Topologically guided tuning of Zr-MOF pore structures for highly selective separation of C6 alkane isomers
Abstract
Effective separation of alkane isomers is a critical step in the petroleum refining process to produce gasoline with high octane rating. Current technology relies on energy intensive distillation method. Adsorptive separation using porous solids offers an alternative route that is more cost effective, lower energy and higher efficiency. Guided by topology-directed design and synthesis, we have developed a series of zirconium-based metal-organic frameworks with optimized pore structure for efficient separation of C6 alkane isomers, Zr-bptc adsorbs a large amount of n-hexane while excluding branched isomers. The n-hexane uptake is ~70% higher than that of a benchmark adsorbent, zeolite-5A. A derivative structure, Zr-abtc, is capable of discriminating all three C6 isomers with a high separation factor for 3-methylpentane over 2,3-dimethylbutane. This property is important for producing gasoline with further improved quality.
- Publication Date:
- Research Org.:
- Rutgers Univ., Piscataway, NJ (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Materials Sciences & Engineering Division
- OSTI Identifier:
- 1505257
- Grant/Contract Number:
- FG02-08ER46491
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Nature Communications
- Additional Journal Information:
- Journal Volume: 9; Journal Issue: 1; Journal ID: ISSN 2041-1723
- Publisher:
- Nature Publishing Group
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE
Citation Formats
Wang, Hao, Dong, Xinglong, Lin, Junzhong, Teat, Simon J., Jensen, Stephanie, Cure, Jeremy, Alexandrov, Eugeny V., Xia, Qibin, Tan, Kui, Wang, Qining, Olson, David H., Proserpio, Davide M., Chabal, Yves J., Thonhauser, Timo, Sun, Junliang, Han, Yu, and Li, Jing. Topologically guided tuning of Zr-MOF pore structures for highly selective separation of C6 alkane isomers. United States: N. p., 2018.
Web. doi:10.1038/s41467-018-04152-5.
Wang, Hao, Dong, Xinglong, Lin, Junzhong, Teat, Simon J., Jensen, Stephanie, Cure, Jeremy, Alexandrov, Eugeny V., Xia, Qibin, Tan, Kui, Wang, Qining, Olson, David H., Proserpio, Davide M., Chabal, Yves J., Thonhauser, Timo, Sun, Junliang, Han, Yu, & Li, Jing. Topologically guided tuning of Zr-MOF pore structures for highly selective separation of C6 alkane isomers. United States. https://doi.org/10.1038/s41467-018-04152-5
Wang, Hao, Dong, Xinglong, Lin, Junzhong, Teat, Simon J., Jensen, Stephanie, Cure, Jeremy, Alexandrov, Eugeny V., Xia, Qibin, Tan, Kui, Wang, Qining, Olson, David H., Proserpio, Davide M., Chabal, Yves J., Thonhauser, Timo, Sun, Junliang, Han, Yu, and Li, Jing. Tue .
"Topologically guided tuning of Zr-MOF pore structures for highly selective separation of C6 alkane isomers". United States. https://doi.org/10.1038/s41467-018-04152-5. https://www.osti.gov/servlets/purl/1505257.
@article{osti_1505257,
title = {Topologically guided tuning of Zr-MOF pore structures for highly selective separation of C6 alkane isomers},
author = {Wang, Hao and Dong, Xinglong and Lin, Junzhong and Teat, Simon J. and Jensen, Stephanie and Cure, Jeremy and Alexandrov, Eugeny V. and Xia, Qibin and Tan, Kui and Wang, Qining and Olson, David H. and Proserpio, Davide M. and Chabal, Yves J. and Thonhauser, Timo and Sun, Junliang and Han, Yu and Li, Jing},
abstractNote = {Effective separation of alkane isomers is a critical step in the petroleum refining process to produce gasoline with high octane rating. Current technology relies on energy intensive distillation method. Adsorptive separation using porous solids offers an alternative route that is more cost effective, lower energy and higher efficiency. Guided by topology-directed design and synthesis, we have developed a series of zirconium-based metal-organic frameworks with optimized pore structure for efficient separation of C6 alkane isomers, Zr-bptc adsorbs a large amount of n-hexane while excluding branched isomers. The n-hexane uptake is ~70% higher than that of a benchmark adsorbent, zeolite-5A. A derivative structure, Zr-abtc, is capable of discriminating all three C6 isomers with a high separation factor for 3-methylpentane over 2,3-dimethylbutane. This property is important for producing gasoline with further improved quality.},
doi = {10.1038/s41467-018-04152-5},
journal = {Nature Communications},
number = 1,
volume = 9,
place = {United States},
year = {Tue May 01 00:00:00 EDT 2018},
month = {Tue May 01 00:00:00 EDT 2018}
}
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Works referenced in this record:
Stability and degradation mechanisms of metal–organic frameworks containing the Zr6O4(OH)4 secondary building unit
journal, January 2013
- DeCoste, Jared B.; Peterson, Gregory W.; Jasuja, Himanshu
- Journal of Materials Chemistry A, Vol. 1, Issue 18
Hydrogen Storage in Metal–Organic Frameworks
journal, September 2011
- Suh, Myunghyun Paik; Park, Hye Jeong; Prasad, Thazhe Kootteri
- Chemical Reviews, Vol. 112, Issue 2, p. 782-835
Identifying the Role of Terahertz Vibrations in Metal-Organic Frameworks: From Gate-Opening Phenomenon to Shear-Driven Structural Destabilization
journal, November 2014
- Ryder, Matthew R.; Civalleri, Bartolomeo; Bennett, Thomas D.
- Physical Review Letters, Vol. 113, Issue 21
Methane storage in metal–organic frameworks
journal, January 2014
- He, Yabing; Zhou, Wei; Qian, Guodong
- Chem. Soc. Rev., Vol. 43, Issue 16
Water Vapor Sorption in Hybrid Pillared Square Grid Materials
journal, June 2017
- O’Nolan, Daniel; Kumar, Amrit; Zaworotko, Michael J.
- Journal of the American Chemical Society, Vol. 139, Issue 25
Seven chemical separations to change the world
journal, April 2016
- Sholl, David S.; Lively, Ryan P.
- Nature, Vol. 532, Issue 7600
First examples of aliphatic zirconium MOFs and the influence of inorganic anions on their crystal structures
journal, January 2015
- Reinsch, Helge; Stassen, Ivo; Bueken, Bart
- CrystEngComm, Vol. 17, Issue 2
Controlling guest conformation for efficient purification of butadiene
journal, June 2017
- Liao, Pei-Qin; Huang, Ning-Yu; Zhang, Wei-Xiong
- Science, Vol. 356, Issue 6343
From ultrasoft pseudopotentials to the projector augmented-wave method
journal, January 1999
- Kresse, G.; Joubert, D.
- Physical Review B, Vol. 59, Issue 3, p. 1758-1775
Ultra-Tuning of the Rare-Earth fcu-MOF Aperture Size for Selective Molecular Exclusion of Branched Paraffins
journal, October 2015
- Assen, Ayalew H.; Belmabkhout, Youssef; Adil, Karim
- Angewandte Chemie International Edition, Vol. 54, Issue 48
Separation of C 6 Paraffins Using Zeolitic Imidazolate Frameworks: Comparison with Zeolite 5A
journal, March 2012
- Peralta, David; Chaplais, Gérald; Simon-Masseron, Angélique
- Industrial & Engineering Chemistry Research, Vol. 51, Issue 12
Reticular synthesis and the design of new materials
journal, June 2003
- Yaghi, Omar M.; O'Keeffe, Michael; Ockwig, Nathan W.
- Nature, Vol. 423, Issue 6941, p. 705-714
Separation of Hexane Isomers in a Metal-Organic Framework with Triangular Channels
journal, May 2013
- Herm, Z. R.; Wiers, B. M.; Mason, J. A.
- Science, Vol. 340, Issue 6135, p. 960-964
Topology-dependent emissive properties of zirconium-based porphyrin MOFs
journal, January 2016
- Deria, Pravas; Yu, Jierui; Balaraman, Rajesh P.
- Chemical Communications, Vol. 52, Issue 88
Chemical and Structural Stability of Zirconium-based Metal-Organic Frameworks with Large Three-Dimensional Pores by Linker Engineering
journal, December 2014
- Kalidindi, Suresh B.; Nayak, Sanjit; Briggs, Michael E.
- Angewandte Chemie International Edition, Vol. 54, Issue 1
Mercury nano-trap for effective and efficient removal of mercury(II) from aqueous solution
journal, November 2014
- Li, Baiyan; Zhang, Yiming; Ma, Dingxuan
- Nature Communications, Vol. 5, Issue 1
Computational Screening of Nanoporous Materials for Hexane and Heptane Isomer Separation
journal, July 2017
- Chung, Yongchul G.; Bai, Peng; Haranczyk, Maciej
- Chemistry of Materials, Vol. 29, Issue 15
Metal–organic frameworks for membrane-based separations
journal, November 2016
- Denny, Michael S.; Moreton, Jessica C.; Benz, Lauren
- Nature Reviews Materials, Vol. 1, Issue 12
Vapor-Phase Metalation by Atomic Layer Deposition in a Metal–Organic Framework
journal, May 2013
- Mondloch, Joseph E.; Bury, Wojciech; Fairen-Jimenez, David
- Journal of the American Chemical Society, Vol. 135, Issue 28, p. 10294-10297
Dramatic Tuning of Carbon Dioxide Uptake via Metal Substitution in a Coordination Polymer with Cylindrical Pores
journal, August 2008
- Caskey, Stephen R.; Wong-Foy, Antek G.; Matzger, Adam J.
- Journal of the American Chemical Society, Vol. 130, Issue 33, p. 10870-10871
Gas Separation by Adsorption Processes
book, June 1997
- Yang, Ralph T.
- Series on Chemical Engineering
Adsorptive Bulk Separations by Zeolite Molecular Sieves
journal, August 1988
- Jasra, R. V.; Bhat, S. G. T.
- Separation Science and Technology, Vol. 23, Issue 10-11
Deconstructing the Crystal Structures of Metal–Organic Frameworks and Related Materials into Their Underlying Nets
journal, September 2011
- O’Keeffe, Michael; Yaghi, Omar M.
- Chemical Reviews, Vol. 112, Issue 2, p. 675-702
Equilibrium and kinetics ofn– hexane sorption in pellets of 5A zeolite
journal, October 1997
- Silva, José A. C.; Rodrigues, Alírio E.
- AIChE Journal, Vol. 43, Issue 10
Structural Phase Transitions and Thermal Hysteresis in the Metal−Organic Framework Compound MIL-53 As Studied by Electron Spin Resonance Spectroscopy
journal, October 2010
- Mendt, Matthias; Jee, Bettina; Stock, Norbert
- The Journal of Physical Chemistry C, Vol. 114, Issue 45
Zr-based metal–organic frameworks: design, synthesis, structure, and applications
journal, January 2016
- Bai, Yan; Dou, Yibo; Xie, Lin-Hua
- Chemical Society Reviews, Vol. 45, Issue 8
Imparting amphiphobicity on single-crystalline porous materials
journal, October 2016
- Sun, Qi; He, Hongming; Gao, Wen-Yang
- Nature Communications, Vol. 7, Issue 1
Commensurate Adsorption of Hydrocarbons and Alcohols in Microporous Metal Organic Frameworks
journal, September 2011
- Wu, Haohan; Gong, Qihan; Olson, David H.
- Chemical Reviews, Vol. 112, Issue 2
Topology-Guided Design and Syntheses of Highly Stable Mesoporous Porphyrinic Zirconium Metal–Organic Frameworks with High Surface Area
journal, December 2014
- Liu, Tian-Fu; Feng, Dawei; Chen, Ying-Pin
- Journal of the American Chemical Society, Vol. 137, Issue 1
Effective Adsorption Separation of n -Hexane/2-Methylpentane in Facilely Synthesized Zeolitic Imidazolate Frameworks ZIF-8 and ZIF-69
journal, September 2016
- Chen, Le; Yuan, Sheng; Qian, Jun-Feng
- Industrial & Engineering Chemistry Research, Vol. 55, Issue 40
Underlying nets in three-periodic coordination polymers: topology, taxonomy and prediction from a computer-aided analysis of the Cambridge Structural Database
journal, January 2011
- Alexandrov, E. V.; Blatov, V. A.; Kochetkov, A. V.
- CrystEngComm, Vol. 13, Issue 12
Topological Analysis of Metal–Organic Frameworks with Polytopic Linkers and/or Multiple Building Units and the Minimal Transitivity Principle
journal, November 2013
- Li, Mian; Li, Dan; O’Keeffe, Michael
- Chemical Reviews, Vol. 114, Issue 2
Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
journal, January 2002
- Eddaoudi, Mohamed; Kim, Jaheon; Rosi, Nathaniel
- Science, Vol. 295, Issue 5554, p. 469-472
Metal–organic frameworks with wine-rack motif: What determines their flexibility and elastic properties?
journal, May 2013
- Ortiz, Aurélie U.; Boutin, A.; Fuchs, Alain H.
- The Journal of Chemical Physics, Vol. 138, Issue 17
Carbon Dioxide Capture in Metal–Organic Frameworks
journal, September 2011
- Sumida, Kenji; Rogow, David L.; Mason, Jarad A.
- Chemical Reviews, Vol. 112, Issue 2, p. 724-781
Hydrocarbon Separations in Metal–Organic Frameworks
journal, September 2013
- Herm, Zoey R.; Bloch, Eric D.; Long, Jeffrey R.
- Chemistry of Materials, Vol. 26, Issue 1
Tuning the Gate Opening Pressure of Metal–Organic Frameworks (MOFs) for the Selective Separation of Hydrocarbons
journal, September 2012
- Nijem, Nour; Wu, Haohan; Canepa, Pieremanuele
- Journal of the American Chemical Society, Vol. 134, Issue 37
Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set
journal, October 1996
- Kresse, G.; Furthmüller, J.
- Physical Review B, Vol. 54, Issue 16, p. 11169-11186
Applied Topological Analysis of Crystal Structures with the Program Package ToposPro
journal, May 2014
- Blatov, Vladislav A.; Shevchenko, Alexander P.; Proserpio, Davide M.
- Crystal Growth & Design, Vol. 14, Issue 7
Metal Azolate Frameworks: From Crystal Engineering to Functional Materials
journal, September 2011
- Zhang, Jie-Peng; Zhang, Yue-Biao; Lin, Jian-Bin
- Chemical Reviews, Vol. 112, Issue 2
Topological relations between three-dimensional periodic nets. I. Uninodal nets
journal, June 2007
- Blatov, Vladislav A.
- Acta Crystallographica Section A Foundations of Crystallography, Vol. 63, Issue 4
A partially interpenetrated metal–organic framework for selective hysteretic sorption of carbon dioxide
journal, June 2012
- Yang, Sihai; Lin, Xiang; Lewis, William
- Nature Materials, Vol. 11, Issue 8
Ultraporous, Water Stable, and Breathing Zirconium-Based Metal–Organic Frameworks with ftw Topology
journal, September 2015
- Deria, Pravas; Gómez-Gualdrón, Diego A.; Bury, Wojciech
- Journal of the American Chemical Society, Vol. 137, Issue 40
A New Zirconium Inorganic Building Brick Forming Metal Organic Frameworks with Exceptional Stability
journal, October 2008
- Cavka, Jasmina Hafizovic; Jakobsen, Søren; Olsbye, Unni
- Journal of the American Chemical Society, Vol. 130, Issue 42, p. 13850-13851
Pore chemistry and size control in hybrid porous materials for acetylene capture from ethylene
journal, May 2016
- Cui, X.; Chen, K.; Xing, H.
- Science, Vol. 353, Issue 6295
Toward Topology Prediction in Zr-Based Microporous Coordination Polymers: The Role of Linker Geometry and Flexibility
journal, May 2016
- Ma, Jialiu; Tran, Ly D.; Matzger, Adam J.
- Crystal Growth & Design, Vol. 16, Issue 7
Synthesis and structure of Zr( iv )- and Ce( iv )-based CAU-24 with 1,2,4,5-tetrakis(4-carboxyphenyl)benzene
journal, January 2016
- Lammert, M.; Reinsch, H.; Murray, C. A.
- Dalton Transactions, Vol. 45, Issue 47
The Effect of Pressure on ZIF-8: Increasing Pore Size with Pressure and the Formation of a High-Pressure Phase at 1.47 GPa
journal, September 2009
- Moggach, Stephen A.; Bennett, Thomas D.; Cheetham, Anthony K.
- Angewandte Chemie International Edition, Vol. 48, Issue 38
Ionic liquid lubricants: designed chemistry for engineering applications
journal, January 2009
- Zhou, Feng; Liang, Yongmin; Liu, Weimin
- Chemical Society Reviews, Vol. 38, Issue 9
Multifunctional metal–organic frameworks constructed from meta-benzenedicarboxylate units
journal, January 2014
- He, Yabing; Li, Bin; O'Keeffe, Michael
- Chem. Soc. Rev., Vol. 43, Issue 16
Porous materials with optimal adsorption thermodynamics and kinetics for CO2 separation
journal, February 2013
- Nugent, Patrick; Belmabkhout, Youssef; Burd, Stephen D.
- Nature, Vol. 495, Issue 7439, p. 80-84
A metal-organic framework-based splitter for separating propylene from propane
journal, July 2016
- Cadiau, A.; Adil, K.; Bhatt, P. M.
- Science, Vol. 353, Issue 6295
The Chemistry and Applications of Metal-Organic Frameworks
journal, August 2013
- Furukawa, H.; Cordova, K. E.; O'Keeffe, M.
- Science, Vol. 341, Issue 6149, p. 1230444-1230444
Screening metal–organic frameworks for mixture separations in fixed-bed adsorbers using a combined selectivity/capacity metric
journal, January 2017
- Krishna, Rajamani
- RSC Advances, Vol. 7, Issue 57
Zr- and Hf-Based Metal–Organic Frameworks: Tracking Down the Polymorphism
journal, February 2013
- Bon, Volodymyr; Senkovska, Irena; Baburin, Igor A.
- Crystal Growth & Design, Vol. 13, Issue 3, p. 1231-1237
Single and multicomponent adsorption of hexane isomers in the microporous ZIF-8
journal, August 2014
- Mendes, Patricia A. P.; Rodrigues, Alírio E.; Horcajada, Patricia
- Microporous and Mesoporous Materials, Vol. 194
Light hydrocarbon sorption properties of pure silica Si-CHA and ITQ-3 and high silica ZSM-58
journal, January 2004
- Olson, David H.; Camblor, Miguel A.; Villaescusa, Luis A.
- Microporous and Mesoporous Materials, Vol. 67, Issue 1
Water-Stable Zirconium-Based Metal-Organic Framework Material with High-Surface Area and Gas-Storage Capacities
journal, August 2014
- Gutov, Oleksii V.; Bury, Wojciech; Gomez-Gualdron, Diego A.
- Chemistry - A European Journal, Vol. 20, Issue 39
A zinc(ii) metal–organic framework based on triazole and dicarboxylate ligands for selective adsorption of hexane isomers
journal, January 2011
- Ling, Yun; Chen, Zhen-Xia; Zhai, Fu-Peng
- Chemical Communications, Vol. 47, Issue 25, p. 7197-7199
A Rotating Adsorber for Multistage Cyclic Processes: Principle and Experimental Demonstration in the Separation of Paraffins
journal, January 2001
- Babich, Igor V.; van Langeveld, A. Dick; Zhu, Weidong
- Industrial & Engineering Chemistry Research, Vol. 40, Issue 1
Metal–Organic Frameworks as Micromotors with Tunable Engines and Brakes
journal, January 2017
- Li, Jinxing; Yu, Xiao; Xu, Mingli
- Journal of the American Chemical Society, Vol. 139, Issue 2
Sieving di-branched from mono-branched and linear alkanes using ZIF-8: experimental proof and theoretical explanation
journal, January 2013
- Ferreira, Alexandre F. P.; Mittelmeijer-Hazeleger, Marjo C.; Granato, Miguel Angelo
- Physical Chemistry Chemical Physics, Vol. 15, Issue 22
Gas Separation by Adsorption Processes
journal, January 1988
- Yang, RalphT.
- Chemical Engineering Science, Vol. 43, Issue 4
Chemical and Structural Stability of Zirconium-based Metal-Organic Frameworks with Large Three-Dimensional Pores by Linker Engineering
journal, December 2014
- Kalidindi, Suresh B.; Nayak, Sanjit; Briggs, Michael E.
- Angewandte Chemie, Vol. 127, Issue 1
Ultra-Tuning of the Rare-Earth fcu-MOF Aperture Size for Selective Molecular Exclusion of Branched Paraffins
journal, October 2015
- Assen, Ayalew H.; Belmabkhout, Youssef; Adil, Karim
- Angewandte Chemie, Vol. 127, Issue 48
Gas separation by adsorption processes
journal, December 1988
- Helfferich, Friedrich G.
- Reactive Polymers, Ion Exchangers, Sorbents, Vol. 9, Issue 3
Reducing Dzyaloshinskii-Moriya interaction and field-free spin-orbit torque switching in synthetic antiferromagnets
journal, May 2021
- Chen, Ruyi; Cui, Qirui; Liao, Liyang
- Nature Communications, Vol. 12, Issue 1
The Effect of Pressure on ZIF-8: Increasing Pore Size with Pressure and the Formation of a High-Pressure Phase at 1.47 GPa
journal, September 2009
- Moggach, Stephen A.; Bennett, Thomas D.; Cheetham, Anthony K.
- Angewandte Chemie, Vol. 121, Issue 38
Gas Separation by Adsorption Processes
journal, March 1988
- Kirkby, N.
- Gas Separation & Purification, Vol. 2, Issue 1
Works referencing / citing this record:
Versatile Amorphous Structures of Phosphonate Metal−Organic Framework/Alginate Composite for Tunable Sieving of Ions
journal, August 2019
- Park, Sung Ho; Lee, Sang Joon
- Advanced Functional Materials, Vol. 29, Issue 42
Tailor-Made Microporous Metal-Organic Frameworks for the Full Separation of Propane from Propylene Through Selective Size Exclusion
journal, October 2018
- Wang, Hao; Dong, Xinglong; Colombo, Valentina
- Advanced Materials, Vol. 30, Issue 49
Metal–Organic Framework Materials for the Separation and Purification of Light Hydrocarbons
journal, May 2019
- Cui, Wen‐Gang; Hu, Tong‐Liang; Bu, Xian‐He
- Advanced Materials, Vol. 32, Issue 3
A Chemically Stable Hofmann‐Type Metal−Organic Framework with Sandwich‐Like Binding Sites for Benchmark Acetylene Capture
journal, May 2020
- Pei, Jiyan; Shao, Kai; Wang, Jia‐Xin
- Advanced Materials
Atomic‐ and Molecular‐Level Design of Functional Metal–Organic Frameworks (MOFs) and Derivatives for Energy and Environmental Applications
journal, August 2019
- Yilmaz, Gamze; Peh, Shing Bo; Zhao, Dan
- Advanced Science, Vol. 6, Issue 21
Moisture stability of ethane‐selective Ni(II), Fe(III), Zr(IV)‐based metal–organic frameworks
journal, April 2019
- Lv, Daofei; Chen, Jiayu; Chen, Yongwei
- AIChE Journal, Vol. 65, Issue 8
A Metal–Organic Framework with Suitable Pore Size and Specific Functional Sites for the Removal of Trace Propyne from Propylene
journal, October 2018
- Li, Libo; Wen, Hui‐Min; He, Chaohui
- Angewandte Chemie, Vol. 130, Issue 46
Stack the Bowls: Tailoring the Electronic Structure of Corannulene-Integrated Crystalline Materials
journal, July 2018
- Rice, Allison M.; Dolgopolova, Ekaterina A.; Yarbrough, Brandon J.
- Angewandte Chemie International Edition, Vol. 57, Issue 35
A Metal-Organic Framework with Suitable Pore Size and Specific Functional Sites for the Removal of Trace Propyne from Propylene
journal, October 2018
- Li, Libo; Wen, Hui-Min; He, Chaohui
- Angewandte Chemie International Edition, Vol. 57, Issue 46
A Dual Threat: Redox‐Activity and Electronic Structures of Well‐Defined Donor–Acceptor Fulleretic Covalent‐Organic Materials
journal, February 2020
- Leith, Gabrielle A.; Rice, Allison M.; Yarbrough, Brandon J.
- Angewandte Chemie International Edition, Vol. 59, Issue 15
A Flexible Two‐Fold Interpenetrated Indium MOF Exhibiting Dynamic Response to Gas Adsorption and High‐Sensitivity Detection of Nitroaromatic Explosives
journal, July 2019
- Cao, Zhen; Chen, Lian; Li, Shengchang
- Chemistry – An Asian Journal, Vol. 14, Issue 20
Efficient Separation of n‐ Butene and iso ‐Butene by Flexible Ultramicroporous Metal‐Organic Frameworks with Pocket‐like Cavities
journal, July 2019
- Cui, Jiyu; Zhang, Zhaoqiang; Tan, Bin
- Chemistry – An Asian Journal, Vol. 14, Issue 20
Adsorptive Separation of Acetylene from Ethylene in Isostructural Gallate‐Based Metal–Organic Frameworks
journal, December 2019
- Wang, Jiawei; Li, Liangying; Guo, Lidong
- Chemistry – A European Journal, Vol. 25, Issue 68
Metal‐Organic Sheets for Efficient Drug Delivery and Bioimaging
journal, January 2020
- Song, Yucong; Yang, Jingjie; Wang, Lei
- ChemMedChem, Vol. 15, Issue 5
Current Status of Microporous Metal–Organic Frameworks for Hydrocarbon Separations
journal, October 2019
- Pei, Jiyan; Shao, Kai; Zhang, Ling
- Topics in Current Chemistry, Vol. 377, Issue 6
Why Design Matters: From Decorated Metal Oxide Clusters to Functional Metal–Organic Frameworks
journal, February 2020
- Schoedel, Alexander; Rajeh, Sahar
- Topics in Current Chemistry, Vol. 378, Issue 1
Fast and selective fluoride ion conduction in sub-1-nanometer metal-organic framework channels
journal, June 2019
- Li, Xingya; Zhang, Huacheng; Wang, Peiyao
- Nature Communications, Vol. 10, Issue 1
A metal–organic framework with suitable pore size and dual functionalities for highly efficient post-combustion CO 2 capture
journal, January 2019
- Wen, Hui-Min; Liao, Caijun; Li, Libo
- Journal of Materials Chemistry A, Vol. 7, Issue 7
Near-infrared-emissive metal–organic frameworks
journal, January 2019
- Zou, Danna; Zhang, Jun; Cui, Yuanjing
- Dalton Transactions, Vol. 48, Issue 20
Identifying the best metal–organic frameworks and unravelling different mechanisms for the separation of pentane isomers
journal, January 2019
- Qiao, Zhiwei; Cheetham, Anthony K.; Jiang, Jianwen
- Molecular Systems Design & Engineering, Vol. 4, Issue 3
The synthesis and applications of chiral pyrrolidine functionalized metal–organic frameworks and covalent-organic frameworks
journal, January 2020
- Zhou, Mi; El-Sayed, El-Sayed M.; Ju, Zhanfeng
- Inorganic Chemistry Frontiers, Vol. 7, Issue 6
“Induced-Fit Suction” effect: a booster for biofuel storage and separation
journal, January 2019
- Li, He; Guo, Fangyuan; Hu, Jun
- Journal of Materials Chemistry A, Vol. 7, Issue 39
Stable metal–organic frameworks with low water affinity built from methyl-siloxane linkers
journal, January 2020
- Delmas, Luke C.; White, Andrew J. P.; Pugh, David
- Chemical Communications
van der Waals density functional with corrected coefficients
journal, May 2019
- Berland, K.; Chakraborty, D.; Thonhauser, T.
- Physical Review B, Vol. 99, Issue 19
A Dual Threat: Redox‐Activity and Electronic Structures of Well‐Defined Donor–Acceptor Fulleretic Covalent‐Organic Materials
journal, February 2020
- Leith, Gabrielle A.; Rice, Allison M.; Yarbrough, Brandon J.
- Angewandte Chemie, Vol. 132, Issue 15
Engineering microporous ethane-trapping metal–organic frameworks for boosting ethane/ethylene separation
journal, January 2020
- Pei, Jiyan; Wang, Jia-Xin; Shao, Kai
- Journal of Materials Chemistry A, Vol. 8, Issue 7
Stack the Bowls: Tailoring the Electronic Structure of Corannulene-Integrated Crystalline Materials
journal, July 2018
- Rice, Allison M.; Dolgopolova, Ekaterina A.; Yarbrough, Brandon J.
- Angewandte Chemie, Vol. 130, Issue 35