Mitigation of Shuttle Effect in Li–S Battery Using a Self-Assembled Ultrathin Molybdenum Disulfide Interlayer
Abstract
Lithium–sulfur batteries are promising for low-cost and high-energy storage, but their applications are still limited by poor cycling stability owing to soluble lithium polysulfide shuttling during battery operation. Avoiding shuttle effect is challenging but it is essential to avoid active material loss and prevent performance decay. We use an ultrathin layer of MoS2 with thickness of 10–40 nm, which is 1–2 orders of magnitude thinner than conventional interlayers, for Li–S batteries to mitigate polysulfide shuttling. The MoS2 layer formed by exfoliated nanoflakes is deposited by the scalable liquid-based self-assembly method. With less than 1% of additional weight in the cathode, the MoS2 interlayer with complete coverage inhibits polysulfide diffusion across the separator and therefore remarkably improves the battery performances. Reversible specific capacity reaches 1010 and 600 mA h g–1 at 0.5 and 2C rates, respectively, which decay slowly over 400 cycles (0.11% per cycle). Moreover, the MoS2 films with high density of catalytic active flake edges enable high areal sulfur loading up to 10 mg cm–2 and areal capacity up to 9.7 mA h cm–2 at a current density of 3.2 mA cm–2.
- Authors:
-
- Stanford Univ., CA (United States). Dept. of Materials Science and Engineering
- Stanford Univ., CA (United States). Dept. of Materials Science and Engineering; SLAC National Accelerator Lab., Menlo Park, CA (United States). Stanford Inst. for Materials and Energy Sciences
- Publication Date:
- Research Org.:
- SLAC National Accelerator Laboratory (SLAC), Menlo Park, CA (United States); Stanford Univ., CA (United States)
- Sponsoring Org.:
- USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V); Swiss National Science Foundation (SNSF)
- OSTI Identifier:
- 1503543
- Grant/Contract Number:
- AC02-76SF00515; P2ELP2_172291
- Resource Type:
- Accepted Manuscript
- Journal Name:
- ACS Applied Materials and Interfaces
- Additional Journal Information:
- Journal Volume: 11; Journal Issue: 3; Journal ID: ISSN 1944-8244
- Publisher:
- American Chemical Society (ACS)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE; lithium−sulfur battery; polysulfide; self-assembly; shuttle effect; transition-metal dichalcogenide
Citation Formats
Yu, Xiaoyun, Zhou, Guangmin, and Cui, Yi. Mitigation of Shuttle Effect in Li–S Battery Using a Self-Assembled Ultrathin Molybdenum Disulfide Interlayer. United States: N. p., 2018.
Web. doi:10.1021/acsami.8b19354.
Yu, Xiaoyun, Zhou, Guangmin, & Cui, Yi. Mitigation of Shuttle Effect in Li–S Battery Using a Self-Assembled Ultrathin Molybdenum Disulfide Interlayer. United States. https://doi.org/10.1021/acsami.8b19354
Yu, Xiaoyun, Zhou, Guangmin, and Cui, Yi. Thu .
"Mitigation of Shuttle Effect in Li–S Battery Using a Self-Assembled Ultrathin Molybdenum Disulfide Interlayer". United States. https://doi.org/10.1021/acsami.8b19354. https://www.osti.gov/servlets/purl/1503543.
@article{osti_1503543,
title = {Mitigation of Shuttle Effect in Li–S Battery Using a Self-Assembled Ultrathin Molybdenum Disulfide Interlayer},
author = {Yu, Xiaoyun and Zhou, Guangmin and Cui, Yi},
abstractNote = {Lithium–sulfur batteries are promising for low-cost and high-energy storage, but their applications are still limited by poor cycling stability owing to soluble lithium polysulfide shuttling during battery operation. Avoiding shuttle effect is challenging but it is essential to avoid active material loss and prevent performance decay. We use an ultrathin layer of MoS2 with thickness of 10–40 nm, which is 1–2 orders of magnitude thinner than conventional interlayers, for Li–S batteries to mitigate polysulfide shuttling. The MoS2 layer formed by exfoliated nanoflakes is deposited by the scalable liquid-based self-assembly method. With less than 1% of additional weight in the cathode, the MoS2 interlayer with complete coverage inhibits polysulfide diffusion across the separator and therefore remarkably improves the battery performances. Reversible specific capacity reaches 1010 and 600 mA h g–1 at 0.5 and 2C rates, respectively, which decay slowly over 400 cycles (0.11% per cycle). Moreover, the MoS2 films with high density of catalytic active flake edges enable high areal sulfur loading up to 10 mg cm–2 and areal capacity up to 9.7 mA h cm–2 at a current density of 3.2 mA cm–2.},
doi = {10.1021/acsami.8b19354},
journal = {ACS Applied Materials and Interfaces},
number = 3,
volume = 11,
place = {United States},
year = {Thu Dec 27 00:00:00 EST 2018},
month = {Thu Dec 27 00:00:00 EST 2018}
}
Web of Science
Works referenced in this record:
Li–O2 and Li–S batteries with high energy storage
journal, January 2012
- Bruce, Peter G.; Freunberger, Stefan A.; Hardwick, Laurence J.
- Nature Materials, Vol. 11, Issue 1, p. 19-29
Nanostructured sulfur cathodes
journal, January 2013
- Yang, Yuan; Zheng, Guangyuan; Cui, Yi
- Chemical Society Reviews, Vol. 42, Issue 7, p. 3018-3032
In Situ Raman Spectroscopy of Sulfur Speciation in Lithium–Sulfur Batteries
journal, January 2015
- Wu, Heng-Liang; Huff, Laura A.; Gewirth, Andrew A.
- ACS Applied Materials & Interfaces, Vol. 7, Issue 3
Spherical Ordered Mesoporous Carbon Nanoparticles with High Porosity for Lithium-Sulfur Batteries
journal, March 2012
- Schuster, Jörg; He, Guang; Mandlmeier, Benjamin
- Angewandte Chemie International Edition, Vol. 51, Issue 15, p. 3591-3595
A highly ordered nanostructured carbon–sulphur cathode for lithium–sulphur batteries
journal, May 2009
- Ji, Xiulei; Lee, Kyu Tae; Nazar, Linda F.
- Nature Materials, Vol. 8, Issue 6, p. 500-506
Amphiphilic Surface Modification of Hollow Carbon Nanofibers for Improved Cycle Life of Lithium Sulfur Batteries
journal, February 2013
- Zheng, Guangyuan; Zhang, Qianfan; Cha, Judy J.
- Nano Letters, Vol. 13, Issue 3, p. 1265-1270
Smaller Sulfur Molecules Promise Better Lithium–Sulfur Batteries
journal, October 2012
- Xin, Sen; Gu, Lin; Zhao, Na-Hong
- Journal of the American Chemical Society, Vol. 134, Issue 45
Porous Hollow Carbon@Sulfur Composites for High-Power Lithium-Sulfur Batteries
journal, May 2011
- Jayaprakash, N.; Shen, J.; Moganty, Surya S.
- Angewandte Chemie International Edition, Vol. 50, Issue 26, p. 5904-5908
A Graphene-Pure-Sulfur Sandwich Structure for Ultrafast, Long-Life Lithium-Sulfur Batteries
journal, November 2013
- Zhou, Guangmin; Pei, Songfeng; Li, Lu
- Advanced Materials, Vol. 26, Issue 4
Challenges and Prospects of Lithium–Sulfur Batteries
journal, June 2012
- Manthiram, Arumugam; Fu, Yongzhu; Su, Yu-Sheng
- Accounts of Chemical Research, Vol. 46, Issue 5
Design of Complex Nanomaterials for Energy Storage: Past Success and Future Opportunity
journal, December 2017
- Liu, Yayuan; Zhou, Guangmin; Liu, Kai
- Accounts of Chemical Research, Vol. 50, Issue 12
Nitrogen-Doped Mesoporous Carbon Promoted Chemical Adsorption of Sulfur and Fabrication of High-Areal-Capacity Sulfur Cathode with Exceptional Cycling Stability for Lithium-Sulfur Batteries
journal, October 2013
- Song, Jiangxuan; Xu, Terrence; Gordin, Mikhail L.
- Advanced Functional Materials, Vol. 24, Issue 9
Graphene Oxide as a Sulfur Immobilizer in High Performance Lithium/Sulfur Cells
journal, November 2011
- Ji, Liwen; Rao, Mumin; Zheng, Haimei
- Journal of the American Chemical Society, Vol. 133, Issue 46, p. 18522-18525
Enhancing lithium–sulphur battery performance by strongly binding the discharge products on amino-functionalized reduced graphene oxide
journal, September 2014
- Wang, Zhiyu; Dong, Yanfeng; Li, Hongjiang
- Nature Communications, Vol. 5, Issue 1
High-Rate, Ultralong Cycle-Life Lithium/Sulfur Batteries Enabled by Nitrogen-Doped Graphene
journal, July 2014
- Qiu, Yongcai; Li, Wanfei; Zhao, Wen
- Nano Letters, Vol. 14, Issue 8
Graphene Sandwiched by Sulfur-Confined Mesoporous Carbon Nanosheets: A Kinetically Stable Cathode for Li–S Batteries
journal, November 2016
- Xin, Sen; You, Ya; Li, Hui-Qin
- ACS Applied Materials & Interfaces, Vol. 8, Issue 49
Stable cycling of lithium sulfide cathodes through strong affinity with a bifunctional binder
journal, January 2013
- Seh, Zhi Wei; Zhang, Qianfan; Li, Weiyang
- Chemical Science, Vol. 4, Issue 9
Understanding the Role of Different Conductive Polymers in Improving the Nanostructured Sulfur Cathode Performance
journal, October 2013
- Li, Weiyang; Zhang, Qianfan; Zheng, Guangyuan
- Nano Letters, Vol. 13, Issue 11
Facile synthesis of Li2S–polypyrrole composite structures for high-performance Li2S cathodes
journal, January 2014
- Seh, Zhi Wei; Wang, Haotian; Hsu, Po-Chun
- Energy & Environmental Science, Vol. 7, Issue 2
Improving the Performance of Lithium–Sulfur Batteries by Conductive Polymer Coating
journal, October 2011
- Yang, Yuan; Yu, Guihua; Cha, Judy J.
- ACS Nano, Vol. 5, Issue 11, p. 9187-9193
Strong Sulfur Binding with Conducting Magnéli-Phase Ti n O 2 n –1 Nanomaterials for Improving Lithium–Sulfur Batteries
journal, August 2014
- Tao, Xinyong; Wang, Jianguo; Ying, Zhuogao
- Nano Letters, Vol. 14, Issue 9
Surface-enhanced redox chemistry of polysulphides on a metallic and polar host for lithium-sulphur batteries
journal, August 2014
- Pang, Quan; Kundu, Dipan; Cuisinier, Marine
- Nature Communications, Vol. 5, Issue 1
Sulphur–TiO2 yolk–shell nanoarchitecture with internal void space for long-cycle lithium–sulphur batteries
journal, January 2013
- Wei Seh, Zhi; Li, Weiyang; Cha, Judy J.
- Nature Communications, Vol. 4, Article No. 1331
Catalytic oxidation of Li 2 S on the surface of metal sulfides for Li−S batteries
journal, January 2017
- Zhou, Guangmin; Tian, Hongzhen; Jin, Yang
- Proceedings of the National Academy of Sciences, Vol. 114, Issue 5
Two-dimensional layered transition metal disulphides for effective encapsulation of high-capacity lithium sulphide cathodes
journal, September 2014
- Seh, Zhi Wei; Yu, Jung Ho; Li, Weiyang
- Nature Communications, Vol. 5, Issue 1
Lithium–sulphur batteries with a microporous carbon paper as a bifunctional interlayer
journal, January 2012
- Su, Yu-Sheng; Manthiram, Arumugam
- Nature Communications, Vol. 3, Article No. 1166
Improved lithium–sulfur batteries with a conductive coating on the separator to prevent the accumulation of inactive S-related species at the cathode–separator interface
journal, January 2014
- Yao, Hongbin; Yan, Kai; Li, Weiyang
- Energy Environ. Sci., Vol. 7, Issue 10
A Two-Dimensional Porous Carbon-Modified Separator for High-Energy-Density Li-S Batteries
journal, February 2018
- Pei, Fei; Lin, Lele; Fu, Ang
- Joule, Vol. 2, Issue 2
Entrapment of Polysulfides by a Black-Phosphorus-Modified Separator for Lithium-Sulfur Batteries
journal, September 2016
- Sun, Jie; Sun, Yongming; Pasta, Mauro
- Advanced Materials, Vol. 28, Issue 44
Tungsten Disulfide Catalysts Supported on a Carbon Cloth Interlayer for High Performance Li-S Battery
journal, January 2017
- Park, Jungjin; Yu, Byeong-Chul; Park, Joong Sun
- Advanced Energy Materials, Vol. 7, Issue 11
Lightweight Reduced Graphene Oxide@MoS 2 Interlayer as Polysulfide Barrier for High-Performance Lithium–Sulfur Batteries
journal, January 2018
- Tan, Lei; Li, Xinhai; Wang, Zhixing
- ACS Applied Materials & Interfaces, Vol. 10, Issue 4
Emerging Opportunities for Two-Dimensional Materials in Lithium-Ion Batteries
journal, August 2017
- Chen, Kan-Sheng; Balla, Itamar; Luu, Norman S.
- ACS Energy Letters, Vol. 2, Issue 9
Lithium ion battery applications of molybdenum disulfide (MoS 2 ) nanocomposites
journal, January 2014
- Stephenson, Tyler; Li, Zhi; Olsen, Brian
- Energy Environ. Sci., Vol. 7, Issue 1
Transition Metal Dichalcogenide Atomic Layers for Lithium Polysulfides Electrocatalysis
journal, December 2016
- Babu, Ganguli; Masurkar, Nirul; Al Salem, Hesham
- Journal of the American Chemical Society, Vol. 139, Issue 1
Multi-Functional Layered WS 2 Nanosheets for Enhancing the Performance of Lithium-Sulfur Batteries
journal, October 2016
- Lei, Tianyu; Chen, Wei; Huang, Jianwen
- Advanced Energy Materials, Vol. 7, Issue 4
Transition Metal Dichalcogenides and Beyond: Synthesis, Properties, and Applications of Single- and Few-Layer Nanosheets
journal, December 2014
- Lv, Ruitao; Robinson, Joshua A.; Schaak, Raymond E.
- Accounts of Chemical Research, Vol. 48, Issue 1
Multiflake Thin Film Electronic Devices of Solution Processed 2D MoS 2 Enabled by Sonopolymer Assisted Exfoliation and Surface Modification
journal, October 2014
- Yu, Xiaoyun; Prévot, Mathieu S.; Sivula, Kevin
- Chemistry of Materials, Vol. 26, Issue 20
Liquid Exfoliation of Layered Materials
journal, June 2013
- Nicolosi, V.; Chhowalla, M.; Kanatzidis, M. G.
- Science, Vol. 340, Issue 6139, p. 1226419
Scalable production of large quantities of defect-free few-layer graphene by shear exfoliation in liquids
journal, April 2014
- Paton, Keith R.; Varrla, Eswaraiah; Backes, Claudia
- Nature Materials, Vol. 13, Issue 6
Hybrid Heterojunctions of Solution-Processed Semiconducting 2D Transition Metal Dichalcogenides
journal, February 2017
- Yu, Xiaoyun; Rahmanudin, Aiman; Jeanbourquin, Xavier A.
- ACS Energy Letters, Vol. 2, Issue 2
Self-assembled 2D WSe2 thin films for photoelectrochemical hydrogen production
journal, July 2015
- Yu, Xiaoyun; Prévot, Mathieu S.; Guijarro, Néstor
- Nature Communications, Vol. 6, Issue 1
Photogenerated Charge Harvesting and Recombination in Photocathodes of Solvent-Exfoliated WSe 2
journal, August 2017
- Yu, Xiaoyun; Sivula, Kevin
- Chemistry of Materials, Vol. 29, Issue 16
High Electrochemical Selectivity of Edge versus Terrace Sites in Two-Dimensional Layered MoS 2 Materials
journal, November 2014
- Wang, Haotian; Zhang, Qianfan; Yao, Hongbin
- Nano Letters, Vol. 14, Issue 12
Understanding the Anchoring Effect of Two-Dimensional Layered Materials for Lithium–Sulfur Batteries
journal, May 2015
- Zhang, Qianfan; Wang, Yapeng; Seh, Zhi Wei
- Nano Letters, Vol. 15, Issue 6
Lithium–Sulfur Batteries with the Lowest Self-Discharge and the Longest Shelf life
journal, April 2017
- Chung, Sheng-Heng; Manthiram, Arumugam
- ACS Energy Letters, Vol. 2, Issue 5
New insight into the discharge process of sulfur cathode by electrochemical impedance spectroscopy
journal, April 2009
- Yuan, Lixia; Qiu, Xinping; Chen, Liquan
- Journal of Power Sources, Vol. 189, Issue 1
Electrochemical impedance spectroscopy of a Li–S battery: Part 1. Influence of the electrode and electrolyte compositions on the impedance of symmetric cells
journal, August 2017
- Conder, Joanna; Villevieille, Claire; Trabesinger, Sigita
- Electrochimica Acta, Vol. 244
Works referencing / citing this record:
Decorating CoSe2 hollow nanospheres on reduced graphene oxide as advanced sulfur host material for performance enhanced lithium-sulfur batteries
journal, September 2019
- Chen, Liang; Yang, Weiwei; Liu, Jianguo
- Nano Research, Vol. 12, Issue 11
A review of biomass materials for advanced lithium–sulfur batteries
journal, January 2019
- Yuan, Huadong; Liu, Tiefeng; Liu, Yujing
- Chemical Science, Vol. 10, Issue 32
Sulfiphilic Few‐Layered MoSe 2 Nanoflakes Decorated rGO as a Highly Efficient Sulfur Host for Lithium‐Sulfur Batteries
journal, August 2019
- Tian, Wenzhi; Xi, Baojuan; Feng, Zhenyu
- Advanced Energy Materials, Vol. 9, Issue 36
An atomic-confined-space separator for high performance lithium–sulfur batteries
journal, January 2020
- Cui, Junya; Li, Zhenhua; Li, Jianbo
- Journal of Materials Chemistry A, Vol. 8, Issue 4
Two‐Dimensional Material‐Functionalized Separators for High‐Energy‐Density Metal–Sulfur and Metal‐Based Batteries
journal, March 2020
- Hu, Yuxiang; Zhu, Xiaobo; Wang, Lianzhou
- ChemSusChem, Vol. 13, Issue 6
A review of biomass materials for advanced lithium–sulfur batteries
journal, January 2019
- Yuan, Huadong; Liu, Tiefeng; Liu, Yujing
- Chemical Science, Vol. 10, Issue 32