High-Rate Performance and Ultralong Cycle Life Enabled by Hybrid Organic-Inorganic Vanadyl Ethylene Glycolate for Lithium-Ion Batteries
Abstract
Abstract Transition metal oxides (TMOs) possess high theoretical capacity and serve as promising anode candidates for lithium‐ion batteries. However, the intrinsic low conductivity handicaps the application of TMOs. Molecular modification by coupling TMOs structure with Li‐ion conductive polymer ligands can facilitate the kinetics of electrochemical lithiation/delithiation process. Herein, a proof‐of‐concept investigation on the Li‐ion storage capability by vanadyl ethylene glycolate (VEG) is achieved with the improvement of Li‐ion diffusion kinetics by modifiying the vanadium oxide with organic ligands. VEG demonstrates unprecedented advantage for fast rate capability, stable cycleability, and high capacity at both room temperarture (25 °C) and elevated temperature (60 °C).
- Authors:
-
- Chinese Academy of Sciences (CAS), Beijing (China)
- Argonne National Lab. (ANL), Lemont, IL (United States)
- Chinese Academy of Sciences (CAS), Beijing (China); Univ. of Chinese Academy of Sciences, Beijing (China)
- Publication Date:
- Research Org.:
- Argonne National Laboratory (ANL), Argonne, IL (United States)
- Sponsoring Org.:
- USDOE Office of Energy Efficiency and Renewable Energy (EERE)
- OSTI Identifier:
- 1489780
- Alternate Identifier(s):
- OSTI ID: 1479538
- Grant/Contract Number:
- AC02-06CH11357
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Advanced Energy Materials
- Additional Journal Information:
- Journal Volume: 8; Journal Issue: 33; Journal ID: ISSN 1614-6832
- Publisher:
- Wiley
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE; hybrid electrodes; lithium-ion batteries; rate performance; vanadyl ethylene glycolate
Citation Formats
Wang, Xinran, Bi, Xuanxuan, Zheng, Shili, Wang, Shaona, Zhang, Yi, Du, Hao, and Lu, Jun. High-Rate Performance and Ultralong Cycle Life Enabled by Hybrid Organic-Inorganic Vanadyl Ethylene Glycolate for Lithium-Ion Batteries. United States: N. p., 2018.
Web. doi:10.1002/aenm.201801978.
Wang, Xinran, Bi, Xuanxuan, Zheng, Shili, Wang, Shaona, Zhang, Yi, Du, Hao, & Lu, Jun. High-Rate Performance and Ultralong Cycle Life Enabled by Hybrid Organic-Inorganic Vanadyl Ethylene Glycolate for Lithium-Ion Batteries. United States. https://doi.org/10.1002/aenm.201801978
Wang, Xinran, Bi, Xuanxuan, Zheng, Shili, Wang, Shaona, Zhang, Yi, Du, Hao, and Lu, Jun. Mon .
"High-Rate Performance and Ultralong Cycle Life Enabled by Hybrid Organic-Inorganic Vanadyl Ethylene Glycolate for Lithium-Ion Batteries". United States. https://doi.org/10.1002/aenm.201801978. https://www.osti.gov/servlets/purl/1489780.
@article{osti_1489780,
title = {High-Rate Performance and Ultralong Cycle Life Enabled by Hybrid Organic-Inorganic Vanadyl Ethylene Glycolate for Lithium-Ion Batteries},
author = {Wang, Xinran and Bi, Xuanxuan and Zheng, Shili and Wang, Shaona and Zhang, Yi and Du, Hao and Lu, Jun},
abstractNote = {Abstract Transition metal oxides (TMOs) possess high theoretical capacity and serve as promising anode candidates for lithium‐ion batteries. However, the intrinsic low conductivity handicaps the application of TMOs. Molecular modification by coupling TMOs structure with Li‐ion conductive polymer ligands can facilitate the kinetics of electrochemical lithiation/delithiation process. Herein, a proof‐of‐concept investigation on the Li‐ion storage capability by vanadyl ethylene glycolate (VEG) is achieved with the improvement of Li‐ion diffusion kinetics by modifiying the vanadium oxide with organic ligands. VEG demonstrates unprecedented advantage for fast rate capability, stable cycleability, and high capacity at both room temperarture (25 °C) and elevated temperature (60 °C).},
doi = {10.1002/aenm.201801978},
journal = {Advanced Energy Materials},
number = 33,
volume = 8,
place = {United States},
year = {Mon Oct 08 00:00:00 EDT 2018},
month = {Mon Oct 08 00:00:00 EDT 2018}
}
Web of Science
Figures / Tables:
Works referenced in this record:
In situ FTIR spectroscopic studies of ethylene glycol electrooxidation on Pd electrode in alkaline solution: The effects of concentration
journal, January 2013
- Lin, Jian-Long; Ren, Jie; Tian, Na
- Journal of Electroanalytical Chemistry, Vol. 688
Nanophase ZnCo2O4 as a High Performance Anode Material for Li-Ion Batteries
journal, October 2007
- Sharma, Y.; Sharma, N.; Subba Rao, G. V.
- Advanced Functional Materials, Vol. 17, Issue 15
Ti-based compounds as anode materials for Li-ion batteries
journal, January 2012
- Zhu, Guan-Nan; Wang, Yong-Gang; Xia, Yong-Yao
- Energy & Environmental Science, Vol. 5, Issue 5
Additive-free synthesis of V 4 O 7 hierarchical structures as high performance cathodes for lithium ion batteries
journal, January 2014
- Wang, Xinran; Zheng, Shili; Mu, Xuechao
- Chem. Commun., Vol. 50, Issue 51
Issues and challenges facing rechargeable lithium batteries
journal, November 2001
- Tarascon, J.-M.; Armand, M.
- Nature, Vol. 414, Issue 6861, p. 359-367
Review on gel polymer electrolytes for lithium batteries
journal, January 2006
- Manuel Stephan, A.
- European Polymer Journal, Vol. 42, Issue 1
Carbon-Encapsulated Hollow Porous Vanadium-Oxide Nanofibers for Improved Lithium Storage Properties
journal, July 2016
- An, Geon-Hyoung; Lee, Do-Young; Ahn, Hyo-Jin
- ACS Applied Materials & Interfaces, Vol. 8, Issue 30
General synthesis of vanadium-based mixed metal oxides hollow nanofibers for high performance lithium-ion batteries
journal, October 2016
- Xiang, Juan; Yu, Xin-Yao; Paik, Ungyu
- Journal of Power Sources, Vol. 329
Ultrahigh-Capacity Organic Anode with High-Rate Capability and Long Cycle Life for Lithium-Ion Batteries
journal, August 2017
- Wang, Yan; Deng, Yonghong; Qu, Qunting
- ACS Energy Letters, Vol. 2, Issue 9
Nanosheet-Constructed Porous TiO2-B for Advanced Lithium Ion Batteries
journal, May 2012
- Liu, Shaohua; Jia, Haiping; Han, Lu
- Advanced Materials, Vol. 24, Issue 24
Carbon Coated Fe 3 O 4 Nanospindles as a Superior Anode Material for Lithium-Ion Batteries
journal, December 2008
- Zhang, Wei-Ming; Wu, Xing-Long; Hu, Jin-Song
- Advanced Functional Materials, Vol. 18, Issue 24
Polymer-pyrolysis assisted synthesis of vanadium trioxide and carbon nanocomposites as high performance anode materials for lithium-ion batteries
journal, September 2014
- Dong, Yucheng; Ma, Ruguang; Hu, Mingjun
- Journal of Power Sources, Vol. 261
VO 2 /rGO nanorods as a potential anode for sodium- and lithium-ion batteries
journal, January 2015
- He, Guang; Li, Longjun; Manthiram, Arumugam
- Journal of Materials Chemistry A, Vol. 3, Issue 28
Ultra-High Capacity Lithium-Ion Batteries with Hierarchical CoO Nanowire Clusters as Binder Free Electrodes
journal, January 2015
- Cao, Kangzhe; Jiao, Lifang; Liu, Yongchang
- Advanced Functional Materials, Vol. 25, Issue 7
Review of gel-type polymer electrolytes for lithium-ion batteries
journal, February 1999
- Song, J. Y.; Wang, Y. Y.; Wan, C. C.
- Journal of Power Sources, Vol. 77, Issue 2, p. 183-197
In situ preparation of poly(ethylene oxide)–SiO2 composite polymer electrolytes
journal, April 2004
- Liu, Y.; Lee, J. Y.; Hong, L.
- Journal of Power Sources, Vol. 129, Issue 2
Single-crystal H 2 V 3 O 8 nanowires: a competitive anode with large capacity for aqueous lithium-ion batteries
journal, January 2011
- Li, Huiqiao; Zhai, Tianyou; He, Ping
- J. Mater. Chem., Vol. 21, Issue 6
Hydrothermal Synthesis of Nanostructured Vanadium Oxides
journal, August 2010
- Livage, Jacques
- Materials, Vol. 3, Issue 8
Li-ion battery materials: present and future
journal, June 2015
- Nitta, Naoki; Wu, Feixiang; Lee, Jung Tae
- Materials Today, Vol. 18, Issue 5
Composites of V2O3–ordered mesoporous carbon as anode materials for lithium-ion batteries
journal, October 2013
- Zeng, Lingxing; Zheng, Cheng; Xi, Jingchao
- Carbon, Vol. 62
An interlaced silver vanadium oxide–graphene hybrid with high structural stability for use in lithium ion batteries
journal, January 2014
- Qin, Jiwen; Lv, Wei; Li, Zhengjie
- Chem. Commun., Vol. 50, Issue 88
Amorphous Vanadium Oxide Matrixes Supporting Hierarchical Porous Fe 3 O 4 /Graphene Nanowires as a High-Rate Lithium Storage Anode
journal, October 2014
- An, Qinyou; Lv, Fan; Liu, Qiuqi
- Nano Letters, Vol. 14, Issue 11
Self-Assembled Vanadium Pentoxide (V2O5) Hollow Microspheres from Nanorods and Their Application in Lithium-Ion Batteries
journal, July 2005
- Cao, An-Min; Hu, Jin-Song; Liang, Han-Pu
- Angewandte Chemie International Edition, Vol. 44, Issue 28
Synthesis of CuO/graphene nanocomposite as a high-performance anode material for lithium-ion batteries
journal, January 2010
- Wang, Bao; Wu, Xing-Long; Shu, Chun-Ying
- Journal of Materials Chemistry, Vol. 20, Issue 47
Nano-sized transition-metal oxides as negative-electrode materials for lithium-ion batteries
journal, September 2000
- Poizot, P.; Laruelle, S.; Grugeon, S.
- Nature, Vol. 407, Issue 6803, p. 496-499
V 2 O 5 -Anchored Carbon Nanotubes for Enhanced Electrochemical Energy Storage
journal, October 2011
- Sathiya, M.; Prakash, A. S.; Ramesha, K.
- Journal of the American Chemical Society, Vol. 133, Issue 40
Homologous V 2 O 3 /C box-in-box and V 2 O 5 box for lithium-ion full cells
journal, January 2016
- Liu, Xue; Hu, Yanjie; Jia, Guiqi
- Journal of Materials Chemistry A, Vol. 4, Issue 31
Polyol-Mediated Solvothermal Synthesis and Electrochemical Performance of Nanostructured V 2 O 5 Hollow Microspheres
journal, January 2013
- Uchaker, Evan; Zhou, Nan; Li, Yanwei
- The Journal of Physical Chemistry C, Vol. 117, Issue 4
Nanoparticles Encapsulated in Porous Carbon Matrix Coated on Carbon Fibers: An Ultrastable Cathode for Li-Ion Batteries
journal, October 2016
- Zou, Rujia; Liu, Qian; He, Guanjie
- Advanced Energy Materials, Vol. 7, Issue 2
Interaction of [V IV O(acac) 2 ] with Human Serum Transferrin and Albumin
journal, July 2017
- Correia, Isabel; Chorna, Ielyzaveta; Cavaco, Isabel
- Chemistry - An Asian Journal, Vol. 12, Issue 16
Determination of the V2p XPS binding energies for different vanadium oxidation states (V5+ to V0+)
journal, April 2004
- Silversmit, Geert; Depla, Diederik; Poelman, Hilde
- Journal of Electron Spectroscopy and Related Phenomena, Vol. 135, Issue 2-3
Beyond Intercalation-Based Li-Ion Batteries: The State of the Art and Challenges of Electrode Materials Reacting Through Conversion Reactions
journal, August 2010
- Cabana, Jordi; Monconduit, Laure; Larcher, Dominique
- Advanced Materials, Vol. 22, Issue 35
Mechanical Force-Driven Growth of Elongated Bending TiO 2 -based Nanotubular Materials for Ultrafast Rechargeable Lithium Ion Batteries
journal, July 2014
- Tang, Yuxin; Zhang, Yanyan; Deng, Jiyang
- Advanced Materials, Vol. 26, Issue 35
1D nanostructured sodium vanadium oxide as a novel anode material for aqueous sodium ion batteries
journal, March 2014
- Deng, C.; Zhang, S.; Dong, Z.
- Nano Energy, Vol. 4
Self-anchoring dendritic ternary vanadate compound on graphene nanoflake as high-performance conversion-type anode for lithium ion batteries
journal, April 2016
- Wang, Xinran; Zheng, Shili; Wang, Shaona
- Nano Energy, Vol. 22
Recent Advances in Metal Oxide-based Electrode Architecture Design for Electrochemical Energy Storage
journal, August 2012
- Jiang, Jian; Li, Yuanyuan; Liu, Jinping
- Advanced Materials, Vol. 24, Issue 38
Hierarchical Porous Intercalation-Type V 2 O 3 as High-Performance Anode Materials for Li-Ion Batteries
journal, May 2017
- Liu, Pengcheng; Zhu, Kongjun; Xu, Yuan
- Chemistry - A European Journal, Vol. 23, Issue 31
Carbon materials for lithium-ion rechargeable batteries
journal, February 1999
- Flandrois, S.; Simon, B.
- Carbon, Vol. 37, Issue 2
Ternary Self-Assembly of Ordered Metal Oxide−Graphene Nanocomposites for Electrochemical Energy Storage
journal, March 2010
- Wang, Donghai; Kou, Rong; Choi, Daiwon
- ACS Nano, Vol. 4, Issue 3, p. 1587-1595
Phase change effect on the structural and electrochemical behaviour of pure and doped vanadium pentoxide as positive electrodes for lithium ion batteries
journal, June 2017
- Armer, Ceilidh F.; Lübke, Mechthild; Reddy, M. V.
- Journal of Power Sources, Vol. 353
Carbon Nanotube-CoF 2 Multifunctional Cathode for Lithium Ion Batteries: Effect of Electrolyte on Cycle Stability
journal, July 2015
- Wang, Xinran; Gu, Wentian; Lee, Jung Tae
- Small, Vol. 11, Issue 38
Liquid phase hydroxylation of benzene to phenol over vanadyl acetylacetonate supported on amine functionalized SBA-15
journal, June 2015
- Bao, Yaohui; Jiang, Hong; Xing, Weihong
- Reaction Kinetics, Mechanisms and Catalysis, Vol. 116, Issue 2
The Chemistry and Biochemistry of Vanadium and the Biological Activities Exerted by Vanadium Compounds
journal, February 2004
- Crans, Debbie C.; Smee, Jason J.; Gaidamauskas, Ernestas
- Chemical Reviews, Vol. 104, Issue 2
Three-dimensional VS4/graphene hierarchical architecture as high-capacity anode for lithium-ion batteries
journal, November 2016
- Li, Qian; Chen, Yuanfu; He, Jiarui
- Journal of Alloys and Compounds, Vol. 685
Building better batteries
journal, February 2008
- Armand, M.; Tarascon, J.-M.
- Nature, Vol. 451, Issue 7179, p. 652-657
Electrospun Ultralong Hierarchical Vanadium Oxide Nanowires with High Performance for Lithium Ion Batteries
journal, November 2010
- Mai, Liqiang; Xu, Lin; Han, Chunhua
- Nano Letters, Vol. 10, Issue 11
Multi-shelled metal oxides prepared via an anion-adsorption mechanism for lithium-ion batteries
journal, April 2016
- Wang, Jiangyan; Tang, Hongjie; Zhang, Lijuan
- Nature Energy, Vol. 1, Issue 5
Smart construction of three-dimensional hierarchical tubular transition metal oxide core/shell heterostructures with high-capacity and long-cycle-life lithium storage
journal, March 2015
- Wang, Jiexi; Zhang, Qiaobao; Li, Xinhai
- Nano Energy, Vol. 12
Hollow Porous VO x /C Nanoscrolls as High-Performance Anodes for Lithium-Ion Batteries
journal, September 2016
- Jia, Bao-Rui; Qin, Ming-Li; Zhang, Zi-Li
- ACS Applied Materials & Interfaces, Vol. 8, Issue 39
Facile synthesis of metal oxide/reduced graphene oxide hybrids with high lithium storage capacity and stable cyclability
journal, January 2011
- Zhu, Jixin; Zhu, Ting; Zhou, Xiaozhu
- Nanoscale, Vol. 3, Issue 3
Synthesis and Lithium Storage Properties of Co3O4 Nanosheet-Assembled Multishelled Hollow Spheres
journal, May 2010
- Wang, Xi; Wu, Xing-Long; Guo, Yu-Guo
- Advanced Functional Materials, Vol. 20, Issue 10
The effect of plasticizers on transport and electrochemical properties of PEO-based electrolytes for lithium rechargeable batteries
journal, July 2002
- Kim, Y.
- Solid State Ionics, Vol. 149, Issue 1-2
Nanostructured Vanadium Oxide Electrodes for Enhanced Lithium-Ion Intercalation
journal, June 2006
- Wang, Y.; Takahashi, K.; Lee, K. H.
- Advanced Functional Materials, Vol. 16, Issue 9, p. 1133-1144
Design of vanadium oxide core–shell nanoplatelets for lithium ion storage
journal, January 2015
- Cheng, Wei; Zeng, Guobo; Niederberger, Markus
- Journal of Materials Chemistry A, Vol. 3, Issue 6
Metal Fluorides Nanoconfined in Carbon Nanopores as Reversible High Capacity Cathodes for Li and Li-Ion Rechargeable Batteries: FeF 2 as an Example
journal, February 2015
- Gu, Wentian; Magasinski, Alexandre; Zdyrko, Bogdan
- Advanced Energy Materials, Vol. 5, Issue 4
Nanostructured metal oxide-based materials as advanced anodes for lithium-ion batteries
journal, January 2012
- Wu, Hao Bin; Chen, Jun Song; Hng, Huey Hoon
- Nanoscale, Vol. 4, Issue 8, p. 2526-2542
In Situ Transmission Electron Microscopy Observation of the Conversion Mechanism of Fe 2 O 3 /Graphene Anode during Lithiation–Delithiation Processes
journal, September 2013
- Su, Qingmei; Xie, Dong; Zhang, Jun
- ACS Nano, Vol. 7, Issue 10
Amorphous vanadium oxide coating on graphene by atomic layer deposition for stable high energy lithium ion anodes
journal, January 2014
- Sun, Xiang; Zhou, Changgong; Xie, Ming
- Chemical Communications, Vol. 50, Issue 73
Hierarchical orthorhombic V2O5 hollow nanospheres as high performance cathode materials for sodium-ion batteries
journal, January 2014
- Su, D. W.; Dou, S. X.; Wang, G. X.
- Journal of Materials Chemistry A, Vol. 2, Issue 29
Self-Assembled Vanadium Pentoxide (V2O5) Hollow Microspheres from Nanorods and Their Application in Lithium-Ion Batteries
journal, July 2005
- Cao, An-Min; Hu, Jin-Song; Liang, Han-Pu
- Angewandte Chemie, Vol. 117, Issue 28
The Chemistry and Biochemistry of Vanadium and the Biological Activities Exerted by Vanadium Compounds
journal, May 2004
- Crans, Debbie C.; Smee, Jason J.; Gaidamauskas, Ernestas
- ChemInform, Vol. 35, Issue 20
Self-Assembled Vanadium Pentoxide (V2O5) Hollow Microspheres from Nanorods and Their Application in Lithium-Ion Batteries.
journal, October 2005
- Cao, An-Min; Hu, Jin-Song; Liang, Han-Pu
- ChemInform, Vol. 36, Issue 41
Works referencing / citing this record:
Electrode Engineering by Atomic Layer Deposition for Sodium‐Ion Batteries: From Traditional to Advanced Batteries
journal, December 2019
- Yu, Fan; Du, Lei; Zhang, Gaixia
- Advanced Functional Materials, Vol. 30, Issue 9
Figures / Tables found in this record: