Significance of an anion effect in the selective oxidation of Ce3+ to Ce4+ over a porous WO3 photoanode
Abstract
We report the oxidation of Ce3+ to Ce4+ using a porous WO3 photoanode and a Pt cathode with excellent Faradaic efficiency (FE (Ce4+)) of up to 98% under solar simulated light in an aqueous electrolyte solution containing a high concentration of SO42- anions. The competing side oxidative reactions such as S2O82- and O2 production were found to be suppressed in the presence of Ce3+. The Ce4+ yield (YI (Ce4+)) from Ce3+ reached up to 95%. Also, a noble-metal-free biomass-derived inexpensive electrode was found to be an efficient replacement of the Pt cathode.
- Authors:
-
- National Inst. of Advanced Industrial Science and Technology (AIST), Tsukuba (Japan). Advanced Functional Material Team. Research Center for Photovoltaics (PCPV)
- Brookhaven National Lab. (BNL), Upton, NY (United States). Chemistry Division
- Publication Date:
- Research Org.:
- Brookhaven National Lab. (BNL), Upton, NY (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1504378
- Alternate Identifier(s):
- OSTI ID: 1508175
- Report Number(s):
- BNL-211493-2019-JAAM
Journal ID: ISSN 0013-4686
- Grant/Contract Number:
- SC0012704
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Electrochimica Acta
- Additional Journal Information:
- Journal Volume: 307; Journal ID: ISSN 0013-4686
- Publisher:
- Elsevier
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; electrochemistry; photocatalysis; photooxidation; anion effect; biomass
Citation Formats
Takasugi, Soichi, Miseki, Yugo, Sasaki, Kotaro, Fujita, Etsuko, and Sayama, Kazuhiro. Significance of an anion effect in the selective oxidation of Ce3+ to Ce4+ over a porous WO3 photoanode. United States: N. p., 2019.
Web. doi:10.1016/j.electacta.2019.03.178.
Takasugi, Soichi, Miseki, Yugo, Sasaki, Kotaro, Fujita, Etsuko, & Sayama, Kazuhiro. Significance of an anion effect in the selective oxidation of Ce3+ to Ce4+ over a porous WO3 photoanode. United States. https://doi.org/10.1016/j.electacta.2019.03.178
Takasugi, Soichi, Miseki, Yugo, Sasaki, Kotaro, Fujita, Etsuko, and Sayama, Kazuhiro. Thu .
"Significance of an anion effect in the selective oxidation of Ce3+ to Ce4+ over a porous WO3 photoanode". United States. https://doi.org/10.1016/j.electacta.2019.03.178. https://www.osti.gov/servlets/purl/1504378.
@article{osti_1504378,
title = {Significance of an anion effect in the selective oxidation of Ce3+ to Ce4+ over a porous WO3 photoanode},
author = {Takasugi, Soichi and Miseki, Yugo and Sasaki, Kotaro and Fujita, Etsuko and Sayama, Kazuhiro},
abstractNote = {We report the oxidation of Ce3+ to Ce4+ using a porous WO3 photoanode and a Pt cathode with excellent Faradaic efficiency (FE (Ce4+)) of up to 98% under solar simulated light in an aqueous electrolyte solution containing a high concentration of SO42- anions. The competing side oxidative reactions such as S2O82- and O2 production were found to be suppressed in the presence of Ce3+. The Ce4+ yield (YI (Ce4+)) from Ce3+ reached up to 95%. Also, a noble-metal-free biomass-derived inexpensive electrode was found to be an efficient replacement of the Pt cathode.},
doi = {10.1016/j.electacta.2019.03.178},
journal = {Electrochimica Acta},
number = ,
volume = 307,
place = {United States},
year = {Thu Mar 28 00:00:00 EDT 2019},
month = {Thu Mar 28 00:00:00 EDT 2019}
}
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Works referencing / citing this record:
Solar-light-driven non-bias photoelectrolysis for bleach production from sea water and atmospheric oxygen
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