Ultra-Stable and High-Cobalt-Loaded Cobalt@Ordered Mesoporous Carbon Catalysts: All-in-One Deoxygenation of Ketone into Alkylbenzene
Abstract
Catalytic deoxygenation represents a straightforward and core methodology for fine-chemical production and biomass upgrading. Generally, the application of homogeneous metal complexes or heterogeneous noble-metal catalysts prevails in academia and the chemical industry. We introduce cobalt@ordered mesoporous carbon (Co@OMC) catalysts, which are constructed conveniently by a mechanochemical coordination self-assembly based on a renewable tannin precursor. Importantly, the Co@OMC catalysts with a high loading of in situ confined Co species promote the selective deoxygenation of various ketones, aldehydes, and alcohols efficiently into the corresponding alkanes under mild conditions. Therefore, a simple, inexpensive, and heterogeneous catalyst for selective deoxygenation can be expected, meanwhile the solid-state synthesis affords a green, rapid, and scalable pathway to Co@OMC catalysts.
- Authors:
-
[1];
- Shanghai Jiao Tong Univ. (China). School of Chemistry and Chemical Engineering; Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Univ. of Tennessee, Knoxville, TN (United States). Dept. of Chemistry
- Shanghai Jiao Tong Univ. (China). School of Chemistry and Chemical Engineering
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); East China Univ. of Science and Technology, Shanghai (China). Inst. of Industrial Catalysis
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Univ. of Tennessee, Knoxville, TN (United States). Dept. of Chemistry
- Publication Date:
- Research Org.:
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Univ. of Tennessee, Knoxville, TN (United States); Shanghai Jiao Tong Univ. (China)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES); Shanghai Pujiang Program (China); National Natural Science Foundation of China (NSFC); Thousand Talent Program of China
- OSTI Identifier:
- 1479713
- Grant/Contract Number:
- AC05-00OR22725; 17PJ1403500; 21776174
- Resource Type:
- Accepted Manuscript
- Journal Name:
- ChemCatChem
- Additional Journal Information:
- Journal Volume: 10; Journal Issue: 15; Journal ID: ISSN 1867-3880
- Publisher:
- ChemPubSoc Europe
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; cobalt; heterogeneous catalysis; hydrogenation; nanoparticles; mesoporous materials
Citation Formats
Zhang, Pengfei, Chen, Nanqing, Chen, Dong, Yang, Shize, Liu, Xiaofei, Wang, Li, Wu, Peiwen, Phillip, Nathan, Yang, Guang, and Dai, Sheng. Ultra-Stable and High-Cobalt-Loaded Cobalt@Ordered Mesoporous Carbon Catalysts: All-in-One Deoxygenation of Ketone into Alkylbenzene. United States: N. p., 2018.
Web. doi:10.1002/cctc.201800358.
Zhang, Pengfei, Chen, Nanqing, Chen, Dong, Yang, Shize, Liu, Xiaofei, Wang, Li, Wu, Peiwen, Phillip, Nathan, Yang, Guang, & Dai, Sheng. Ultra-Stable and High-Cobalt-Loaded Cobalt@Ordered Mesoporous Carbon Catalysts: All-in-One Deoxygenation of Ketone into Alkylbenzene. United States. https://doi.org/10.1002/cctc.201800358
Zhang, Pengfei, Chen, Nanqing, Chen, Dong, Yang, Shize, Liu, Xiaofei, Wang, Li, Wu, Peiwen, Phillip, Nathan, Yang, Guang, and Dai, Sheng. Mon .
"Ultra-Stable and High-Cobalt-Loaded Cobalt@Ordered Mesoporous Carbon Catalysts: All-in-One Deoxygenation of Ketone into Alkylbenzene". United States. https://doi.org/10.1002/cctc.201800358. https://www.osti.gov/servlets/purl/1479713.
@article{osti_1479713,
title = {Ultra-Stable and High-Cobalt-Loaded Cobalt@Ordered Mesoporous Carbon Catalysts: All-in-One Deoxygenation of Ketone into Alkylbenzene},
author = {Zhang, Pengfei and Chen, Nanqing and Chen, Dong and Yang, Shize and Liu, Xiaofei and Wang, Li and Wu, Peiwen and Phillip, Nathan and Yang, Guang and Dai, Sheng},
abstractNote = {Catalytic deoxygenation represents a straightforward and core methodology for fine-chemical production and biomass upgrading. Generally, the application of homogeneous metal complexes or heterogeneous noble-metal catalysts prevails in academia and the chemical industry. We introduce cobalt@ordered mesoporous carbon (Co@OMC) catalysts, which are constructed conveniently by a mechanochemical coordination self-assembly based on a renewable tannin precursor. Importantly, the Co@OMC catalysts with a high loading of in situ confined Co species promote the selective deoxygenation of various ketones, aldehydes, and alcohols efficiently into the corresponding alkanes under mild conditions. Therefore, a simple, inexpensive, and heterogeneous catalyst for selective deoxygenation can be expected, meanwhile the solid-state synthesis affords a green, rapid, and scalable pathway to Co@OMC catalysts.},
doi = {10.1002/cctc.201800358},
journal = {ChemCatChem},
number = 15,
volume = 10,
place = {United States},
year = {Mon Apr 23 00:00:00 EDT 2018},
month = {Mon Apr 23 00:00:00 EDT 2018}
}
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