Comparative study of bulk and nano-structured mesoporous SnO2 electrodes on the electrochemical performances for next generation Li rechargeable batteries
Abstract
For next generation Li-ion batteries, advanced electrode materials with high energy densities are mightily important issue. Since the partial oxidation of Sn with Li2O to form SnOx was demonstrated upon delithiation in SnO2 anode, the additional conversion reaction has contributed that the theoretical capacity of SnO2 can be extended from 783 to 1494 mAh g-1. Herein, with the design of additional conversion reaction, we discuss key factors for high electrochemical performances of the SnO2 anodes through comparative analysis between nano-structured mesoporous SnO2 and conventional bulk SnO2, based on synchrotron radiation-based techniques, quantitative analysis of extended X-ray absorption fine structure spectra, and bond strength calculation. In this way, we demonstrate that the mesoporous SnO2 has a nano-engineering structure, inducing the facilitated electrochemical reaction and the weak Sn-O bond strength that would have an advantage in the additional conversion reaction as well as a void structure, relieving the severe volume changes during lithiation/delithiation. Consequently, excellent electrochemical performance is obtained in the mesoporous SnO2. Furthermore, insight from this research enables important advance in the development of metal oxide-based anode materials by making irreversible reaction reversible, providing a realizable strategy for the design and creation of high-energy storage devices.
- Authors:
-
[1];
[3];
- Sungkyunkwan Univ., Suwon (South Korea); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
- Chungbuk National Univ., Cheongju (South Korea)
- Sungkyunkwan Univ., Suwon (South Korea)
- Argonne National Lab. (ANL), Argonne, IL (United States)
- Publication Date:
- Research Org.:
- Argonne National Lab. (ANL), Argonne, IL (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES); National Research Foundation of Korea (NRF)
- OSTI Identifier:
- 1491845
- Grant/Contract Number:
- AC02-06CH11357
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of Power Sources
- Additional Journal Information:
- Journal Volume: 413; Journal Issue: C; Journal ID: ISSN 0378-7753
- Publisher:
- Elsevier
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE; 36 MATERIALS SCIENCE; Li storage mechanism; SnO2 anodes; high electrochemical performance; metal oxide; nano-engineering
Citation Formats
Kim, Hyunchul, Yang, Dong -Seok, Um, Ji Hyun, Balasubramanian, Mahalingam, Yoo, Jaeseung, Kim, Hyunwoo, Park, Su Bin, Kim, Ji Man, and Yoon, Won -Sub. Comparative study of bulk and nano-structured mesoporous SnO2 electrodes on the electrochemical performances for next generation Li rechargeable batteries. United States: N. p., 2018.
Web. doi:10.1016/j.jpowsour.2018.12.035.
Kim, Hyunchul, Yang, Dong -Seok, Um, Ji Hyun, Balasubramanian, Mahalingam, Yoo, Jaeseung, Kim, Hyunwoo, Park, Su Bin, Kim, Ji Man, & Yoon, Won -Sub. Comparative study of bulk and nano-structured mesoporous SnO2 electrodes on the electrochemical performances for next generation Li rechargeable batteries. United States. https://doi.org/10.1016/j.jpowsour.2018.12.035
Kim, Hyunchul, Yang, Dong -Seok, Um, Ji Hyun, Balasubramanian, Mahalingam, Yoo, Jaeseung, Kim, Hyunwoo, Park, Su Bin, Kim, Ji Man, and Yoon, Won -Sub. Mon .
"Comparative study of bulk and nano-structured mesoporous SnO2 electrodes on the electrochemical performances for next generation Li rechargeable batteries". United States. https://doi.org/10.1016/j.jpowsour.2018.12.035. https://www.osti.gov/servlets/purl/1491845.
@article{osti_1491845,
title = {Comparative study of bulk and nano-structured mesoporous SnO2 electrodes on the electrochemical performances for next generation Li rechargeable batteries},
author = {Kim, Hyunchul and Yang, Dong -Seok and Um, Ji Hyun and Balasubramanian, Mahalingam and Yoo, Jaeseung and Kim, Hyunwoo and Park, Su Bin and Kim, Ji Man and Yoon, Won -Sub},
abstractNote = {For next generation Li-ion batteries, advanced electrode materials with high energy densities are mightily important issue. Since the partial oxidation of Sn with Li2O to form SnOx was demonstrated upon delithiation in SnO2 anode, the additional conversion reaction has contributed that the theoretical capacity of SnO2 can be extended from 783 to 1494 mAh g-1. Herein, with the design of additional conversion reaction, we discuss key factors for high electrochemical performances of the SnO2 anodes through comparative analysis between nano-structured mesoporous SnO2 and conventional bulk SnO2, based on synchrotron radiation-based techniques, quantitative analysis of extended X-ray absorption fine structure spectra, and bond strength calculation. In this way, we demonstrate that the mesoporous SnO2 has a nano-engineering structure, inducing the facilitated electrochemical reaction and the weak Sn-O bond strength that would have an advantage in the additional conversion reaction as well as a void structure, relieving the severe volume changes during lithiation/delithiation. Consequently, excellent electrochemical performance is obtained in the mesoporous SnO2. Furthermore, insight from this research enables important advance in the development of metal oxide-based anode materials by making irreversible reaction reversible, providing a realizable strategy for the design and creation of high-energy storage devices.},
doi = {10.1016/j.jpowsour.2018.12.035},
journal = {Journal of Power Sources},
number = C,
volume = 413,
place = {United States},
year = {Mon Dec 24 00:00:00 EST 2018},
month = {Mon Dec 24 00:00:00 EST 2018}
}
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Works referenced in this record:
The development of lithium ion secondary batteries
journal, January 2001
- Nishi, Yoshio
- The Chemical Record, Vol. 1, Issue 5
Issues and challenges facing rechargeable lithium batteries
journal, November 2001
- Tarascon, J.-M.; Armand, M.
- Nature, Vol. 414, Issue 6861, p. 359-367
Ordered, Nanostructured Tin-Based Oxides/Carbon Composite as the Negative-Electrode Material for Lithium-Ion Batteries
journal, August 2004
- Fan, J.; Wang, T.; Yu, C.
- Advanced Materials, Vol. 16, Issue 16
Manganese oxide nanoparticle-loaded porous carbon nanofibers as anode materials for high-performance lithium-ion batteries
journal, April 2009
- Ji, Liwen; Zhang, Xiangwu
- Electrochemistry Communications, Vol. 11, Issue 4
Intercalation of lithium into graphite and other carbons
journal, August 1975
- Guerard, D.; Herold, A.
- Carbon, Vol. 13, Issue 4
Lithium Batteries: A Practical Application of Chemical Principles
journal, September 2003
- Treptow, Richard S.
- Journal of Chemical Education, Vol. 80, Issue 9
Recent advances in lithium ion battery materials
journal, May 2000
- Scrosati, Bruno
- Electrochimica Acta, Vol. 45, Issue 15-16
Building better batteries
journal, February 2008
- Armand, M.; Tarascon, J.-M.
- Nature, Vol. 451, Issue 7179, p. 652-657
High-performance lithium battery anodes using silicon nanowires
journal, December 2007
- Chan, Candace K.; Peng, Hailin; Liu, Gao
- Nature Nanotechnology, Vol. 3, Issue 1, p. 31-35
In Situ Observation of the Electrochemical Lithiation of a Single SnO2 Nanowire Electrode
journal, December 2010
- Huang, J. Y.; Zhong, L.; Wang, C. M.
- Science, Vol. 330, Issue 6010, p. 1515-1520
Positive Electrode Materials for Li-Ion and Li-Batteries †
journal, February 2010
- Ellis, Brian L.; Lee, Kyu Tae; Nazar, Linda F.
- Chemistry of Materials, Vol. 22, Issue 3
Prospective materials and applications for Li secondary batteries
journal, January 2011
- Jeong, Goojin; Kim, Young-Ugk; Kim, Hansu
- Energy & Environmental Science, Vol. 4, Issue 6
Electrochemical Performance of M2GeO4(M = Co, Fe and Ni) as Anode Materials with High Capacity for Lithium-Ion Batteries
journal, December 2017
- Yuvaraj, Subramanian; Park, Myung-Soo; Kumar, Veerasubramani Ganesh
- Journal of Electrochemical Science and Technology, Vol. 8, Issue 4
A New Way to Prepare MoO3/C as Anode of Lithium ion Battery for Enhancing the Electrochemical Performance at Room Temperature
journal, June 2016
- Yu, Zhian; Jiang, Hongying; Gu, Dawei
- Journal of Electrochemical Science and Technology, Vol. 7, Issue 2
Cobalt Oxide Nanorods Prepared by a Template-Free Method for Lithium Battery Application
journal, September 2016
- Kim, Seong-Jun; Kim, Eun-Ji; Liu, Meilin
- Journal of Electrochemical Science and Technology, Vol. 7, Issue 3
Three-dimensional porous amorphous SnO2 thin films as anodes for Li-ion batteries
journal, December 2009
- Yu, Yan; Gu, Lin; Dhanabalan, Abirami
- Electrochimica Acta, Vol. 54, Issue 28, p. 7227-7230
Facile synthesis and superior anodic performance of ultrafine SnO2-containing nanocomposites
journal, October 2009
- Liu, Hongpeng; Long, Donghui; Liu, Xiaojun
- Electrochimica Acta, Vol. 54, Issue 24
The role of carbon incorporation in SnO2 nanoparticles for Li rechargeable batteries
journal, August 2012
- Nam, Seunghoon; Kim, Sungsoo; Wi, Sungun
- Journal of Power Sources, Vol. 211
Electrochemical and In Situ X-Ray Diffraction Studies of the Reaction of Lithium with Tin Oxide Composites
journal, January 1997
- Courtney, Ian A.; Dahn, J. R.
- Journal of The Electrochemical Society, Vol. 144, Issue 6, p. 2045-2052
Key Factors Controlling the Reversibility of the Reaction of Lithium with SnO2 and Sn2 BPO 6 Glass
journal, September 1997
- Courtney, Ian A.; Dahn, J. R.
- Journal of The Electrochemical Society, Vol. 144, Issue 9
Lithium alloy negative electrodes formed from convertible oxides
journal, December 1998
- Huggins, R.
- Solid State Ionics, Vol. 113-115, Issue 1-2
Preparation of SnO 2 /Carbon Composite Hollow Spheres and Their Lithium Storage Properties
journal, October 2008
- Lou, Xiong Wen; Deng, Da; Lee, Jim Yang
- Chemistry of Materials, Vol. 20, Issue 20
SnO2 nanosheet hollow spheres with improved lithium storage capabilities
journal, January 2011
- Ding, Shujiang; Wen (David) Lou, Xiong
- Nanoscale, Vol. 3, Issue 9
In Situ Transmission Electron Microscopy Observation of Microstructure and Phase Evolution in a SnO 2 Nanowire during Lithium Intercalation
journal, May 2011
- Wang, Chong-Min; Xu, Wu; Liu, Jun
- Nano Letters, Vol. 11, Issue 5
In Situ TEM Study of Lithiation Behavior of Silicon Nanoparticles Attached to and Embedded in a Carbon Matrix
journal, August 2012
- Gu, Meng; Li, Ying; Li, Xiaolin
- ACS Nano, Vol. 6, Issue 9
The state of understanding of the lithium-ion-battery graphite solid electrolyte interphase (SEI) and its relationship to formation cycling
journal, August 2016
- An, Seong Jin; Li, Jianlin; Daniel, Claus
- Carbon, Vol. 105
Ordered mesoporous SnO2 with a highly crystalline state as an anode material for lithium ion batteries with enhanced electrochemical performance
journal, January 2013
- Wang, Xuekun; Li, Zhaoqiang; Li, Qun
- CrystEngComm, Vol. 15, Issue 18
Electrochemical properties of SnO 2 nanorods as anode materials in lithium-ion battery
journal, September 2009
- Song-Lin, Shi; Yong-Gang, Liu; Jing-Yuan, Zhang
- Chinese Physics B, Vol. 18, Issue 10
Graphene Nanoribbon and Nanostructured SnO 2 Composite Anodes for Lithium Ion Batteries
journal, June 2013
- Lin, Jian; Peng, Zhiwei; Xiang, Changsheng
- ACS Nano, Vol. 7, Issue 7
New Insight into the Reaction Mechanism for Exceptional Capacity of Ordered Mesoporous SnO 2 Electrodes via Synchrotron-Based X-ray Analysis
journal, November 2014
- Kim, Hyunchul; Park, Gwi Ok; Kim, Yunok
- Chemistry of Materials, Vol. 26, Issue 22
119 Sn NMR probe of magnetic fluctuations in SnO 2 nanoparticles
journal, December 2011
- Dey, Tusharkanti; Khuntia, P.; Mahajan, A. V.
- EPL (Europhysics Letters), Vol. 96, Issue 6
On the Origin of the Extra Electrochemical Capacity Displayed by MO/Li Cells at Low Potential
journal, January 2002
- Laruelle, S.; Grugeon, S.; Poizot, P.
- Journal of The Electrochemical Society, Vol. 149, Issue 5, p. A627-A634
Synthesis, Characterization, and Li-Electrochemical Performance of Highly Porous Co 3 O 4 Powders
journal, June 2007
- Binotto, G.; Larcher, D.; Prakash, A. S.
- Chemistry of Materials, Vol. 19, Issue 12
TiO2-(B) Nanotubes as Anodes for Lithium Batteries: Origin and Mitigation of Irreversible Capacity
journal, January 2012
- Brutti, Sergio; Gentili, Valentina; Menard, Hervé
- Advanced Energy Materials, Vol. 2, Issue 3
Ordered mesoporous molecular sieves synthesized by a liquid-crystal template mechanism
journal, October 1992
- Kresge, C. T.; Leonowicz, M. E.; Roth, W. J.
- Nature, Vol. 359, Issue 6397, p. 710-712
Triblock Copolymer Syntheses of Mesoporous Silica with Periodic 50 to 300 Angstrom Pores
journal, January 1998
- Zhao, Dongyuan; Feng, Jianglin; Huo, Qisheng
- Science, Vol. 279, Issue 5350, p. 548-552
Ordered nanoporous arrays of carbon supporting high dispersions of platinum nanoparticles
journal, July 2001
- Joo, Sang Hoon; Choi, Seong Jae; Oh, Ilwhan
- Nature, Vol. 412, Issue 6843
Spontaneous Phase Separation Mediated Synthesis of 3D Mesoporous Carbon with Controllable Cage and Window Size
journal, April 2011
- Lee, Hyung Ik; Stucky, Galen D.; Kim, Jin Hoe
- Advanced Materials, Vol. 23, Issue 20
Inorganic materials for the negative electrode of lithium-ion batteries: state-of-the-art and future prospects
journal, February 2003
- Tirado, José L.
- Materials Science and Engineering: R: Reports, Vol. 40, Issue 3
In Situ Growth of Mesoporous SnO2 on Multiwalled Carbon Nanotubes: A Novel Composite with Porous-Tube Structure as Anode for Lithium Batteries
journal, October 2007
- Wen, Z.; Wang, Q.; Zhang, Q.
- Advanced Functional Materials, Vol. 17, Issue 15
Sodiation vs. lithiation phase transformations in a high rate – high stability SnO 2 in carbon nanocomposite
journal, January 2015
- Ding, Jia; Li, Zhi; Wang, Huanlei
- Journal of Materials Chemistry A, Vol. 3, Issue 13
XAFS investigations of tin nitrides
journal, March 2001
- Lützenkirchen-Hecht, Dirk; Scotti, Nicole; Jacobs, Herbert
- Journal of Synchrotron Radiation, Vol. 8, Issue 2
Probing the chemical state of tin oxide NP catalysts during CO2 electroreduction: A complementary operando approach
journal, November 2018
- Dutta, Abhijit; Kuzume, Akiyoshi; Kaliginedi, Veerabhadrarao
- Nano Energy, Vol. 53
Effects of alloying elements on the electronic structure and ductility of NiAl compounds investigated by X-ray absorption fine structure
journal, June 2013
- Tian, J. S.; Han, G. M.; Wei, H.
- Philosophical Magazine, Vol. 93, Issue 17
In Situ X-Ray Absorption and Diffraction Study of the Li Reaction with a Tin Composite Oxide Glass
journal, January 2000
- Mansour, A. N.; Mukerjee, S.; Yang, X. Q.
- Journal of The Electrochemical Society, Vol. 147, Issue 3
Darstellung und Struktur der Phase Li 7 Sn 3 / Preparation und Crystal Structure of Li 7 Sn 3
journal, June 1974
- Müller, Wiking
- Zeitschrift für Naturforschung B, Vol. 29, Issue 5-6
Die Struktur der Phase Li 5 Sn 2 / The Crystal Structure of Li 5 Sn 2
journal, February 1975
- Frank, Ursula; Müller, Wiking; Schäfer, Herbert
- Zeitschrift für Naturforschung B, Vol. 30, Issue 1-2
Darstellung und Struktur der Phase Li13Sn5 und die strukturelle Verwandtschaft der Phasen in den Systemen Li-Sn und Li-Pb / The Preparation and Crystal Structure of Li13Sn5 and the Structural Relations Between the Phases of the Systems Li-Sn and Li-Pb
journal, June 1975
- Frank, Ursula; Müller, Wiking
- Zeitschrift für Naturforschung B, Vol. 30, Issue 5-6
Die Kristallstruktur der Phase Li 7 Sn 2 / The Crystal Structure of Li 7 Sn 2
journal, February 1975
- Frank, Ursula; Müller, Wiking; Schäfer, Herbert
- Zeitschrift für Naturforschung B, Vol. 30, Issue 1-2
In situ XAS of the reaction mechanism of lithium with tin-based composite oxide glass
journal, May 1999
- Mansour, A. N.; Mukerjee, S.; Yang, X. Q.
- Journal of Synchrotron Radiation, Vol. 6, Issue 3
EXAFS study for slightly anharmonic vibrational system
journal, March 1998
- Yang, D. S.; Joo, S. K.
- Solid State Communications, Vol. 105, Issue 9
Temperature and polarization dependence of extended x-ray absorption fine-structure spectra
journal, August 1976
- Beni, G.; Platzman, P. M.
- Physical Review B, Vol. 14, Issue 4
New developments in NEXAFS/EXAFS theory
journal, March 1998
- Rehr, J. J.; Ankudinov, A.; Zabinsky, S. I.
- Catalysis Today, Vol. 39, Issue 4
Remarkable spreading behavior of molybdena on silica catalysts. Anin situ EXAFS-Raman study
journal, March 1991
- de Boer, M.; van Dillen, A. J.; Koningsberger, D. C.
- Catalysis Letters, Vol. 11, Issue 2
High Lithium Electroactivity of Nanometer-Sized Rutile TiO2
journal, June 2006
- Hu, Y.-S.; Kienle, L.; Guo, Y.-G.
- Advanced Materials, Vol. 18, Issue 11, p. 1421-1426
Research on Advanced Materials for Li-ion Batteries
journal, December 2009
- Li, Hong; Wang, Zhaoxiang; Chen, Liquan
- Advanced Materials, Vol. 21, Issue 45, p. 4593-4607
Synthesis and Electrode Performance of Nanostructured V 2 O 5 by Using a Carbon Tube-in-Tube as a Nanoreactor and an Efficient Mixed-Conducting Network
journal, November 2008
- Hu, Yong-Sheng; Liu, Xi; Müller, Jens-O.
- Angewandte Chemie International Edition, Vol. 48, Issue 1
Ultrahigh Capacity Due to Multi-Electron Conversion Reaction in Reduced Graphene Oxide-Wrapped MoO 2 Porous Nanobelts
journal, January 2015
- Tang, Wei; Peng, Cheng Xin; Nai, Chang Tai
- Small, Vol. 11, Issue 20
Oxygen Bridges between NiO Nanosheets and Graphene for Improvement of Lithium Storage
journal, March 2012
- Zhou, Guangmin; Wang, Da-Wei; Yin, Li-Chang
- ACS Nano, Vol. 6, Issue 4
XANES study of the support effect on the state of platinum catalysts
journal, May 1999
- Yoshida, H.; Yazawa, Y.; Takagi, N.
- Journal of Synchrotron Radiation, Vol. 6, Issue 3
Works referencing / citing this record:
Lattice Distortion in Hollow Multi‐Shelled Structures for Efficient Visible‐Light CO 2 Reduction with a SnS 2 /SnO 2 Junction
journal, November 2019
- You, Feifei; Wan, Jiawei; Qi, Jian
- Angewandte Chemie, Vol. 132, Issue 2
Lattice Distortion in Hollow Multi‐Shelled Structures for Efficient Visible‐Light CO 2 Reduction with a SnS 2 /SnO 2 Junction
journal, January 2020
- You, Feifei; Wan, Jiawei; Qi, Jian
- Angewandte Chemie International Edition, Vol. 59, Issue 2