atmosphere
journal, May 2016
- Tröstl, Jasmin; Chuang, Wayne K.; Gordon, Hamish
- Nature, Vol. 533, Issue 7604
Rapid Formation of Sulfuric Acid Particles at Near-Atmospheric Conditions
journal, February 2005
- Berndt, T.
- Science, Vol. 307, Issue 5710
Oxidation Products of Biogenic Emissions Contribute to Nucleation of Atmospheric Particles
journal, May 2014
- Riccobono, F.; Schobesberger, S.; Scott, C. E.
- Science, Vol. 344, Issue 6185
New particle formation in the free troposphere: A question of chemistry and timing
journal, May 2016
- Bianchi, F.; Trostl, J.; Junninen, H.
- Science, Vol. 352, Issue 6289
Reactivity of stabilized Criegee intermediates (sCIs) from isoprene and monoterpene ozonolysis toward SO2 and organic acids
text, January 2014
- Sipilä, M.; Jokinen, T.; Berndt, T.
- München : European Geopyhsical Union
Enhancement of atmospheric H2SO4/H2O nucleation: Organic oxidation products versus amines
text, January 2014
- Berndt, T.; Sipilä, M.; Stratmann, F.
- München : European Geopyhsical Union
Numerical simulations of mixing conditions and aerosol dynamics in the CERN CLOUD chamber
journal, January 2012
- Voigtländer, J.; Duplissy, J.; Rondo, L.
- Atmospheric Chemistry and Physics, Vol. 12, Issue 4
On the formation of sulphuric acid – amine clusters in varying atmospheric conditions and its influence on atmospheric new particle formation
journal, January 2012
- Paasonen, P.; Olenius, T.; Kupiainen, O.
- Atmospheric Chemistry and Physics, Vol. 12, Issue 19
Amines are likely to enhance neutral and ion-induced sulfuric acid-water nucleation in the atmosphere more effectively than ammonia
journal, January 2008
- Kurtén, T.; Loukonen, V.; Vehkamäki, H.
- Atmospheric Chemistry and Physics, Vol. 8, Issue 14
Sulfuric acid and OH concentrations in a boreal forest site
journal, January 2009
- Petäjä, T.; Mauldin, III, R. L.; Kosciuch, E.
- Atmospheric Chemistry and Physics, Vol. 9, Issue 19
Effect of ions on the measurement of sulfuric acid in the CLOUD experiment at CERN
journal, January 2014
- Rondo, L.; Kürten, A.; Ehrhart, S.
- Atmospheric Measurement Techniques, Vol. 7, Issue 11
Works referencing / citing this record:
Effect of temperature on the formation of highly oxygenated organic molecules (HOMs) from alpha-pinene ozonolysis
journal, January 2019
- Quéléver, Lauriane L. J.; Kristensen, Kasper; Normann Jensen, Louise
- Atmospheric Chemistry and Physics, Vol. 19, Issue 11
Growth of Aitken mode ammonium sulfate particles by α-pinene ozonolysis
text, January 2019
- Krasnomowitz, Justin M.; Apsokardu, Michael J.; Stangl, Christopher M.
- Taylor & Francis
Growth of Aitken mode ammonium sulfate particles by α-pinene ozonolysis
journal, February 2019
- Krasnomowitz, Justin M.; Apsokardu, Michael J.; Stangl, Christopher M.
- Aerosol Science and Technology, Vol. 53, Issue 4
Growth of Aitken Mode Ammonium Sulfate Particles by α-Pinene Ozonolysis
text, January 2019
- Krasnomowitz, Justin M.; Apsokardu, Michael J.; Stangl, Christopher M.
- Figshare
Growth of Aitken mode ammonium sulfate particles by α-pinene ozonolysis
text, January 2019
- Krasnomowitz, Justin M.; Apsokardu, Michael J.; Stangl, Christopher M.
- Figshare
High concentration of ultrafine particles in the Amazon free troposphere produced by organic new particle formation
journal, September 2020
- Zhao, Bin; Shrivastava, Manish; Donahue, Neil M.
- Proceedings of the National Academy of Sciences, Vol. 117, Issue 41
Effect of temperature on the formation of highly oxygenated organic molecules (HOMs) from alpha-pinene ozonolysis
journal, January 2019
- Quéléver, Lauriane L. J.; Kristensen, Kasper; Normann Jensen, Louise
- Atmospheric Chemistry and Physics, Vol. 19, Issue 11