Yet again, new compounds found in systems with known binary phase diagrams. Synthesis, crystal and electronic structure of Nd3Bi7 and Sm3Bi7
Abstract
The binary bismuthides Nd3Bi7 and Sm3Bi7 were synthesized and structurally characterized for the first time. Here, the results from the calorimetric analysis show that both compounds are stable only up to about 500 °C, which may explain why they were overlooked during the original assessment of the corresponding phase diagrams.
- Authors:
-
- Univ. of Delaware, Newark, DE (United States)
- Publication Date:
- Research Org.:
- Univ. of Delaware, Newark, DE (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1504902
- Alternate Identifier(s):
- OSTI ID: 1441062
- Grant/Contract Number:
- SC0008885
- Resource Type:
- Accepted Manuscript
- Journal Name:
- ChemComm
- Additional Journal Information:
- Journal Volume: 54; Journal Issue: 51; Journal ID: ISSN 1359-7345
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 36 MATERIALS SCIENCE
Citation Formats
Ovchinnikov, Alexander, Makongo, Julien P. A., and Bobev, Svilen. Yet again, new compounds found in systems with known binary phase diagrams. Synthesis, crystal and electronic structure of Nd3Bi7 and Sm3Bi7. United States: N. p., 2018.
Web. doi:10.1039/c8cc02563k.
Ovchinnikov, Alexander, Makongo, Julien P. A., & Bobev, Svilen. Yet again, new compounds found in systems with known binary phase diagrams. Synthesis, crystal and electronic structure of Nd3Bi7 and Sm3Bi7. United States. https://doi.org/10.1039/c8cc02563k
Ovchinnikov, Alexander, Makongo, Julien P. A., and Bobev, Svilen. Mon .
"Yet again, new compounds found in systems with known binary phase diagrams. Synthesis, crystal and electronic structure of Nd3Bi7 and Sm3Bi7". United States. https://doi.org/10.1039/c8cc02563k. https://www.osti.gov/servlets/purl/1504902.
@article{osti_1504902,
title = {Yet again, new compounds found in systems with known binary phase diagrams. Synthesis, crystal and electronic structure of Nd3Bi7 and Sm3Bi7},
author = {Ovchinnikov, Alexander and Makongo, Julien P. A. and Bobev, Svilen},
abstractNote = {The binary bismuthides Nd3Bi7 and Sm3Bi7 were synthesized and structurally characterized for the first time. Here, the results from the calorimetric analysis show that both compounds are stable only up to about 500 °C, which may explain why they were overlooked during the original assessment of the corresponding phase diagrams.},
doi = {10.1039/c8cc02563k},
journal = {ChemComm},
number = 51,
volume = 54,
place = {United States},
year = {Mon Jun 04 00:00:00 EDT 2018},
month = {Mon Jun 04 00:00:00 EDT 2018}
}
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Cited by: 12 works
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Figures / Tables:
Fig. 1: Crystal structure of RE3Bi7 (RE = Nd, Sm). RE and Bi atoms are shown in orange and purple, respectively. The unit cell is outlined wish dashed lines.
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Works referencing / citing this record:
Exploration of Multi-Component Vanadium and Titanium Pnictides Using Flux Growth and Conventional High-Temperature Methods
journal, January 2020
- Ovchinnikov, Alexander; Bobev, Svilen
- Frontiers in Chemistry, Vol. 7
Exploratory Work in the Quaternary System of Ca–Eu–Cd–Sb: Synthesis, Crystal, and Electronic Structures of New Zintl Solid Solutions
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Figures / Tables found in this record:
Figures/Tables have been extracted from DOE-funded journal article accepted manuscripts.